A Tri-Salt Composite Electrolyte with Temperature Switch Function for Intelligently Temperature-Controlled Lithium Batteries

The intense research of lithium-ion batteries has been motivated by their successful applications in mobile devices and electronic vehicles.The emerging of intelligent control in kinds of devices brings new requirements for battery systems.The high-energy lithium batteries are expected to respond or react under different environmental conditions.In this work,a tri-salt composite electrolyte is designed with a temperature switch function for intelligently temperature-controlled lithium batteries.Specifically,the halide Li_(3)YBr_(6)together with LiTFSI and LiNO_(3)works as active fillers in a low-melting-point polymer matrix(polyethyleneglycol dimethyl ether(PEGDME)and polyethylene oxide(PEO)),which is further filled into the pre-lithiated alumina fiber skeleton.Above 60°C,the composite electrolyte exists in the liquid state and fully contacts with the working electrodes on the liquid–solid interface,effectively minimizing the interfacial resistance and leading to high discharge capacity in the cell.The electrolyte is changed into a solid state below 30°C so that the ionic conductivity is significantly reduced and the interface resistance is increased dramatically on the solid–solid interface.Therefore,by simply adjusting the temperature,the cell can be turned“ON”or“OFF”intentionally.This novel function of the composite electrolyte has enlightening significance in developing intelligently temperature-controlled lithium batteries.

Improvement of a temperature response function for divertor heat flux monitoring in fusion devices

Temperature response functions have been developed to investigate sensor design and divertor heat flux estimation in magnetically confined plasmas. The time-dependent heat flux can be derived by fitting the response function to experimental thermocouple(TC) data. Because the TC signals have a time delay to transit events such as discharge start or confinement transition, the time delay is taken into account in a temperature response function. Such a function accurately describes the signal from each TC channel with time delay in a sensor test using a neutral beam injection. Measurement for commercial TCs shows that the time delay is caused by the finite heat capacity of TC wire and contact heat resistance between TC and target surface.

Early application of percutaneous neuromuscular electric stimulation in interfering motor function of limbs and difference in temperature of axilla of patients with ischemic stroke

BACKGROUND： Temperature of axilla could be affected due to motor dysfunction of limbs and neural changes of vessel after ischemic stroke. OBJECTIVE： To observe the effect of percutaneous neuromuscular electric stimulation （PNES） on difference in temperature of axilla and analyze the relationship between function of limbs and difference in temperature of axilla. DESIGN： Randomized grouping and controlled observation SETTING： Department of Neurology, General Hospital of Shenyang Military Area Command of Chinese PLA PARTICIPANTS： Sixty patients with ischemic stroke were selected from Neurological Department of General Hospital of Shenyang Military Area Command of Chinese PLA from January to June 2003. All cases were diagnosed with clinical diagnosis criteria of ischemic stroke established by the Fourth Chinese Classification of Cerebrovasular Disease and CT examination and received neuromuscular electric stimulation （NES）. Patients were randomly divided into control group and treatment group with 30 in each group. METHODS： Control group： Patients received routinely neurological therapy. Treatment group： Except routine therapy, patients suffered from NES at 48 hours after hospitalization. NMT-91 NES equipment was used to stimulated injured limbs with low frequency once 30 minutes a day in total of 10 times a course, especially extensor muscle of upper limb and flexor muscle of lower limb. Prescription of hemiplegia was internally decided by equipment with the output frequency of 200 Hz. Intensity of electric output could cause muscle contraction. The therapy needed two or three courses. Temperature of bilateral axilla was measured every day to calculate the difference with the formula of （temperature of axilla on the injured side - temperature of axilla on the healthy side）. Motor function of limbs was measured with FugI-Meyer Motor Assessment （FMA） during hospitalization and at 2 and 4 hours after hospitalization. Among 90 points, upper and lower limb function was 54, equilibrium function 10, sensory function 10, and motion of joint 16. The higher the scores were, the better the function was. Correlation of data was dealt with linear correlation analysis. MAIN OUTCOME MEASURES ： Assessment and correlation between difference in temperature of axilla and motor function of injured limbs during hospitalization and at 2 and 4 weeks after hospitalization. RESULTS： All 60 patients with ischemic stroke were involved in the final analysis. ① Difference in temperature： Difference of 2 and 4 weeks after hospitalization was lower than that in control group and at just hospitalization [treatment group： （0.056±0.000）, （0.024±0.003） ℃; control group： （0.250±0.001）, （0.131 ±0.001）℃; hospitalization; （0.513±0.001） ℃, P 〈 0.05-0,01]. ② FMA scores： Scores of 2 and 4 weeks after hospitalization were higher than those in control group and at just hospitalization [treatment group; （43.50±15.09）, （67.97 ±18.21） points; control group： （33.33 ±13.54）, （40.87±19.34） points; hospitalization： （26.43 ±11.87） points, P 〈 0.05-0.01]. ③ Correlation： Difference in temperature of axilla was negative correlation with FMA scores （c=- -0.255 1, P 〈 0.05）. CONCLUSION： ① PNES can accelerate recovery of limb function and decrease temperature of axilla of patients with ischemic stroke. ② The lower the difference in temperature is, the better the functional recovery is.

