Effect of CO_(2)flooding in an oil reservoir with strong bottom-water drive in the Tahe Oilfield,Tarim Basin,Northwest China

The dissolution and diffusion of CO_(2)in oil and water and its displacement mechanism were investigated by laboratory experiment and numerical simulation for Block 9 in the Tahe oilfield,a sandstone oil reservoir with strong bottom-water drive in Tarim Basin,Northwest China.Such parameters were analyzed as solubility ratio of CO_(2)in oil,gas and water,interfacial tension,in-situ oil viscosity distribution,remaining oil saturation distribution,and oil compositions.The results show that CO_(2)flooding could control water coning and increase oil production.In the early stage of the injection process,CO_(2)expanded vertically due to gravity differentiation,and extended laterally under the action of strong bottom water in the intermediate and late stages.The CO_(2)got enriched and extended at the oil-water interface,forming a high interfacial tension zone,which inhibited the coning of bottom water to some extent.A miscible region with low interfacial tension formed at the gas injection front,which reduced the in-situ oil viscosity by about 50%.The numerical simulation results show that enhanced oil recovery(EOR)is estimated at 5.72%and the oil exchange ratio of CO_(2)is 0.17 t/t.

Reservoir characterization of the Odovician oil and gas pools in the Tahe Oilfield, Tarim Basin, Northwest China

About 88. 1% of the proven reserves in the Tahe Oilfield in the Tarim Basin of Northwest China are trapped in Ordovician carbonate reservoirs. These reservoirs are formed by unconnected and interconnected networks of karstic porosity forming a heterogeneous and complex reservoir system. Oil, water and gas characteristics vary significantly in different portions of the Ordovician reservoir. There is no uniform oil/water contact in the field, adding to its complexity.An acid fracture treatment is beneficial in 76% of the wells, stimulating nonproductive wells and enhancing production in other wells by fracturing into unconnected reservoirs and enhancing flow pathways with acid. Acid fracture treatments should be a standard procedure for developing this and similar oil fields.

Hydrocarbon Inclusion Characteristics in the Cambrian-Ordovician Carbonates of the TS2 Well:Implication for Deep Hydrocarbon Exploration in the Tahe Oilfield,Tarim Basin,Northwest China

Going deep has been the strategy for the sustainable development of the Tahe Oilfield.Following the TS1 well in block 1,which revealed excellent combinations of hydrocarbon generation,migration and accumulation in the deeper parts of the Tarim Basin,the TS2 well was drilled to learn more about the prospectivity in the deeper parts of the main blocks of the Tahe Oilfield.Seventeen core samples were collected to perform fluid inclusion studies,including petrography,fluorescence microspectrometry,and microthermometry.The results show that the deeper parts of the Tahe Oilfield have a good hydrocarbon potential.The Cambrian source rocks can supply sufficient oil for not only the Cambrian reservoirs,but also for the Lower Ordovician reservoirs.The CambrianOrdovician carbonates reservoirs experienced at least three oil charging events and one late gas charging event.Oil accumulations formed in the early stage of basin evolution were likely destroyed in the late stage with deep burial,tectonic movements,or invasion of hydrothermal fluids.Therefore,the deep hydrocarbon exploration of the Tahe Oilfield,even the whole Tarim Basin,should focus on gas accumulations,although oil accumulations,especially in Cambrian reservoirs,cannot be neglected.

Dynamic simulation of differential accumulation history of deep marine oil and gas in superimposed basin:A case study of Lower Paleozoic petroleum system of Tahe Oilfield,Tarim Basin,NW China

