Techno-economic assessment of a chemical looping splitting system for H2 and CO Co-generation

The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850
C and 600
C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.

A Techno-Economical Characterization of Solar PV Power Generation in Rwanda:The Role of Subsidies and Incentives

Standalone Solar PV systems have been vital in the improvement of access to energy in many countries.However,given the large cost of solar PV plants’components,in developing countries,there is a dear need for such components to be subsidised and incentivised for the consumers to afford the produced energy.Moreover,there is a need for optimal sizing of the solar PV plants taking into account the solar information,energy requirement for various activities,and economic conditions in the off-grid regions in Rwanda.This study aims to develop optimally sized solar PV plants suited to rural communities in Rwanda.Likewise,it aims at characterizing the impacts of subsidies and incentives on the profitability and affordability of solar PV plants’energy in Rwanda.In the study,we have developed a model on basis of which the plant power(peak power)and costs of energy can be predicted given the load requirements using PVSyst.The model was validated using data corrected at eight different sites.Our generalized predictive model’s results matched the results obtained using field measurement data as inputs.The models have been able to replicate with a by degree of accuracy the peak powers and the plants’costs for different loads and were used to evaluate the economic viability of solar PV plants in Rwanda.It was found that with incentives and subsidies of 20%,the solar PV systems’costs,the Levelised Cost of Energy would drop from a maximum of 0.098 Euro to a minimum of 0.072 Euro,the payback period was reduced from a maximum of 7.5 years to a minimum of 6.0 years while the return on investments was seen to vary between 425.72 and 615.32 per cent over the plants’lifetime of 25 years.Overall our findings underscore the importance of government subsidies and incentives for solar PV energy generation projects to be significantly profitable.

Techno-economic analysis of single U-tube and double U-tube heat exchangers in Chongqing area

On the basis of practical projects in Chongqing,the thermal performance of heat exchangers (single U-tube type and double U-tube type) of the ground-source heat pump (GSHP) system in the hot summer was obtained and analyzed. The data obtained from test could match with the result deduced from theoretical calculation. From the test results,the cooling capacity of double U-tube is 1.6 times that of single U-tube. Taking cost per depth per watt Clq as the evaluation standard,Clq of single U-tube is 4.69 RMB$/W,and Clq of double U-tube is 3.14 RMB$/W. The double U-tube heat exchangers usage should be prioritized.

Techno-Economic Analysis and Life Cycle Assessment for the Typical Intermediate Crude Refining Scheme in China

The integration of refinery and petrochemical units(IRPUs)has become an inevitable choice for the sustainable development of petrochemical industry.The utilization efficiency of petroleum resources could be improved obviously through IRPUs.However,integrating economic and environmental impacts into the model of IRPUs is still a grand challenge.Herein,a model called TEA-GHG-OPWM(Techno-Economic Analysis and GreenHouse Gases Oriented Plant-Wide Model)has been established on Aspen HYSYSTM platform to calculate the energy consumption,the technoeconomic performance,and the GHG emissions for two different kinds of schemes,viz,:VRHCU(Vacuum Residue Hydrocracking Unit)and VRDS-RFCC(Vacuum Residue Desulfurization and Residue Fluid Catalytic Cracking).Furthermore,a novel processing pathway named VGOHDT-HTMP-DC(Vacuum Gas Oil Hydrotreating,Hydrogenation and TMP coupling process and Delayed Coking)has also been developed to find methods to improve the economic performance based on a ten-million-CNY output value(TMYOV)and a reduced GHG emissions.Our results demonstrate that VRHCRU could consume more energy and emit more GHG(877.11 t of CO2 eq·TMYOV^-1·h^-1)than VRDS-RFCC(817.03 t of CO2 eq·TMYOV^-1·h^-1)and VGOHDT-HTMP-DC(721.96 t of CO2 eq·TMYOV^-1·h^-1),while obtaining a higher mass yield of petrochemicals.The VGOHDT-HTMP-DC process exhibits the lowest feedstock consumption,hydrogen consumption,energy consumption,and GHG emissions,indicating that VGOHDT-HTMP-DC has both well economic and environmentally friendly performance.