Stability of operation versus temperature of a three-phase clock-driven chaotic circuit

We evaluate the influence of temperature on the behavior of a three-phase clock-driven metal–oxide–semiconductor （MOS） chaotic circuit. The chaotic circuit consists of two nonlinear functions, a level shifter, and three sample and hold blocks. It is necessary to analyze a CMOS-based chaotic circuit with respect to variation in temperature for stability because the circuit is sensitive to the behavior of the circuit design parameters. The temperature dependence of the proposed chaotic circuit is investigated via the simulation program with integrated circuit emphasis （SPICE） using 0.6-μm CMOS process technology with a 5-V power supply and a 20-kHz clock frequency. The simulation results demonstrate the effects of temperature on the chaotic dynamics of the proposed chaotic circuit. The time series, frequency spectra, bifurcation phenomena, and Lyapunov exponent results are provided.

Thermodynamic properties of ZnSe under pressure and with variation in temperature

The thermodynamic properties of Zn Se are obtained by using quasi-harmonic Debye model embedded in Gibbscode for pressure range 0–10 GPa and for temperature range 0–1000 K. Helmholtz free energy, internal energy, entropy,Debye temperature, and specific heat are calculated. The thermal expansion coefficient along with Gruneisen parameter are also calculated at room temperature for the pressure range. It is found that internal energy is pressure dependent at low temperature, whereas entropy and Helmholtz free energy are pressure sensitive at high temperature. At ambient conditions,the obtained results are found to be in close agreement to available theoretical and experimental data.

Sterilization Effect of Cooking Process for Guilin Rice Noodles Based on Heat Conduction Model

Guilin rice noodles, a unique cuisine from Guilin, Guangxi, is renowned both domestically and internationally as one of the top ten “Guilin Classics”. Utilizing a heat conduction model, this study explores the effectiveness of the cooking process in sterilizing Guilin rice noodles before consumption. The model assumes that a large pot is filled with boiling water which is maintained at a constant high temperature heat resource through continuous gentle heating. And the room temperature is set as the initial temperature for the preheating process and the final temperature for the cooling process. The objective is to assess whether the cooking process achieves satisfactory sterilization results. The temperature distribution function of rice noodle with time is analytically obtained using the separation of variables method in the three-dimensional cylindrical coordinate system. Meanwhile, the thermal diffusion coefficient of Guilin rice noodles is obtained in terms of Riedel’ theory. By analyzing the elimination characteristics of Pseudomonas cocovenenans subsp. farinofermentans, this study obtains the optimal time required for effective sterilization at the core of Guilin rice noodles. The results show that the potential Pseudomonas cocovenenans subsp. farinofermentans will be completely eliminated through continuously preheating more than 31 seconds during the cooking process before consumption. This study provides a valuable reference of food safety standards in the cooking process of Guilin rice noodles, particularly in ensuring the complete inactivation of potentially harmful strains such as Pseudomonas cocovenenans subsp. farinofermentans.

