Techno-economic assessment of a chemical looping splitting system for H2 and CO Co-generation

The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850
C and 600
C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.

A Techno-Economical Characterization of Solar PV Power Generation in Rwanda:The Role of Subsidies and Incentives

Standalone Solar PV systems have been vital in the improvement of access to energy in many countries.However,given the large cost of solar PV plants’components,in developing countries,there is a dear need for such components to be subsidised and incentivised for the consumers to afford the produced energy.Moreover,there is a need for optimal sizing of the solar PV plants taking into account the solar information,energy requirement for various activities,and economic conditions in the off-grid regions in Rwanda.This study aims to develop optimally sized solar PV plants suited to rural communities in Rwanda.Likewise,it aims at characterizing the impacts of subsidies and incentives on the profitability and affordability of solar PV plants’energy in Rwanda.In the study,we have developed a model on basis of which the plant power(peak power)and costs of energy can be predicted given the load requirements using PVSyst.The model was validated using data corrected at eight different sites.Our generalized predictive model’s results matched the results obtained using field measurement data as inputs.The models have been able to replicate with a by degree of accuracy the peak powers and the plants’costs for different loads and were used to evaluate the economic viability of solar PV plants in Rwanda.It was found that with incentives and subsidies of 20%,the solar PV systems’costs,the Levelised Cost of Energy would drop from a maximum of 0.098 Euro to a minimum of 0.072 Euro,the payback period was reduced from a maximum of 7.5 years to a minimum of 6.0 years while the return on investments was seen to vary between 425.72 and 615.32 per cent over the plants’lifetime of 25 years.Overall our findings underscore the importance of government subsidies and incentives for solar PV energy generation projects to be significantly profitable.

Locomotion Paradigms of Topological Space in Shakespeare’s Double Falsehood

In the 16th and 17th century,Britain was constantly strained by sporadic plagues,famines,fires and political conflicts.As a response in literature,Shakespeare has constructed an annular locomotion paradigm in Fletcher and his collaboration work Cardenio.Be more specific,the locomotion routes can be exemplified in Möbius strip,a rhizome system,a reciprocating juxtaposition between the foreground and the background,either of which finally runs to an annular schema.The annular in narration corresponds with The Globe theater and the round world.Shakespeare may express his expectation and prospect for the uprising bourgeoise and the newly found world by the resurrection theme in literature.

The Research on Cross-Cultural Critical Thinking in English Teaching: A Pedagogical Paradigm Within the Ideological and Political Course Framework

The conflation of linguistic competencies with ideological and political educational paradigms presents unique opportunities and challenges for English language teaching(ELT)in our increasingly interconnected world.This research seeks to address the role of cross-cultural critical thinking within the landscape of English pedagogy,framed by the imperatives of ideological and political education.Employing a multi-method approach,including thematic content analysis and action research,the study proposes a pedagogical model designed to integrate transcultural discourse and ideologically reflective practices into the conventional ELT curriculum.This paper argues for a reimagined approach to teaching English that encourages students to engage with diverse cultural perspectives and develop a nuanced understanding of global issues.

Positioning Theory in Paradigms

This article discusses the importance of theory and paradigm to a researcher. It starts from introducing and analyzing thedefinition of the two terms, by using the theories in the field of intercultural communication as examples. To a good researcher, heneeds not only clarifying the paradigm his research is positioned, but also integrating the theories in his paradigm.

Paradigm Shifts or Methodology Changes ? Think Twice Before You Put Paradigms into Practice

ThepresentpaperaddressestheapplicabilityofKuhn'stheoryofparadigmshiftsandscientificrevolutionstothefieldoflanguageteaching.First,itillustratestheconceptionofparadigmshiftsandscientificrevolutions.Andthen,itsetsuptwotestsforexaminingtheissueofwhetherK...

Low Power Computing Paradigms Based on Emerging Non-Volatile Nanodevices

Traditional digital processing approaches are based on semiconductor transistors, which suffer from high power consumption, aggravating with technology node scaling. To solve definitively this problem, a number of emerging non-volatile nanodevices are under intense investigations. Meanwhile, novel computing circuits are invented to dig the full potential of the nanodevices. The combination of non-volatile nanodevices with suitable computing paradigms have many merits compared with the complementary metal-oxide-semiconductor transistor （CMOS） technology based structures, such as zero standby power, ultra-high density, non-volatility, and acceptable access speed. In this paper, we overview and compare the computing paradigms based on the emerging nanodevices towards ultra-low dissipation.

