Copper sulfate pentahydrate is investigated by terahertz time-domain spectroscopy. It is shown that the terahertz absorption coefficients are correlated with the particle size of the samples, as well as the heating ra...Copper sulfate pentahydrate is investigated by terahertz time-domain spectroscopy. It is shown that the terahertz absorption coefficients are correlated with the particle size of the samples, as well as the heating rates of the ambient temperature. Furthermore, the water molecules of copper sulfate pentahydrate can be quantitatively characterized due to the high sensitivity of the terahertz wave to water molecules. Based on such results, the status of water incorporated in mineral opal is also characterized using terahertz time-domain spectroscopy. It indicates that terahertz technology can be considered as an efficient method to detect the dehydration of minerals.展开更多
A method for extracting optical parameters of plastics materials based on terahertz time domain spectroscopy is presented. The transmission-type Terahertz Time-Domain Spectroscopy(THz TDS) system is adopted to detect ...A method for extracting optical parameters of plastics materials based on terahertz time domain spectroscopy is presented. The transmission-type Terahertz Time-Domain Spectroscopy(THz TDS) system is adopted to detect the refractive index and extinction coefficient on different plastic materials. Then the corresponding spectral information is obtained by Fourier transform of the terahertz time domain waveform of the sampling points, including the corresponding amplitude and phase information of the waveform. The optical parameter extraction model is built. By using the simplex optimization method, the curves of the refractive index and extinction coefficient for the plastic material are obtained. The experimental samples are made of different plastic parallel plate materials. The experimental results show that the optimization of optical parameters can improve their extraction accuracy, and the error of refractive index is ±0.005. Extraction technology with the simplex optimization method of optical parameter based on THz TDS can help to extract the optical parameters of engineering plastics. It is of great significance for the research of terahertz nondestructive testing.展开更多
This paper reports that terahertz time-domain spectroscopy is used to measure the optical properties of CuS nanoparticles in composite samples. The complex conductivity of pure CuS nanoparticles is extracted by applyi...This paper reports that terahertz time-domain spectroscopy is used to measure the optical properties of CuS nanoparticles in composite samples. The complex conductivity of pure CuS nanoparticles is extracted by applying the Bruggeman effective medium theory. The experimental data are consistent with the Drude-Smith model of conductivity in the range of 0.2 1.5 THz. The results demonstrate that carriers become localized with a backscattering behaviour in small-size nanostructures. In addition, the time constant for the carrier scattering is obtained and is only 64.3 fs due to increased electron interaction with interfaces and grain boundaries.展开更多
Terahertz （THz） radiation, whose frequency ranges from 0.1 THz to 10.0 THz, has rich science, but limited technology. It has long been considered the last remaining scientific gap in the electromagnetic spectrum. Fa...Terahertz （THz） radiation, whose frequency ranges from 0.1 THz to 10.0 THz, has rich science, but limited technology. It has long been considered the last remaining scientific gap in the electromagnetic spectrum. Far from being fully exploited, it offers great opportunities in science, innovation, new technology, and potential applications. THz science and technology enables fundamental research directly impact our lives, from industrial quality control,展开更多
The terahertz time-domain spectroscopy （THz-TDS） system and the related technology and the applications in Capital Normal University are presented. The most often used THz-TDS system as a spectroscopic measurement ...The terahertz time-domain spectroscopy （THz-TDS） system and the related technology and the applications in Capital Normal University are presented. The most often used THz-TDS system as a spectroscopic measurement setup in our lab is introduced in detail, including the THz radiation source, the THz detection method and its measurement, and the control system. THz spectra of various materials is summarized and discussed. These materials include but not limited to two kinds of typical matter-the illegal drugs and explosives. The biological macro-molecules, cosmetics and fine chemical materials, edible pigments and food additives, homocysteic acid and related compounds, heavy ions in soil, Chinese medicines, tobacco and crops, oil and chemical products, carbon nanotubes, superconductors, and various semiconductors and their heterojunctions, are presented. THz emissions from the InAs and InN semiconductors surface are compared. THz spectral investigation of metallic mesh structures is summarized. Finally, an outlook of THz spectroscopic applications is given.展开更多
