The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) sepa...The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850C and 600C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.展开更多
Standalone Solar PV systems have been vital in the improvement of access to energy in many countries.However,given the large cost of solar PV plants’components,in developing countries,there is a dear need for such co...Standalone Solar PV systems have been vital in the improvement of access to energy in many countries.However,given the large cost of solar PV plants’components,in developing countries,there is a dear need for such components to be subsidised and incentivised for the consumers to afford the produced energy.Moreover,there is a need for optimal sizing of the solar PV plants taking into account the solar information,energy requirement for various activities,and economic conditions in the off-grid regions in Rwanda.This study aims to develop optimally sized solar PV plants suited to rural communities in Rwanda.Likewise,it aims at characterizing the impacts of subsidies and incentives on the profitability and affordability of solar PV plants’energy in Rwanda.In the study,we have developed a model on basis of which the plant power(peak power)and costs of energy can be predicted given the load requirements using PVSyst.The model was validated using data corrected at eight different sites.Our generalized predictive model’s results matched the results obtained using field measurement data as inputs.The models have been able to replicate with a by degree of accuracy the peak powers and the plants’costs for different loads and were used to evaluate the economic viability of solar PV plants in Rwanda.It was found that with incentives and subsidies of 20%,the solar PV systems’costs,the Levelised Cost of Energy would drop from a maximum of 0.098 Euro to a minimum of 0.072 Euro,the payback period was reduced from a maximum of 7.5 years to a minimum of 6.0 years while the return on investments was seen to vary between 425.72 and 615.32 per cent over the plants’lifetime of 25 years.Overall our findings underscore the importance of government subsidies and incentives for solar PV energy generation projects to be significantly profitable.展开更多
The conflation of linguistic competencies with ideological and political educational paradigms presents unique opportunities and challenges for English language teaching(ELT)in our increasingly interconnected world.Th...The conflation of linguistic competencies with ideological and political educational paradigms presents unique opportunities and challenges for English language teaching(ELT)in our increasingly interconnected world.This research seeks to address the role of cross-cultural critical thinking within the landscape of English pedagogy,framed by the imperatives of ideological and political education.Employing a multi-method approach,including thematic content analysis and action research,the study proposes a pedagogical model designed to integrate transcultural discourse and ideologically reflective practices into the conventional ELT curriculum.This paper argues for a reimagined approach to teaching English that encourages students to engage with diverse cultural perspectives and develop a nuanced understanding of global issues.展开更多
On the basis of practical projects in Chongqing,the thermal performance of heat exchangers (single U-tube type and double U-tube type) of the ground-source heat pump (GSHP) system in the hot summer was obtained and an...On the basis of practical projects in Chongqing,the thermal performance of heat exchangers (single U-tube type and double U-tube type) of the ground-source heat pump (GSHP) system in the hot summer was obtained and analyzed. The data obtained from test could match with the result deduced from theoretical calculation. From the test results,the cooling capacity of double U-tube is 1.6 times that of single U-tube. Taking cost per depth per watt Clq as the evaluation standard,Clq of single U-tube is 4.69 RMB$/W,and Clq of double U-tube is 3.14 RMB$/W. The double U-tube heat exchangers usage should be prioritized.展开更多
The integration of refinery and petrochemical units(IRPUs)has become an inevitable choice for the sustainable development of petrochemical industry.The utilization efficiency of petroleum resources could be improved o...The integration of refinery and petrochemical units(IRPUs)has become an inevitable choice for the sustainable development of petrochemical industry.The utilization efficiency of petroleum resources could be improved obviously through IRPUs.However,integrating economic and environmental impacts into the model of IRPUs is still a grand challenge.Herein,a model called TEA-GHG-OPWM(Techno-Economic Analysis and GreenHouse Gases Oriented Plant-Wide Model)has been established on Aspen HYSYSTM platform to calculate the energy consumption,the technoeconomic performance,and the GHG emissions for two different kinds of schemes,viz,:VRHCU(Vacuum Residue Hydrocracking Unit)and VRDS-RFCC(Vacuum Residue Desulfurization and Residue Fluid Catalytic Cracking).Furthermore,a novel processing pathway named VGOHDT-HTMP-DC(Vacuum Gas Oil Hydrotreating,Hydrogenation and TMP coupling process and Delayed Coking)has also been developed to find methods to improve the economic performance based on a ten-million-CNY output value(TMYOV)and a reduced GHG emissions.Our results demonstrate that VRHCRU could consume more energy and emit more GHG(877.11 t of CO2 eq·TMYOV^-1·h^-1)than VRDS-RFCC(817.03 t of CO2 eq·TMYOV^-1·h^-1)and VGOHDT-HTMP-DC(721.96 t of CO2 eq·TMYOV^-1·h^-1),while obtaining a higher mass yield of petrochemicals.The VGOHDT-HTMP-DC process exhibits the lowest feedstock consumption,hydrogen consumption,energy consumption,and GHG emissions,indicating that VGOHDT-HTMP-DC has both well economic and environmentally friendly performance.展开更多
Process algorithm, numerical model and techno-economic assessment of charge calculation and furnace bath optimization for target alloy for induction furnace-based steelmaking is presented in this study. The developed ...Process algorithm, numerical model and techno-economic assessment of charge calculation and furnace bath optimization for target alloy for induction furnace-based steelmaking is presented in this study. The developed algorithm combines the make-to-order (MTO) and charge optimization planning (COP) of the steel melting shop in the production of target steel composition. Using a system-level approach, the unit operations involved in the melting process were analyzed with the purpose of initial charge calculation, prevailing alloy charge prediction and optimizing the sequence of melt chemistry modification. The model performance was established using real-time production data from a cast iron-based foundry with a 1- and 2-ton induction furnace capacity and a medium carbon-based foundry with a 10- and 15-ton induction furnace capacity. A simulation engine (CastMELT) was developed in Java IDE with a MySQL database for continuous interaction with