Simulation and Techno-Economic Performance of a Novel Charge Calculation and Melt Optimization Planning Model for Steel Making

Process algorithm, numerical model and techno-economic assessment of charge calculation and furnace bath optimization for target alloy for induction furnace-based steelmaking is presented in this study. The developed algorithm combines the make-to-order (MTO) and charge optimization planning (COP) of the steel melting shop in the production of target steel composition. Using a system-level approach, the unit operations involved in the melting process were analyzed with the purpose of initial charge calculation, prevailing alloy charge prediction and optimizing the sequence of melt chemistry modification. The model performance was established using real-time production data from a cast iron-based foundry with a 1- and 2-ton induction furnace capacity and a medium carbon-based foundry with a 10- and 15-ton induction furnace capacity. A simulation engine (CastMELT) was developed in Java IDE with a MySQL database for continuous interaction with changing process parameters to run the model for validation. The comparison between the model prediction and production results was analyzed for charge prediction, melt modification and ferroalloy optimization and possible cost savings. The model performance for elemental charge prediction and calculation purpose with respect to the charge input (at overall scrap meltdown) gave R-squared, Standard Error, Pearson correlation and Significance value of (0.934, 0.06, 0.97, 0.0003) for Carbon prediction, (0.962, 0.06, 0.98, 0.00009) for Silicon prediction, (0.999, 0.048, 0.999, 9E -11) for Manganese Prediction, and (0.997, 0.076, 0.999, 6E -7) for Chromium prediction respectively. Correlation analysis for melt modification (after charging of ferroalloy) using the model for after-alloying spark analysis compared with the target chemistry is at 99.82%. The results validate the suitability of the developed model as a functional system of induction furnace melting for combined charge calculation and melt optimization Techno-economic evaluation results showed that 0.98% - 0.25% ferroalloy saving per ton of melt is possible using the model. This brings about an annual production cost savings of 100,000 $/y in foundry A (medium carbon steel) and 20,000 $/y in foundry B (cast iron) on the use of different ferroalloy materials.

Techno-Economic Feasibility Analysis of Solar Photovoltaic Power Generation: A Review

With the rapid depletion of fossil fuel reserves, it is feared that the world will soon run out of its energy resources. This is a matter of concern for developing countries whose economy heavily leans on its use of energy. Under the circums-tances it is highly desirable that renewable energy resources should be utilized with maximum conversion efficiency to cope with the ever increasing energy demand. Furthermore, the global economic and political conditions that tend to make countries more dependent on their own energy resources have caused growing interest in the development and use of renewable energy based technologies. In terms of its environmental advantages, renewable energy sources generate electricity with insignificant contribution of carbon dioxide (CO2) or other greenhouse gases (GHG) to the atmosphere and they produce no pollutant discharge on water or soil and hence power generation from renewable becomes very important. Major types of renewable energy sources include solar, wind, hydro and biomass, all of which have huge potential to meet future energy challenges. Solar photovoltaic technology in one of the first among several renewable energy technologies that have been adopted worldwide for meeting the basic needs of electricity particularly in remote areas. In this paper literature review pertaining to techno-economic feasibility analysis of solar photovoltaic power generation is discussed. The literature is basically classified into the following three main category design methods, techno-economic feasibility of solar photovoltaic power generation, performance evaluations of various systems.

Techno-Economic Analysis of Power Production by Using Waste Biomass Gasification

Energy recovery from waste biomass can have significant impacts on the most pressing development challenges of rural poverty and environmental damages. In this paper, a techno-economic analysis is carried out for electricity generation by using timber and wood waste (T & WW) gasification in Iceland. Different expenses were considered, like capital, installation, engineering, operation and maintenance costs and the interest rate of the investment. Regarding to revenues, they come from of the electricity sale and the fee paid by the Icelandic municipalities for waste collection and disposal. The economic feasibility was conducted based on the economic indicators of net present value (NPV) and discounted payback period (DPP), bringing together three different subgroups based on gasifier capacities, subgroup a: 50 kW, subgroup b: 100 kW and subgroup c: 200 kW. The results show that total cost increases as the implemented power is increased. This indicator varies from 1228.6 k€ for subgroups a to 1334.7 k€ for subgroups b and 1479.5 k€ for subgroups c. It is worth mentioning that NPV is positive for three subgroups and it grows as gasifier scale is extended. NPV is about 122 k€ (111,020 $), 1824 k€ (1,659,840 $) and 4392 k€ (3,996,720 $) for subgroups a, b and c, respectively. Moreover, DPP has an inversely proportional to the installed capacity. It is around 5.5 years (subgroups a), 9.5 months (subgroups b) and 6 months (subgroups c). The obtained results confirm that using small scale waste biomass gasification integrated with power generation could be techno-economically feasible for remote area in Iceland.

