A special method based on the local equilibrium principle has been introduced in the research of the phase diagram of Mn-MnO system.With this method,the problems of volatilization of Mn and the corrosion of Mn and MnO...A special method based on the local equilibrium principle has been introduced in the research of the phase diagram of Mn-MnO system.With this method,the problems of volatilization of Mn and the corrosion of Mn and MnO to refractory materials were prevented efficiently.The solubility of oxygen in Mn and the composition of the interface between MnO and Mn were determined.Partial phase diagram of Mn-MnO system were constructed according to pres- ent experimental results.展开更多
Numerical methods commonly used for the calculating phase diagrams were listed. A new method to calculate stable phase diagrams was presented which possesse the advantages of both the New-ton Raphson method and the si...Numerical methods commonly used for the calculating phase diagrams were listed. A new method to calculate stable phase diagrams was presented which possesse the advantages of both the New-ton Raphson method and the simplex method. This method is suitable for the calculation of the stable equilibria in complicated systems. For example. calculated results in comparison with experimental results as well as the prediction of new systems were shown in the present work展开更多
Experimental and theoretical studies of the mechanisms of vibration stimulation of oil recovery in watered fields lead to the conclusion that resonance oscillations develop in fractured-block formations. These oscilla...Experimental and theoretical studies of the mechanisms of vibration stimulation of oil recovery in watered fields lead to the conclusion that resonance oscillations develop in fractured-block formations. These oscillations, caused by weak but long-lasting and frequency-stable influences, create the conditions for ultrasonic wave’s generation in the layers, which are capable of destroying thickened oil membranes in reservoir cracks. For fractured-porous reservoirs in the process of exploitation by the method of water high-pressure oil displacement, the possibility of intensifying ultrasonic vibrations can have an important technological significance. Even a very weak ultrasound can destroy, over a long period of time, the viscous oil membranes formed in the cracks between the blocks, which can be the reason for lowering the permeability of the layers and increasing the oil recovery. To describe these effects, it is necessary to consider the wave process in a hierarchically blocky environment and theoretically simulate the mechanism of the appearance of self-oscillations under the action of relaxation shear stresses. For the analysis of seism acoustic response in time on fixed intervals along the borehole an algorithm of phase diagrams of the state of many-phase medium is suggested.展开更多
The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design...The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams （CALPHAD） method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.展开更多
In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main ...In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main objective is to evaluate the efficiency and accuracy of the methods in separation of anomalies on the shear zone gold mineralization.For this purpose,samples were taken from the secondary lithogeochemical environment(stream sediment samples)on the gold mineralization in Saqqez,NW of Iran.Interpretation of the histograms and diagrams showed that the MPD is capable of identifying two phases of mineralization.The fractal method could separate only one phase of change based on the fractal dimension with high concentration areas of the Au element.The spatial analysis showed two mixed subpopulations after U=0 and another subpopulation with very high U values.The MPD analysis followed spatial analysis,which shows the detail of the variations.Six mineralized zones detected from local geochemical exploration results were used for validating the methods mentioned above.The MPD method was able to identify the anomalous areas higher than 90%,whereas the two other methods identified 60%(maximum)of the anomalous areas.The raw data without any estimation for the concentration was used by the MPD method using aminimum of calculations to determine the threshold values.Therefore,the MPD method is more robust than the other methods.The spatial analysis identified the detail soft hegeological and mineralization events that were affected in the study area.MPD is recommended as the best,and the spatial U-analysis is the next reliable method to be used.The fractal method could show more detail of the events and variations in the area with asymmetrical grid net and a higher density of sampling or at the detailed exploration stage.展开更多
A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-C...A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-CaBt2 system has been determined by visual polythermal method in order to prove the prediction. The phase diagrams of the quasibinary system KCl-CsBr, KCl-CaBr2 and the quasiternary system CsBr-CaBr2-KCl were determined by using visual polythermal method. The phase diagrams of CsBr-CaBr2 and KCl-CaBr2 show that the intermediate compound is formed. The results are in agreement with the computer prediction. Here, the various parts of the phase diagram of the quasiternary system CsBr-CaBr2-KCl were discussed.展开更多