changing process parameters to run the model for validation. The comparison between the model prediction and production results was analyzed for charge prediction, melt modification and ferroalloy optimization and possible cost savings. The model performance for elemental charge prediction and calculation purpose with respect to the charge input (at overall scrap meltdown) gave R-squared, Standard Error, Pearson correlation and Significance value of (0.934, 0.06, 0.97, 0.0003) for Carbon prediction, (0.962, 0.06, 0.98, 0.00009) for Silicon prediction, (0.999, 0.048, 0.999, 9E -11) for Manganese Prediction, and (0.997, 0.076, 0.999, 6E -7) for Chromium prediction respectively. Correlation analysis for melt modification (after charging of ferroalloy) using the model for after-alloying spark analysis compared with the target chemistry is at 99.82%. The results validate the suitability of the developed model as a functional system of induction furnace melting for combined charge calculation and melt optimization Techno-economic evaluation results showed that 0.98% - 0.25% ferroalloy saving per ton of melt is possible using the model. This brings about an annual production cost savings of 100,000 $/y in foundry A (medium carbon steel) and 20,000 $/y in foundry B (cast iron) on the use of different ferroalloy materials.展开更多
Energy recovery from waste biomass can have significant impacts on the most pressing development challenges of rural poverty and environmental damages. In this paper, a techno-economic analysis is carried out for elec...Energy recovery from waste biomass can have significant impacts on the most pressing development challenges of rural poverty and environmental damages. In this paper, a techno-economic analysis is carried out for electricity generation by using timber and wood waste (T & WW) gasification in Iceland. Different expenses were considered, like capital, installation, engineering, operation and maintenance costs and the interest rate of the investment. Regarding to revenues, they come from of the electricity sale and the fee paid by the Icelandic municipalities for waste collection and disposal. The economic feasibility was conducted based on the economic indicators of net present value (NPV) and discounted payback period (DPP), bringing together three different subgroups based on gasifier capacities, subgroup a: 50 kW, subgroup b: 100 kW and subgroup c: 200 kW. The results show that total cost increases as the implemented power is increased. This indicator varies from 1228.6 k€ for subgroups a to 1334.7 k€ for subgroups b and 1479.5 k€ for subgroups c. It is worth mentioning that NPV is positive for three subgroups and it grows as gasifier scale is extended. NPV is about 122 k€ (111,020 $), 1824 k€ (1,659,840 $) and 4392 k€ (3,996,720 $) for subgroups a, b and c, respectively. Moreover, DPP has an inversely proportional to the installed capacity. It is around 5.5 years (subgroups a), 9.5 months (subgroups b) and 6 months (subgroups c). The obtained results confirm that using small scale waste biomass gasification integrated with power generation could be techno-economically feasible for remote area in Iceland.展开更多
With the rapid depletion of fossil fuel reserves, it is feared that the world will soon run out of its energy resources. This is a matter of concern for developing countries whose economy heavily leans on its use of e...With the rapid depletion of fossil fuel reserves, it is feared that the world will soon run out of its energy resources. This is a matter of concern for developing countries whose economy heavily leans on its use of energy. Under the circums-tances it is highly desirable that renewable energy resources should be utilized with maximum conversion efficiency to cope with the ever increasing energy demand. Furthermore, the global economic and political conditions that tend to make countries more dependent on their own energy resources have caused growing interest in the development and use of renewable energy based technologies. In terms of its environmental advantages, renewable energy sources generate electricity with insignificant contribution of carbon dioxide (CO2) or other greenhouse gases (GHG) to the atmosphere and they produce no pollutant discharge on water or soil and hence power generation from renewable becomes very important. Major types of renewable energy sources include solar, wind, hydro and biomass, all of which have huge potential to meet future energy challenges. Solar photovoltaic technology in one of the first among several renewable energy technologies that have been adopted worldwide for meeting the basic needs of electricity particularly in remote areas. In this paper literature review pertaining to techno-economic feasibility analysis of solar photovoltaic power generation is discussed. The literature is basically classified into the following three main category design methods, techno-economic feasibility of solar photovoltaic power generation, performance evaluations of various systems.展开更多
From AlphaGo to ChatGPT,the field of AI has launched a series of remarkable achievements in recent years.Analyzing,comparing,and summarizing these achievements at the paradigm level is important for future AI innovati...From AlphaGo to ChatGPT,the field of AI has launched a series of remarkable achievements in recent years.Analyzing,comparing,and summarizing these achievements at the paradigm level is important for future AI innovation,but has not received sufficient attention.In this paper,we give an overview and perspective on machine learning paradigms.First,we propose a paradigm taxonomy with three levels and seven dimensions from a knowledge perspective.Accordingly,we give an overview on three basic and twelve extended learning paradigms,such as Ensemble Learning,Transfer Learning,etc.,with figures in unified style.We further analyze three advanced paradigms,i.e.,AlphaGo,AlphaFold and ChatGPT.Second,to enable more efficient and effective scientific discovery,we propose to build a new ecosystem that drives AI paradigm shifts through the decentralized science(DeSci)movement based on decentralized autonomous organization(DAO).To this end,we design the Hanoi framework,which integrates human factors,parallel intelligence based on a combination of artificial systems and the natural world,and the DAO to inspire AI innovations.展开更多