Techno-economical evaluation of membrane based biogas upgrading system:A comparison between polymeric membrane and carbon membrane technology

A shift to renewable energy sources will reduce emissions of greenhouse gases and secure future energy supplies. In this context, utilization of biogas will play a prominent role. Focus of this work is upgrading of biogas to fuel quality by membrane separation using a carbon hollow fibre(CHF) membrane and compare with a commercially available polymeric membrane(polyimide) through economical assessment. CHF membrane modules were prepared for pilot plant testing and performance measured using CO_2, O_2, N_2. The CHF membrane was modified through oxidation, chemical vapour deposition(CVD) and reduction process thus tailoring pores for separation and increased performance. The post oxidized and reduced carbon hollow fibres(PORCHFs) significantly exceeded CHF performance showing higher CO_2 permeance(0.021 m^3(STP)/m^2 h bar) and CO_2/CH_4 selectivity of 246(5 bar feed vs 50 mbar permeate pressure). The highest performance recorded through experiments(CHF and PORCHF) was used as simulation basis. A membrane simulation model was used and interfaced to 8.6 V Aspen HYSYS.A 300 Nm^3/h mixture of CO_2/CH_4 containing 30-50% CO_2 at feed pressures 6, 8 and 10 bar, was simulated and process designed to recover99.5% CH_4 with 97.5% purity. Net present value(NPV) was calculated for base case and optimal pressure(50 bar for CHF and PORCHF). The results indicated that recycle ratio(recycle/feed) ranged from 0.2 to 10, specific energy from 0.15 to 0.8(kW/Nm^3 feed) and specific membrane area from 45 to 4700(m^2/Nm^3 feed). The high recycle ratio can create problems during start-up, as it would take long to adjust volumetric flow ratio towards 10. The best membrane separation system employs a three-stage system with polyimide at 10 bar, and a two-stage membrane system with PORCHF membranes at 50 bar with recycle. Considering biomethane price of 0.78 $/Nm^3 and a lifetime of 15 years, the technoeconomic analysis showed that payback time for the best cascade is 1.6 months.

Thermodynamic and Techno-economic Analysis of a Triple-pressure Organic Rankine Cycle: Comparison with Dual-pressure and Single-pressure ORCs

Investigation of a triple-pressure organic Rankine cycle(TPORC) using geothermal energy for power generation with the net power output of the TPORC analyzed by varying the evaporation pressures, pinch temperature differences(tpp) and degrees of superheat(tsup) aimed to find the optimum operation conditions of the system. The thermodynamic performance of the TPORC was compared with a dual-pressure organic Rankine cycle(DPORC) and a single-pressure ORC(SPORC) for geofluid temperatures ranging from 100°C to 200°C, with particular reference to the utilization of a hot dry rock(HDR) geothermal resource. Thermodynamic performances of the TPORC system using eight different organic working fluids have also been investigated in terms of the net power outputs. Results show that a higher geofluid mass flow rate can make a considerable contribution to shortening the payback period(PBP) as well as to decreasing the levelized electricity cost(LEC), especially when the geofluid temperature is low. For the temperature range investigated, the order from high to low based on thermodynamic and techno-economic performances is found to be TPORC > DPORC > SPORC. In terms of using geothermal resources within the given temperatures range(100°C–200°C), the TPORC system can be a better choice for geothermal power generation so long as the wellhead geofluid temperature is between 140°C and 180°C.

Techno-Economic Analysis of a Grid-Connected Waste to Energy Gasification Plant:A Case Study

With population growth around the world,municipal waste disposal and continued energy demand becomes some of the major challenges to deal with.In order to address these,an approach is required for an optimal waste management system that offers the population benefit with a lower environmental impact.This study evaluates the technical-economic and environmental impact analysis of a grid-connected waste to energy(WtE)plant to power a Univerisiti Teknologi Malaysia(UTM)community.The energy recovery potential of the waste stream was assessed using the life cycle assessment(LCA)method with GaBi^(TM) software(version 4).A technical,economic and environmental analysis was then carried out for the grid-connected WtE system using HOMERPro software with gasification conversion technology.The cash flow analysis was based on levelized costs of energy(LCOE)and total net present value(NPV).The results gave an NPV for the system at USD 1.11×10^(7),with most of the effects resulting from the grid operating costs and the LCOE of USD 0.43/kWh compared to the grid unit price of USD 0.7/kWh which corresponds to a saving of$0.27/kWh in energy purchase.From an environmental point of view,the results showed a significant reduction in carbon dioxide emissions from around 2,000 tons per year to around 400 tons per year.With regard to the amount of waste sent to landfills,the results show a significant improvement from 142,605.5 kg/year to 0.13 kg/year.

