Effect of TbF_(3)diffusion on the demagnetization behavior and domain evolution of sintered Nd-Fe-B magnets by electrophoretic deposition

We studied the magnetic properties and domain evolution of annealed and TbF3-diffused sintered Nd-Fe-B magnets using the electrophoretic deposition method.After TbF_(3)diffusion,the coercivity increased significantly by 9.9 kOe and microstructural analysis suggested that Tb favored the formation of the(Nd,Tb)_(2)Fe_(14)B shell phase in the outer region of the matrix grains.The first magnetization reversal and the dynamic successive domain propagation process were detected with a magneto-optical Kerr microscope.For the TbF_(3)-diffused magnet,the magnetization reversal appeared at a larger applied field and the degree of simultaneous magnetization reversal decreased compared with an annealed magnet.During demagnetization after full magnetization,the occurrence of domain wall motion(DWM)in the reproduced multi-domain regions was observed by the step method.The maximum polarization change resulting from the reproduced DWM was inversely related to the coercivity.The increased coercivity for the diffused magnet was mainly attributed to the more difficult nucleation of the magnetic reversed region owing to the improved magneto-crystalline anisotropy field as a result of Tb diffusion.

Entropy variances of pure coherent states in the diffusion channel

Using the operator correspondence of the real and fictious modes in the thermo entangled state representation, wesolve the quantum master equation describing the diffusion channel and obtain the Kraus operator-sum representation ofits analytical solution. we find that the pure coherent states evolve into the new mixed thermal superposed states in thediffusion channel. Also, we investigate the statistical properties of the initial coherent states and their entropy evolutions inthe diffusion channel, and find that the entropy evolutions are only related to the decay time and without the amplitudes ofthe initial coherent states.

Temporal Analysis of the Diffusion of Knowledge in Networks of Software Maintenance and Development Project Team

Different approaches have been established for applications of social and complex networks involving biological systems, passing through collaborative systems in knowledge networks and organizational systems. In this latter application, we highlight the studies focused on the diffusion of information and knowledge in networks. However, most of the time, the propagation of information in these networks and the resulting process of creation and diffusion of knowledge, have been studied from static perspectives. Additionally, the very concept of diffusion inevitably implies the inclusion of the temporal dimension, due to that it is an essentially dynamic process. Although static analysis provides an important perspective in structural terms, the behavioral view that reflects the evolution of the relationships of the members of these networks over time is best described by temporal networks. Thus, it is possible to analyze both the information flow and the structural changes that occur over time, which influences the dynamics of the creation and diffusion of knowledge. This article describes the computational modeling used to elucidate the creation and diffusion of knowledge in temporal networks formed to execute software maintenance and construction projects, for the period between 2007 and 2013, in the SERVIÇO FEDERAL DE PROCESSAMENTO DE DADOS (FEDERAL DATA PROCESSING SERVICE-SERPRO)—a public organization that provides information and communication technology services. The methodological approach adopted for the study was based on techniques for analyzing social and complex networks and on the complementary extensions that address temporal modeling of these networks. We present an exploratory longitudinal study that enabled a dynamic and structural analysis of the knowledge networks formed by members of software maintenance and development project teams between 2007 and 2013. The study enabled identification of knowledge categories throughout this period, in addition to the determination that the networks have a structure with small-world and scale-free models. Finally, we concluded that, in general, the topologies of the networks studies had characteristics for facilitating the flow of knowledge within the organization.

General laws of funding for scientific citations:how citations change in funded and unfunded research between basic and applied sciences

Purpose:The goal of this study is to analyze the relationship between funded and unfunded papers and their citations in both basic and applied sciences.Design/methodology/approach:A power law model analyzes the relationship between research funding and citations of papers using 831,337 documents recorded in the Web of Science database.Findings:The original results reveal general characteristics of the diffusion of science in research fields:a)Funded articles receive higher citations compared to unfunded papers in journals;b)Funded articles exhibit a super-linear growth in citations,surpassing the increase seen in unfunded articles.This finding reveals a higher diffusion of scientific knowledge in funded articles.Moreover,c)funded articles in both basic and applied sciences demonstrate a similar expected change in citations,equivalent to about 1.23%,when the number of funded papers increases by 1%in journals.This result suggests,for the first time,that funding effect of scientific research is an invariant driver,irrespective of the nature of the basic or applied sciences.Originality/value:This evidence suggests empirical laws of funding for scientific citations that explain the importance of robust funding mechanisms for achieving impactful research outcomes in science and society.These findings here also highlight that funding for scientific research is a critical driving force in supporting citations and the dissemination of scientific knowledge in recorded documents in both basic and applied sciences.Practical implications:This comprehensive result provides a holistic view of the relationship between funding and citation performance in science to guide policymakers and R&D managers with science policies by directing funding to research in promoting the scientific development and higher diffusion of results for the progress of human society.

