The iso-conversion method to could calculate the kinetics parameters effectively, the present paper built an evaluation equation for iso-conversion methods according to the thermo kinetics integral equation and analys...The iso-conversion method to could calculate the kinetics parameters effectively, the present paper built an evaluation equation for iso-conversion methods according to the thermo kinetics integral equation and analyses the temperatures of the same degree of conversion for different heating rates by ideal TG （thermo-gravity） curve data. It is obtained that the temperatures of the same degree of conversion for different heating rates＇ TG curve have good linearity connection validating the correction of the evaluation equation for iso-conversion methods and the scope of linear slope for theratio between heating rates being 2 is 1.05 to 1.09.展开更多
Sohd-solid reaction under low heat or low temperature is an approach to synthesize various kinds of materials that were widely used in electrochemistry field. In this paper a theoretical treatment has been presented f...Sohd-solid reaction under low heat or low temperature is an approach to synthesize various kinds of materials that were widely used in electrochemistry field. In this paper a theoretical treatment has been presented for analyzing the mechanism of sohd-solid reaction and deriving a series of formulae to describe the variation and rate of reactions. This new model has been used in the manufacturing of spinel Li4Ti5O12. The results show that this new model works very well and will play a useful role for guiding the manufacturing of electrochemical materials.展开更多
文摘The iso-conversion method to could calculate the kinetics parameters effectively, the present paper built an evaluation equation for iso-conversion methods according to the thermo kinetics integral equation and analyses the temperatures of the same degree of conversion for different heating rates by ideal TG （thermo-gravity） curve data. It is obtained that the temperatures of the same degree of conversion for different heating rates＇ TG curve have good linearity connection validating the correction of the evaluation equation for iso-conversion methods and the scope of linear slope for theratio between heating rates being 2 is 1.05 to 1.09.
文摘Sohd-solid reaction under low heat or low temperature is an approach to synthesize various kinds of materials that were widely used in electrochemistry field. In this paper a theoretical treatment has been presented for analyzing the mechanism of sohd-solid reaction and deriving a series of formulae to describe the variation and rate of reactions. This new model has been used in the manufacturing of spinel Li4Ti5O12. The results show that this new model works very well and will play a useful role for guiding the manufacturing of electrochemical materials.