Modifying Plant Oils for Use as Fuel in Rural Contexts Tanzania: Techno-Economic Analysis

Techno-economic analysis of a small-scale Modified Plant Oil (MPO) production plant that has an annual production capacity of 15,072,741 kg of MPO (batch process) was carried out to estimate the capital and operating costs of a plant. The analysis was done by using a computer model that was designed and simulated with an aid of SuperPro Designer (Version 4.32) software. The specified feedstock was crude Jatropha oil (JO) and the main product was MPO. The major processes involved were degumming, neutralisation and blending. Degumming involved the removal of gums or phospholipids, and two methods were used: water degumming and acid degumming, whereas blending involved mixing of degummed or purified JO with natural gas condensate (NGC) modifier to lower the viscosity of JO. From techno-economic analysis of the process, it was found that the total capital investment of a plant was about US $ 10,222,000 and the predicted unit production cost of MPO was US $ 1.315/kg at a value of US $ 1.0/kg of JO. The economic feasibility of MPO production was found to be highly influenced by the price of feedstock, which contributed about 95% of the total annual production cost. The relationship between plant throughput and unit cost of producing MPO showed that unit production cost was very sensitive to production rate at low annual throughputs. The MPO cost showed a direct linear relationship with the cost of JO, with a change of US $ 0.50/kg of MPO in MPO cost in every change of US $ 0.50/kg of JO in JO price. The process technology simulated was found to be economically viable and can be implemented in rural setting, taking into consideration Tanzania’s rural situation.

A model of techno-economic evaluation for eco-industrial park project

An eco-industrial park or estate is a community of manufactaring and service businesses located together on a common property. The goat of ElP is to create a win-win harmonious development aspect of ecooomic development and environmental protection. This paper emphasizes that the external .effect of an EIP is its main characteristic of technoeconomic evaluation for eco-industrial park project. From the view of the property, rights, the EIP＇s product is typicalty public-private. The government should take some inca.rares for the quantitative analysis on ecological positive externalities of the enterprises in EIP, and also should adopt Coase＇s Theorem, which supports that the market transaction is the best way to deal with positive externalities （external economics or diseconoraics）, or Pigou＇s Theorem, which holds that the government anti-positive externalities programs are the best way to cope with positive externalities, to internalize the EIP＇s external effects, which is also a fundamental tool to encourage investors to actively invest in EIP projects, Furthermore. this paper thinks that the EIP ＇s income should be equal to the income of staple products of the private property, and that of its by-products of the public property. According to this principle, this paper has put forward three major indicators, net present value （NPV）, internal rate of renan （IRR）, and investment repayment period （IRP）, which are also extensively used indicators in ardinary project techno-economic evaluation model to evaluate EIP technoeconomic effects. Theoretically, the indicatory not only can be used in EIP project evaluation, but also can provide a quantitative measure toot for the government to support EIP＇s construction to the maximum. In the end. a case is analyzed.

Ethics and the Techno-Economic Future

The general theme-“ethics in the future”-intends to question a form of human knowledge,ethics,in relation to a dimension of time,the future.In broader terms,the title refers to a question about the relationship between knowledge and time,which in turn includes questions such as:“To what do different forms of knowledge-ethics,economics,physics-refer when they discuss the future?”;“What do they mean by a possible,probable,preferable future?”;“What future emerges through their key concepts?”;“What kind of future challenges present knowledge within an epochal context that is established in the form of an incessant reproduction of relative means and ends,one that is constantly outdated?”;“What form of knowledge is required first and foremost so that the establishment of this epoch can take place?”