A shift to renewable energy sources will reduce emissions of greenhouse gases and secure future energy supplies. In this context, utilization of biogas will play a prominent role. Focus of this work is upgrading of bi...A shift to renewable energy sources will reduce emissions of greenhouse gases and secure future energy supplies. In this context, utilization of biogas will play a prominent role. Focus of this work is upgrading of biogas to fuel quality by membrane separation using a carbon hollow fibre(CHF) membrane and compare with a commercially available polymeric membrane(polyimide) through economical assessment. CHF membrane modules were prepared for pilot plant testing and performance measured using CO_2, O_2, N_2. The CHF membrane was modified through oxidation, chemical vapour deposition(CVD) and reduction process thus tailoring pores for separation and increased performance. The post oxidized and reduced carbon hollow fibres(PORCHFs) significantly exceeded CHF performance showing higher CO_2 permeance(0.021 m^3(STP)/m^2 h bar) and CO_2/CH_4 selectivity of 246(5 bar feed vs 50 mbar permeate pressure). The highest performance recorded through experiments(CHF and PORCHF) was used as simulation basis. A membrane simulation model was used and interfaced to 8.6 V Aspen HYSYS.A 300 Nm^3/h mixture of CO_2/CH_4 containing 30-50% CO_2 at feed pressures 6, 8 and 10 bar, was simulated and process designed to recover99.5% CH_4 with 97.5% purity. Net present value(NPV) was calculated for base case and optimal pressure(50 bar for CHF and PORCHF). The results indicated that recycle ratio(recycle/feed) ranged from 0.2 to 10, specific energy from 0.15 to 0.8(kW/Nm^3 feed) and specific membrane area from 45 to 4700(m^2/Nm^3 feed). The high recycle ratio can create problems during start-up, as it would take long to adjust volumetric flow ratio towards 10. The best membrane separation system employs a three-stage system with polyimide at 10 bar, and a two-stage membrane system with PORCHF membranes at 50 bar with recycle. Considering biomethane price of 0.78 $/Nm^3 and a lifetime of 15 years, the technoeconomic analysis showed that payback time for the best cascade is 1.6 months.展开更多
Investigation of a triple-pressure organic Rankine cycle(TPORC) using geothermal energy for power generation with the net power output of the TPORC analyzed by varying the evaporation pressures, pinch temperature diff...Investigation of a triple-pressure organic Rankine cycle(TPORC) using geothermal energy for power generation with the net power output of the TPORC analyzed by varying the evaporation pressures, pinch temperature differences(tpp) and degrees of superheat(tsup) aimed to find the optimum operation conditions of the system. The thermodynamic performance of the TPORC was compared with a dual-pressure organic Rankine cycle(DPORC) and a single-pressure ORC(SPORC) for geofluid temperatures ranging from 100°C to 200°C, with particular reference to the utilization of a hot dry rock(HDR) geothermal resource. Thermodynamic performances of the TPORC system using eight different organic working fluids have also been investigated in terms of the net power outputs. Results show that a higher geofluid mass flow rate can make a considerable contribution to shortening the payback period(PBP) as well as to decreasing the levelized electricity cost(LEC), especially when the geofluid temperature is low. For the temperature range investigated, the order from high to low based on thermodynamic and techno-economic performances is found to be TPORC > DPORC > SPORC. In terms of using geothermal resources within the given temperatures range(100°C–200°C), the TPORC system can be a better choice for geothermal power generation so long as the wellhead geofluid temperature is between 140°C and 180°C.展开更多
With population growth around the world,municipal waste disposal and continued energy demand becomes some of the major challenges to deal with.In order to address these,an approach is required for an optimal waste man...With population growth around the world,municipal waste disposal and continued energy demand becomes some of the major challenges to deal with.In order to address these,an approach is required for an optimal waste management system that offers the population benefit with a lower environmental impact.This study evaluates the technical-economic and environmental impact analysis of a grid-connected waste to energy(WtE)plant to power a Univerisiti Teknologi Malaysia(UTM)community.The energy recovery potential of the waste stream was assessed using the life cycle assessment(LCA)method with GaBi^(TM) software(version 4).A technical,economic and environmental analysis was then carried out for the grid-connected WtE system using HOMERPro software with gasification conversion technology.The cash flow analysis was based on levelized costs of energy(LCOE)and total net present value(NPV).The results gave an NPV for the system at USD 1.11×10^(7),with most of the effects resulting from the grid operating costs and the LCOE of USD 0.43/kWh compared to the grid unit price of USD 0.7/kWh which corresponds to a saving of$0.27/kWh in energy purchase.From an environmental point of view,the results showed a significant reduction in carbon dioxide emissions from around 2,000 tons per year to around 400 tons per year.With regard to the amount of waste sent to landfills,the results show a significant improvement from 142,605.5 kg/year to 0.13 kg/year.展开更多
Techno-economic analysis of a small-scale Modified Plant Oil (MPO) production plant that has an annual production capacity of 15,072,741 kg of MPO (batch process) was carried out to estimate the capital and operating ...Techno-economic analysis of a small-scale Modified Plant Oil (MPO) production plant that has an annual production capacity of 15,072,741 kg of MPO (batch process) was carried out to estimate the capital and operating costs of a plant. The analysis was done by using a computer model that was designed and simulated with an aid of SuperPro Designer (Version 4.32) software. The specified feedstock was crude Jatropha oil (JO) and the main product was MPO. The major processes involved were degumming, neutralisation and blending. Degumming involved the removal of gums or phospholipids, and two methods were used: water degumming and acid degumming, whereas blending involved mixing of degummed or purified JO with natural gas condensate (NGC) modifier to lower the viscosity of JO. From techno-economic analysis of the process, it was found that the total capital investment of a plant was about US $ 10,222,000 and the predicted unit production cost of MPO was US $ 1.315/kg at a value of US $ 1.0/kg of JO. The economic feasibility of MPO production was found to be highly influenced by the price of feedstock, which contributed about 95% of the total annual production cost. The relationship between plant throughput and unit cost of producing MPO showed that unit production cost was very sensitive to production rate at low annual throughputs. The MPO cost showed a direct linear relationship with the cost of JO, with a change of US $ 0.50/kg of MPO in MPO cost in every change of US $ 0.50/kg of JO in JO price. The process technology simulated was found to be economically viable and can be implemented in rural setting, taking into consideration Tanzania’s rural situation.展开更多
