Leaching kinetics of selenium from copper anode slimes by nitric acid-sulfuric acid mixture

The leaching kinetics of selenium from copper anode slimes was studied in a nitric acid?sulfuric acid mixture.The effects of main parameters on selenium leaching showed that the leaching rate of selenium was practically independent of stirring speed,while dependent on temperature and the concentrations of HNO3and H2SO4.The leaching of selenium includes two stages.The activation energy in the first stage is103.5kJ/mol,and the chemical reaction is the rate controlling step.It was almost independent of H2SO4concentration and dependent on HNO3concentration since the empirical reaction order with respect to HNO3concentration is0.5613.In the second stage,the activation energy is30.6kJ/mol,and the process is controlled by a mixture of diffusion and chemical reaction.The leaching of selenium was almost independent of HNO3concentration.

Comparison of mechanical and column flotation performances on recovery of phosphate slimes in presence of nano-microbubbles

Fine particle flotation has been one of the main problems in many mineral processing plants.The bubble particle collision rate is very low for fine particles,which reduces flotation efficiency.Also,the existence of slimes is,generally,detrimental to the flotation process,affecting the selectivity and the quality of the concentrates.Besides,it causes an increase in reagents consumption.Hence,in most of processing plants,some of these particles are transmitted to the tailing ponds to reduce the effects of these problems and increase the selectivity of the process.Esfordi phosphate plant in Iran loses more than 30%of its capacity as particles with d 80 finer than 30μm.These fine particles with 15.9%P_(2)O_(5)content are transferred to tailing dam.Processing of fine particles is very important for phosphate industry from economic and environmental aspects.This study addressed the processing of fine tailings(slimes)from a phosphate ore concentrator via flotation,despite the traditional view that ultrafine particles do not float.Phosphate flotation performances in the presence and absence of nanobubbles(NBs)in both mechanical and column cells were compared according to the metallurgical results of the process.NBs(generated by hydrodynamic cavitation)have interesting and exclusive properties such as high stability,durability and high surface area per volume,leading to increase of their utilization in mining-metallurgy and environmental areas.The results of this study revealed that,in the absence of NBs,a concentrate containing 26.9%P_(2)O_(5)with a recovery of 29.13%was obtained using mechanical cells in comparison to 31.6%P_(2)O_(5)with a recovery of 32.74%obtained using column flotation.In the presence of NBs,the recoveries of the concentrate of the mechanical and column flotation increased to 40.49%and 41.26%with 28.47%and 30.43%P_(2)O_(5)contents,respectively.Comparative study showed that the column flotation was almost more efficient for processing the phosphate ore in the presence of the NBs,and had thicker froth layer compared to the mechanical flotation.

Dolochar as a reductant in the reduction roasting of iron ore slimes

The present investigation examines the viability of dolochar, a sponge iron industry waste material, as a reductant in the reduction roasting of iron ore slimes, which are another waste generated by iron ore beneficiation plants. Under statistically determined optimum conditions, which include a temperature of 900°C, a reductant-to-feed mass ratio of 0.35, and a reduction time of 30–45 min, the roasted mass, after being subjected to low-intensity magnetic separation, yielded an iron ore concentrate of approximately 64 wt% Fe at a mass recovery of approximately 71% from the feed iron ore slime assaying 56.2 wt% Fe. X-ray diffraction analyses indicated that the magnetic products contain magnetite and hematite as the major phases, whereas the nonmagnetic fractions contain quartz and hematite.

Heuristic algorithms for scheduling on uniform parallel machines with heads and tails

This paper considers the uniform parallel machine scheduling problem with unequal release dates and delivery times to minimize the maximum completion time.For this NP-hard problem,the largest sum of release date,processing time and delivery time first rule is designed to determine a certain machine for each job,and the largest difference between delivery time and release date first rule is designed to sequence the jobs scheduled on the same machine,and then a novel algorithm for the scheduling problem is built.To evaluate the performance of the proposed algorithm,a lower bound for the problem is proposed.The accuracy of the proposed algorithm is tested based on the data with problem size varying from 200 jobs to 600 jobs.The computational results indicate that the average relative error between the proposed algorithm and the lower bound is only 0.667%,therefore the solutions obtained by the proposed algorithm are very accurate.

