In order to form large-diameter thin-wall cylindrical workpieces of TA15 titanium alloy,tube hot spinning experiments of the alloy were conducted on a CNC hot spinning machine.The causes of some forming defects occuri...In order to form large-diameter thin-wall cylindrical workpieces of TA15 titanium alloy,tube hot spinning experiments of the alloy were conducted on a CNC hot spinning machine.The causes of some forming defects occuring in hot spinning,such as crack,pileup,bulge and corrugation,were analyzed and the corresponding measures were put forward to avoid spinning defects,based on which a proper process scheme of hot spinning of TA15 alloy was obtained and the large-diameter and thin-walled cylindrical workpieces were formed with good quality.The results show that spinning temperature has distinct influence on forming quality of spun workpieces.The range of spinning temperature determines the spinnability of titanium alloy and the ununiformity of temperature distribution near the deformation zone leads to the formation of bulge.The reasonable heating method is that the deforming region is heated to the optimum temperature range of 600-700 ℃,the deformed region is heated continuously and a certain length of undeformed region is preheated.With the thickness-to-diameter ratio(t/D) of spun workpiece reducing to certain value(t/D<1%),surface bulge and corrugation is rather easier to come into being,which could be controlled through restraining diameter growth and employing smaller reduction rate and lower temperature in the optimum spinning temperature range.展开更多
The influence of deformation parameters including deformation temperature,degree and speed on the microstructure and mechanical properties of TA15 titanium alloy was studied. The volume fraction,size and aspect ratio ...The influence of deformation parameters including deformation temperature,degree and speed on the microstructure and mechanical properties of TA15 titanium alloy was studied. The volume fraction,size and aspect ratio of primary α phase in deformed TA15 titanium alloy were quantitatively characterized. With increasing deformation temperature,the volume fraction and size of primary α phase decrease. The aspect ratio of primary α phase decreases with increasing deformation temperature. The tensile strength of TA15 alloy deformed at 0.1 mm/s is higher than that at 0.3 mm/s. After thermoforming at 960 ℃,0.1 mm/s,the tensile strength is the highest up to 1 035 MPa and the elongation is 13.5%. When the thermoforming temperature is 1 050 ℃,the strength and elongation are both relative low,because the microstructure is Widmanstaten structure.展开更多
Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the count...Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the counter-rotating state.This paper aims to analyse the anode dissolution behaviour of TA15 and obtain desired surface qualities in CRECM.The anodic characteristics were measured by polarization and cyclic voltammetry curves,and the passive-trans passive behaviour of TA15 was revealed.The electrode surface structures at different stages were analysed using electrochemical impedance spectroscopy(EIS),and a quantitative dissolution model was established to illustrate the electrochemical dissolution and structural evolution of the revolving surfaces.A series of CRECM experiments were conducted,and three stages(pitting corrosion,pitting expansion,and smoothing)were detected according to the current signals.In the first stage,an oxide film with small pores was formed initially on the metal surface when exposed to air.This air-formed oxide film was broken down locally during the electrochemical reaction process,resulting in the occurrence of pitting.With the increase of electricity,the oxide layer became thinner,and the pitting areas expanded and began to connect with each other.In this stage,the surface quality was poor owing to the uneven material dissolution.When the amount of electricity approximately reached a constant,the oxide layer was completely removed,and a very thin salt film was generated at the metal-electrolyte interface.In this stage,the material was dissolved uniformly,and the surface was smooth without pitting corrosion.Based on the obtained results,anode workpieces with grid-like convex structures were fabricated using CRECM.Both the revolving surface and the sidewalls of the convex structures can be controlled from pitting to smoothness.展开更多