The general theme-“ethics in the future”-intends to question a form of human knowledge,ethics,in relation to a dimension of time,the future.In broader terms,the title refers to a question about the relationship betw...The general theme-“ethics in the future”-intends to question a form of human knowledge,ethics,in relation to a dimension of time,the future.In broader terms,the title refers to a question about the relationship between knowledge and time,which in turn includes questions such as:“To what do different forms of knowledge-ethics,economics,physics-refer when they discuss the future?”;“What do they mean by a possible,probable,preferable future?”;“What future emerges through their key concepts?”;“What kind of future challenges present knowledge within an epochal context that is established in the form of an incessant reproduction of relative means and ends,one that is constantly outdated?”;“What form of knowledge is required first and foremost so that the establishment of this epoch can take place?”展开更多
India generates more than 140 million tonnes of surplus crop residue every year In Haryana, the agricultural sector alone produces 24.64 million tonnes of residue annually;of which only 71</span><span style=&...India generates more than 140 million tonnes of surplus crop residue every year In Haryana, the agricultural sector alone produces 24.64 million tonnes of residue annually;of which only 71</span><span style="white-space:nowrap;font-family:Verdana;">%</span><span style="font-family:Verdana;"></span><span style="font-family:Verdana;"> is consumed in various domestic and commercial activities within the state. The rest of the material is burned causing severe contamination of air with smoke. There is an urgent need to identify suitable and sustainable conversion technologies that are efficient, eco-friendly as well as cost-effective for managing the huge available biomass not only in the state but also in the country. This paper reviews briefly the available crop residue and quantities burned, proposes a scheme to incorporate part of the residue in the field for its fertilizer value. The remaining biomass is harvested for animal feed and the excess is converted to bioenergy and biofuels. Among the developed and developing biofuels, the paper identifies biogas production from biomass for on-farm use. Pelletization is identified as an enabling technology to provide high quality feedstock for conversion to heat/power and in near future to advanced biofuels.展开更多
11% of Irish electricity was consumed by data centres in 2020. The Irish data centre industry and the cooling methods utilised require reformative actions in the coming years to meet EU Energy policies. The resell of ...11% of Irish electricity was consumed by data centres in 2020. The Irish data centre industry and the cooling methods utilised require reformative actions in the coming years to meet EU Energy policies. The resell of heat, alternative cooling methods or carbon reduction methods are all possibilities to conform to these policies. This study aims to determine the viability of the resell of waste heat from data centres both technically and economically. This was determined using a novel application of thermodynamics to determine waste heat recovery potential in Irish data centres, and the current methods of heat generation for economical comparison. This paper also explores policy surrounding waste heat recovery within the industry. The Recoverable Carnot Equivalent Power (RCEP) is theoretically calculated for the three potential cooling methods for Irish data centres. These are air, hybrid, and immersion cooling techniques. This is the maximum useable heat that can be recovered from a data centre rack. This study is established under current operating conditions which are optimised for cooling performance, that air cooling has the highest potential RCEP of 0.39 kW/rack. This is approximately 8% of the input electrical power that can be captured as useable heat. Indicating that Irish data centres have the energy potential to be heat providers in the Irish economy. This study highlighted the technical and economic aspects of prevalent cooling techniques and determined air cooling heat recovery cost can be reduced to 0.01 €/kWhth using offsetting. This is financially competitive with current heating solutions in Ireland.展开更多
An often unrecognized problem is the geology and glacial history paradigm’s inability to explain topographic map drainage system and erosional landform evidence, which means geology research studies rarely address th...An often unrecognized problem is the geology and glacial history paradigm’s inability to explain topographic map drainage system and erosional landform evidence, which means geology research studies rarely address that type of topographic map evidence. The problem originated in the late 19<sup>th</sup> century with William Morris Davis who is sometimes called the father of geomorphology and was one of the first geologists to interpret what in the late 19<sup>th</sup> century were newly available topographic maps. An 1889 Davis paper describes selected drainage system evidence observed on an advance copy of the 1890 Doylestown (Pennsylvania) topographic map and an 1892 Ward paper written after discussions with Davis describes additional selected drainage system evidence seen on the same map. Both papers fail to mention the majority of the Doylestown map’s drainage system features including most barbed tributaries, asymmetric drainage divides, and through (dry) valleys crossing major drainage divides. Had Davis used all of the map’s drainage system and erosional landform evidence he should have recognized the map evidence shows headward erosion of an east-oriented Neshaminy Creek valley captured southwest-oriented streams which headward erosion of the south-oriented Delaware River valley and its east-oriented tributary Tohickon Creek valley had beheaded. Consciously or unconsciously, Davis chose not to alert future investigators that Doylestown topographic map evidence did not support his yet-to-be-published Pennsylvania and New Jersey erosion history interpretations and instead Davis proceeded to develop and promote erosion history interpretations which the map evidence did not support.展开更多
In the 16th and 17th century,Britain was constantly strained by sporadic plagues,famines,fires and political conflicts.As a response in literature,Shakespeare has constructed an annular locomotion paradigm in Fletcher...In the 16th and 17th century,Britain was constantly strained by sporadic plagues,famines,fires and political conflicts.As a response in literature,Shakespeare has constructed an annular locomotion paradigm in Fletcher and his collaboration work Cardenio.Be more specific,the locomotion routes can be exemplified in Möbius strip,a rhizome system,a reciprocating juxtaposition between the foreground and the background,either of which finally runs to an annular schema.The annular in narration corresponds with The Globe theater and the round world.Shakespeare may express his expectation and prospect for the uprising bourgeoise and the newly found world by the resurrection theme in literature.展开更多
基金supported by National Natural Science Foundation of China(U1810205)The authors would also like to thank the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province(20220003)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L002)for their support.