A Calculation Method of Rolling Characteristics of Canard Missile with Free-Spinning Tails

The steady flow field of a canard missile on different angles of attack and Mach numbers were studied. Based on analysis, a method was proposed to reduce the calculation for the rolling characteristics of the canard missile with free-spinning tails, and was tested to obtain the relations between rolling moment coefficient, Mach number, and angle of attack. All the computed rolling moment coefficients obtained from the proposed method greatly agreed with the experimental results of FD-06 wind tunnel in CAAA, which proved that the method can not only reduce the calculation cost but also keep precision in calculating the rolling characteristics of canard missiles.

Numerical Study of Propulsion Mechanism for Oscillating Rigid and Flexible Tuna-Tails

Numerical study on the unsteady hydrodynamic characteristics of oscillating rigid and flexible tuna-tails in viscous flow-field is performed. Investigations are conducted using Reynolds-Averaged Navier-Stokes （RANS） equations with a moving adaptive mesh. The effect of swimming speed, flapping amplitude, frequency and flexure amplitude on the propulsion performance of the rigid and flexible tuna-tails are investigated. Computational results reveal that a pair of leading edge vortices develop along the tail surface as it undergoes an oscillating motion. The propulsive efficiency has a strong correlation with various locomotive parameters. Peak propulsive efficiency can be obtained by adjusting these parameters. Particularly, when input power coeffcient is less than 2.8, the rigid tail generates larger thrust force and higher propulsive efficiency than flexible tail. However, when input power coefficient is larger than 2.8, flexible tail is superior to rigid tail.

Reinforcing effects of polypropylene on energy absorption and fracturing of cement-based tailings backfill under impact loading

Polypropylene(PP)fiber-reinforced cement-based tailings backfill(FRCTB)is a green compound material with superior crack resistance and has good prospects for application in underground mining.However,FRCTB exhibits susceptibility to dynamic events,such as impact ground pressure and blast vibrations.This paper investigates the energy and crack distribution behavior of FRCTB under dynamic impact,considering the height/diameter(H/D)effect.Split Hopkinson pressure bar,industrial computed tomography scan,and scanning electron microscopy(SEM)experiments were carried out on six types of FRCTB.Laboratory outcomes confirmed fiber aggregation at the bottom of specimens.When H/D was less than 0.8,the proportion of PP fibers distributed along theθangle direction of80°-90°increased.For the total energy,all samples presented similar energy absorption,reflectance,and transmittance.However,a rise in H/D may cause a rise in the energy absorption rate of FRCTB during the peak phase.A positive correlation existed between the average strain rate and absorbed energy per unit volume.The increase in H/D resulted in a decreased crack volume fraction of FRCTB.When the H/D was greater than or equal to 0.7,the maximum crack volume fraction of FRCTB was observed close to the incidence plane.Radial cracks were present only in the FRCTB with an H/D ratio of 0.5.Samples with H/D ratios of 0.5 and 0.6 showed similar distributions of weakly and heavily damaged areas.PP fibers can limit the emergence and expansion of cracks by influencing their path.SEM observations revealed considerable differences in the bonding strengths between fibers and the FRCTB.Fibers that adhered particularly well to the substrate were attracted together with the hydration products adhering to surfaces.These results show that FRCTB is promising as a sustainable and green backfill for determining the design properties of mining with backfill.

Rheological properties and concentration evolution of thickened tailings under the coupling effect of compression and shear

Cemented paste backfill(CPB)is a key technology for green mining in metal mines,in which tailings thickening comprises the primary link of CPB technology.However,difficult flocculation and substandard concentrations of thickened tailings often occur.The rheological properties and concentration evolution in the thickened tailings remain unclear.Moreover,traditional indoor thickening experiments have yet to quantitatively characterize their rheological properties.An experiment of flocculation condition optimization based on the Box-Behnken design(BBD)was performed in the study,and the two response values were investigated:concentration and the mean weighted chord length(MWCL)of flocs.Thus,optimal flocculation conditions were obtained.In addition,the rheological properties and concentration evolution of different flocculant dosages and ultrafine tailing contents under shear,compression,and compression-shear coupling experimental conditions were tested and compared.The results show that the shear yield stress under compression and compression-shear coupling increases with the growth of compressive yield stress,while the shear yield stress increases slightly under shear.The order of shear yield stress from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Under compression and compression-shear coupling,the concentration first rapidly increases with the growth of compressive yield stress and then slowly increases,while concentration increases slightly under shear.The order of concentration from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Finally,the evolution mechanism of the flocs and drainage channels during the thickening of the thickened tailings under different experimental conditions was revealed.