According to the complex differential accumulation history of deep marine oil and gas in superimposed basins,the Lower Paleozoic petroleum system in Tahe Oilfield of Tarim Basin is selected as a typical case,and the process of hydrocarbon generation and expulsion,migration and accumulation,adjustment and transformation of deep oil and gas is restored by means of reservoine-forming dynamics simulation.The thermal evolution history of the Lower Cambrian source rocks in Tahe Oilfield reflects the obvious differences in hydrocarbon generation and expulsion process and intensity in different tectonic zones,which is the main reason controlling the differences in deep oil and gas phases.The complex transport system composed of strike-slip fault and unconformity,etc.controlled early migration and accumulation and late adjustment of deep oil and gas,while the Middle Cambrian gypsum-salt rock in inner carbonate platform prevented vertical migration and accumulation of deep oil and gas,resulting in an obvious"fault-controlled"feature of deep oil and gas,in which the low potential area superimposed by the NE-strike-slip fault zone and deep oil and gas migration was conducive to accumulation,and it is mainly beaded along the strike-slip fault zone in the northeast direction.The dynamic simulation of reservoir formation reveals that the spatio-temporal configuration of"source-fault-fracture-gypsum-preservation"controls the differential accumulation of deep oil and gas in Tahe Oilfield.The Ordovician has experienced the accumulation history of multiple periods of charging,vertical migration and accumulation,and lateral adjustment and transformation,and deep oil and gas have always been in the dynamic equilibrium of migration,accumulation and escape.The statistics of residual oil and gas show that the deep stratum of Tahe Oilfield still has exploration and development potential in the Ordovician Yingshan Formation and Penglaiba Formation,and the Middle and Upper Cambrian ultra-deep stratum has a certain oil and gas resource prospect.This study provides a reference for the dynamic quantitative evaluation of deep oil and gas in the Tarim Basin,and also provides a reference for the study of reservoir formation and evolution in carbonate reservoir of paleo-craton basin.

Migration,filling history and geochemical characteristics of Ordovician natural gases in the Tahe Oilfield,Tarim Basin,Northwest China

Ordovician natural gases in the Tahe Oilfield are composed predominantly of hydrocarbon gases dominated by methane with a significant amount of heavy hydrocarbon gas component. The non-hydrocarbon gases include N2, CO2 and minor H2S. The Ordovician natural gases are believed to have originated from the same source rocks, and are composite of gases differing in thermal maturity. Carbon dioxide was derived from thermal metamorphism of Ordovician carbonate rocks. The generation of natural gases involves multiple stages from mature normal oil and condensate-associated gas to thermally cracked gas at the maturity to over-maturity stages. In the main part of the Tahe Oilfield, the Ordovician natural gases appear to be filled in two major phases with a typical petroleum-associated gas from southeast to northwest and from east to west in the early stage; and a thermally cracked gas from east to west in the late stage. At the same time, the oil/gas filling boundary has been primarily established between the two stages.

Burial Dissolution of Ordovician Granule Limestone in the Tahe Oilfield of the Tarim Basin,NW China,and Its Geological Significance

With a comprehensive study on the petrology, geology and geochemistry of some Ordovician granule limestone samples in the Tahe Oiifieid of the Tarim Basin, two stages of burial dissolution were put forward as an in-source dissolution and out-source dissolution based on macro-microcosmic petrology and geochemistry features. The main differences in the two stages are in the origin and moving pass of acid fluids. Geochemical evidence indicates that burial dissolution fluids might be ingredients of organic acids, CO2 and H2S associated with organic matter maturation and hydrocarbon decomposition, and the in-source fluid came from organic matter in the granule limestone itself, but the out-source was mainly from other argillaceous carbonate rocks far away. So, the forming of a burial dissolution reservoir resulted from both in-source and the out-source dissolutions. The granule limestone firstly formed unattached pinholes under in-source dissolution in situ, and afterwards suffered wider dissolution with out-source fluids moving along unconformities, seams, faults and associate fissures. The second stage was much more important, and the mineral composition in the stratum and heat convection of the fluid were also important in forming favorable reservoirs.

Types of Karst-fractured and Porous Reservoirs in China's Carbonates and the Nature of the Tahe Oilfield in the Tarim Basin

Almost all the oil and gas reservoirs developed in marine sedimentary strata of China have undergone processes of multi-phase reservoir formation and later modification. The irregular reservoirs are classified into three types as the Naxi, Tahe and Renqiu ones, increasing successively in the development degree of karstificated pores and fissures and the connection degree of independent reservoirs. In these reservoirs, the unity in the fluid feature, pressure and oil-gas-water interface also increases successively from the Naxi to the Renqiu type. The main body of Ordovician reservoirs of the Tahe Oilfield in the Tarim Basin is a network pool rather than a stratified, massive, stratigraphically-unconformed or weathering-crust one. The fluid nature of oil, gas and water, the interface positions and the pressures, as well as the dynamic conditions of fluids within the reservoirs during the production are all different from those in stratified or massive oil and gas reservoirs. Carbonates in the Akekule uplift and the Tahe Oilfield are assemblages of various types of reservoirs, which have an overall oil-bearing potential and obvious uneven distribution. Testing and producing tests are the major means to evaluate this type of reservoirs and acid fracturing improvement is a key link in petroleum exploration and development.

