A new preparation method for a highly sinterable Y 2O 3 powder was developed, using the mixture of the powder with Al 2O 3 powder, a transparent yttrium aluminum garnet(YAG) ceramic was prepared at relatively low temp...A new preparation method for a highly sinterable Y 2O 3 powder was developed, using the mixture of the powder with Al 2O 3 powder, a transparent yttrium aluminum garnet(YAG) ceramic was prepared at relatively low temperature by a solid state reaction method. Yttrium nitrate was used as a mother salt, and aqueous ammonia was used as a precipitant reagent, the fine and dendritic precursor crystalline was prepared by adding 0.5% ammonium sulfate into the precipitation reaction system. The highly pure and low agglomerated Y 2O 3 powders were obtained by calcinating the precursor at 1 100 ℃, the primary particles are spherical and 60 nm in diameter. The mixture of Y 2O 3 and Al 2O 3 powders was calcinated, and the resulting mixture compact pressed in mold could be sintered to transparency under vacuum at 1 700 ℃. The sintered transparent YAG polycrystalline exhibits a homogeneous microstructure and its transmittance reaches 45% in the visible light region and 70% in the near infrared wavelength region.展开更多
Recent progress on rare-earth doped polycrystalline YAG transparent ceramics has made them an alternative novel solid-state laser gain material. In this paper, we present results of our research on polycrystalline RE:...Recent progress on rare-earth doped polycrystalline YAG transparent ceramics has made them an alternative novel solid-state laser gain material. In this paper, we present results of our research on polycrystalline RE:YAG transparent ceramics. High optical quality YAG ceramics doped with various rare-earth(RE) ions such as Nd3+, Yb3+, Er3+,Tm3+, and Ho3+have been successfully fabricated using the solid-state reactive sintering method. Highly efficient laser oscillations of the fabricated ceramics are demonstrated.展开更多
文摘A new preparation method for a highly sinterable Y 2O 3 powder was developed, using the mixture of the powder with Al 2O 3 powder, a transparent yttrium aluminum garnet(YAG) ceramic was prepared at relatively low temperature by a solid state reaction method. Yttrium nitrate was used as a mother salt, and aqueous ammonia was used as a precipitant reagent, the fine and dendritic precursor crystalline was prepared by adding 0.5% ammonium sulfate into the precipitation reaction system. The highly pure and low agglomerated Y 2O 3 powders were obtained by calcinating the precursor at 1 100 ℃, the primary particles are spherical and 60 nm in diameter. The mixture of Y 2O 3 and Al 2O 3 powders was calcinated, and the resulting mixture compact pressed in mold could be sintered to transparency under vacuum at 1 700 ℃. The sintered transparent YAG polycrystalline exhibits a homogeneous microstructure and its transmittance reaches 45% in the visible light region and 70% in the near infrared wavelength region.
基金supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the National Research Foundation of Singapore under contract NRF-G-CRP-2007-01
文摘Recent progress on rare-earth doped polycrystalline YAG transparent ceramics has made them an alternative novel solid-state laser gain material. In this paper, we present results of our research on polycrystalline RE:YAG transparent ceramics. High optical quality YAG ceramics doped with various rare-earth(RE) ions such as Nd3+, Yb3+, Er3+,Tm3+, and Ho3+have been successfully fabricated using the solid-state reactive sintering method. Highly efficient laser oscillations of the fabricated ceramics are demonstrated.