On the Relationship between the Evolution of Technological Firms and Their Knowledge Development Regimes

Differences in knowledge regimes and growth dynamics amongst four ideal types of knowledge based firms are analyzed. Two aspects of technological knowledge, technological opportunity and appropriability are traditionally seen as vital to understand the incentives for research and development activities in firms. However, they do not fully define the technology regimes, when one asks how the knowledge based firm competes. Therefore, the dynamic nature of firm capabilities and knowledge development in terms of expansion and in terms of deepening are also discussed. These two additional aspects of knowledge implies that even if all firms in an industry can be considered to be knowledge intensive these firms do also differ. Using cases of entrepreneurial start-up firms in Sweden, we illustrate whether our conceptual ideas of knowledge development help us understand the diversity and contradictions of firm evolution. Our finding is that firm evolution and capability development is dependent upon both the potential for expanding knowledge, such as by innovations, and by deepening the understanding within established knowledge, such as by learning. This implies that the shaping of a science based industry must be seen in relation both to the value of current knowledge and capabilities together with the sometimes only limited and temporarily advantages of radical innovations.

Time-dependent effects in transient liquid phase bonding of 304L and Cp-Ti using an Ag-Cu interlayer

One of the challenges for bimetal manufacturing is the joining process.Hence,transient liquid phase(TLP)bonding was performed between 304L stainless steel and Cp-Ti using an Ag-Cu interlayer with a thickness of 75μm for bonding time of 20,40,60,and 90 min.The bonding temperature of 860℃ was considered,which is under the β transus temperature of Cp-Ti.During TLP bonding,various intermetallic compounds(IMCs),including Ti_(5)Cr_(7)Fe_(17),(Cr,Fe)_(2)Ti,Ti(Cu,Fe),Ti_(2)(Cu,Ag),and Ti_(2)Cu from 304L toward Cp-Ti formed in the joint.Also,on the one side,with the increase in time,further diffusion of elements decreases the blocky IMCs such as Ti_(5)Cr_(7)Fe_(17),(Cr,Fe)_(2)Ti,Ti(Cu,Fe)in the 304L diffusion-affected zone(DAZ)and reaction zone,and on the other side,Ti_(2)(Cu,Ag)IMC transformed into fine morphology toward Cp-Ti DAZ.The microhardness test also demonstrated that the(Cr,Fe)_(2)Ti+Ti_(5)Cr_(7)Fe_(17) IMCs in the DAZ on the side of 304L have a hardness value of HV 564,making it the hardest phase.The maximum and minimum shear strength values are equal to 78.84 and 29.0 MPa,respectively.The cleavage pattern dominated fracture surfaces due to the formation of brittle phases in dissimilar joints.

Looking up Prescriptions to Treat Infectious Disease:Anti-epidemic Books of Medical Formularies and Epidemic Prevention and Control in the Qing Dynasty

Copying,compiling,publishing,disseminating,and referencing anti-epidemic books of medical formularies were common activities during the outbreak of epidemics in the Qing dynasty.Its emergence,motivated by epidemic disease again and again,was important component parts of epidemic prevention and control.They played a unique role as media on affairs such as treating patients suffering from infectious diseases,mobilizing peoples to make contributions to anti-epidemic activities,integrating and popularizing knowledge of epidemic prevention.Anti-epidemic books of medical formularies were important to link peoples,things,and substances related with epidemic prevention and control,and were a kind of motivation to actively deal with the infectious disease,control the epidemic,and maintain health.Compared to other common measures,anti-epidemic books of medical formularies participated in many prevention and control practices deeply,which actually built a low cost,spontaneous,dispersed and non-institutional system to respond to epidemic,and the system had characteristics of stronger conductibility,bigger coverage area,and better external benefits.