Techno-economic analysis of single U-tube and double U-tube heat exchangers in Chongqing area

On the basis of practical projects in Chongqing,the thermal performance of heat exchangers (single U-tube type and double U-tube type) of the ground-source heat pump (GSHP) system in the hot summer was obtained and analyzed. The data obtained from test could match with the result deduced from theoretical calculation. From the test results,the cooling capacity of double U-tube is 1.6 times that of single U-tube. Taking cost per depth per watt Clq as the evaluation standard,Clq of single U-tube is 4.69 RMB$/W,and Clq of double U-tube is 3.14 RMB$/W. The double U-tube heat exchangers usage should be prioritized.

Techno-Economic Analysis and Life Cycle Assessment for the Typical Intermediate Crude Refining Scheme in China

The integration of refinery and petrochemical units(IRPUs)has become an inevitable choice for the sustainable development of petrochemical industry.The utilization efficiency of petroleum resources could be improved obviously through IRPUs.However,integrating economic and environmental impacts into the model of IRPUs is still a grand challenge.Herein,a model called TEA-GHG-OPWM(Techno-Economic Analysis and GreenHouse Gases Oriented Plant-Wide Model)has been established on Aspen HYSYSTM platform to calculate the energy consumption,the technoeconomic performance,and the GHG emissions for two different kinds of schemes,viz,:VRHCU(Vacuum Residue Hydrocracking Unit)and VRDS-RFCC(Vacuum Residue Desulfurization and Residue Fluid Catalytic Cracking).Furthermore,a novel processing pathway named VGOHDT-HTMP-DC(Vacuum Gas Oil Hydrotreating,Hydrogenation and TMP coupling process and Delayed Coking)has also been developed to find methods to improve the economic performance based on a ten-million-CNY output value(TMYOV)and a reduced GHG emissions.Our results demonstrate that VRHCRU could consume more energy and emit more GHG(877.11 t of CO2 eq·TMYOV^-1·h^-1)than VRDS-RFCC(817.03 t of CO2 eq·TMYOV^-1·h^-1)and VGOHDT-HTMP-DC(721.96 t of CO2 eq·TMYOV^-1·h^-1),while obtaining a higher mass yield of petrochemicals.The VGOHDT-HTMP-DC process exhibits the lowest feedstock consumption,hydrogen consumption,energy consumption,and GHG emissions,indicating that VGOHDT-HTMP-DC has both well economic and environmentally friendly performance.

Computing Paradigms in Emerging Vehicular Environments:A Review

Determining how to structure vehicular network environments can be done in various ways.Here,we highlight vehicle networks’evolution from vehicular ad-hoc networks(VANET)to the internet of vehicles(Io Vs),listing their benefits and limitations.We also highlight the reasons in adopting wireless technologies,in particular,IEEE 802.11 p and 5 G vehicle-toeverything,as well as the use of paradigms able to store and analyze a vast amount of data to produce intelligence and their applications in vehicular environments.We also correlate the use of each of these paradigms with the desire to meet existing intelligent transportation systems’requirements.The presentation of each paradigm is given from a historical and logical standpoint.In particular,vehicular fog computing improves on the deficiences of vehicular cloud computing,so both are not exclusive from the application point of view.We also emphasize some security issues that are linked to the characteristics of these paradigms and vehicular networks,showing that they complement each other and share problems and limitations.As these networks still have many opportunities to grow in both concept and application,we finally discuss concepts and technologies that we believe are beneficial.Throughout this work,we emphasize the crucial role of these concepts for the well-being of humanity.

Simulation and Techno-Economic Performance of a Novel Charge Calculation and Melt Optimization Planning Model for Steel Making

Process algorithm, numerical model and techno-economic assessment of charge calculation and furnace bath optimization for target alloy for induction furnace-based steelmaking is presented in this study. The developed algorithm combines the make-to-order (MTO) and charge optimization planning (COP) of the steel melting shop in the production of target steel composition. Using a system-level approach, the unit operations involved in the melting process were analyzed with the purpose of initial charge calculation, prevailing alloy charge prediction and optimizing the sequence of melt chemistry modification. The model performance was established using real-time production data from a cast iron-based foundry with a 1- and 2-ton induction furnace capacity and a medium carbon-based foundry with a 10- and 15-ton induction furnace capacity. A simulation engine (CastMELT) was developed in Java IDE with a MySQL database for continuous interaction with changing process parameters to run the model for validation. The comparison between the model prediction and production results was analyzed for charge prediction, melt modification and ferroalloy optimization and possible cost savings. The model performance for elemental charge prediction and calculation purpose with respect to the charge input (at overall scrap meltdown) gave R-squared, Standard Error, Pearson correlation and Significance value of (0.934, 0.06, 0.97, 0.0003) for Carbon prediction, (0.962, 0.06, 0.98, 0.00009) for Silicon prediction, (0.999, 0.048, 0.999, 9E -11) for Manganese Prediction, and (0.997, 0.076, 0.999, 6E -7) for Chromium prediction respectively. Correlation analysis for melt modification (after charging of ferroalloy) using the model for after-alloying spark analysis compared with the target chemistry is at 99.82%. The results validate the suitability of the developed model as a functional system of induction furnace melting for combined charge calculation and melt optimization Techno-economic evaluation results showed that 0.98% - 0.25% ferroalloy saving per ton of melt is possible using the model. This brings about an annual production cost savings of 100,000 $/y in foundry A (medium carbon steel) and 20,000 $/y in foundry B (cast iron) on the use of different ferroalloy materials.