A Study of the Genesis of Karst-type Subtle Reservoir in Tahe Oilfield

The genesis of the Ordovician karst in the Tahe Oilfield is hypothesized on the basis of many analyses of the geo-chemical data and the sporopollen. Ordovician carbonate rocks experienced multistage karst reconstructions under the condition of low-temperature oxidation meteoric water on the surface or near-surface. The karst occurred mainly in the early Hercynian, which has undergone three stages of karst cycle and developed three sets of cave reservoirs under the influence of the tectonic uplift, and the upper of the cave was formed earlier. The evidence of karst was found in the Caledonian. On the above basis, the genetic prediction pattern of the Ordovician palaeokarst reservoir in this region was set up.

Distribution of the Ordovician Fluid in the Tahe Oilfield and Dynamic Response of Cave System S48 to Exploitation

The Tahe Oilfield is a complex petroleum reservoir of Ordovician carbonate formation and made up of spatially overlapping fracture-cavity units. The oilfield is controlled by a cave system resulting from structure-karst cyclic sedimentation. Due to significant heterogeneity of the reservoir, the distribution of oil and water is complicated. Horizontally, a fresh water zone due to meteoric water can be found in the north part of the Akekule uplift. A marginal freshening zone caused by water released from mudstone compaction is found at the bottom of the southern slope. Located in a crossformational flow discharge zone caused by centripetal and the centrifugal flows, the main part of the Tahe Oilfield, featuring high salinity and concentrations of CI^- and K^＋＋Na^＋, is favorable for accumulation of hydrocarbon. Three types of formation water in the Tahe Ordovician reservoir are identified： （1） residual water at the bottom of the cave after oil and gas displacement, （2） residual water in fractures/pores around the cave after oil and gas displacement, and （3） interlayer water below reservoirs. The cave system is the main reservoir space, which consists of the main cave, branch caves and depressions between caves. Taking Cave System S48 in the Ordovician reservoir as an example, the paper analyzes the fluid distribution and exploitation performance in the cave system. Owing to evaporation of groundwater during cross-formational flow, the central part of the main cave, where oil layers are thick and there is a high degree of displacement, is characterized by high salinity and Br^- concentration. With high potential and a long stable production period, most wells in the central part of the main cave have a long water-free oil production period. Even after water breakthrough, the water content has a slow or stepwise increase and the hydrochemistral characteristics of the produced water in the central part of the main cave are uniform. From the center to the edge of the main cave, displacement and enrichment of oil/gas become weaker, residual water increases, and the salinity and concentration of Br^- decrease. At the edge of the main cave, although the wells have a high deliverability at the beginning with a short stable production period and water-free production period. After water breakthrough, the pressure and deliverability drop quickly, and the water content rises quickly. The hydrochemistral characteristics of the produced water are relatively uniform. Wells in the branch caves have a relatively low deliverability at the beginning, with a short stable production period. Water breakthrough appears quickly and then the pressure and deliverability drop quickly. The salinity and concentrations of CI^-and K^＋＋Na^＋ are usually fluctuant or descend slowly in the produced water. Wells in low areas of ancient karst have a low deliverability and a short stable production period. The yield drops quickly and the water content is high, while the characteristics of the produced water may vary significantly well to well. The salinity and concentrations of CI^-and K^＋＋Na^＋ in the produced water are usually fluctuant with a precipitous decline.