文摘The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850C and 600C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.
文摘Standalone Solar PV systems have been vital in the improvement of access to energy in many countries.However,given the large cost of solar PV plants’components,in developing countries,there is a dear need for such components to be subsidised and incentivised for the consumers to afford the produced energy.Moreover,there is a need for optimal sizing of the solar PV plants taking into account the solar information,energy requirement for various activities,and economic conditions in the off-grid regions in Rwanda.This study aims to develop optimally sized solar PV plants suited to rural communities in Rwanda.Likewise,it aims at characterizing the impacts of subsidies and incentives on the profitability and affordability of solar PV plants’energy in Rwanda.In the study,we have developed a model on basis of which the plant power(peak power)and costs of energy can be predicted given the load requirements using PVSyst.The model was validated using data corrected at eight different sites.Our generalized predictive model’s results matched the results obtained using field measurement data as inputs.The models have been able to replicate with a by degree of accuracy the peak powers and the plants’costs for different loads and were used to evaluate the economic viability of solar PV plants in Rwanda.It was found that with incentives and subsidies of 20%,the solar PV systems’costs,the Levelised Cost of Energy would drop from a maximum of 0.098 Euro to a minimum of 0.072 Euro,the payback period was reduced from a maximum of 7.5 years to a minimum of 6.0 years while the return on investments was seen to vary between 425.72 and 615.32 per cent over the plants’lifetime of 25 years.Overall our findings underscore the importance of government subsidies and incentives for solar PV energy generation projects to be significantly profitable.
文摘The conflation of linguistic competencies with ideological and political educational paradigms presents unique opportunities and challenges for English language teaching(ELT)in our increasingly interconnected world.This research seeks to address the role of cross-cultural critical thinking within the landscape of English pedagogy,framed by the imperatives of ideological and political education.Employing a multi-method approach,including thematic content analysis and action research,the study proposes a pedagogical model designed to integrate transcultural discourse and ideologically reflective practices into the conventional ELT curriculum.This paper argues for a reimagined approach to teaching English that encourages students to engage with diverse cultural perspectives and develop a nuanced understanding of global issues.
文摘On the basis of practical projects in Chongqing,the thermal performance of heat exchangers (single U-tube type and double U-tube type) of the ground-source heat pump (GSHP) system in the hot summer was obtained and analyzed. The data obtained from test could match with the result deduced from theoretical calculation. From the test results,the cooling capacity of double U-tube is 1.6 times that of single U-tube. Taking cost per depth per watt Clq as the evaluation standard,Clq of single U-tube is 4.69 RMB$/W,and Clq of double U-tube is 3.14 RMB$/W. The double U-tube heat exchangers usage should be prioritized.
基金The research was supported by the National Natural Science Foundation of China(21978325 and 21776312)the Fundamental Research Funds for the Central Universities(20CX06073A,20CX06095A,and 20CX06096A).
文摘The integration of refinery and petrochemical units(IRPUs)has become an inevitable choice for the sustainable development of petrochemical industry.The utilization efficiency of petroleum resources could be improved obviously through IRPUs.However,integrating economic and environmental impacts into the model of IRPUs is still a grand challenge.Herein,a model called TEA-GHG-OPWM(Techno-Economic Analysis and GreenHouse Gases Oriented Plant-Wide Model)has been established on Aspen HYSYSTM platform to calculate the energy consumption,the technoeconomic performance,and the GHG emissions for two different kinds of schemes,viz,:VRHCU(Vacuum Residue Hydrocracking Unit)and VRDS-RFCC(Vacuum Residue Desulfurization and Residue Fluid Catalytic Cracking).Furthermore,a novel processing pathway named VGOHDT-HTMP-DC(Vacuum Gas Oil Hydrotreating,Hydrogenation and TMP coupling process and Delayed Coking)has also been developed to find methods to improve the economic performance based on a ten-million-CNY output value(TMYOV)and a reduced GHG emissions.Our results demonstrate that VRHCRU could consume more energy and emit more GHG(877.11 t of CO2 eq·TMYOV^-1·h^-1)than VRDS-RFCC(817.03 t of CO2 eq·TMYOV^-1·h^-1)and VGOHDT-HTMP-DC(721.96 t of CO2 eq·TMYOV^-1·h^-1),while obtaining a higher mass yield of petrochemicals.The VGOHDT-HTMP-DC process exhibits the lowest feedstock consumption,hydrogen consumption,energy consumption,and GHG emissions,indicating that VGOHDT-HTMP-DC has both well economic and environmentally friendly performance.