Techno-Economic Analysis of Power Production by Using Waste Biomass Gasification

Energy recovery from waste biomass can have significant impacts on the most pressing development challenges of rural poverty and environmental damages. In this paper, a techno-economic analysis is carried out for electricity generation by using timber and wood waste (T & WW) gasification in Iceland. Different expenses were considered, like capital, installation, engineering, operation and maintenance costs and the interest rate of the investment. Regarding to revenues, they come from of the electricity sale and the fee paid by the Icelandic municipalities for waste collection and disposal. The economic feasibility was conducted based on the economic indicators of net present value (NPV) and discounted payback period (DPP), bringing together three different subgroups based on gasifier capacities, subgroup a: 50 kW, subgroup b: 100 kW and subgroup c: 200 kW. The results show that total cost increases as the implemented power is increased. This indicator varies from 1228.6 k€ for subgroups a to 1334.7 k€ for subgroups b and 1479.5 k€ for subgroups c. It is worth mentioning that NPV is positive for three subgroups and it grows as gasifier scale is extended. NPV is about 122 k€ (111,020 $), 1824 k€ (1,659,840 $) and 4392 k€ (3,996,720 $) for subgroups a, b and c, respectively. Moreover, DPP has an inversely proportional to the installed capacity. It is around 5.5 years (subgroups a), 9.5 months (subgroups b) and 6 months (subgroups c). The obtained results confirm that using small scale waste biomass gasification integrated with power generation could be techno-economically feasible for remote area in Iceland.

Techno-Economic Feasibility Analysis of Solar Photovoltaic Power Generation: A Review

With the rapid depletion of fossil fuel reserves, it is feared that the world will soon run out of its energy resources. This is a matter of concern for developing countries whose economy heavily leans on its use of energy. Under the circums-tances it is highly desirable that renewable energy resources should be utilized with maximum conversion efficiency to cope with the ever increasing energy demand. Furthermore, the global economic and political conditions that tend to make countries more dependent on their own energy resources have caused growing interest in the development and use of renewable energy based technologies. In terms of its environmental advantages, renewable energy sources generate electricity with insignificant contribution of carbon dioxide (CO2) or other greenhouse gases (GHG) to the atmosphere and they produce no pollutant discharge on water or soil and hence power generation from renewable becomes very important. Major types of renewable energy sources include solar, wind, hydro and biomass, all of which have huge potential to meet future energy challenges. Solar photovoltaic technology in one of the first among several renewable energy technologies that have been adopted worldwide for meeting the basic needs of electricity particularly in remote areas. In this paper literature review pertaining to techno-economic feasibility analysis of solar photovoltaic power generation is discussed. The literature is basically classified into the following three main category design methods, techno-economic feasibility of solar photovoltaic power generation, performance evaluations of various systems.

DAO to HANOI via DeSci: AI Paradigm Shifts from AlphaGo to ChatGPT

From AlphaGo to ChatGPT,the field of AI has launched a series of remarkable achievements in recent years.Analyzing,comparing,and summarizing these achievements at the paradigm level is important for future AI innovation,but has not received sufficient attention.In this paper,we give an overview and perspective on machine learning paradigms.First,we propose a paradigm taxonomy with three levels and seven dimensions from a knowledge perspective.Accordingly,we give an overview on three basic and twelve extended learning paradigms,such as Ensemble Learning,Transfer Learning,etc.,with figures in unified style.We further analyze three advanced paradigms,i.e.,AlphaGo,AlphaFold and ChatGPT.Second,to enable more efficient and effective scientific discovery,we propose to build a new ecosystem that drives AI paradigm shifts through the decentralized science(DeSci)movement based on decentralized autonomous organization(DAO).To this end,we design the Hanoi framework,which integrates human factors,parallel intelligence based on a combination of artificial systems and the natural world,and the DAO to inspire AI innovations.

