Porous heterostructure of graphene/hexagonal boron nitride as an efficient electrocatalyst for hydrogen peroxide generation

Compared with the traditional heteroatom doping,employing heterostructure is a new modulating approach for carbon-based electrocatalysts.Herein,a facile ball milling-assisted route is proposed to synthesize porous carbon materials composed of abundant graphene/hexagonal boron nitride(G/h-BN)heterostructures.Metal Ni powder and nanoscale h-BN sheets are used as a catalytic substrate/hard template and“nucleation seed”for the formation of the heterostructure,respectively.As-prepared G/h-BN heterostructures exhibit enhanced electrocatalytic activity toward H_(2)O_(2) generation with 86%-95%selectivity at the range of 0.45-0.75 V versus reversible hydrogen electrode(RHE)and a positive onset potential of 0.79 versus RHE(defined at a ring current density of 0.3 mA cm^(-2))in the alkaline solution.In a flow cell,G/h-BN heterostructured electrocatalyst has a H_(2)O_(2) production rate of up to 762 mmol g_(catalyst)^(-1) h^(-1) and Faradaic efficiency of over 75%during 12 h testing,superior to the reported carbon-based electrocatalysts.The density functional theory simulation suggests that the B atoms at the interface of the G/h-BN heterostructure are the key active sites.This research provides a new route to activate carbon catalysts toward highly active and selective O_(2)-to-H_(2)O_(2) conversion.

High-Throughput Growth of Hexagonal Boron Nitride Film Using Porous-Structure Isolation Layer

Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. .

Dynamic behavior of outburst two-phase flow in a coal mine T-shaped roadway:The formation of impact airflow and its disaster-causing effect

The study of the dynamic disaster mechanism of coal and gas outburst two-phase flow is crucial for improving disaster reduction and rescue ability of coal mine outburst accidents.An outburst test in a T-shaped roadway was conducted using a self-developed large-scale outburst dynamic disaster test system.We investigated the release characteristics of main energy sources in coal seam,and obtained the dynamic characteristics of outburst two-phase flow in a roadway.Additionally,we established a formation model for outburst impact flow and a model for its flow in a bifurcated structure.The results indicate that the outburst process exhibits pulse characteristics,and the rapid destruction process of coal seam and the blocking state of gas flow are the main causes of the pulse phenomenon.The outburst energy is released in stages,and the elastic potential energy is released in the vertical direction before the horizontal direction.In a straight roadway,the impact force oscillates along the roadway.With an increase in the solid–gas ratio,the two-phase flow impact force gradually increases,and the disaster range extends from the middle of the roadway to the coal seam.In the area near the coal seam,the disaster caused by the two-phase flow impact is characterized by intermittent recovery.In a bifurcated roadway,the effect of impact airflow on impact dynamic disaster is much higher than that of two-phase flow,and the impact force tends to weaken with increasing solid-gas ratio.The impact force is asymmetrically distributed;it is higher on the left of the bifurcated roadway.With an increase in the solid-gas ratio,the static pressure rapidly decreases,and the bifurcated structure accelerates the attenuation of static pressure.Moreover,secondary acceleration is observed when the shock wave moves along the T-shaped roadway,indicating that the bifurcated structure increases the shock wave velocity.

Thermal-induced interfacial behavior of a thin one-dimensional hexagonal quasicrystal film

In this paper,we investigate the interfacial behavior of a thin one-dimensional(1D)hexagonal quasicrystal(QC)film bonded on an elastic substrate subjected to a mismatch strain due to thermal variation.The contact interface is assumed to be nonslipping,with both perfectly bonded and debonded boundary conditions.The Fourier transform technique is adopted to establish the integral equations in terms of interfacial shear stress,which are solved as a linear algebraic system by approximating the unknown phonon interfacial shear stress via the series expansion of the Chebyshev polynomials.The expressions are explicitly obtained for the phonon interfacial shear stress,internal normal stress,and stress intensity factors(SIFs).Finally,based on numerical calculations,we briefly discuss the effects of the material mismatch,the geometry of the QC film,and the debonded length and location on stresses and SIFs.