文摘Process algorithm, numerical model and techno-economic assessment of charge calculation and furnace bath optimization for target alloy for induction furnace-based steelmaking is presented in this study. The developed algorithm combines the make-to-order (MTO) and charge optimization planning (COP) of the steel melting shop in the production of target steel composition. Using a system-level approach, the unit operations involved in the melting process were analyzed with the purpose of initial charge calculation, prevailing alloy charge prediction and optimizing the sequence of melt chemistry modification. The model performance was established using real-time production data from a cast iron-based foundry with a 1- and 2-ton induction furnace capacity and a medium carbon-based foundry with a 10- and 15-ton induction furnace capacity. A simulation engine (CastMELT) was developed in Java IDE with a MySQL database for continuous interaction with changing process parameters to run the model for validation. The comparison between the model prediction and production results was analyzed for charge prediction, melt modification and ferroalloy optimization and possible cost savings. The model performance for elemental charge prediction and calculation purpose with respect to the charge input (at overall scrap meltdown) gave R-squared, Standard Error, Pearson correlation and Significance value of (0.934, 0.06, 0.97, 0.0003) for Carbon prediction, (0.962, 0.06, 0.98, 0.00009) for Silicon prediction, (0.999, 0.048, 0.999, 9E -11) for Manganese Prediction, and (0.997, 0.076, 0.999, 6E -7) for Chromium prediction respectively. Correlation analysis for melt modification (after charging of ferroalloy) using the model for after-alloying spark analysis compared with the target chemistry is at 99.82%. The results validate the suitability of the developed model as a functional system of induction furnace melting for combined charge calculation and melt optimization Techno-economic evaluation results showed that 0.98% - 0.25% ferroalloy saving per ton of melt is possible using the model. This brings about an annual production cost savings of 100,000 $/y in foundry A (medium carbon steel) and 20,000 $/y in foundry B (cast iron) on the use of different ferroalloy materials.
文摘Energy recovery from waste biomass can have significant impacts on the most pressing development challenges of rural poverty and environmental damages. In this paper, a techno-economic analysis is carried out for electricity generation by using timber and wood waste (T & WW) gasification in Iceland. Different expenses were considered, like capital, installation, engineering, operation and maintenance costs and the interest rate of the investment. Regarding to revenues, they come from of the electricity sale and the fee paid by the Icelandic municipalities for waste collection and disposal. The economic feasibility was conducted based on the economic indicators of net present value (NPV) and discounted payback period (DPP), bringing together three different subgroups based on gasifier capacities, subgroup a: 50 kW, subgroup b: 100 kW and subgroup c: 200 kW. The results show that total cost increases as the implemented power is increased. This indicator varies from 1228.6 k€ for subgroups a to 1334.7 k€ for subgroups b and 1479.5 k€ for subgroups c. It is worth mentioning that NPV is positive for three subgroups and it grows as gasifier scale is extended. NPV is about 122 k€ (111,020 $), 1824 k€ (1,659,840 $) and 4392 k€ (3,996,720 $) for subgroups a, b and c, respectively. Moreover, DPP has an inversely proportional to the installed capacity. It is around 5.5 years (subgroups a), 9.5 months (subgroups b) and 6 months (subgroups c). The obtained results confirm that using small scale waste biomass gasification integrated with power generation could be techno-economically feasible for remote area in Iceland.
文摘With the rapid depletion of fossil fuel reserves, it is feared that the world will soon run out of its energy resources. This is a matter of concern for developing countries whose economy heavily leans on its use of energy. Under the circums-tances it is highly desirable that renewable energy resources should be utilized with maximum conversion efficiency to cope with the ever increasing energy demand. Furthermore, the global economic and political conditions that tend to make countries more dependent on their own energy resources have caused growing interest in the development and use of renewable energy based technologies. In terms of its environmental advantages, renewable energy sources generate electricity with insignificant contribution of carbon dioxide (CO2) or other greenhouse gases (GHG) to the atmosphere and they produce no pollutant discharge on water or soil and hence power generation from renewable becomes very important. Major types of renewable energy sources include solar, wind, hydro and biomass, all of which have huge potential to meet future energy challenges. Solar photovoltaic technology in one of the first among several renewable energy technologies that have been adopted worldwide for meeting the basic needs of electricity particularly in remote areas. In this paper literature review pertaining to techno-economic feasibility analysis of solar photovoltaic power generation is discussed. The literature is basically classified into the following three main category design methods, techno-economic feasibility of solar photovoltaic power generation, performance evaluations of various systems.
基金This work was supported by the National Key Research and Development Program of China(2020YFB2104001)the National Natural Science Foundation of China(62271485,61903363,U1811463)Open Project of the State Key Laboratory for Management and Control of Complex Systems(20220117).
文摘From AlphaGo to ChatGPT,the field of AI has launched a series of remarkable achievements in recent years.Analyzing,comparing,and summarizing these achievements at the paradigm level is important for future AI innovation,but has not received sufficient attention.In this paper,we give an overview and perspective on machine learning paradigms.First,we propose a paradigm taxonomy with three levels and seven dimensions from a knowledge perspective.Accordingly,we give an overview on three basic and twelve extended learning paradigms,such as Ensemble Learning,Transfer Learning,etc.,with figures in unified style.We further analyze three advanced paradigms,i.e.,AlphaGo,AlphaFold and ChatGPT.Second,to enable more efficient and effective scientific discovery,we propose to build a new ecosystem that drives AI paradigm shifts through the decentralized science(DeSci)movement based on decentralized autonomous organization(DAO).To this end,we design the Hanoi framework,which integrates human factors,parallel intelligence based on a combination of artificial systems and the natural world,and the DAO to inspire AI innovations.