This paper reports a new way to detect the enhanced transmission of a THz electromagnetic wave through an Ag/Ag2O layer by THz-TDS （time-domain spectroscopy）. As the THz beam illuminates the sub-wavelength Ag partic...This paper reports a new way to detect the enhanced transmission of a THz electromagnetic wave through an Ag/Ag2O layer by THz-TDS （time-domain spectroscopy）. As the THz beam illuminates the sub-wavelength Ag particles gained by Ag2O thermal decomposition, the evanescent wave is generated. The evanescent wave is coupled by a 500μm-GaAs substrate, which attaches behind the Ag/Ag2O layer, and then it transmits to the far field to be detected. The experimental results indicate that the transmitting amplitude is enhanced, as well as the frequent shifting and spectra broadening.展开更多
Terahertz time-domain spectroscopy(THz-TDS)was utilized to investigate the solid-state reaction between L(+)-Tartaric acid and sodium hydrogen carbonate.Solid sodium hydrogen L(+)-tartrate monohydrate was synthesized ...Terahertz time-domain spectroscopy(THz-TDS)was utilized to investigate the solid-state reaction between L(+)-Tartaric acid and sodium hydrogen carbonate.Solid sodium hydrogen L(+)-tartrate monohydrate was synthesized efficiently by mechanical grinding,which is particularly sustainable and environmentally benign.Distinct THz absorptions were observed for pure reactants and the proposed product.The reaction process could be clearly visualized by THz spectral patterns of the reaction mixtures at different grinding time.The observed results were further confirmed by synchrotron radiation X-ray powder diffraction(SRXRPD)and Fourier transform infrared (FT-IR)spectroscopy.The study demonstrates that THz-TDS is an effective novel tool to monitor solid-state reactions in pharmaceutical industry.展开更多
In this study, the terahertz time-domain spectroscopy (THz-TDS) of crystalline methedrine, which is one of the illegal drugs, is performed using molecular dynamics simulation by the Fourier transform of time derivativ...In this study, the terahertz time-domain spectroscopy (THz-TDS) of crystalline methedrine, which is one of the illegal drugs, is performed using molecular dynamics simulation by the Fourier transform of time derivative auto-correlation functions of the dipole moment. In order to accurately detect the drugs from samples, it is necessary to build a complete database for terahertz spectra under different external conditions from theoretical calculation, which are hardly obtained from the experiments directly. Our results show remarkable consistency with the available experimental data in the frequency range of 10 - 100 cm-1 indicating that the presented method has significant capability to simulate terahertz spectra at various conditions. We investigated the effects of temperature and pressure on THz-TDS by simulating the system at temperature range between 78.4 K and 400 K at pressures up to 100 atm. Results show the spectral features of THz-TDS both in intensity and profile are highly sensitive to the variation of temperature and with a lower magnitude to the variation of pressure. The vanishing, rebuilding and shifting of spectral peaks are due to the complex mechanisms such as the anharmonicity, shifting in the vibration energy levels, formation and destruction of hydrogen-binding and the deformation of the potential energy surface during the environment changing. This improved our understanding for complicated THz-TDS of crystalline methedrine and would be useful for assignment of the practical measurements.展开更多
THz Radar Cross Section(RCS)measurement setup based on THz Time Domain Spectroscopy(TDS)is built to provide large scaled targets test ability in recent years.As calibrations,the metal plates and dihedrons are used in ...THz Radar Cross Section(RCS)measurement setup based on THz Time Domain Spectroscopy(TDS)is built to provide large scaled targets test ability in recent years.As calibrations,the metal plates and dihedrons are used in our experiments.The measurements are performed in a monostatic terahertz time-domain setup.The author proposed time domain and frequency domain calibration methods for angular RCS of calibrations,comparing the measurements with the theory to verify the ability of the time domain measurement setup.展开更多
In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive...In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive indexes. By analyzing the spectra, we got different drops in amplitude and delays in time. The absorption and refractive properties of samples changed with its components and types. In addition, we also found there was a nearly linear relationship between the absorption coefficient and the frequency. We calculated the slope value (K) of each sample by linear fitting, and find the K was corresponding to the contents of the samples. The results showed THz-TDS was an effective method to the analysis of stream sediments.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.61805214)the Fundamental Research Funds for the Central Universities,China(Grant No.2652017142)
文摘Copper sulfate pentahydrate is investigated by terahertz time-domain spectroscopy. It is shown that the terahertz absorption coefficients are correlated with the particle size of the samples, as well as the heating rates of the ambient temperature. Furthermore, the water molecules of copper sulfate pentahydrate can be quantitatively characterized due to the high sensitivity of the terahertz wave to water molecules. Based on such results, the status of water incorporated in mineral opal is also characterized using terahertz time-domain spectroscopy. It indicates that terahertz technology can be considered as an efficient method to detect the dehydration of minerals.