We used the Jordan-Wigner transform and the invariant eigenoperator method to study the magnetic phase diagram and the magnetization curve of the spin-1/2 alternating ferrimagnetic diamond chain in an external magneti...We used the Jordan-Wigner transform and the invariant eigenoperator method to study the magnetic phase diagram and the magnetization curve of the spin-1/2 alternating ferrimagnetic diamond chain in an external magnetic field at finite temperature.The magnetization versus external magnetic field curve exhibits a 1/3 magnetization plateau at absolute zero and finite temperatures,and the width of the 1/3 magnetization plateau was modulated by tuning the temperature and the exchange interactions.Three critical magnetic field intensities H_(CB),H_(CE)and H_(CS) were obtained,in which the H_(CB) and H_(CE)correspond to the appearance and disappearance of the 1/3 magnetization plateau,respectively,and the higher H_(CS) correspond to the appearance of fully polarized magnetization plateau of the system.The energies of elementary excitation hω_(σ,k)(σ=1,2,3)present the extrema of zero at the three critical magnetic fields at 0 K,i.e.,[hω_(3,k)(H_(CB)]_(min)=0,[hω_(2,k)(H_(CE)]_(max)=0 and[hω_(2,k)(H_(CS)]_(min)=0,and the magnetic phase diagram of magnetic field versus different exchange interactions at 0 K was established by the above relationships.According to the relationships between the system’s magnetization curve at finite temperatures and the critical magnetic field intensities,the magnetic field-temperature phase diagram was drawn.It was observed that if the magnetic phase diagram shows a three-phase critical point,which is intersected by the ferrimagnetic phase,the ferrimagnetic plateau phase,and the Luttinger liquid phase,the disappearance of the 1/3 magnetization plateau would inevitably occur.However,the 1/3 magnetization plateau would not disappear without the three-phase critical point.The appearance of the 1/3 magnetization plateau in the low temperature region is the macroscopic manifestations of quantum effect.展开更多
The refolding of reduced and non-reducing egg white lysozymes in a urea solution was studied by a ＂phase diagram＂ method of fluorescence. The result showed that in the refolding of the reduced egg white lysozyme, an...The refolding of reduced and non-reducing egg white lysozymes in a urea solution was studied by a ＂phase diagram＂ method of fluorescence. The result showed that in the refolding of the reduced egg white lysozyme, an intermediate state of an egg white lysozyme exists at the urea concentrations in a final renaturation solution being about 4.5 mol/L, their refolding follows a three-state model; while in the refolding of the non-reducing egg white lysozyme, two intermediate states exist at the urea concentrations being separately 4.0 and 2.5 mol/L, and their refolding follows a four-state model. Through the comparison between the unfolding and refolding of an egg white lysozyme in the urea solution, it was found that both of the refolding of reduced and non-reducing egg white lysozyme molecules was irreversible to their unfolding in the urea solution. Finally, a suggested refolding was separately presented for the reduced and non-reducing egg white lysozymes in the urea solution.展开更多
文摘A special method based on the local equilibrium principle has been introduced in the research of the phase diagram of Mn-MnO system.With this method,the problems of volatilization of Mn and the corrosion of Mn and MnO to refractory materials were prevented efficiently.The solubility of oxygen in Mn and the composition of the interface between MnO and Mn were determined.Partial phase diagram of Mn-MnO system were constructed according to pres- ent experimental results.
文摘Numerical methods commonly used for the calculating phase diagrams were listed. A new method to calculate stable phase diagrams was presented which possesse the advantages of both the New-ton Raphson method and the simplex method. This method is suitable for the calculation of the stable equilibria in complicated systems. For example. calculated results in comparison with experimental results as well as the prediction of new systems were shown in the present work
文摘Experimental and theoretical studies of the mechanisms of vibration stimulation of oil recovery in watered fields lead to the conclusion that resonance oscillations develop in fractured-block formations. These oscillations, caused by weak but long-lasting and frequency-stable influences, create the conditions for ultrasonic wave’s generation in the layers, which are capable of destroying thickened oil membranes in reservoir cracks. For fractured-porous reservoirs in the process of exploitation by the method of water high-pressure oil displacement, the possibility of intensifying ultrasonic vibrations can have an important technological significance. Even a very weak ultrasound can destroy, over a long period of time, the viscous oil membranes formed in the cracks between the blocks, which can be the reason for lowering the permeability of the layers and increasing the oil recovery. To describe these effects, it is necessary to consider the wave process in a hierarchically blocky environment and theoretically simulate the mechanism of the appearance of self-oscillations under the action of relaxation shear stresses. For the analysis of seism acoustic response in time on fixed intervals along the borehole an algorithm of phase diagrams of the state of many-phase medium is suggested.
基金This study was financially supported by the National Natural Science Foundation of China and Chongqing Science and Technology Commission.
文摘The Mg-Al-Zn-Y-Ce system is one of the key systems for designing high-strength Mg alloys. The purpose of the present article is to develop a thermodynamic database for the Mg-Al-Zn-Y-Ce multicomponent system to design Mg alloys using the calculation of phase diagrams （CALPHAD） method, where the Gibbs energies of solution phases such as liquid, fcc, bcc, and hcp phases were described by the subregular solution model, whereas those of all the compounds were described by the sublattice model. The thermodynamic parameters describing Gibbs energies of the different phases in this database were evaluated by fitting the experimental data for phase equilibria and thermodynamic properties. On the basis of this database, a lot of information concerning stable and metastable phase equilibria of isothermal and vertical sections, molar fractions of constituent phases, the liquidus projection, etc., can be predicted. This database is expected to play an important role in the design of Mg alloys.
