BiFeO_(3)(BFO)has received considerable attention as a lead-free ferroelectric film due to its large theoretical remnant polariza-tion.However,BFO suffers from a large leakage current,resulting in poor ferroelectric p...BiFeO_(3)(BFO)has received considerable attention as a lead-free ferroelectric film due to its large theoretical remnant polariza-tion.However,BFO suffers from a large leakage current,resulting in poor ferroelectric properties.Herein,the sol-gel method was used to deposit a series of BFO-based thin films on fluorine-doped tin oxide substrates,and the effects of the substitution of the elements Co,Cu,Mn(B-site)and Sm,Eu,La(A-site)on the crystal structure,ferroelectricity,and leakage current of the BFO-based thin films were invest-igated.Results confirmed that lattice distortion by X-ray diffraction can be attributed to the substitution of individual elements in the BFO-based films.Sm and Eu substitutions contribute to the lattice distortion in a pseudo-cubic structure,while La is biased toward pseudo-tet-ragonal.Piezoelectric force microscopy confirmed that reversible switching of ferroelectric domains by nearly 180°can be realized through the prepared films.The ferroelectric hysteresis loops showed that the order for the polarization contribution is as follows:Cu>Co>Mn(B-site),Sm>La>Eu(A-site).The current density voltage curves indicated that the order for leakage contribution is as follows:Mn<Cu<Co(B-site),La<Eu<Sm(A-site).Scanning electron microscopy showed that the introduction of Cu elements facilitates the formation of dense grains,and the grain size distribution statistics proved that La element promotes the reduction of grain size,leading to the increase of grain boundaries and the reduction of leakage.Finally,a Bi_(0.985)Sm_(0.045)La_(0.03)Fe_(0.96)Co_(0.02)Cu_(0.02)O_(3)(SmLa-CoCu)thin film with a qualitative leap in the remnant polarization from 25.5(Bi_(0.985)Sm_(0.075)FeO_(3))to 98.8µC/cm^(2)(SmLa-CoCu)was prepared through the syner-gistic action of Sm,La,Co,and Cu elements.The leakage current is also drastically reduced from 160 to 8.4 mA/cm^(2)at a field strength of 150 kV/cm.Thus,based on the increasing entropy strategy of chemical engineering,this study focuses on enhancing ferroelectricity and decreasing leakage current,providing a promising path for the advancement of ferroelectric devices.展开更多
The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ...The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ensemble (GCE) that the kinetic energy distribution of the solute is a common characteristic of the entropy and the distribution of solute zones.Under the assumptions. EI of the solute system is directly proportional to the logarithm of the difference between one and one half of the substantial separation ratio. the ratio of moles of a sparated solute to its total moles. and EIPUT is direchy proportional to corrected separation rate of separation system. EI or EIPUT is a important bridge between separation efficiency of chromatography or electrophoresis and operating parameters, especially. when nonequilibriumthermodynamics(NET) would be adopted.展开更多
We show that the collapse of the entangled quantum state makes the entropy increase in an isolated system. The second law of thermodynamics is thus proven in its most genera/form.
In this paper,based on the generalized heat transfer law,an air conditioning system is analyzed with the entropy generation minimization and the entransy theory.Taking the coefficient of performance（denoted as COP） ...In this paper,based on the generalized heat transfer law,an air conditioning system is analyzed with the entropy generation minimization and the entransy theory.Taking the coefficient of performance（denoted as COP） and heat flow rate Qout which is released into the room as the optimization objectives,we discuss the applicabilities of the entropy generation minimization and entransy theory to the optimizations.Five numerical cases are presented.Combining the numerical results and theoretical analyses,we can conclude that the optimization applicabilities of the two theories are conditional.If Qout is the optimization objective,larger entransy increase rate always leads to larger Qout,while smaller entropy generation rate does not.If we take COP as the optimization objective,neither the entropy generation minimization nor the concept of entransy increase is always applicable.Furthermore,we find that the concept of entransy dissipation is not applicable for the discussed cases.展开更多
基金supported by the National Natural Science Foundation of China(No.22371013)the National Key Research and Development Program of China(No.2018YFA0703700)+3 种基金the Fundamental Research Funds for the Central Universities,China(Nos.FRF-IDRY-19-007 and FRF-TP-19-055A2Z)the National Program for Support of Top-notch Young Professionals,Chinathe Young Elite Scientists Sponsorship Program by the China Association for Science and Technology(CAST),China(No.2019-2021 QNRC)the“Xiaomi Young Scholar”Funding Project,China.
