Evidence for water exchange between the South China Sea and the Pacific Ocean through the Luzon Strait

An analysis of historical oxygen data provides evidence on the water exchange between theSouth China Sea (SCS) and the Pacific Ocean (PO). In the vicinity of the Luzon Strait (LS) , the dissolved oxygen concentration of sea water is found to be lower on the Pacific side than on the SCS side at depths between 700 and 1500 m (intermediate layer) , while the situation is reversed above 700 m (upper layer) and below 1 500 m (deep layer). The evidence suggests that water exits the SCS in the intermediate layer but enters it from the Pacific in both the upper and the deep layers, supporting the earlier speculation that the Luzon Strait transport has a sandwiched structure in the vertical. Within the SCS basin, the oxygen distribution indicates widespread vertical movement, including the upwelling in the intermediate layer and the downwelling in the deep layer.

Deep-water Fan Systems and Petroleum Resources on the Northern Slope of the South China Sea

The shallow shelf delta/strand arenaceous-pelitic deposit region in the north of the Pearl River mouth basin, sitting on the northern continental shelf of the South China Sea, has already become an important oil production base in China. Recent researched has revealed that a great deal of deep-water fans of great petroleum potentiality exist on the Baiyun deep-water slope below the big paleo Pearl River and its large delta. Based on a mass of exploration wells and 2-D seismic data of the shallow shelf region, a interpretation of sequence stratigraphy confirmed the existence of deep-water fans. The cyclic falling of sea level, abundant detrital matter from the paleo Pearl River and the persistent geothermal subsidence in the Baiyun sag are the three prerequisites for the formation and development of deep-water fans. There are many in common between the deep-water shelf depositional system of the northern South China Sea and the exploration hotspots region on the two banks of the Atlantic. For example, both are located on passive continent margins, and persistent secular thermal subsidence and large paleo rivers have supplied abundant material sources and organic matter. More recently, the discovery of the big gas pool on the northern slope of the Baiyun sag confirms that the Lower Tertiary lacustrine facies in the Baiyun sag has a great potentiality of source rocks. The fans overlying the Lower Tertiary source rocks should become the main exploration areas for oil and gas resources.

Types,Characteristics and Significances of Migrating Pathways of Gas-bearing Fluids in the Shenhu Area,Northern Continental Slope of the South China Sea

The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways（largescale faults, gas chimneys and mud diapirs） presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways（large-scale faults and mud diapirs） in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways（composed of gas chimneys） in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.

Impact of the Thermal State of the Tropical Western Pacific on Onset Date and Process of the South China Sea Summer Monsoon

Since the early or late onset of the South China Sea summer monsoon （SCSM） has a large impact on summer monsoon rainfall in East Asia, the mechanism and process of early or late onset of the SCSM are an worthy issue to study. In this paper, the results analyzed by using the observed data show that the onset date and process of the SCSM are closely associated with the thermal state of the tropical western Pacific in spring. When the tropical western Pacific is in a warming state in spring, the western Pacific subtropical high shifts eastward, and twin cyclones are early caused over the Bay of Bengal and Sumatra before the SCSM onset. In this case, the cyclonic circulation located over the Bay of Bengal can be early intensified and become into a strong trough. Thus, the westerly flow and convective activity can be intensified over Sumatra, the Indo-China Peninsula and the South China Sea （SCS） in mid-May. This leads to early onset of the SCSM. In contrast, when the tropical western Pacific is in a cooling state, the western Pacific subtropical high anomalously shifts westward, the twin cyclones located over the equatorial eastern Indian Ocean and Sumatra are weakened, and the twin anomaly anticyclones appear over these regions from late April to mid-May. Thus, the westerly flow and convective activity cannot be early intensified over the Indo-China Peninsula and the SCS. Only when the western Pacific subtropical high moves eastward, the weak trough located over the Bay of Bengal can be intensified and become into a strong trough, the strong southwesterly wind and convective activity can be intensified over the Indo-China Peninsula and the SCS in late May. Thus, this leads to late onset of the SCSM. Moreover, in this paper, the influencing mechanism of the thermal state of the tropical western Pacific on the SCSM onset is discussed further from the Walker circulation anomalies in the different thermal states of the tropical western Pacific.

Features of eddy kinetic energy and variations of upper circulation in the South China Sea

The features of eddy kinetic energy (EKE) and the variations of upper circulation in theSouth China Sea (SCS) are discussed in this paper using geostrophic currents estimated from Maps of Sea Level Anomalies of the TOPEX/Poseidon altimetry data. A high EKE center is identified in the southeast of Vietnam coast with the highest energy level 1 400 cm2 ·s^(-2) in both summer and autumn. This high EKE center is caused by the instability of the current axis leaving the coast of Vietnam in summer and the transition of seasonal circulation patterns in autumn. There exists another high EKE region in the northeastern SCS, southwest to Taiwan Island in winter. This high EKE region is generated from the eddy activities caused by the Kuroshio intrusion and accumulates more than one third of the annual EKE, which confirms that the eddies are most active in winter. The transition of upper circulation patterns is also evidenced by the directions of the major axises of velocity variance ellipses between 10?and 14.5°N, which supports the model results reported before.