LARGE DEVIATIONS FOR SUMS OF INDEPENDENT RANDOM VARIABLES WITH DOMINATEDLY VARYING TAILS

In this paper the large deviation results for partial and random sums Sn-ESn=n∑i=1Xi-n∑i=1EXi,n≥1;S（t）-ES（t）=N（t）∑i=1Xi-E（N（t）∑i=1Xi）,t≥0 are proved, where {N（t）;t ≥ 0} is a counting process of non-negative integer-valued random variables, and {Xn; n ≥ 1} are a sequence of independent non-negative random variables independent of {N（t）; t ≥ 0}. These results extend and improve some known conclusions.

Flocculation of the Moroccan phosphates slimes

In Morocco, the phosphate industry generates by washing during the ore beneficiation in humid way, big quantities of sludge loaded in fine mineral particles （or slimes） with contents of water in the order of 90-95%. The specific consumption in water for the beneficiation of one tone of dry ore is approximately 0.6 m3. The management of this sludge and the recycling of process water are played to a schema of solid-liquid separation by flocculation, settling then stocking in basins of several dozens hectares. Recovered clear waters are recycled into the circuit of washing. The principal motivation of this work which is a part of EL MAA project is dedicated to the study of the impact of the speed of agitation on the flocculation behavior in terms of dewatering of the phosphate slimes and recycling of the process water. Study was driven on sample of slimes taken in entrance of the thickeners of a Moroccan washing plants, before flocculation. The raw slimes have a concentration in solid of 75.5 g·L^-1, a P205 grade of 17.3% and a free settling velocity 9 cm·h^-1. Fine fraction -2 μm, responsible for the poor settling of slimes is composed in practice of nearly 96% of smectite. It represents 9% of the dry solid content in the slimes. Measurements reveal important variations of the granulometric and textural properties of large floes in response to flocculation, opening ways of optimization for the velocity gradient.

Synthesis and Properties of the Composite Sorbents on the Basis of Alumosilicates Separated from the Clay-Salt slimes

The composite sorbent, including an active inorganic component （alumosilicates derived from clay-salt slimes） in the quantity of more than 80 mas.% and the polymer binder （polyacrylamide） was obtained. The influences of various factors on its sorption and mechanical properties were studied. It is established that the content of polyacrylamide in the composite sorbent should be in the range of 10-15 mas.%. It is shown that quasi-equilibrium of ^137Cs in the system ＂sorbent-solution＂ is reached within 80 rain. The distribution coefficient （Kd） is 2.4× 10^4 cm^3/g. The obtained data of kinetic parameters （diffusion coefficient and sorption during half-time） show that the received sorbent can be referred to sorbents with high rate of ^137Cs sorption.

Recovery of Rare Earth Elements Present in Mining Tails, by Leaching with Nitric and Hydrochloric Solutions

The rare earth elements (REE) include the group of 15 lanthanides, scandium and yttrium and have diverse applications in technological and nuclear areas. The existence of REE in massive solid mining wastes generated in leaching processes of copper minerals in the Atacama region of Chile generates the possibility of creating added value to the treatment of this type of waste and supporting the development of a circular economy, generating a useful by-product in different industries. In order to know the behavior of these elements present in the solid carrier waste, a leaching process was carried out by using two agents separately, corresponding to hydrochloric and nitric acid. The technical feasibility to recover REE from carrier tail was demonstrated, the best leaching agent for these elements being a hydrochloric solution, obtaining a maximum recovery efficiency of 64.5%, for an acid concentration: 3M, temperature: 40°C and (liquid/solid) ratio: 4. Lanthanum and cerium present the best individual recoveries compared to the other REE, with a maximum efficiency for a hydrochloric solution of 75.7% and 70.0%, respectively. The interaction of operational parameters that most influence the REE recovery corresponds to the temperature and the (liquid/solid) ratio. After 4 hours of leaching, REE recovery efficiencies remain practically constant. Acid consumptions correspond to 11 (kg HCl/ton mining tail) and 29 (kg HNO3/ton mining tail). The highest amount recovery ratios of these elements correspond to 0.355 and 0.224 (kg REE/ton mining tail), for hydrochloric and nitric solutions, respectively. These results influence the types of reagents and parameters to be studied in the following stages of the global process.