基金National defense technical basic research project,Terahertz detection technology and application research on ceramic matrix composites(JSZL2015411C002)
文摘A method for extracting optical parameters of plastics materials based on terahertz time domain spectroscopy is presented. The transmission-type Terahertz Time-Domain Spectroscopy(THz TDS) system is adopted to detect the refractive index and extinction coefficient on different plastic materials. Then the corresponding spectral information is obtained by Fourier transform of the terahertz time domain waveform of the sampling points, including the corresponding amplitude and phase information of the waveform. The optical parameter extraction model is built. By using the simplex optimization method, the curves of the refractive index and extinction coefficient for the plastic material are obtained. The experimental samples are made of different plastic parallel plate materials. The experimental results show that the optimization of optical parameters can improve their extraction accuracy, and the error of refractive index is ±0.005. Extraction technology with the simplex optimization method of optical parameter based on THz TDS can help to extract the optical parameters of engineering plastics. It is of great significance for the research of terahertz nondestructive testing.
基金Project supported by the Research Foundation of the State Ethnic Affairs Commission of People’s Repulic of China (Grant No. 09ZY012)the National Natural Science Foundation of China (Grant No. 10904176)+1 种基金the "Project 985"the "Project 211" of Minzu University of China
文摘This paper reports that terahertz time-domain spectroscopy is used to measure the optical properties of CuS nanoparticles in composite samples. The complex conductivity of pure CuS nanoparticles is extracted by applying the Bruggeman effective medium theory. The experimental data are consistent with the Drude-Smith model of conductivity in the range of 0.2 1.5 THz. The results demonstrate that carriers become localized with a backscattering behaviour in small-size nanostructures. In addition, the time constant for the carrier scattering is obtained and is only 64.3 fs due to increased electron interaction with interfaces and grain boundaries.
文摘Terahertz （THz） radiation, whose frequency ranges from 0.1 THz to 10.0 THz, has rich science, but limited technology. It has long been considered the last remaining scientific gap in the electromagnetic spectrum. Far from being fully exploited, it offers great opportunities in science, innovation, new technology, and potential applications. THz science and technology enables fundamental research directly impact our lives, from industrial quality control,
基金supported by the National Natural Science Foundation of China under Grant No. 50971094, 61171051Beijing Key Project of Science and Technology Development under Grant No. KZ201310028032
文摘The terahertz time-domain spectroscopy （THz-TDS） system and the related technology and the applications in Capital Normal University are presented. The most often used THz-TDS system as a spectroscopic measurement setup in our lab is introduced in detail, including the THz radiation source, the THz detection method and its measurement, and the control system. THz spectra of various materials is summarized and discussed. These materials include but not limited to two kinds of typical matter-the illegal drugs and explosives. The biological macro-molecules, cosmetics and fine chemical materials, edible pigments and food additives, homocysteic acid and related compounds, heavy ions in soil, Chinese medicines, tobacco and crops, oil and chemical products, carbon nanotubes, superconductors, and various semiconductors and their heterojunctions, are presented. THz emissions from the InAs and InN semiconductors surface are compared. THz spectral investigation of metallic mesh structures is summarized. Finally, an outlook of THz spectroscopic applications is given.