文摘BiFeO_(3)(BFO)has received considerable attention as a lead-free ferroelectric film due to its large theoretical remnant polariza-tion.However,BFO suffers from a large leakage current,resulting in poor ferroelectric properties.Herein,the sol-gel method was used to deposit a series of BFO-based thin films on fluorine-doped tin oxide substrates,and the effects of the substitution of the elements Co,Cu,Mn(B-site)and Sm,Eu,La(A-site)on the crystal structure,ferroelectricity,and leakage current of the BFO-based thin films were invest-igated.Results confirmed that lattice distortion by X-ray diffraction can be attributed to the substitution of individual elements in the BFO-based films.Sm and Eu substitutions contribute to the lattice distortion in a pseudo-cubic structure,while La is biased toward pseudo-tet-ragonal.Piezoelectric force microscopy confirmed that reversible switching of ferroelectric domains by nearly 180°can be realized through the prepared films.The ferroelectric hysteresis loops showed that the order for the polarization contribution is as follows:Cu>Co>Mn(B-site),Sm>La>Eu(A-site).The current density voltage curves indicated that the order for leakage contribution is as follows:Mn<Cu<Co(B-site),La<Eu<Sm(A-site).Scanning electron microscopy showed that the introduction of Cu elements facilitates the formation of dense grains,and the grain size distribution statistics proved that La element promotes the reduction of grain size,leading to the increase of grain boundaries and the reduction of leakage.Finally,a Bi_(0.985)Sm_(0.045)La_(0.03)Fe_(0.96)Co_(0.02)Cu_(0.02)O_(3)(SmLa-CoCu)thin film with a qualitative leap in the remnant polarization from 25.5(Bi_(0.985)Sm_(0.075)FeO_(3))to 98.8µC/cm^(2)(SmLa-CoCu)was prepared through the syner-gistic action of Sm,La,Co,and Cu elements.The leakage current is also drastically reduced from 160 to 8.4 mA/cm^(2)at a field strength of 150 kV/cm.Thus,based on the increasing entropy strategy of chemical engineering,this study focuses on enhancing ferroelectricity and decreasing leakage current,providing a promising path for the advancement of ferroelectric devices.
文摘The entropy increase (EI) and the entropy increase per unit time (EIPUT) of the solute zone are chosen as new criteria of separation efficiency in chromatography and electrophoresis. It is verified by grand canonical ensemble (GCE) that the kinetic energy distribution of the solute is a common characteristic of the entropy and the distribution of solute zones.Under the assumptions. EI of the solute system is directly proportional to the logarithm of the difference between one and one half of the substantial separation ratio. the ratio of moles of a sparated solute to its total moles. and EIPUT is direchy proportional to corrected separation rate of separation system. EI or EIPUT is a important bridge between separation efficiency of chromatography or electrophoresis and operating parameters, especially. when nonequilibriumthermodynamics(NET) would be adopted.
基金The project supported by National Natural Science Foundation of China under Grant No.10305001
文摘We show that the collapse of the entangled quantum state makes the entropy increase in an isolated system. The second law of thermodynamics is thus proven in its most genera/form.
基金Project supported by the Youth Programs of Chongqing Three Gorges University,China(Grant No.13QN18)
文摘In this paper,based on the generalized heat transfer law,an air conditioning system is analyzed with the entropy generation minimization and the entransy theory.Taking the coefficient of performance（denoted as COP） and heat flow rate Qout which is released into the room as the optimization objectives,we discuss the applicabilities of the entropy generation minimization and entransy theory to the optimizations.Five numerical cases are presented.Combining the numerical results and theoretical analyses,we can conclude that the optimization applicabilities of the two theories are conditional.If Qout is the optimization objective,larger entransy increase rate always leads to larger Qout,while smaller entropy generation rate does not.If we take COP as the optimization objective,neither the entropy generation minimization nor the concept of entransy increase is always applicable.Furthermore,we find that the concept of entransy dissipation is not applicable for the discussed cases.