The microstructural characteristics, elemental distribution law and microscopic formation mechanism of the burning products of TA15 titanium alloy were investigated by friction oxygen concentration method, associated ...The microstructural characteristics, elemental distribution law and microscopic formation mechanism of the burning products of TA15 titanium alloy were investigated by friction oxygen concentration method, associated with in situ observation, X-ray diffraction(XRD),scanning electron microscopy(SEM) and energy-dispersive spectroscopy(EDS) analyses, providing the thoughts to improve fireproof property. The results show that, when the friction contact pressure(p) is 0.20 MPa and oxygen concentration of premixed air flow(c) is 60 vol%, TA15 titanium alloy produces violent sparks and presents dazzling white light during combustion. The generated products after burning are mainly TiOand small amount of AlOoxides. Four distinct zones form from the combustion surface to the alloy matrix, and they are in the sequence of combustion zone, fusion zone, heat-affected zone and transition zone. Further, combustion zone is composed of TiOand A1203 compounds, containing obvious cracks. In the fusion zone, discontinuous oxygenrich Al-based solid solution forms, and the elemental distribution has strong volatility. In the heat-affected zone,there are abundant of Ti-based solid solution and small amount of Al-and Mo-based solid solution. Transition zone is made of lamellar structure. Two technical approaches are given to prevent oxygen diffusion inside the reaction zone and reaction-affected zone. On the one hand,the content of Al is designed as the upper limit of alloy composition; on the other hand, fireproof coatings are deposited on the surface of the alloy.展开更多
Temperature rise is a significant factor influencing microstructure during(α+β) deformation of TA15 titanium alloy.An experiment was designed to explore microstructure evolution induced by temperature rise due to...Temperature rise is a significant factor influencing microstructure during(α+β) deformation of TA15 titanium alloy.An experiment was designed to explore microstructure evolution induced by temperature rise due to deformation heat.The experiment was carried out in(α+β) phase field at typical temperature rise rates.The microstructures of the alloy under different temperature rise rates were observed by scanning electron microscopy(SEM).It is found that the dissolution rate of primary equiaxed a phase increases with the increase in both temperature and temperature rise rate.In the same temperature range,the higher the temperature rise rate is,the larger the final content and grain size of primary equiaxed a phase are due to less dissolution time.To quantitatively depict the evolution behavior of primary equiaxed a phase under any temperature rise rates,the dissolution kinetics of primary equiaxed a phase were well described by a diffusion model.The model predictions,including content and grain size of primary equiaxed a phase,are in good agreement with experimental observations.The work provides an important basis for the prediction and control of microstructure during hot working of titanium alloy.展开更多
文摘In order to form large-diameter thin-wall cylindrical workpieces of TA15 titanium alloy,tube hot spinning experiments of the alloy were conducted on a CNC hot spinning machine.The causes of some forming defects occuring in hot spinning,such as crack,pileup,bulge and corrugation,were analyzed and the corresponding measures were put forward to avoid spinning defects,based on which a proper process scheme of hot spinning of TA15 alloy was obtained and the large-diameter and thin-walled cylindrical workpieces were formed with good quality.The results show that spinning temperature has distinct influence on forming quality of spun workpieces.The range of spinning temperature determines the spinnability of titanium alloy and the ununiformity of temperature distribution near the deformation zone leads to the formation of bulge.The reasonable heating method is that the deforming region is heated to the optimum temperature range of 600-700 ℃,the deformed region is heated continuously and a certain length of undeformed region is preheated.With the thickness-to-diameter ratio(t/D) of spun workpiece reducing to certain value(t/D<1%),surface bulge and corrugation is rather easier to come into being,which could be controlled through restraining diameter growth and employing smaller reduction rate and lower temperature in the optimum spinning temperature range.
文摘The influence of deformation parameters including deformation temperature,degree and speed on the microstructure and mechanical properties of TA15 titanium alloy was studied. The volume fraction,size and aspect ratio of primary α phase in deformed TA15 titanium alloy were quantitatively characterized. With increasing deformation temperature,the volume fraction and size of primary α phase decrease. The aspect ratio of primary α phase decreases with increasing deformation temperature. The tensile strength of TA15 alloy deformed at 0.1 mm/s is higher than that at 0.3 mm/s. After thermoforming at 960 ℃,0.1 mm/s,the tensile strength is the highest up to 1 035 MPa and the elongation is 13.5%. When the thermoforming temperature is 1 050 ℃,the strength and elongation are both relative low,because the microstructure is Widmanstaten structure.