Elastic Field of a Straight Dislocation in One-Dimensional Hexagonal Quasicrystals

目的研究准晶中的位错弹性理论．方法通过将位错分解为刃型和螺型分量，该位错引起的整个弹性场可由两个分量所引起的弹性场叠加得到．结果与结论获得了平行于准周期轴的直位错的弹性场及两个平行的直螺型位错之间的广义ＰｅａｃｈＫｏｅｈｌｅｒ力。

Simulation on damage effectiveness of hexagonal prism aimable warhead with multi-point synchronous initiations

In order to study the impacts of warhead geometry and initiation pattern on the lethality of aimable warhead, multi-point synchronous initiated hexagonal prism and cylindrical warheads were compared through numerical simulation, combined with theoretical formulas of fragment decelera- tion and target plugging. Enhancements of fragment velocity, kinetic energy and density toward the target and target destructions were analyzed. The results show that hexagonal prism warhead can produce dense fragment beams and enhance average velocity and kinetic energy with asymmetric eight-point initiation by 24. 13% and 54. 52% respectively, which are higher than those of the isomet- ric or same weight cylindrical warhead. The effective fragments are still relatively concentrated in an area of 8 m × 2 m for the hexagonal prism warhead when the distance between warhead and target is 40 m.

Hexagonal boron nitride adsorbent: Synthesis, performance tailoring and applications

Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specific surface area,h-BN-related nanostructures exhibit appealing adsorption propertiewhich can be widely applied for separation and purification towards energy and environment treatmenIn this review,recent progress in designing h-BN micro,nano-structure,controlled synthesis,performancoptimizing as well as energy and environment-related adsorption applications are summarized.Strategieto tailor the h-BN can be classified as morphology control,element doping,defect control and surfacmodification,focusing on how to optimize the adsorption performance.In order to insight the intrinsimechanism of tuning strategies for property optimization,the significant adsorption applications of h-Btowards hydrogen storage,CO2 capture,pollutants removal from water and adsorption desulfurization arpresented.

Exact analytic solutions for an elliptic hole with asymmetric collinear cracks in a one-dimensional hexagonal quasi-crystal

Using the complex variable function method and the technique of conformal mapping, the anti-plane shear problem of an elliptic hole with asymmetric colfinear cracks in a one-dimensional hexagonal quasi-crystal is solved, and the exact analytic solutions of the stress intensity factors （SIFs） for mode Ⅲ problem are obtained. Under the limiting conditions, the present results reduce to the Griffith crack and many new results obtained as well, such as the circular hole with asymmetric collinear cracks, the elliptic hole with a straight crack, the mode T crack, the cross crack and so on. As far as the phonon field is concerned, these results, which play an important role in many practical and theoretical applications, are shown to be in good agreement with the classical results.

The interaction between a screw dislocation and a wedge-shaped crack in one-dimensional hexagonal piezoelectric quasicrystals

Based on the fundamental equations of piezoelasticity of quasicrystal material,we investigated the interaction between a screw dislocation and a wedge-shaped crack in the piezoelectricity of one-dimensional hexagonal quasicrystals.Explicit analytical solutions are obtained for stress and electric displacement intensity factors of the crack,as well as the force on dislocation.The derivation is based on the conformal mapping method and the perturbation technique.The influences of the wedge angle and dislocation location on the image force are also discussed.The results obtained in this paper can be fully reduced to some special cases already available or deriving new ones.

Crushing analysis and multi-objective optimization of bitubular hexagonal columns with ribs

In order to improve the crashworthiness of thin-walled columns, the energy absorption characteristics of three columns under quasi-static axial crushing loads were analyzed through LS-DYNA. Numerical results show that the energy absorption capability of the bitubular hexagonal columns with middle to middle(MTM) ribs is the best, followed by the bitubular hexagonal columns with corner to corner(CTC) ribs and the bitubular hexagonal columns without(NOT) ribs, respectively. Then, the MTM rib was optimized by using multi-objective particle swarm optimization algorithm. Through the analysis of the Pareto front for specific energy absorption(SEA, A_(se)) and peak crushing force(PCF, F_(pc)), it is found that there is a vertex on the Pareto front. The vertex has the design parameters of t_1=1.2 mm, t_2=1.2 mm, A_(se)=11.3729 k J/kg, F_(pc)=235.8491 kN. When the PCF is in a certain size, on the left of the vertex, the point with t_2=1.2 mm has the biggest SEA, meanwhile on the right of the vertex, the point with t_1=1.2 mm has the biggest SEA. Finally, the global sensitivity analysis was conducted to investigate the effect of two design parameters. The result is obtained that both SEA and PCF for MTM are more sensitive to t_1 rather than t_2 in the design domain.