文摘This paper reports a new way to detect the enhanced transmission of a THz electromagnetic wave through an Ag/Ag2O layer by THz-TDS （time-domain spectroscopy）. As the THz beam illuminates the sub-wavelength Ag particles gained by Ag2O thermal decomposition, the evanescent wave is generated. The evanescent wave is coupled by a 500μm-GaAs substrate, which attaches behind the Ag/Ag2O layer, and then it transmits to the far field to be detected. The experimental results indicate that the transmitting amplitude is enhanced, as well as the frequent shifting and spectra broadening.
基金Supported by National Natural Science Foundation of China(Nos.10574134,10805068,and 60907044) and National Basic Research Program of China(No. 2010CB832903)
文摘Terahertz time-domain spectroscopy(THz-TDS)was utilized to investigate the solid-state reaction between L(+)-Tartaric acid and sodium hydrogen carbonate.Solid sodium hydrogen L(+)-tartrate monohydrate was synthesized efficiently by mechanical grinding,which is particularly sustainable and environmentally benign.Distinct THz absorptions were observed for pure reactants and the proposed product.The reaction process could be clearly visualized by THz spectral patterns of the reaction mixtures at different grinding time.The observed results were further confirmed by synchrotron radiation X-ray powder diffraction(SRXRPD)and Fourier transform infrared (FT-IR)spectroscopy.The study demonstrates that THz-TDS is an effective novel tool to monitor solid-state reactions in pharmaceutical industry.
文摘In this study, the terahertz time-domain spectroscopy (THz-TDS) of crystalline methedrine, which is one of the illegal drugs, is performed using molecular dynamics simulation by the Fourier transform of time derivative auto-correlation functions of the dipole moment. In order to accurately detect the drugs from samples, it is necessary to build a complete database for terahertz spectra under different external conditions from theoretical calculation, which are hardly obtained from the experiments directly. Our results show remarkable consistency with the available experimental data in the frequency range of 10 - 100 cm-1 indicating that the presented method has significant capability to simulate terahertz spectra at various conditions. We investigated the effects of temperature and pressure on THz-TDS by simulating the system at temperature range between 78.4 K and 400 K at pressures up to 100 atm. Results show the spectral features of THz-TDS both in intensity and profile are highly sensitive to the variation of temperature and with a lower magnitude to the variation of pressure. The vanishing, rebuilding and shifting of spectral peaks are due to the complex mechanisms such as the anharmonicity, shifting in the vibration energy levels, formation and destruction of hydrogen-binding and the deformation of the potential energy surface during the environment changing. This improved our understanding for complicated THz-TDS of crystalline methedrine and would be useful for assignment of the practical measurements.
基金The Science and Technology Commission of Shanghai Municipality under Grant(16ZR1435000)
文摘THz Radar Cross Section(RCS)measurement setup based on THz Time Domain Spectroscopy(TDS)is built to provide large scaled targets test ability in recent years.As calibrations,the metal plates and dihedrons are used in our experiments.The measurements are performed in a monostatic terahertz time-domain setup.The author proposed time domain and frequency domain calibration methods for angular RCS of calibrations,comparing the measurements with the theory to verify the ability of the time domain measurement setup.
文摘In order to study stream sediments in the terahertz range, we have measured six reference stream sediment samples by terahertz time-domain spectroscopy (THz-TDS). We obtained the absorption coefficients and refractive indexes. By analyzing the spectra, we got different drops in amplitude and delays in time. The absorption and refractive properties of samples changed with its components and types. In addition, we also found there was a nearly linear relationship between the absorption coefficient and the frequency. We calculated the slope value (K) of each sample by linear fitting, and find the K was corresponding to the contents of the samples. The results showed THz-TDS was an effective method to the analysis of stream sediments.