Thermal properties of harzburgite and dunite at 0.8–3 GPa and 300–823 K and implications for the thermal evolution of Tibet

Thermal diffusivity(D)and thermal conductivity(κ)of harzburgite and dunite from Luobusha ophiolite were simultaneously measured up to 3 GPa and 823 K using the transient plane-source method in a multi anvil apparatus.The results show that the values of D andκof both samples systematically decrease with increasing temperature and increase with increasing pressure.By combination of the thermal physical data of rocks and minerals and geophysical constraints,we performed numerical simulation on the thermal evolution of Tibet vary over depth,distance and geologic ages.The present results provide new constraints on occurrence of partial melting and its geophysical significance beneath Tibetan crust.

Evolution of Campus Form from the Perspective of Knowledge Science

Through analyzing influence of various factors on spatial form of campus, the author proposed from the perspective of knowledge science that orientation and mode of knowledge activities play a decisive role in the spatial form evolution of campus, and then demonstrated the viewpoint by elaborating spatial form evolution history of campuses of different ages in different regions. On this basis, the future development trend of campus form in the information era was explored.

The influences of convective overshooting and semiconvection on the chemical evolution of massive stars

In massive stars, convection in the interior is different from that of inter- mediate and small mass stars. In the main-sequence phase of small mass stars, there is a convective core and a radiative envelope, between which are the radiative inter- mediate layers with uneven chemical abundances. Semiconvection would occur in the intermediate layers between the convective core and the homogeneous envelope in massive stars. We treat core convective overshooting and semiconvection together as a process. We found that when decreasing overshooting, the semiconvection is more pronounced. In these two processes, we introduce one diffusive parameter D, which is different from other authors who have introduced different parameters for these two zones. The influences of the turbulent diffusion process on chemical evolution and other quantities of the stellar structure are shown in the present paper.

The spontaneous evolution of components of Ag-ultrafine particle in diffusion process

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Effect of liquid diffusion coefficients on microstructure evolution during solidification of Al356.1 alloy

（The effect of liquid diffusion coefficients on the microstructure evolution during solidification of primary （Al） phase in Al356.1 alloy was investigated by means of the phase-field simulation using two sets of diffusion coefficients in liquid phase, while fixing other thermophysical and numerical parameters. The first set is only with impurity coefficients of liquid phase in Arrhenius formula representing only the temperature dependence. While the second set is with the well-established atomic mobility database representing both temperature and concentration dependence. For the second set of liquid diffusion coefficients, the effect of non-diagonal diffusion coefficients on the microstructure evolution in Al356.1 alloy during solidification was also analyzed. The differences were observed in the morphology, tip velocity and composition profile ahead of the tip of the dendrite due to the three cases of liquid diffusivities. The simulation results indicate that accurate databases of mobilities in the liquid phase are highly needed for the quantitative simulation of microstructural evolution during solidification.

Mesoporous molybdenum carbide for greatly enhanced hydrogen evolution at high current density and its mechanism studies

Currently the catalysis of hydrogen evolution reaction(HER)is mainly focused on the inherent electrocatalytic activity at relatively lower current densities while scarce at high current densities.Nevertheless,the latter is highly demanding in efficient mass-production of hydrogen.A SiO_(2) nanospheres template-synthesis is used to prepare mesoporous molybdenum carbide nanocrystals-embedded nitrogen-doped carbon foams(mp-Mo_(2)C/NC).The material shows much more excellent catalytic activity than the non-etched Mo_(2)C/NC toward hydrogen evolution reaction(HER)in acidic medium.More interestingly mp-Mo_(2)C/NC still has larger overpotential than Pt/C at lower current densities,but possess remarkably smaller overpotential than the latter at higher current densities for much better electrocatalytic performance.An approach is developed to investigate the electrode kinetics by Tafel plots,especially with eliminating the diffusion effect,indicating that Pt/C and mp-Mo_(2)C/NC display different reaction mechanisms.At low current densities the former presents reversible reaction,while the latter shows mixed electrochemical polarization/reversible electrode process.In the region of higher current densities,the former becomes totally gas-diffusion controlled with large overpotential,while the latter can still retain an electrode polarization process for much lower overpotential at the same current density.Result endorses that the meso-porously structured mp-Mo_(2)C/NC plays a critical role in avoiding gas diffusion control-resulting large overpotential at high current densities.This work holds great potential for an inexpensive catalyst better than Pt/C in practical applications of mass-production hydrogen at high current densities,while clearly shedding fundamental lights on designs of rational HER catalysts for the uses at high current densities.