文摘A shift to renewable energy sources will reduce emissions of greenhouse gases and secure future energy supplies. In this context, utilization of biogas will play a prominent role. Focus of this work is upgrading of biogas to fuel quality by membrane separation using a carbon hollow fibre(CHF) membrane and compare with a commercially available polymeric membrane(polyimide) through economical assessment. CHF membrane modules were prepared for pilot plant testing and performance measured using CO_2, O_2, N_2. The CHF membrane was modified through oxidation, chemical vapour deposition(CVD) and reduction process thus tailoring pores for separation and increased performance. The post oxidized and reduced carbon hollow fibres(PORCHFs) significantly exceeded CHF performance showing higher CO_2 permeance(0.021 m^3(STP)/m^2 h bar) and CO_2/CH_4 selectivity of 246(5 bar feed vs 50 mbar permeate pressure). The highest performance recorded through experiments(CHF and PORCHF) was used as simulation basis. A membrane simulation model was used and interfaced to 8.6 V Aspen HYSYS.A 300 Nm^3/h mixture of CO_2/CH_4 containing 30-50% CO_2 at feed pressures 6, 8 and 10 bar, was simulated and process designed to recover99.5% CH_4 with 97.5% purity. Net present value(NPV) was calculated for base case and optimal pressure(50 bar for CHF and PORCHF). The results indicated that recycle ratio(recycle/feed) ranged from 0.2 to 10, specific energy from 0.15 to 0.8(kW/Nm^3 feed) and specific membrane area from 45 to 4700(m^2/Nm^3 feed). The high recycle ratio can create problems during start-up, as it would take long to adjust volumetric flow ratio towards 10. The best membrane separation system employs a three-stage system with polyimide at 10 bar, and a two-stage membrane system with PORCHF membranes at 50 bar with recycle. Considering biomethane price of 0.78 $/Nm^3 and a lifetime of 15 years, the technoeconomic analysis showed that payback time for the best cascade is 1.6 months.
基金supported by the National Key Research and Development Program of the 13th FiveYear Plan of China(Grant No.2018YFB1501805)。
文摘Investigation of a triple-pressure organic Rankine cycle(TPORC) using geothermal energy for power generation with the net power output of the TPORC analyzed by varying the evaporation pressures, pinch temperature differences(tpp) and degrees of superheat(tsup) aimed to find the optimum operation conditions of the system. The thermodynamic performance of the TPORC was compared with a dual-pressure organic Rankine cycle(DPORC) and a single-pressure ORC(SPORC) for geofluid temperatures ranging from 100°C to 200°C, with particular reference to the utilization of a hot dry rock(HDR) geothermal resource. Thermodynamic performances of the TPORC system using eight different organic working fluids have also been investigated in terms of the net power outputs. Results show that a higher geofluid mass flow rate can make a considerable contribution to shortening the payback period(PBP) as well as to decreasing the levelized electricity cost(LEC), especially when the geofluid temperature is low. For the temperature range investigated, the order from high to low based on thermodynamic and techno-economic performances is found to be TPORC > DPORC > SPORC. In terms of using geothermal resources within the given temperatures range(100°C–200°C), the TPORC system can be a better choice for geothermal power generation so long as the wellhead geofluid temperature is between 140°C and 180°C.
基金supported/funded by the Ministry of Higher Education under Fundamental Research Grant.Grant No.FRGS/1/2018/TK07/UTM/02/6.https://www.mohe.gov.my/en/initiatives-2/187-program-utama/penyelidikan/548-research-grants-inf-ormation.
文摘With population growth around the world,municipal waste disposal and continued energy demand becomes some of the major challenges to deal with.In order to address these,an approach is required for an optimal waste management system that offers the population benefit with a lower environmental impact.This study evaluates the technical-economic and environmental impact analysis of a grid-connected waste to energy(WtE)plant to power a Univerisiti Teknologi Malaysia(UTM)community.The energy recovery potential of the waste stream was assessed using the life cycle assessment(LCA)method with GaBi^(TM) software(version 4).A technical,economic and environmental analysis was then carried out for the grid-connected WtE system using HOMERPro software with gasification conversion technology.The cash flow analysis was based on levelized costs of energy(LCOE)and total net present value(NPV).The results gave an NPV for the system at USD 1.11×10^(7),with most of the effects resulting from the grid operating costs and the LCOE of USD 0.43/kWh compared to the grid unit price of USD 0.7/kWh which corresponds to a saving of$0.27/kWh in energy purchase.From an environmental point of view,the results showed a significant reduction in carbon dioxide emissions from around 2,000 tons per year to around 400 tons per year.With regard to the amount of waste sent to landfills,the results show a significant improvement from 142,605.5 kg/year to 0.13 kg/year.
文摘Techno-economic analysis of a small-scale Modified Plant Oil (MPO) production plant that has an annual production capacity of 15,072,741 kg of MPO (batch process) was carried out to estimate the capital and operating costs of a plant. The analysis was done by using a computer model that was designed and simulated with an aid of SuperPro Designer (Version 4.32) software. The specified feedstock was crude Jatropha oil (JO) and the main product was MPO. The major processes involved were degumming, neutralisation and blending. Degumming involved the removal of gums or phospholipids, and two methods were used: water degumming and acid degumming, whereas blending involved mixing of degummed or purified JO with natural gas condensate (NGC) modifier to lower the viscosity of JO. From techno-economic analysis of the process, it was found that the total capital investment of a plant was about US $ 10,222,000 and the predicted unit production cost of MPO was US $ 1.315/kg at a value of US $ 1.0/kg of JO. The economic feasibility of MPO production was found to be highly influenced by the price of feedstock, which contributed about 95% of the total annual production cost. The relationship between plant throughput and unit cost of producing MPO showed that unit production cost was very sensitive to production rate at low annual throughputs. The MPO cost showed a direct linear relationship with the cost of JO, with a change of US $ 0.50/kg of MPO in MPO cost in every change of US $ 0.50/kg of JO in JO price. The process technology simulated was found to be economically viable and can be implemented in rural setting, taking into consideration Tanzania’s rural situation.
