The interaction of TbC13 and lanthanide（Ⅲ） β-diketonate complexes with poly（N-vinylpyrrolidone） （PVP） polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3＋ in cthano...The interaction of TbC13 and lanthanide（Ⅲ） β-diketonate complexes with poly（N-vinylpyrrolidone） （PVP） polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3＋ in cthanolic solution of TbCl3 significantly in- creased owing to the excitation energy transfer from PVP to Tb3＋ ions, which was more efficient as compared to a direct excitation of the Tb3＋ 4f75d1 levels. In contrast, emission of NEt4Tb（hfa）4 and NEt4Eu（hfa）4 complexes was almost completely quenched in solu- tion containing PVP. The PVP bound both Ln3＋ ions and hfa ligands which caused decomposition of Ln-hfa complexes and switched off the excitation energy transfer from the ligand to the emitting Ln3＋ ion. The important role of hydrogen bonds in stabilization of in- teraction ofhfa ligands with PVP was indicated.展开更多
文摘The interaction of TbC13 and lanthanide（Ⅲ） β-diketonate complexes with poly（N-vinylpyrrolidone） （PVP） polymer was studied using fluorescence spectroscopy. In the presence of PVP the emission of Tb3＋ in cthanolic solution of TbCl3 significantly in- creased owing to the excitation energy transfer from PVP to Tb3＋ ions, which was more efficient as compared to a direct excitation of the Tb3＋ 4f75d1 levels. In contrast, emission of NEt4Tb（hfa）4 and NEt4Eu（hfa）4 complexes was almost completely quenched in solu- tion containing PVP. The PVP bound both Ln3＋ ions and hfa ligands which caused decomposition of Ln-hfa complexes and switched off the excitation energy transfer from the ligand to the emitting Ln3＋ ion. The important role of hydrogen bonds in stabilization of in- teraction ofhfa ligands with PVP was indicated.