A Techno-Economic Paradigm Perspective on the ＇Third Industrial Revolution＇ and China＇s Strategies in Response

Built on artificial intelligence, digitalization, and information technologies, the ＂Third Industrial Revolution ＂＂ transforms large-scale assembly lines and flexible manufacturing system with fundamental modern manufacturing technologies and features personalized manufacturing, which is enabled by reconfigurable manufacturing system, and quick market response. It is a profound transformation of techno-economic paradigms, imbedded in the technology, management, and institutional systems. As this revolution deepens, it is likely that manufacturing and the manufacturing sector would acquire new definitions. In addition, the resource foundation and factor structure, which are central to the competitiveness of a nation and an enterprise, would perhaps be reconfigured, hence rewriting the landscape of global industrial competition. Under this scenario, the ＂smiling curve ＇＂ which used to portray the economic features of the value chain, may change into a ＂silence curve＂ or even ＂sadness curve ＂. The catching- up pathway of latecomer countries, as predicted by the traditional ＇flying geese model＂, is likely to be blocked, solidifying the division of＂core and periphery countries＂ which is unfavorable to developing countries. Industrial competition between countries would move from competition between enterprises and supply chains to competition in industrial ecosystems, matdng system adaptability and dynamics the key to long-term industrial competitiveness. As an effort to embrace the ＂Third Industrial Revolution＂ and meet the challenges brought by ＂multi-facets competition＂ with developed industrial nations in various links of value chain, in the future China should make appropriate adjustments in its strategies for economic transition and upgrading, global competition, technological innovation, industrial development and information technology.

Identification of Techno-Economically Viable Crop Residue Utilization in India

India generates more than 140 million tonnes of surplus crop residue every year In Haryana, the agricultural sector alone produces 24.64 million tonnes of residue annually;of which only 71% is consumed in various domestic and commercial activities within the state. The rest of the material is burned causing severe contamination of air with smoke. There is an urgent need to identify suitable and sustainable conversion technologies that are efficient, eco-friendly as well as cost-effective for managing the huge available biomass not only in the state but also in the country. This paper reviews briefly the available crop residue and quantities burned, proposes a scheme to incorporate part of the residue in the field for its fertilizer value. The remaining biomass is harvested for animal feed and the excess is converted to bioenergy and biofuels. Among the developed and developing biofuels, the paper identifies biogas production from biomass for on-farm use. Pelletization is identified as an enabling technology to provide high quality feedstock for conversion to heat/power and in near future to advanced biofuels.

Techno-Economic and Sustainability Analysis of Potential Cooling Methods in Irish Data Centres

11% of Irish electricity was consumed by data centres in 2020. The Irish data centre industry and the cooling methods utilised require reformative actions in the coming years to meet EU Energy policies. The resell of heat, alternative cooling methods or carbon reduction methods are all possibilities to conform to these policies. This study aims to determine the viability of the resell of waste heat from data centres both technically and economically. This was determined using a novel application of thermodynamics to determine waste heat recovery potential in Irish data centres, and the current methods of heat generation for economical comparison. This paper also explores policy surrounding waste heat recovery within the industry. The Recoverable Carnot Equivalent Power (RCEP) is theoretically calculated for the three potential cooling methods for Irish data centres. These are air, hybrid, and immersion cooling techniques. This is the maximum useable heat that can be recovered from a data centre rack. This study is established under current operating conditions which are optimised for cooling performance, that air cooling has the highest potential RCEP of 0.39 kW/rack. This is approximately 8% of the input electrical power that can be captured as useable heat. Indicating that Irish data centres have the energy potential to be heat providers in the Irish economy. This study highlighted the technical and economic aspects of prevalent cooling techniques and determined air cooling heat recovery cost can be reduced to 0.01 €/kWhth using offsetting. This is financially competitive with current heating solutions in Ireland.

Thermal pyrolysis conversion of methane to hydrogen(H_(2)):A review on process parameters,reaction kinetics and techno-economic analysis

Hydrogen(H_(2))is a promising renewable energy which finds wide applications as the world gears toward low-carbon economy.However,current H_(2) production via steam methane reforming of natural gas or gasification of coal are laden with high CO_(2) footprints.Recently,methane(CH_(4))pyrolysis has emerged as a potential technology to generate low-carbon H_(2) and solid carbon.In this review,the current state-of-art and recent progress of H_(2) production from CH_(4) pyrolysis are reviewed in detail.Aspects such as funda-mental mechanism and chemistry involved,effect of process parameters on the conversion efficiency and reaction kinetics for various reaction media and catalysts are elucidated and critically discussed.Temper-ature,among other factors,plays the most critical influence on the methane pyrolysis reaction.Molten metal/salt could lower the operating temperature of methane pyrolysis to<1000℃,whereas plasma technology usually operates in the regime of>1000℃.Based on the reaction kinetics,metal-based cata-lysts were more efficient in lowering the activation energy of the reaction to 29.5-88 kJ/mol from that of uncatalyzed reaction(147-420.7 kJ/mol).Besides,the current techno-economic performance of the pro-cess reveals that the levelized cost of H_(2) is directly influenced by the sales price of carbon(by-product)generated,which could offset the overall cost.Lastly,the main challenges of reactor design for efficient product separation and retrieval,as well as catalyst deactivation/poisoning need to be debottlenecked.