Temperature sensitivity of organic compound destruction in SCWO process

To study the temperature sensitivity of the destruction of organic compounds in supercritical water oxidation process （SCWO）, oxidation effects of twelve chemicals in supercritical water were investigated. The SCWO reaction rates of different compounds improved to varying degrees with the increase of temperature, so the highest slope of the temperature-effect curve （/max） was defined as the maximum ratio of removal ratio to working temperature. It is an important index to stand for the temperature sensitivity effect in SCWO. It was proven that the higher imax is, the more significant the effect of temperature on the SCWO effect is. Since the high-temperature area of SCWO equipment is subject to considerable damage from fatigue, the temperature is of great significance in SCWO equipment operation. Generally, most compounds （/max 〉 0.25） can be completely oxidized when the reactor temperature reaches 500~C. However, some compounds （/max 〉 0.25） need a higher temperature for complete oxidation, up to 560~C. To analyze the correlation coefficients between/max and various molecular descriptors, a quantum chemical method was used in this study. The structures of the twelve organic compounds were optimized by the Density Functional Theory B3LYP/6-311G method, as well as their quantum properties. It was shown that six molecular descriptors were negatively correlated to imax while other three descriptors were positively correlated to imax. Among them, dipole moment had the greatest effect on the oxidation thermodynamics of the twelve organic compounds. Once a correlation between molecular descriptors and imax is established, SCWO can be run at an appropriate temperature according to molecular structure.

Secretome profiling reveals temperature-dependent growth of Aspergillus fumigatus

Aspergillus fumigatus is a ubiquitous opportunistic fungus. In this study, systematic analyses were carried out to study the temperature adaptability of A. fumigatus. A total of 241 glycoside hydrolases and 69 proteases in the secretome revealed the strong capability of A. fumigatus to degrade plant biomass and protein substrates. In total, 129 pathogenesis-related proteins detected in the secretome were strongly correlated with glycoside hydrolases and proteases. The variety and abundance of proteins remained at temperatures of 34°C–45°C. The percentage of endo-1,4-xylanase increased when the temperature was lowered to 20°C, while the percentage of cellobiohydrolase increased as temperature was increased, suggesting that the strain obtains carbon mainly by degrading xylan and cellulose, and the main types of proteases in the secretome were aminopeptidases and carboxypeptidases. Only half of the proteins were retained and their abundance declined to 9.7% at 55°C. The activities of the remaining β-glycosidases and proteases were merely 35% and 24%, respectively, when the secretome was treated at 60°C for 2 h. Therefore, temperatures >60°C restrict the growth of A. fumigatus.

A tracing of the fractional temperature field

This paper is devoted to a study of L^q-tracing of the fractional temperature field u(t, x)—the weak solution of the fractional heat equation(?_t +(-?_x)~α)u(t, x) = g(t, x) in L^p(R_+^(1+n)) subject to the initial temperature u(0, x) = f(x) in L^p(R^n).