Architecture characterization of Ordovician fault-controlled paleokarst carbonate reservoirs in Tuoputai,Tahe oilfield,Tarim Basin,NW China

Based on outcrop,core,logging,seismic and production data,and the formation of fault-controlled karst reservoirs,the types and characterization of Ordovician fault-controlled karst reservoir architectures in the Tuoputai area of the Tahe oilfield are studied.According to the concept of genetic geologic body,the fault-controlled karst reservoir is divided into architecture elements of four levels,the strike-slip fault impact zone is the level-1 architecture element,the fault-controlled karst reservoir the level-2 architecture element,the fracture-cave zone(which can be further subdivided into dissolution cave,dissolution pore and vug,and fracture zones)inside the fault-controlled karst reservoir the level-3 architecture element,and fillings inside caves is the level-4 architecture element(which can be further divided based on the filling degree and lithologic types of the fillings).Specific characterization techniques have been optimized according to the characteristics of various architecture elements.The zone impacted by strike-slip fault is characterized by seismic coherence and artificial interpretation.Under the constraint of zone impacted by strike-slip fault,fault likelihood(FL)property is used to characterize the outline of fault-controlled karst reservoir.Under the constraint of fault-controlled karst reservoir outline,the internal structures are divided based on seismic texture attribute.Finally,the cavern filling pattern is interpreted based on drilling and logging data.The fault-controlled karst reservoirs can be interpreted in 3-dimensional space by architecture element levels,and the characterization technology combining log and seismic data for fault-controlled karst reservoir has been worked out,which has complemented the development theory and technologies for this kind of reservoirs in the Tahe oilfield.

Origin, hydrocarbon accumulation and oil-gas enrichment of fault-karst carbonate reservoirs: A case study of Ordovician carbonate reservoirs in South Tahe area of Halahatang oilfield, Tarim Basin

Based on comprehensive analysis of tectonic and fault evolution, core, well logging, seismic, drilling, and production data, the reservoir space characteristic, distribution, origin of fault-karst carbonate reservoir in Yueman block of South Tahe area, Halahatang oilfield, Tarim Basin, were studied systematically. And the regular pattern of hydrocarbon accumulation and enrichment was analyzed systematically based on development practice of the reservoirs. The results show that fault-karst carbonate reservoirs are distributed in the form of "body by body" discontinuously, heterogeneously and irregularly, which are controlled by the development of faults. Three formation models of fault-karst carbonate reservoirs, namely, the models controlled by the main deep-large fault, the secondary fault and the secondary internal fault, are built. The hydrocarbon accumulation and enrichment of fault-karst carbonate reservoirs is controlled by the spatiotemporal matching relation between hydrocarbon generation period and fault activity, and the size and segmentation of fault. The study results can effectively guide the well deployment and help the efficient development of fault-karst carbonate reservoirs of South Tahe area, Halahatang oilfield.

纳米Ag@ZnO/Zn_(2)Ti_(3)O_(8)的制备及光催化降解油田污水的研究

采用共沉淀法合成银锌钛纳米复合光催化剂,并通过XRD、SEM对其进行了表征。以油田污水中的石油类为降解物,探究其光催化效果。以溴酸钾、EDTA-2Na作为自由基捕获剂,探究银锌钛纳米复合物的光催化机理。XRD结果表明,该催化剂为Ag@ZnO/Zn_(2)Ti_(3)O_(8)。SEM结果表明,其形貌为10~40 nm的纳米球组成的纳米棒。光催化结果表明,该催化剂具有良好的石油类降解效果。在15 W紫外灯辐射下,5 h石油类的去除率可达89%。该催化剂经5次循环使用后,光催化效果仍可保持76%以上。通过自由基捕获实验可知,此过程中起主要作用的是空穴。

Quantitative assessment and significance of gas washing of oil in Block 9 of the Tahe Oilfield,Tarim Basin,NW China

Some Ordovician and Triassic oils in Block 9 are characterized by light oils,which have distinctly differentiated from heavy oils in other blocks in the Tahe Oilfield,Tarim Basin.Based on the whole oil gas chroma- tograms,this paper estimates the effect of oil migration and fractionation and the amount of depletion(Q)in terms of the n-alkanes depletion model.The results showed that the amount of depletion in the Ordovician reservoir is highest in the east of this block,e.g.the depletion is 97% in Well T904.The amount of Q gets lower to the west,e.g.the depletion is 53.4%in Well T115 and there is no sign of depletion in Well S69.It is suggested that the direction of gas washing is from the east to the west.The compositions and isotopic characteristics of associated gas in Ordovician oils indicated that the gas might be derived from Cambrian source rocks of the Caohu Depression which lies to the east of Block 9.In contrast,no obvious depletion of n-alkanes in Triassic oils was found,suggesting that the migration pathway of natural gas has been limited to the Ordovician karst fracture system formed in the Early Hercynian Orogeny.Different depletions of the Ordovician and Triassic oils can reveal fault activities in this region.