Characterization of a Y-type hexagonal ferrite-based frequency tunable microwave absorber

A Y-type hexaferrite rod with the composition of Ba2COl.8Cuo.2Fe12022 was presented as an absorbing material with high absorb- anee. Its high absorbance and wide absorption band result from ferromagnetic resonance （FMR） that is self-biased by strong shape and mag- netocrystaUine anisotropy fields. Around the FMR frequency the specimen of the ferrite rods exhibits very high absorbance and the FMR frequency can be tuned by the rod dimension. In addition to the high absorbance and the wide tunable absorption band, the microwave ab- sorber has another advantage of light weight due to the use of the ferrite rods instead of ferrite slabs.

A study of transition from n-to p-type based on hexagonal WO3 nanorods sensor

Hexagonal WO3 nanorods are fabricated by a facile hydrothermal process at 180 ℃ using sodium tungstate and sodium chloride as starting materials. The morphology, structure, and composition of the prepared nanorods are studied by scanning electron microscopy, X-ray diffraction spectroscopy, and energy dispersive spectroscopy. It is found that the agglomeration of the nanorods is strongly dependent on the PH value of the reaction solution. Uniform and isolated WO3 nanorods with diameters ranging from 100 nm-150 nm and lengths up to several micrometers are obtained at PH = 2.5 and the nanorods are identified as being hexagonal in phase structure. The sensing characteristics of the WO3 nanorod sensor are obtained by measuring the dynamic response to NO2 with concentrations in the range 0.5 ppm-5 ppm and at working temperatures in the range 25 ℃-250 ℃. The obtained WO3 nanorods sensors are found to exhibit opposite sensing behaviors, depending on the working temperature. When being exposed to oxidizing NO2 gas, the WO3 nanorod sensor behaves as an n-type semiconductor as expected when the working temperature is higher than 50 ℃, whereas, it behaves as a p-type semiconductor below 50 ℃. The origin of the n- to p-type transition is correlated with the formation of an inversion layer at the surface of the WO3 nanorod at room temperature. This finding is useful for making new room temperature NO2 sensors based on hexagonal WO3 nanorods.

Improved design of special boundary elements for T-shaped reinforced concrete walls

This study examines the design provisions of the Chinese GB 50011-2010 code for seismic design of buildings for the special boundary elements of T-shaped reinforced concrete walls and proposes an improved design method. Comparison of the design provisions of the GB 50011-2010 code and those of the American code ACI 318-14 indicates a possible deficiency in the T-shaped wall design provisions in GB 50011-2010. A case study of a typical T-shaped wall designed in accordance with GB 50011-2010 also indicates the insufficient extent of the boundary element at the non-flange end and overly conservative design of the flange end boundary element. Improved designs for special boundary elements ofT-shaped walls are developed using a displacement-based method. The proposed design formulas produce a longer boundary element at the non-flange end and a shorter boundary element at the flange end, relative to those of the GB 50011-2010 provisions. Extensive numerical analysis indicates that T-shaped walls designed using the proposed formulas develop inelastic drift of 0.01 for both cases of the flange in compression and in tension.

TIME-HARMONIC DYNAMIC GREEN'S FUNCTIONS FOR ONE-DIMENSIONAL HEXAGONAL QUASICRYSTALS

Quasicrystals have additional phason degrees of freedom not found in conventional crystals. In this paper, we present an exact solution for time-harmonic dynamic Green＇s function of one-dimensional hexagonal quasicrystals with the Laue classes 6/mh and 6/mhmm. Through the introduction of two new functions φ and ψ, the original problem is reduced to the determination of Green＇s functions for two independent Helmholtz equations. The explicit expressions of displacement and stress fields are presented and their asymptotic behaviors are discussed. The static Green＇s function can be obtained by letting the circular frequency approach zero.

Synthesis of hexagonal barium ferrite nanoparticle by sol-gel method

M-type Ba hexaferrites were successfully synthesized by sol-gel method. Several synthesizing factors, such as pH value, citric acid/metal ion ratio, and dispersion agent were mainly discussed. Fine and pure powders of BaFe12O19 were optimally synthesized under the conditions of the pH value is 7 and citric acid/metal ion ratio is 3. The X-ray diffraction analysis demonstrates that no impurity is observed in the synthesized powders after presintered at 450 ℃ and calcinated at 1100 ℃. SEM observations indicate that the size of the synthesized BaFe12O19 powders is small and uniform distribution. It can also be learned from SEM that the co-synthesizing sol-gel method can be in favor of the formation of finer particles.