文摘The general theme-“ethics in the future”-intends to question a form of human knowledge,ethics,in relation to a dimension of time,the future.In broader terms,the title refers to a question about the relationship between knowledge and time,which in turn includes questions such as:“To what do different forms of knowledge-ethics,economics,physics-refer when they discuss the future?”;“What do they mean by a possible,probable,preferable future?”;“What future emerges through their key concepts?”;“What kind of future challenges present knowledge within an epochal context that is established in the form of an incessant reproduction of relative means and ends,one that is constantly outdated?”;“What form of knowledge is required first and foremost so that the establishment of this epoch can take place?”
文摘India generates more than 140 million tonnes of surplus crop residue every year In Haryana, the agricultural sector alone produces 24.64 million tonnes of residue annually;of which only 71</span><span style="white-space:nowrap;font-family:Verdana;">%</span><span style="font-family:Verdana;"></span><span style="font-family:Verdana;"> is consumed in various domestic and commercial activities within the state. The rest of the material is burned causing severe contamination of air with smoke. There is an urgent need to identify suitable and sustainable conversion technologies that are efficient, eco-friendly as well as cost-effective for managing the huge available biomass not only in the state but also in the country. This paper reviews briefly the available crop residue and quantities burned, proposes a scheme to incorporate part of the residue in the field for its fertilizer value. The remaining biomass is harvested for animal feed and the excess is converted to bioenergy and biofuels. Among the developed and developing biofuels, the paper identifies biogas production from biomass for on-farm use. Pelletization is identified as an enabling technology to provide high quality feedstock for conversion to heat/power and in near future to advanced biofuels.
文摘11% of Irish electricity was consumed by data centres in 2020. The Irish data centre industry and the cooling methods utilised require reformative actions in the coming years to meet EU Energy policies. The resell of heat, alternative cooling methods or carbon reduction methods are all possibilities to conform to these policies. This study aims to determine the viability of the resell of waste heat from data centres both technically and economically. This was determined using a novel application of thermodynamics to determine waste heat recovery potential in Irish data centres, and the current methods of heat generation for economical comparison. This paper also explores policy surrounding waste heat recovery within the industry. The Recoverable Carnot Equivalent Power (RCEP) is theoretically calculated for the three potential cooling methods for Irish data centres. These are air, hybrid, and immersion cooling techniques. This is the maximum useable heat that can be recovered from a data centre rack. This study is established under current operating conditions which are optimised for cooling performance, that air cooling has the highest potential RCEP of 0.39 kW/rack. This is approximately 8% of the input electrical power that can be captured as useable heat. Indicating that Irish data centres have the energy potential to be heat providers in the Irish economy. This study highlighted the technical and economic aspects of prevalent cooling techniques and determined air cooling heat recovery cost can be reduced to 0.01 €/kWhth using offsetting. This is financially competitive with current heating solutions in Ireland.
文摘An often unrecognized problem is the geology and glacial history paradigm’s inability to explain topographic map drainage system and erosional landform evidence, which means geology research studies rarely address that type of topographic map evidence. The problem originated in the late 19<sup>th</sup> century with William Morris Davis who is sometimes called the father of geomorphology and was one of the first geologists to interpret what in the late 19<sup>th</sup> century were newly available topographic maps. An 1889 Davis paper describes selected drainage system evidence observed on an advance copy of the 1890 Doylestown (Pennsylvania) topographic map and an 1892 Ward paper written after discussions with Davis describes additional selected drainage system evidence seen on the same map. Both papers fail to mention the majority of the Doylestown map’s drainage system features including most barbed tributaries, asymmetric drainage divides, and through (dry) valleys crossing major drainage divides. Had Davis used all of the map’s drainage system and erosional landform evidence he should have recognized the map evidence shows headward erosion of an east-oriented Neshaminy Creek valley captured southwest-oriented streams which headward erosion of the south-oriented Delaware River valley and its east-oriented tributary Tohickon Creek valley had beheaded. Consciously or unconsciously, Davis chose not to alert future investigators that Doylestown topographic map evidence did not support his yet-to-be-published Pennsylvania and New Jersey erosion history interpretations and instead Davis proceeded to develop and promote erosion history interpretations which the map evidence did not support.
基金Chongqing Social Science Fund Project“The Ethical Topology of Shakespeare’s Histories”(2020WYZX07).
文摘In the 16th and 17th century,Britain was constantly strained by sporadic plagues,famines,fires and political conflicts.As a response in literature,Shakespeare has constructed an annular locomotion paradigm in Fletcher and his collaboration work Cardenio.Be more specific,the locomotion routes can be exemplified in Möbius strip,a rhizome system,a reciprocating juxtaposition between the foreground and the background,either of which finally runs to an annular schema.The annular in narration corresponds with The Globe theater and the round world.Shakespeare may express his expectation and prospect for the uprising bourgeoise and the newly found world by the resurrection theme in literature.