Spatiotemporal patterns of winter wheat phenology and its climatic drivers based on an improved pDSSAT model

Acquiring spatiotemporal patterns of phenological information and its drivers is essential for understanding the response of crops to climate change and implementing adaptation measures.However,current approaches to obtain phenology and analyse its drivers have deficiencies such as sparse observations,excessive dependence of remote sensing inversion on sensors,and inevitable difficulties in upscaling site-based crop models into larger regions.Based on the Wang-Engel temperature response function,we improved the Crop Estimation through Resource and Environment Synthesis-Wheat(CERES-Wheat)model.First,we calibrated the model at the regional scale and evaluated its performance.Furthermore,the spatiotemporal changes in winter wheat phenology in China from 2000 to 2015 were analysed.The results showed that the improved model significantly enhanced the simulation accuracy of the anthesis and maturity dates by averages of 13%and 12%in most planting areas,especially in the Yunnan-Guizhou Plateau(YG)with improvements of 26%and 28%.The simulated phenology of winter wheat grown in a colder environment(e.g.,the average temperatures during the vegetative growth period range from 0 to 5℃ and from 15 to 20°C,and the reproductive growth period ranges from 10 to 15°C)also notably improved.These results confirmed that the original temperature response function indeed had limitations.Further analyses revealed that the key phenological dates and growth periods over the past 16 years were dominantly advanced and shortened.Specifically,the anthesis date,vegetative growth period(VGP),and reproductive growth period(RGP)indicated obviously spatial characteristics.For example,the anthesis date and VGP in the North China Plain(NCP)and the Middle-Lower Yangtze Plain(YZ)and the RGP in northwestern China(NW)showed opposite trends of delay and prolongation as comparing with the dominant patterns.Sensitivity analysis indicated that the key phenological dates and growth periods were advanced and shortened as the minimum(T_(min))and maximum temperatures(T_(max))rose,while they were postponed and prolonged with the increased precipitation.However,their responses to solar radiation did not show spatial consistency.Additionally,we found that the sensitivity of phenology to climatic factors differed across subregions.In particular,phenology in southwestern China and YG was more sensitive to T_(min),T_(max),and solar radiation than in the NCP and NW.Moreover,the sensitivity to precipitation in NW was higher than that in YZ.Totally,the improved crop model could provide more refined spatial characteristics of phenology at a large scale and benefit to explore its drivers more objectively.Furthermore,our results highlight that different planting areas should adopt suitable adaptation measures to cope with climate change impacts.Ultimately,the improved model is promising to enhance the accuracy of yield prediction and provide powerful tools for assessing regional climate change impact and adaptability.

Uncertainty in Simulating the Impact of Cultivar Improvement on Winter Wheat Phenology in the North China Plain

The phenology model is one of the major tools in evaluating the impact of cultivar improvement on crop pheno-logy. Understanding uncertainty in simulating the impact is an important prerequisite for reliably interpreting the ef-fect of cultivar improvement and climate change on phenology. However, uncertainty induced by different temperat-ure response functions and parameterization methods have not been properly addressed. Based on winter wheat phen-ology observations during 1986-2012 in 47 agro-meteorology observation stations in the North China Plain （NCP）, the uncertainty of the simulated impacts caused by four widely applied temperature response functions and two para- meterization methods were investigated. The functions were firstly calibrated using observed phenology data during 1986-1988 from each station by means of two parameterization methods, and were then used to quantify the impact of cultivar improvement on wheat phenology during 1986-2012. The results showed that all functions and all para-meterization methods could reach acceptable precision （RMSE 〈 3 days for all functions and parameterization meth-ods）, however, substantial differences exist in the simulated impacts between different functions and parameteriza-tion methods. For vegetative growth period, the simulated impact is 0.20 day （10 yr）^-1 [95% confidence interval： -2.81-3.22 day （10 yr）^-1] across the NCP, while for reproductive period, the value is 1.50 day （10 yr）^-1 [-1.03-4.02 day （10 yr）^-1]. Further analysis showed that uncertainty can be induced by both different fimctions and parameteriza-tion methods, while the former has greater influence than the latter. During vegetative period, there is a significant positive linear relationship between ranges of simulated impact and growth period average temperature, while during reproductive period, the relationship is polynomial. This highlights the large inconsistency that exists in most impact quantifying functions and the urgent need to carry out field experiment to provide realistic impacts for all functions. Before applying a simulated effect, we suggest that the function should be calibrated over a wide temperature range.