Synthesis of uniform hexagonal Ag nanoprisms with controlled thickness and tunable surface plasmon bands

In this work,we synthesized monodispersed hexagonal Ag nanoprisms in high yields in a system of poly(vinylpyrrolidone)(PVP)in N-methylpyrrolidone(NMP).A blue shift occurred and was strongly dependent on the thickness of the uniform Ag nanoprisms,which had almost the same radial area.When the Ag nanoprisms grew thicker,their in-plane dipole resonance peaks markedly shifted toward shorter wavelengths(i.e.,blue shift).PVP played a critical role of favoring vertical growth of the Ag nanoplates,preventing aggregation,and inducing the formation of Ag hexagonal nanoprisms(HNPs)through the transformation from thin Ag triangular nanoprisms(TNPs).Compared with similar previous research,the present study provides quite uniform Ag hexagonal nanoplates,which makes the blue shift related more solely and distinctly to the thickness of the Ag nanoprisms.The findings of this work provide a new perspective toward understanding the unique optical characteristics of Ag HNPs with different aspect ratios.

Deposition of hexagonal boron nitride thin films on silver nanoparticle substrates and surface enhanced infrared absorption

Silver nanoparticle thin films with different average particle diameters are grown on silicon substrates. Boron nitride thin films are then deposited on the silver nanoparticle interlayers by radio frequency （RF） magnetron sputtering. The boron nitride thin films are characterized by Fourier transform infrared spectra. The average particle diameters of silver nanoparticle thin films are 126.6, 78.4, and 178.8 nm. The results show that the sizes of the silver nanoparticles have effects on the intensities of infrared spectra of boron nitride thin films. An enhanced infrared absorption is detected for boron nitride thin film grown on silver nanoparticle thin film. This result is helpful to study the growth mechanism of boron nitride thin film.

The magnetic and dielectric properties of multiferroic Sr-substituted Zn_2-Y hexagonal ferrites

The magnetic and dielectric properties of Sr-substituted Zn2-Y hexagonal ferrites （Ba2-x SrxZn2Fe12O22, 1.0 〈 x ≤ 1.5） are studied in this paper. Sr substitution will lead to the variation of cation occupation, which influences both the magnetic and electric properties. As Sr content x rises from 1.0 to 1.5, magnetic hysteresis loop gets wider gradually and the permeability drops rapidly due to the transformation from ferrimagnetic to antiferromagnetic phase. Moreover, permittivity rises with increasing Sr content. Under a certain external magnetic field, the phase transition of helical spin structure of Ba0.5Srl.5Zn2Fe12O22 at about 295 K seems to open a possibility for the room-temperature ferroelectricity induced by magnetic field. But its low resistivity prevents the observation of ferroelectric and magnetoelectric properties at room-temperature.

Optical properties of hexagonal boron nitride thin films deposited by radio frequency bias magnetron sputtering

The optical properties of hexagonal boron nitride （h-BN） thin films were studied in this paper. The films were characterized by Fourier transform infrared spectroscopy, UV-visible transmittance and reflection spectra, h-BN thin films with a wide optical band gap Eg （5.86 eV for the as-deposited film and 5.97 eV for the annealed film） approaching h-BN single crystal were successfully prepared by radio frequency （RF） bias magnetron sputtering and post-deposition annealing at 970 K. The optical absorption behaviour of h-BN films accords with the typical optical absorption characteristics of amorphous materials when fitting is made by the Urbach tail model. The annealed film shows satisfactory structure stability. However, high temperature still has a significant effect on the optical absorption properties, refractive index n, and optical conductivity σ of h-BN thin films. The blue-shift of the optical absorption edge and the increase of Eg probably result from stress relaxation in the film under high temperatures. In addition, it is found that the refractive index clearly exhibits different trends in the visible and ultraviolet regions. Previous calculational results of optical conductivity of h-BN films are confirmed in our experimental results.

Basic Functionalization of Hexagonal Mesoporous Silica

Aminopropyltriethoxysilane (AM), 3-ethyldiaminopropyltrimethoxysilane (ED) and 3-piperazinylpropyltriethoxysilane (PZ), were used to chemically couple with the silanol groups of calcined hexagonal and hexagonal-like mesoporous silica SBA-3 and HMS, respectively, to produce functionalised alkaline mesoporous materials. The increase in the dosage of organosilanes, or in reaction temperature, or in the humidity (i.e., water content) of support, is favorable to the grafting of functional molecules on the surface. When functionalization conditions are the same, the order of loadings on SBA-3 and DDA-HMS is ED>AM>PZ. However, on ODA-HMS, the loading of AM is similar to that of ED.