HAZARD FUNCTION AND CHARACTERIZATIONS ON DISTRIBUTION TAILS OF NONNEGATIVE RANDOM VARIABLES

Some equivalent conditions on the classes of lighted-tailed and heavily heavy-tailed and lightly heavy-tailed d.f.s are introduced.The limit behavior of xα(x) and e λx(x) are discussed.Some properties of the subclass DKc and subclass DK 1 are obtained.

Ash Detection of Coal Slime Flotation Tailings Based on Chromatographic Filter Paper Sampling and Multi-Scale Residual Network

The detection of ash content in coal slime flotation tailings using deep learning can be hindered by various factors such as foam,impurities,and changing lighting conditions that disrupt the collection of tailings images.To address this challenge,we present a method for ash content detection in coal slime flotation tailings.This method utilizes chromatographic filter paper sampling and a multi-scale residual network,which we refer to as MRCN.Initially,tailings are sampled using chromatographic filter paper to obtain static tailings images,effectively isolating interference factors at the flotation site.Subsequently,the MRCN,consisting of a multi-scale residual network,is employed to extract image features and compute ash content.Within the MRCN structure,tailings images undergo convolution operations through two parallel branches that utilize convolution kernels of different sizes,enabling the extraction of image features at various scales and capturing a more comprehensive representation of the ash content information.Furthermore,a channel attention mechanism is integrated to enhance the performance of the model.The combination of the multi-scale residual structure and the channel attention mechanism within MRCN results in robust capabilities for image feature extraction and ash content detection.Comparative experiments demonstrate that this proposed approach,based on chromatographic filter paper sampling and the multi-scale residual network,exhibits significantly superior performance in the detection of ash content in coal slime flotation tailings.

Malargüe Site Remediation:A Successful Solution for Uranium Mill Tailings

Comisión Nacional de Energía Atómica (CNEA) has the responsibility for restoring uranium mining facilities once the operations have finished.CNEA,within its Environmental Program and in compliance with its legal responsibilities,decides to implement a restoration project for all sites related to the mining and processing of uranium ores.The Malargüe Site is located within the Province of Mendoza in the city of Malargüe.It is the first site to successfully complete its remediation.The activities consist of relocation of tailings to an engineering repository.The tailings management(encapsulation) and rehabilitation of the area was finished in June 2017.The remediation alternative for the ore tailings was selected after conducting comparative studies and submitted the project to the society for consideration.The objective of the encapsulation of the mineral tails is to isolate them from the environment,also proceeding with the decontamination and rehabilitation of the area (landscaping,post-closure monitoring and 20 years monitoring period).Encapsulation consisted of the construction of a containment cell for the mine tailings,to isolate them and prevent pollutants from entering the environment through the transfer routes.To clean the impacted areas,the soil was removed,it was incorporated into the encapsulation,and the filling was carried out with natural soils from the area.Remediation prevents radon transfer to the environment,as ^(222)Ra is an alpha emitter with a half-life of four days,which produces its own radioactive progeny.Radon progeny are solids,and when a ^(222)Ra nucleus emits an alpha particle into the air,the resulting ^(218)Po nucleus,momentarily electrically charged,adheres to any dust particle.Remediation prevents the discharge into the air containing radon and also containing dust particles charged with intensely radioactive radon progeny.The tasks mentioned make it possible to decrease radon emanation,reduce radiological risks to the public and prevent the entry of rainwater into the system.In addition,the containment system prevents the discharge of contaminated liquids into the environment,avoiding contamination of the groundwater.All these activities are according to the concepts of sustainability.