Optimization of gas lift system for well performance improvement in Asmari formation:A techno-economic perspective

Well productivity in the Asmari carbonate formation of southwest Iran has decreased in recent years as a result of production issues.The production rate must be maintained below 1500 STB/day to prevent water coning.In this study,a gas lift well is modeled using data from one of the producing wells of this field.Nodal analysis is performed using lift-gas injection rates and wellhead pressures at different reservoir pressures and water cut conditions to optimize production.Economic aspects are considered to optimize the artificial gas injection rates at different tubing head pressures and water cut conditions.Increasing the lift-gas injection rate from 0.4 MMscf/day to 1 MMscf/day enhances the oil production rate by 37.71%and 43.89%for 10%and 30%water cut conditions,respectively.Gas injection rates of 5.2 MMscf/day and 5.4 MMscf/day are determined to be economically optimal for 30%water cut with tubing head pressures of 260 psig and 270 psig,respectively.

Electrocatalytic CO_(2) reduction to C_(2)H_(4): From lab to fab

The global concerns of energy crisis and climate change,primarily caused by carbon dioxide(CO_(2)),are of utmost importance.Recently,the electrocatalytic CO_(2) reduction reaction(CO_(2)RR) to high value-added multi-carbon(C_(2+)) products driven by renewable electricity has emerged as a highly promising solution to alleviate energy shortages and achieve carbon neutrality.Among these C_(2+) products,ethylene(C_(2)H_(4))holds particular importance in the petrochemical industry.Accordingly,this review aims to establish a connection between the fundamentals of electrocatalytic CO_(2) reduction reaction to ethylene(CO_(2)RRto-C_(2)H_(4)) in laboratory-scale research(lab) and its potential applications in industrial-level fabrication(fab).The review begins by summarizing the fundamental aspects,including the design strategies of high-performance Cu-based electrocatalysts and advanced electrolyzer devices.Subsequently,innovative and value-added techniques are presented to address the inherent challenges encountered during the implementations of CO_(2)RR-to-C_(2)H_(4) in industrial scenarios.Additionally,case studies of the technoeconomic analysis of the CO_(2)RR-to-C_(2)H_(4) process are discussed,taking into factors such as costeffectiveness,scalability,and market potential.The review concludes by outlining the perspectives and challenges associated with scaling up the CO_(2)RR-to-C_(2)H_(4) process.The insights presented in this review are expected to make a valuable contribution in advancing the CO_(2)RR-to-C_(2)H_(4) process from lab to fab.

Managing the surge:A comprehensive review of the entire disposal framework for retired lithium-ion batteries from electric vehicles

Anticipating the imminent surge of retired lithium-ion batteries(R-LIBs)from electric vehicles,the need for safe,cost-effective and environmentally friendly disposal technologies has escalated.This paper seeks to offer a comprehensive overview of the entire disposal framework for R-LIBs,encompassing a broad spectrum of activities,including screening,repurposing and recycling.Firstly,we delve deeply into a thorough examination of current screening technologies,shifting the focus from a mere enumeration of screening methods to the exploration of the strategies for enhancing screening efficiency.Secondly,we outline battery repurposing with associated key factors,summarizing stationary applications and sizing methods for R-LIBs in their second life.A particular light is shed on available reconditioning solutions,demonstrating their great potential in facilitating battery safety and lifetime in repurposing scenarios and identifying their techno-economic issues.In the realm of battery recycling,we present an extensive survey of pre-treatment options and subsequent material recovery technologies.Particularly,we introduce several global leading recyclers to illustrate their industrial processes and technical intricacies.Furthermore,relevant challenges and evolving trends are investigated in pursuit of a sustainable end-of-life management and disposal framework.We hope that this study can serve as a valuable resource for researchers,industry professionals and policymakers in this field,ultimately facilitating the adoption of proper disposal practices.