Quantitative characterization of deep fault-karst carbonate reservoirs: A case study of the Yuejin block in the Tahe oilfield

The Ordovician reservoirs in the Tahe oilfield are dominated by fractured-vuggy carbonate reservoirs, of which fault-karst reservoirs are a hot topic in recent years. Fault-karst reservoirs feature high production, large burial depth, and strong heterogeneity under the control of faulting and karstification. Based on geological, logging, and seismic data, this study classified the Ordovician fault-karst reservoirs in the Yuejin block of the Tahe oilfield into three types, namely karst-cave, dissolved-vug, and fractured types, and established the integrated identification criteria of the three types of reservoirs. This study characterized karst caves, dissolved vugs, and multi-scale faults through seismic wave impedance inversion and frequency-domain detection of multi-scale faults. 3D geological models of different types of reservoirs were built using the combined deterministic and stochastic methods and characterized the spatial distribution of multi-scale faults, karst caves, dissolved vugs, and physical property parameters of reservoir. This study established the method for the geological modeling of fault-karst reservoirs, achieved the quantitative characterization and revealed the heterogeneity of fault-karst reservoirs. The karst-cave and dissolved-vug types are high in porosity and act as reservoirs, while the fractured type is high in permeability and act as flow pathway. This study lays the foundation for the development index prediction, well emplacement, and efficient development of the fault-karst carbonate reservoirs.

Geochemical characteristics of Ordovician crude oils in the northwest of the Tahe oil field, Tarim Basin

Forty-six crude oil samples were selected from the Ordovician in the northwestern part of the Tahe oilfield for detailed molecular geochemical and isotopic analysis, including group compositions, carbonhydrogen isotopes and gas chroma-tograms of saturated hydrocarbons, as well as the characteristics of terpane, sterane and other biomarkers, indicating that crude oils are of the same origin from different districts in the Tahe oilfield and were derived from the same source kitchen (or oil source formation), i.e., mainly stemming from marine hydrocarbons. Detailed studies of oil physical properties of 25-honpane revealed that such oils have heavy or thick oil qualities due to biodegradation. Comprehensive assessment in terms of five maturity parameters shows that the oils from the Ordovician with Ro values varying from 0.80% to 1.59% are widely distributed in the northwest of the Tahe oilfield.

Development of Karst Formation in Area 4 of Tahe Oilfield

The main oil-bearing formation of Area 4 of Tahe oilfield is in Yingshan Group of Ordovician consisted of thick pure limestone. The types of the pore space contain the pore, fissure, cave as well as fracture formed by solution collapse. The primary porosity and tectonic fracture are of poor growth. Therefore, the formation growth is mainly controlled by hydraulic units of the palaeo-karst. There are three palaeo-hydraulic zones: vadose zone (including infiltration sub-zone and percolation sub-zone), phreatic zone and tranquil zone. They are identified by retrieving the palaeo-geographical karst environment. The pore space of the infiltration zone is mainly solution fissures, small solution cavities and solution pores. The growth and lateral connection of the formation are favorable. The reservoir/formation ratio is 0. 54. The pore space of the phreatic zone developed large size cavities and fractures related to cave collapse. The height of the cavity can reach 71m. The fractures by collapse have a influencing range of more than 100m, and its reservoir/formation ratio is 0. 51. But the lateral connection is unfavorable. The percolation subzone and the tranquil zone are of relatively poor growth with the reservoir/ formation ratio less than 0. 3.