Determination of critical state line(CSL)for silty-sandy iron ore tailings subjected to low-high confining pressures

The disposal of filtered tailings in high dry stacks can induce particle breakage,changing the material's behaviour during the structure's lifetime.The grading changes influence material properties at the critical state,and this is not mature for intermediate artificial soils(tailings)in a broad range of confining pressures.In this paper,it aims to describe the behaviour of iron ore tailings in a spectrum of confining pressures broader than the reported in previous studies.A series of consolidated drained(CD)triaxial tests was carried out with confining pressures ranging from 0.075 MPa to 120 MPa.These results show that the amount of breakage plays an essential role in the response of iron ore tailings.The existence of curved critical state line(CSL)in both specific volume(ν)-logarithm of mean effective stress(p′)and deviatoric stress(q)-mean effective stress(p′)planes,and different responses in the deviatoric stress-axial strain-volumetric strain curves were verified.An inverse S-shaped equation was proposed to represent the silty-sandy tailings'behaviour up to high pressures onν-lnp′plane.The proposed equation provides a basis for enhancing constitutive models and considers the evolution of the grading up to severe loading conditions.The adjustment considered three regions with different responses associated with particle breakage at different pressure levels.

Preparation and interface state of phosphate tailing-based geopolymers

The long-term storage of phosphate tailings will occupy a large amount of land,pollute soil and groundwater,thus,it is crucial to achieve the harmless disposal of phosphate tailings.In this study,high-performance geopolymers with compressive strength of 38.8 MPa were prepared by using phosphate tailings as the main raw material,fly ash as the active silicon-aluminum material,and water glass as the alkaline activator.The solid content of phosphate tailings and fly ash was 60% and 40%,respectively,and the water-cement ratio was 0.22.The results of XRD,FTIR,SEM-EDS and XPS show that the reactivity of phosphate tailings with alkaline activator is weak,and the silicon-aluminum material can react with alkaline activator to form zeolite and gel,and encapsulate/cover the phosphate tailings to form a dense phosphate tailings-based geopolymer.During the formation of geopolymers,part of the aluminum-oxygen tetrahedron replaced the silicon-oxygen tetrahedron,causing the polycondensation reaction between geopolymers and increasing the strength of geopolymers.The leaching toxicity test results show that the geopolymer has a good solid sealing effect on heavy metal ions.The preparation of geopolymer from phosphate tailings is an important way to alleviate the storage pressure and realize the resource utilization of phosphate tailings.

Classification of Sailboat Tell Tail Based on Deep Learning

The tell tail is usually placed on the triangular sail to display the running state of the air flow on the sail surface.It is of great significance to make accurate judgement on the drift of the tell tail of the sailboat during sailing for the best sailing effect.Normally it is difficult for sailors to keep an eye for a long time on the tell sail for accurate judging its changes,affected by strong sunlight and visual fatigue.In this case,we adopt computer vision technology in hope of helping the sailors judge the changes of the tell tail in ease with ease.This paper proposes for the first time a method to classify sailboat tell tails based on deep learning and an expert guidance system,supported by a sailboat tell tail classification data set on the expert guidance system of interpreting the tell tails states in different sea wind conditions,including the feature extraction performance.Considering the expression capabilities that vary with the computational features in different visual tasks,the paper focuses on five tell tail computing features,which are recoded by an automatic encoder and classified by a SVM classifier.All experimental samples were randomly divided into five groups,and four groups were selected from each group as the training set to train the classifier.The remaining one group was used as the test set for testing.The highest resolution value of the ResNet network was 80.26%.To achieve better operational results on the basis of deep computing features obtained through the ResNet network in the experiments.The method can be used to assist the sailors in making better judgement about the tell tail changes during sailing.

Effects of anode slime removing by Fe^(2+)dissolution method on electrochemical properties of Pb−0.6%Ag anode and zinc electrowinning

Fe^(2+)dissolution method and manual method were used to remove the anode slime and their effects on properties of cast Pb−0.6wt.%Ag anode and zinc electrowinning were compared.The results reveal that the Fe^(2+)dissolution method can avoid mechanical damage to the oxide film layer on the anode surface,which cannot be achieved by traditional manual method.This can lower the anode corrosion rate by 57.14%,thus reducing Pb contamination in electrolyte and zinc products.Meanwhile,compared with manual method,Fe^(2+)dissolution method can significantly improve the electrocatalytic activity of the anode and lower the initial power consumption of zinc electrowinning to 2720 kW·h/t after removing anode slime.