基金supported by the National Natural Science Foundation of China(Grant No.51805259)the National Natural Science Foundation of China for Creative Research Groups(Grant No.51921003)+1 种基金the China Postdoctoral Science Foundation(Grant No.2019M661833)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX21_0192)。
文摘Counter-rotating electrochemical machining(CRECM)is a novel shaping method with advantages in processing revolving parts,especially engine casings.However,few researchers have studied the anodic behaviour of the counter-rotating state.This paper aims to analyse the anode dissolution behaviour of TA15 and obtain desired surface qualities in CRECM.The anodic characteristics were measured by polarization and cyclic voltammetry curves,and the passive-trans passive behaviour of TA15 was revealed.The electrode surface structures at different stages were analysed using electrochemical impedance spectroscopy(EIS),and a quantitative dissolution model was established to illustrate the electrochemical dissolution and structural evolution of the revolving surfaces.A series of CRECM experiments were conducted,and three stages(pitting corrosion,pitting expansion,and smoothing)were detected according to the current signals.In the first stage,an oxide film with small pores was formed initially on the metal surface when exposed to air.This air-formed oxide film was broken down locally during the electrochemical reaction process,resulting in the occurrence of pitting.With the increase of electricity,the oxide layer became thinner,and the pitting areas expanded and began to connect with each other.In this stage,the surface quality was poor owing to the uneven material dissolution.When the amount of electricity approximately reached a constant,the oxide layer was completely removed,and a very thin salt film was generated at the metal-electrolyte interface.In this stage,the material was dissolved uniformly,and the surface was smooth without pitting corrosion.Based on the obtained results,anode workpieces with grid-like convex structures were fabricated using CRECM.Both the revolving surface and the sidewalls of the convex structures can be controlled from pitting to smoothness.
基金financially supported by the National Natural Science Foundation of China (No.51471155)the Aviation Science Foundation of China(No.2014E62149R)
文摘The microstructural characteristics, elemental distribution law and microscopic formation mechanism of the burning products of TA15 titanium alloy were investigated by friction oxygen concentration method, associated with in situ observation, X-ray diffraction(XRD),scanning electron microscopy(SEM) and energy-dispersive spectroscopy(EDS) analyses, providing the thoughts to improve fireproof property. The results show that, when the friction contact pressure(p) is 0.20 MPa and oxygen concentration of premixed air flow(c) is 60 vol%, TA15 titanium alloy produces violent sparks and presents dazzling white light during combustion. The generated products after burning are mainly TiOand small amount of AlOoxides. Four distinct zones form from the combustion surface to the alloy matrix, and they are in the sequence of combustion zone, fusion zone, heat-affected zone and transition zone. Further, combustion zone is composed of TiOand A1203 compounds, containing obvious cracks. In the fusion zone, discontinuous oxygenrich Al-based solid solution forms, and the elemental distribution has strong volatility. In the heat-affected zone,there are abundant of Ti-based solid solution and small amount of Al-and Mo-based solid solution. Transition zone is made of lamellar structure. Two technical approaches are given to prevent oxygen diffusion inside the reaction zone and reaction-affected zone. On the one hand,the content of Al is designed as the upper limit of alloy composition; on the other hand, fireproof coatings are deposited on the surface of the alloy.
基金financially supported by the National Natural Science Foundation of China (Nos.51175427 and 51205317)the Open Fund of State Key Laboratory of Materials Processing and Die & Mould Technology of China (No.P2014-005)+1 种基金the Marie Curie International Research Staff Exchange Scheme within the 7th EC Framework Programme (FP7) (No.318968)the Programme of Introducing Talents of Discipline to Universities (No.B08040)
文摘Temperature rise is a significant factor influencing microstructure during(α+β) deformation of TA15 titanium alloy.An experiment was designed to explore microstructure evolution induced by temperature rise due to deformation heat.The experiment was carried out in(α+β) phase field at typical temperature rise rates.The microstructures of the alloy under different temperature rise rates were observed by scanning electron microscopy(SEM).It is found that the dissolution rate of primary equiaxed a phase increases with the increase in both temperature and temperature rise rate.In the same temperature range,the higher the temperature rise rate is,the larger the final content and grain size of primary equiaxed a phase are due to less dissolution time.To quantitatively depict the evolution behavior of primary equiaxed a phase under any temperature rise rates,the dissolution kinetics of primary equiaxed a phase were well described by a diffusion model.The model predictions,including content and grain size of primary equiaxed a phase,are in good agreement with experimental observations.The work provides an important basis for the prediction and control of microstructure during hot working of titanium alloy.