渤海湾盆地石臼坨凸起秦皇岛27-3大型油田发现与地质新认识

渤海湾盆地石臼坨凸起历经50余年勘探,在凸起高部位背斜区发现了3个浅层亿吨级大油田,而低部位斜坡区浅层由于构造圈闭不发育,勘探程度较低,近10年无规模性发现。随着渤海海域勘探程度提高,现已全面进入岩性勘探阶段,针对石臼坨凸起东段顺向断裂斜坡区浅层油气运移、岩性圈闭刻画和油气成藏规律等展开了深入系统研究。研究认为:(1)研究区南北两侧被富生烃凹陷夹持,凸起边界大断层晚期强烈活动和陡坡带近源扇体普遍发育使凸起区成为规模性油气运聚的最终指向区;(2)凸起边界大断层在馆陶组开启系数最小,馆陶组含砾砂岩输导层是石臼坨凸起之上主要的油气横向运移通道;(3)馆陶组输导脊坡度和切脊断层组合控制顺向斜坡区油气的垂向输导,当坡度小于1°且断层长度大于2.50 km、成藏期断距大于40 m时斜坡区可产生规模性的油气垂向运移,突破顺向断裂斜坡区“过路不留”的传统认识;(4)在凸起斜坡区,与构造脊方向斜交的砂体有利于油气保存,同时,提出井约束谱蓝化整形高分辨率处理技术,实现了对斜坡区岩性圈闭有效刻画,优选出保存条件较好的斜向砂体开展钻探部署。基于上述新认识、新技术,2023年在石臼坨凸起东段顺向斜坡区成功评价了秦皇岛27-3亿吨级油田,实现了勘探老区浅层挖潜的重大突破,为渤海湾盆地高成熟探区持续油气发现提供了借鉴。

Division and Correlation of Lacustrine Gravity Flow Reservoirs Based on High-Resolution Sequence Stratigraphic Analysis—Taking Oil Formation I of Lower Es3 in Wuhaozhuang Oilfield as an Example

The phase change of lacustrine gravity flow deposition is fast and complex. In its reservoir division and correlation, the isochronous problem is very important. Taking the oil formation I of Es3 in Wuhaozhuang oilfield as an example, through the analysis of stratigraphic drilling and logging data in the study area, according to the genetic types of different levels of base level cycle interfaces and the characteristics of high-resolution sequence stratigraphy, this paper subdivides the lacustrine gravity flow oil layer of lower Es3 in Wuhaozhuang Oilfield, divides it into four short-term base level cycle sequences, and establishes the high-resolution isochronous stratigraphic framework of this interval. It is found that the mid-term, short-term and ultra short-term base level cycles correspond to the oil formation, sand layer group and single layer in the oil layer correlation unit of the oilfield respectively. Based on this, the oil layer correlation unit of the interval is divided, and the sublayer correlation model is established according to the identification characteristics of the short-term base level cycle.

基于数字岩心的储层微观孔隙结构定量表征——以渤海蓬莱19-3油田为例

深化储层微观孔隙结构认识对渤海油田的长久高效开发具有重要现实意义,针对渤海蓬莱19-3油田新近系馆陶组储层,在物性特征及孔隙类型认识的基础上,依托基于CT扫描的三维数字岩心分析技术,采用最大球法完成三维孔隙网络模型的处理分割和构建,通过提取网络模型的特征参数,实现岩石微观孔隙结构的可视化、定量化表征,进而利用数值模拟方法分析岩心不同驱替方向带来的渗流差异。结果表明:1)蓬莱19-3油田岩石成分成熟度处于中等,分选较差,成岩作用相对较弱,胶结类型主要包括接触式胶结和孔隙式胶结,整体表现为疏松砂岩特征;2)储层以中-高孔渗为主,孔喉半径较大但分选较差,储集空间以原生粒间孔为主,次生溶蚀孔为辅;3)微观孔喉特征参数决定了储层宏观物性,连通的大孔喉配比越高,对储层物性贡献越大;4)储层内流体驱替具有明显的方向性,优质储层更易受到驱替方向所带来的影响。

35MPa高压喷射钻井技术实践

为了进一步探索高压喷射钻井技术的提速潜力,对高压喷射钻井设备和技术参数进行了优化配置。根据大排量、适当钻头压降的水力参数设计思路,对70D型钻机的钻井液动力及循环系统进行了升级改造;针对塔河油田中上部地层特点,优化了不同井身结构、不同井眼直径的水力参数,形成了适合软—中硬地层的35 MPa高压喷射钻井技术。该技术在塔河油田现场试验了5口井,与常规钻井技术相比,试验井段平均机械钻速提高了78%～262%。试验结果表明,该技术提速潜力巨大,具有较高的推广应用价值。