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微孔容积填充吸附理论的研究 被引量:8
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作者 谢自立 郭坤敏 《化工学报》 EI CAS CSCD 北大核心 1995年第4期452-457,共6页
根据微孔容积填充理论(TVFM)对蒸气在吸附剂微孔中的吸附,提出了1个新的吸附等温线方程,建立了该方程中的各参数对吸附剂的微孔结构特征和吸附特性较独立的表征关系。通过几种有机蒸气在几种商用活性炭上的实测吸附等温线,对方程进行了... 根据微孔容积填充理论(TVFM)对蒸气在吸附剂微孔中的吸附,提出了1个新的吸附等温线方程,建立了该方程中的各参数对吸附剂的微孔结构特征和吸附特性较独立的表征关系。通过几种有机蒸气在几种商用活性炭上的实测吸附等温线,对方程进行了验证,结果令人满意。 展开更多
关键词 微孔结构 微孔容积填充 吸附剂 吸附等温线
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活性炭吸附贮存天然气的最佳压力研究 被引量:6
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作者 邹勇 陆绍信 朱亚杰 《石油与天然气化工》 CAS CSCD 北大核心 1996年第2期59-60,共2页
本文根据微孔容积填充理论(TVFM)对蒸气在活性炭微孔中的吸附,计算出了室温下天然气在活性炭上吸附贮存的最佳压力为3.
关键词 活性炭 天然气 贮存 吸附剂
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Theoretical and Experimental Study on the Adsorption and Desorption of Methane by Granular Activated Carbon at 25℃ 被引量:4
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作者 E.Salehi V.Taghikhani +2 位作者 C.Ghotbi E.Nemati Lay A.Shojaei 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第4期415-422,共8页
A theoretical and experimental study was conducted to accurately determine the amount of adsorption and desorption of methane by various Granular Activated Carbon (GAC) under different physical conditions. To carry ... A theoretical and experimental study was conducted to accurately determine the amount of adsorption and desorption of methane by various Granular Activated Carbon (GAC) under different physical conditions. To carry out the experiments, the volumetric method was used up to 500 psia at constant temperature of 25℃. In these experiments, adsorption as well as desorption capacities of four different GAC in the adsorption of methane, the major constituent of natural gas, at various equilibrium pressures and a constant temperature were studied. Also, various adsorption isotherm models were used to model the experimental data collected from the experiments. The accuracy of the results obtained from the adsorption isotherm models was compared and the values for the regressed parameters were reported. The results shows that the physical characteristics of activated carbons such as BET surface area, micropore volume, packing density, and pore size distribution play an important role in the amount of methane to be adsorbed and desorbed. 展开更多
关键词 methane adsorption volumetric method activated carbon two-term tvfm isotherm
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