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Pd nanoparticles immobilized on graphite oxide modified with a base: Highly efficient catalysts for selective hydrogenation of citral 被引量:3
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作者 ZHAO YanFei ZHANG HongYe +4 位作者 HUANG ChangLiang CHEN Sha YU Bo XU JiLei LIU ZhiMin 《Science China Chemistry》 SCIE EI CAS 2013年第2期203-209,共7页
In this work, the Pd-based catalysts were designed via immobilizing Pd nanoparticles on graphite oxide (GO) modified with organic base, 1,1,3,3-tetramethylguanidine (TMG), which was used for the selective hydrogenatio... In this work, the Pd-based catalysts were designed via immobilizing Pd nanoparticles on graphite oxide (GO) modified with organic base, 1,1,3,3-tetramethylguanidine (TMG), which was used for the selective hydrogenation of citral. These catalysts were characterized by various techniques including IR, X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. It was demonstrated that the Pd particles with size less than 5 nm were uniformly distributed throughout the support, and they were in the electron-deficient state due to the strong interactions with the modified support. The resultant Pd-TMG/GO catalyst displayed high efficiency for the selective hydrogenation of citral with a turnover frequency of 7100 h-1 as well as superior selectivity to citronellal of 89.6%. Moreover, the catalyst can be reused for five times without obvious activity loss, which may result from its stable structure. 展开更多
关键词 tetramethylguanidine graphite oxide PALLADIUM citral hydrogenation
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