目的构建果胶精油联产工艺获得的橙皮精油的指纹图谱,并进行成分分析。方法通过气相色谱-质谱法采集20批次橙皮精油样品的总离子流图(total ions current,TIC),运用“中药色谱指纹图谱相似度评价系统(2012版)”寻找共有峰并建立对照指...目的构建果胶精油联产工艺获得的橙皮精油的指纹图谱,并进行成分分析。方法通过气相色谱-质谱法采集20批次橙皮精油样品的总离子流图(total ions current,TIC),运用“中药色谱指纹图谱相似度评价系统(2012版)”寻找共有峰并建立对照指纹图谱,采用美国国家标准与技术研究院(National Institute of Standards and Technology,NIST)谱库检索结合保留指数技术对共有峰进行成分鉴定,运用SPSS 29.0软件对共有峰进行主成分分析。结果指纹图谱的精密度、重复性和稳定性等方法学考察符合要求,所有样品TIC图相似度均大于0.998,提炼出9个共有峰,经过质谱鉴定,在共有峰中,D-柠檬烯相对含量最高,占82.77%,其次为月桂烯、烩烯、右旋α-蒎烯等,依次占比8.79%、3.62%、3.27%;经主成分分析,前两个主成分因子的累积方差贡献率为67.4%,微量成分烩烯和3-蒈烯对主成分因子的贡献最大。结论对由果胶精油联产工艺获得的橙皮精油建立了气相色谱-质谱指纹图谱,探明其共性化合物成分及影响力,为其质量控制提供了科学依据。展开更多
This work is investigating Mexidol (2-ethyl-6-methyl-3-hydroxy pyridine succinate) effect on the formation of nitric oxide (NO) in animal liver tissues, which is a regulator of many physiological processes and plays a...This work is investigating Mexidol (2-ethyl-6-methyl-3-hydroxy pyridine succinate) effect on the formation of nitric oxide (NO) in animal liver tissues, which is a regulator of many physiological processes and plays an important role in the vascular relaxation, neurotransmission and immune system functioning. Analyses performed by EPR spectroscopy revealed Hem-NO complex signals from paramagnetic centers in arbitrary units;produced nitrogen oxide amount in liver tissues was determined by method of double integration signals from nitrosyl complexes.展开更多
This paper presents a discussion on a problem suggested by N.Salinas（J.Operator Theory,Vol.10,1983）,i.e.,if T=（T<sub>1</sub>,T<sub>2</sub>,…,T<sub>n</sub>）is a commuting n-tupl...This paper presents a discussion on a problem suggested by N.Salinas（J.Operator Theory,Vol.10,1983）,i.e.,if T=（T<sub>1</sub>,T<sub>2</sub>,…,T<sub>n</sub>）is a commuting n-tuple ofhyponormal operators on a complex Hilbert space,do we have（1）（2）δ（T-μ）=dist（μ,σ<sub>l</sub>（T））,μ∈C<sup>n</sup>?It is proved that the problems（1）and（2）are both true for some commuting n-tuples ofsemihyponormal operators.In general case,problem（1）has a negative answer.As an ap-plication,we point out that there exists a commuting n-tuple of hyponormal operatorsT（n≥2）,such that|λ|【,where σ<sub>T</sub>（T）denotes J.L.Taylor’sjoint spectra of T,even if the condition of Taylor’s joint spectra of T is given.展开更多
文摘目的构建果胶精油联产工艺获得的橙皮精油的指纹图谱,并进行成分分析。方法通过气相色谱-质谱法采集20批次橙皮精油样品的总离子流图(total ions current,TIC),运用“中药色谱指纹图谱相似度评价系统(2012版)”寻找共有峰并建立对照指纹图谱,采用美国国家标准与技术研究院(National Institute of Standards and Technology,NIST)谱库检索结合保留指数技术对共有峰进行成分鉴定,运用SPSS 29.0软件对共有峰进行主成分分析。结果指纹图谱的精密度、重复性和稳定性等方法学考察符合要求,所有样品TIC图相似度均大于0.998,提炼出9个共有峰,经过质谱鉴定,在共有峰中,D-柠檬烯相对含量最高,占82.77%,其次为月桂烯、烩烯、右旋α-蒎烯等,依次占比8.79%、3.62%、3.27%;经主成分分析,前两个主成分因子的累积方差贡献率为67.4%,微量成分烩烯和3-蒈烯对主成分因子的贡献最大。结论对由果胶精油联产工艺获得的橙皮精油建立了气相色谱-质谱指纹图谱,探明其共性化合物成分及影响力,为其质量控制提供了科学依据。
文摘This work is investigating Mexidol (2-ethyl-6-methyl-3-hydroxy pyridine succinate) effect on the formation of nitric oxide (NO) in animal liver tissues, which is a regulator of many physiological processes and plays an important role in the vascular relaxation, neurotransmission and immune system functioning. Analyses performed by EPR spectroscopy revealed Hem-NO complex signals from paramagnetic centers in arbitrary units;produced nitrogen oxide amount in liver tissues was determined by method of double integration signals from nitrosyl complexes.
文摘This paper presents a discussion on a problem suggested by N.Salinas（J.Operator Theory,Vol.10,1983）,i.e.,if T=（T<sub>1</sub>,T<sub>2</sub>,…,T<sub>n</sub>）is a commuting n-tuple ofhyponormal operators on a complex Hilbert space,do we have（1）（2）δ（T-μ）=dist（μ,σ<sub>l</sub>（T））,μ∈C<sup>n</sup>?It is proved that the problems（1）and（2）are both true for some commuting n-tuples ofsemihyponormal operators.In general case,problem（1）has a negative answer.As an ap-plication,we point out that there exists a commuting n-tuple of hyponormal operatorsT（n≥2）,such that|λ|【,where σ<sub>T</sub>（T）denotes J.L.Taylor’sjoint spectra of T,even if the condition of Taylor’s joint spectra of T is given.