A theoretical analysis of the electromigration-induced void morphological evolution under high current density

In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed void shapes: circular, ellipse, and cardioid. Void morphological evolution is governed by the competition between the electric field and surface capillary force. In the developed model, both the electric field and capillary force on the void's surface are solved analytically. Based on the mass conversation principle, the normal velocity on the void surface during diffusion is obtained. The void morphological evolution behavior is investigated, and a physical model is developed to predict void collapse to a crack or to split into sub-voids under electric current. It is noted that when the electric current is being applied from the horizontal direction, a circular void may either move stably along the electric current direction or collapse to a finger shape, depending on the relative magnitude of the electric current and surface capillary force. However, the elliptical-shaped void will elongate along the electric current direction and finally collapse to the finger shape. On the other hand, the cardioid-shaped void could bifurcate into two sub-voids when the electric current reaches a critical value. The theoretical predictions agree well with the experimental observations.

Dynamic models of technology management capability development based on knowledge diffusion

Technology management is recognized as a key for organizations to achieve competitiveness. How to promote an organization’s technology management capability is of great significance in creating efficiencies and achieving a competitive edge. The knowledge essence of technology management capability is introduced and then the correlation between knowledge diffusion and the development of technology management capability is discussed. Further, the basic and extended dynamic models of the development of technology management capability are constructed, and is applied into an enterprise. The results show that the dynamic models can well explain how the knowledge improves the development of technology management capability, and they can be used as an useful tool by an enterprise to promote technology management capability. Finally, the managerial implications of the models are discussed.

NATIONAL KNOWLEDGE INNOVATION SYSTEMS: EVOLUTION, DEFINITION AND INDICATORS

The paper examines the three stages of the evolution of national innovation systems: national technology innovation systems, national innovation systems and national knowledge innovation systems. A national knowledge innovation system is a network of institutions and organizations which jointly or individually contributes to the knowledge innovation (including scientific and technical knowledge innovation). The author stresses that knowledge innovation will occur in all processes of the produc-tion, transmission and use of knowledge. There are four subsystems in this system: scientific knowledge innovation, technical knowledge innovation, knowledge trans-mission and knowledge use subsystem. The author also lists some indicators for the System.

BOUNDARY LAYER AND VANISHING DIFFUSION LIMIT FOR NONLINEAR EVOLUTION EQUATIONS

In this paper, we consider an initial-boundary value problem for some nonlinear evolution equations with damping and diffusion. The main purpose is to investigate the boundary layer effect and the convergence rates as the diffusion parameter α goes to zero.

Time evolution of negative binomial optical field in a diffusion channel

We find the time evolution law of a negative binomial optical field in a diffusion channel. We reveal that by adjusting the diffusion parameter, the photon number can be controlled. Therefore, the diffusion process can be considered a quantum controlling scheme through photon addition.

Hydrogen evolution-assisted one-pot aqueous synthesis of hierarchical trimetallic PdNiRu nanochains for hydrazine oxidation reaction

A hydrogen evolution-assisted one-pot aqueous approach was developed for facile synthesis of trimetallic Pd Ni Ru alloy nanochain-like networks（Pd Ni Ru NCNs） by only using KBHas the reductant, without any specific additive（e.g. surfactant, polymer, template or seed）. The products were mainly investigated by transmission electron microscopy（TEM）, X-ray diffraction（XRD） and X-ray photoelectron spectroscopy（XPS）. The hierarchical architectures were formed by the oriented assembly growth and the diffusioncontrolled deposition in the presence of many in-situ generated hydrogen bubbles. The architectures had the largest electrochemically active surface area（ECSA） of 84.32 mgPdthan Pd Ni nanoparticles(NPs,65.23 mgPd), Pd Ru NPs(23.12 mgPd), Ni Ru NPs（nearly zero）, and commercial Pd black(6.01 mgPd), outperforming the referenced catalysts regarding the catalytic characters for hydrazine oxygen reaction（HOR）. The synthetic route provides new insight into the preparation of other trimetallic nanocatalysts in fuel cells.

Time evolution law of a two-mode squeezed light field passing through twin diffusion channels

We explore the time evolution law of a two-mode squeezed light field(pure state)passing through twin diffusion channels,and we find that the final state is a squeezed chaotic light field(mixed state)with entanglement,which shows that even though the two channels are independent of each other,since the two modes of the initial state are entangled with each other,the final state remains entangled.Nevertheless,although the squeezing(entanglement)between the two modes is weakened after the diffusion,it is not completely removed.We also highlight the law of photon number evolution.In the calculation process used in this paper,we make full use of the summation method within the ordered product of operators and the generating function formula for two-variable Hermite polynomials.