A method for the analysis of trace polycyclic aromatic hydrocarbons（PAHs） in aqueous samples has been established by polydimethylsiloxane（PDMS） rod aided stir bar sorptive extraction（SBSE）. The homemade PDMS rod...A method for the analysis of trace polycyclic aromatic hydrocarbons（PAHs） in aqueous samples has been established by polydimethylsiloxane（PDMS） rod aided stir bar sorptive extraction（SBSE）. The homemade PDMS rod has a size of 30 mm×3 mm o.d. with a volume of ca. 200 μL, stable in thermal desorption process. The enriched PAHs by the PDMS rod were released in a homemade thermal desorption system coupled with gas chromatography. Experimental parameters for extraction of six PAHs were optimized including extraction time, pH, ionic strength and temperature of solution. The procedure has good recoveries of 80.0%―100.3% and very low limits of detection of 4.0―33 ng/L. PAHs in rain and river water were analyzed by this method.展开更多
Marine biofouling seriously affects human marine exploitation and transportation activities,to which marine antifouling(AF)coatings are considered to be the most cost-effective solution.Since the mid-20th century,huma...Marine biofouling seriously affects human marine exploitation and transportation activities,to which marine antifouling(AF)coatings are considered to be the most cost-effective solution.Since the mid-20th century,human beings have dedicated their efforts on developing AF coatings with long cycle and high performance,leading to a large number of non-target organisms?distortion,death and marine environmental pollution.Polydimethylsiloxane(PDMS),is considered as one of the representative environment-friendly AF materials thanks to its non-toxic,hydrophobic,low surface energy and AF properties.However,PDMS AF coatings are prone to mechanical damage,weak adhesion strength to substrate,and poor static AF effect,which seriously restrict their use in the ocean.The rapid development of various nanomaterials provides an opportunity to enhance and improve the mechanical properties and antifouling properties of PDMS coating by embedding nanomaterials.Based on our research background and the problems faced in our laboratory,this article presents an overview of the current progress in the fields of PDMS composite coatings enhanced by different nanomaterials,with the discussion focused on the advantages and main bottlenecks currently encountered in this field.Finally,we propose an outlook,hoping to provide fundamental guidance for the development of marine AF field.展开更多
基金Supported by the Natural Science Foundation of Shandong Province, China(No.ZR2010BM035)
文摘A method for the analysis of trace polycyclic aromatic hydrocarbons（PAHs） in aqueous samples has been established by polydimethylsiloxane（PDMS） rod aided stir bar sorptive extraction（SBSE）. The homemade PDMS rod has a size of 30 mm×3 mm o.d. with a volume of ca. 200 μL, stable in thermal desorption process. The enriched PAHs by the PDMS rod were released in a homemade thermal desorption system coupled with gas chromatography. Experimental parameters for extraction of six PAHs were optimized including extraction time, pH, ionic strength and temperature of solution. The procedure has good recoveries of 80.0%―100.3% and very low limits of detection of 4.0―33 ng/L. PAHs in rain and river water were analyzed by this method.
基金financially supported by National Natural Science Foundation of China(Grant No.52073071,51803041)Natural Science Funding for Excellent Young Scholar of Heilongjiang Province(YQ2022E021,L.Wang)+2 种基金the Fundamental Research Funds for the Central Universities(HIT.DZJJ.2023056)the Research Fund of State Key Laboratory for Marine Corrosion and Protection of Luoyang Ship Material Research Institute(No.JS220407)the financial support from the Spanish Ministry of Economy and the Canary Islands program Vieray Clavijo Senior(Ref.2023/00001156)。
文摘Marine biofouling seriously affects human marine exploitation and transportation activities,to which marine antifouling(AF)coatings are considered to be the most cost-effective solution.Since the mid-20th century,human beings have dedicated their efforts on developing AF coatings with long cycle and high performance,leading to a large number of non-target organisms?distortion,death and marine environmental pollution.Polydimethylsiloxane(PDMS),is considered as one of the representative environment-friendly AF materials thanks to its non-toxic,hydrophobic,low surface energy and AF properties.However,PDMS AF coatings are prone to mechanical damage,weak adhesion strength to substrate,and poor static AF effect,which seriously restrict their use in the ocean.The rapid development of various nanomaterials provides an opportunity to enhance and improve the mechanical properties and antifouling properties of PDMS coating by embedding nanomaterials.Based on our research background and the problems faced in our laboratory,this article presents an overview of the current progress in the fields of PDMS composite coatings enhanced by different nanomaterials,with the discussion focused on the advantages and main bottlenecks currently encountered in this field.Finally,we propose an outlook,hoping to provide fundamental guidance for the development of marine AF field.