Regions and Their Typical Paradigms for Soil and Water Conservation in China

China is experiencing conflicts between its large population and scarce arable land,and between a demand for high productivity and the severe soil erosion of arable land.Since 1949,China has committed to soil and water conservation(SWC),for which eight regions and 41 subregions have been developed to improve the environment and increase land productivity.To obtain information from the regional planning and strategies for SWC and to explore whether SWC practices simultaneously contribute to soil conservation,ecosystem functioning,and the livelihoods of local farmers,and to summarize the successful experiences of various SWC paradigms with distinct characteristics and mechanisms of soil erosion,this paper systematically presents seven SWC regions(excluding the Tibetan Plateau region)and 14 typical SWC paradigms,focusing on erosion mechanisms and the key challenges or issues in the seven regions as well as on the core problems,main objectives,key technologies,and the performance of the 14 typical paradigms.In summary,the 14 typical SWC paradigms successfully prevent and control local soil erosion,and have largely enhanced,or at least do not harm,the livelihoods of local farmers.However,there remain many challenges and issues on SWC and socioeconomic development that need to be addressed in the seven SWC regions.China,thus,still has a long way to go in successfully gaining the win-win objective of SWC and human aspects of development.

Assembling Paradigms of Programming in Software Engeneering

Assembling paradigms programming are based on the reuses in any programming language (PL) with the passport data of their settings in WSDL. The method of assembling is formal and secures co-operation of the different reuses (module, object, component, service and so on) being developed. A formal means of these paradigms creation with help of interfaces is presented. Interface IDL (Stub, Skeleton) is containing data and operations for transmission data to other standard elements linked and describes in the standard language IDL. Assembling will be realized by integration of reuses elements in these paradigms on the instrumental-technological complex (ITC).

Analysis on New Paradigms of Informatization in the Countryside

Through the analyses of several typical paradigms of informatization in the countryside,the status of informatization in the countryside and some unresolved issues were studied. A new way was proposed to develop rural information with embedded mobile phone terminal,and to explore an inexpensive and efficient information services paradigm for the future development in the countryside.

Techno-economical evaluation of membrane based biogas upgrading system:A comparison between polymeric membrane and carbon membrane technology

A shift to renewable energy sources will reduce emissions of greenhouse gases and secure future energy supplies. In this context, utilization of biogas will play a prominent role. Focus of this work is upgrading of biogas to fuel quality by membrane separation using a carbon hollow fibre(CHF) membrane and compare with a commercially available polymeric membrane(polyimide) through economical assessment. CHF membrane modules were prepared for pilot plant testing and performance measured using CO_2, O_2, N_2. The CHF membrane was modified through oxidation, chemical vapour deposition(CVD) and reduction process thus tailoring pores for separation and increased performance. The post oxidized and reduced carbon hollow fibres(PORCHFs) significantly exceeded CHF performance showing higher CO_2 permeance(0.021 m^3(STP)/m^2 h bar) and CO_2/CH_4 selectivity of 246(5 bar feed vs 50 mbar permeate pressure). The highest performance recorded through experiments(CHF and PORCHF) was used as simulation basis. A membrane simulation model was used and interfaced to 8.6 V Aspen HYSYS.A 300 Nm^3/h mixture of CO_2/CH_4 containing 30-50% CO_2 at feed pressures 6, 8 and 10 bar, was simulated and process designed to recover99.5% CH_4 with 97.5% purity. Net present value(NPV) was calculated for base case and optimal pressure(50 bar for CHF and PORCHF). The results indicated that recycle ratio(recycle/feed) ranged from 0.2 to 10, specific energy from 0.15 to 0.8(kW/Nm^3 feed) and specific membrane area from 45 to 4700(m^2/Nm^3 feed). The high recycle ratio can create problems during start-up, as it would take long to adjust volumetric flow ratio towards 10. The best membrane separation system employs a three-stage system with polyimide at 10 bar, and a two-stage membrane system with PORCHF membranes at 50 bar with recycle. Considering biomethane price of 0.78 $/Nm^3 and a lifetime of 15 years, the technoeconomic analysis showed that payback time for the best cascade is 1.6 months.

Multidimensional Design Paradigms for Data Warehouses: A Systematic Mapping Study

Data warehouses (DW) must integrate information from the different areas and sources of an organization in order to extract knowledge relevant to decision-making. The DW development is not an easy task, which is why various design approaches have been put forward. These approaches can be classified in three different paradigms according to the origin of the information requirements: supply-driven, demand-driven, and hybrids of these. This article compares the methodologies for the multidimensional design of DW through a systematic mapping as research methodology. The study is presented for each paradigm, the main characteristics of the methodologies, their notations and problem areas exhibited in each one of them. The results indicate that there is no follow-up to the complete process of implementing a DW in either an academic or industrial environment;however, there is also no evidence that the attempt is made to address the design and development of a DW by applying and comparing different methodologies existing in the field.