文摘In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main objective is to evaluate the efficiency and accuracy of the methods in separation of anomalies on the shear zone gold mineralization.For this purpose,samples were taken from the secondary lithogeochemical environment(stream sediment samples)on the gold mineralization in Saqqez,NW of Iran.Interpretation of the histograms and diagrams showed that the MPD is capable of identifying two phases of mineralization.The fractal method could separate only one phase of change based on the fractal dimension with high concentration areas of the Au element.The spatial analysis showed two mixed subpopulations after U=0 and another subpopulation with very high U values.The MPD analysis followed spatial analysis,which shows the detail of the variations.Six mineralized zones detected from local geochemical exploration results were used for validating the methods mentioned above.The MPD method was able to identify the anomalous areas higher than 90%,whereas the two other methods identified 60%(maximum)of the anomalous areas.The raw data without any estimation for the concentration was used by the MPD method using aminimum of calculations to determine the threshold values.Therefore,the MPD method is more robust than the other methods.The spatial analysis identified the detail soft hegeological and mineralization events that were affected in the study area.MPD is recommended as the best,and the spatial U-analysis is the next reliable method to be used.The fractal method could show more detail of the events and variations in the area with asymmetrical grid net and a higher density of sampling or at the detailed exploration stage.
文摘A computer prediction for the regularities of formation of binary bromide system was made. The results indicate that CsBr-CaBf2 molten salt system is binary complex compound-forming system. The phase diagram of CSBr-CaBt2 system has been determined by visual polythermal method in order to prove the prediction. The phase diagrams of the quasibinary system KCl-CsBr, KCl-CaBr2 and the quasiternary system CsBr-CaBr2-KCl were determined by using visual polythermal method. The phase diagrams of CsBr-CaBr2 and KCl-CaBr2 show that the intermediate compound is formed. The results are in agreement with the computer prediction. Here, the various parts of the phase diagram of the quasiternary system CsBr-CaBr2-KCl were discussed.
基金the National Natural Science Foundation of China(Grant Nos.11374215 and 11704262)the Scientific Study Project from Education Department of Liaoning Province of China(Grant No.LJ2019004)the Natural Science Foundation Guidance Project of Liaoning Province of China(Grant No.2019-ZD-0070).
文摘We used the Jordan-Wigner transform and the invariant eigenoperator method to study the magnetic phase diagram and the magnetization curve of the spin-1/2 alternating ferrimagnetic diamond chain in an external magnetic field at finite temperature.The magnetization versus external magnetic field curve exhibits a 1/3 magnetization plateau at absolute zero and finite temperatures,and the width of the 1/3 magnetization plateau was modulated by tuning the temperature and the exchange interactions.Three critical magnetic field intensities H_(CB),H_(CE)and H_(CS) were obtained,in which the H_(CB) and H_(CE)correspond to the appearance and disappearance of the 1/3 magnetization plateau,respectively,and the higher H_(CS) correspond to the appearance of fully polarized magnetization plateau of the system.The energies of elementary excitation hω_(σ,k)(σ=1,2,3)present the extrema of zero at the three critical magnetic fields at 0 K,i.e.,[hω_(3,k)(H_(CB)]_(min)=0,[hω_(2,k)(H_(CE)]_(max)=0 and[hω_(2,k)(H_(CS)]_(min)=0,and the magnetic phase diagram of magnetic field versus different exchange interactions at 0 K was established by the above relationships.According to the relationships between the system’s magnetization curve at finite temperatures and the critical magnetic field intensities,the magnetic field-temperature phase diagram was drawn.It was observed that if the magnetic phase diagram shows a three-phase critical point,which is intersected by the ferrimagnetic phase,the ferrimagnetic plateau phase,and the Luttinger liquid phase,the disappearance of the 1/3 magnetization plateau would inevitably occur.However,the 1/3 magnetization plateau would not disappear without the three-phase critical point.The appearance of the 1/3 magnetization plateau in the low temperature region is the macroscopic manifestations of quantum effect.
基金Project supported by the Natural Science Foundation of Shaanxi Province [No. 2001K 10-G3-（3）].
文摘The refolding of reduced and non-reducing egg white lysozymes in a urea solution was studied by a ＂phase diagram＂ method of fluorescence. The result showed that in the refolding of the reduced egg white lysozyme, an intermediate state of an egg white lysozyme exists at the urea concentrations in a final renaturation solution being about 4.5 mol/L, their refolding follows a three-state model; while in the refolding of the non-reducing egg white lysozyme, two intermediate states exist at the urea concentrations being separately 4.0 and 2.5 mol/L, and their refolding follows a four-state model. Through the comparison between the unfolding and refolding of an egg white lysozyme in the urea solution, it was found that both of the refolding of reduced and non-reducing egg white lysozyme molecules was irreversible to their unfolding in the urea solution. Finally, a suggested refolding was separately presented for the reduced and non-reducing egg white lysozymes in the urea solution.