A numerical study of the South China Sea deep circulation and its relation to the Luzon Strait transport

A fine-resolution MOM code is used to study the South China Sea basin-scale circulationand its relation to the mass transport through the Luzon Strait. The model domain includes the South China Sea, part of the East China Sea, and part of the Philippine Sea so that the currents in the vicinity of the Luzon Strait are free to evolve. In addition, all channels between the South China Sea and the Indonesian seas are closed so that the focus is on the Luzon Strait transport. The model is driven by specified Philippine Sea currents and by surface heat and salt flux conditions. For simplicity, no wind-stress is applied at the surface.The simulated Luzon Strait transport and the South China Sea circulation feature a sandwich vertical structure from the surface to the bottom. The Philippine Sea water is simulated to enter the South China Sea at the surface and in the deep ocean and is carried to the southern basin by western boundary currents. At the intermediate depth, the net Luzon Strait transport is out of the South China Sea and is fed by a western boundary current flowing to the north at the base of the thermocline. Corresponding to the western boundary currents, the basin circulation of the South China Sea is cyclonic gyres at the surface and in the abyss but an anti-cyclonic gyre at the intermediate depth. The vorticity balance of the gyre circulation is between the vortex stretching and the meridional change of the planetary vorticity. Based on these facts, it is hypothesized that the Luzon Strait transports are determined by the diapycnal mixing inside the entire South China Sea. The South China Sea plays the role of a 'mixing mill' that mixes the surface and deep waters to return them to the Luzon Strait at the intermediate depth. The gyre structures are consistent with the Stommel and Arons theory (1960), which suggests that the mixing-induced circulation inside the South China Sea should be cyclonic gyres at the surface and at the bottom but an anti-cyclonic gyre at the intermediate depth. The simulated gyre circulation at the intermediate depth has been confirmed by the dynamic height calculation based on the Levitus hydrography data. The sandwich transports in the Luzon Strait are consistent with recent hydrographical observations.Model results suggest that the Kuroshio tends to form a loop current in the northeastern South China Sea. The simulated Kuroshio Loop Current is generated by the pressure head at the Pacific side of the Luzon Strait and is enhanced by the β-plane effects. The β - plane appears to be of paramount importance to the South China Sea circulation and to the Luzon Strait transports. Without the β-plane, theLuzon Strait transports would be greatly reduced and the South China Sea circulation would be complete-ly different.

Geoacoustic Inversion for Bottom Parameters in the Deep-Water Area of the South China Sea

Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss （TL） data in the shadow zone of deep water. We propose a multiple-step fill inversion method to invert sound speed, density and attenuation in deep water. Based on a uniform liquid hMf-space bottom model, sound speed of the bottom is inverted by using the long range TL at low frequency obtained in an acoustic propagation experiment conducted in the South China Sea （SCS） in summer 2014. Meanwhile, bottom density is estimated combining with the Hamilton sediment empirical relationship. Attenuation coefficients at different frequencies are then estimated from the TL data in the shadow zones by using the known sound speed and density as a constraint condition. The nonlinear relationship between attenuation coefficient and frequency is given in the end. Tile inverted bottom parameters can be used to forecast the transmission loss in the deep water area of SCS very we//.

Diagnostic Study of Apparent Heat Sources and Moisture Sinks in the South China Sea and its Adjacent Areas during the Onset of 1998 SCS Monsoon

The apparent heat sources (?Q1 ?) and moisture sinks (?Q2 ?) are calculated based on the reanalyzed data of the South China Sea Monsoon Experiment (SCSMEX) from May 1 to August 31, 1998. It is found that the formation and distribution of the atmospheric heat sources are important for the monsoon onset. The earlier onset of the SCS monsoon is the result of enduring atmospheric heating in the Indo–China Peninsula and South China areas. The atmospheric heating firstly appears in the Indo–China Peninsula area and the sensible heat is the major one. The 30–50 day periodic oscillation of atmospheric heat sources between the SCS area and the western Pacific warm pool has a reverse phase distribution before the middle of July and the low frequency oscillation of heat sources in SCS area has an obvious longitudinal propagation. The 30–50 day low frequency oscillation has vital modificatory effects on the summer monsoon evolution during 1998. Key words Apparent heat sources - Apparent moisture sinks - The South China Sea monsoon - Diagnostic Study Sponsored by the National Key Project of Fundamental Research “ SCSMEX” and the Research Fund for the Doctoral Program of Higher Education: “ Study of the Air-sea Interaction in the SCS Monsoon Region”.

Mass movements in small canyons in the northeast of Baiyun deepwater area, north of the South China Sea

The process of mass movements and their consequent turbidity currents in large submarine canyons has been widely reported, however, little attention was paid to that in small canyons. In this paper, we document mass movements in small submarine canyons in the northeast of Baiyun deepwater area, north of the South China Sea （SCS）, and their strong effects on the evolution of the canyons based on geophysical data. Submarine canyons in the study area arrange closely below the shelf break zone which was at the depth of -500 m. Within submarine canyons, seabed surface was covered with amounts of failure scars resulted from past small-sized landslides. A complex process of mass transportation in the canyons is indicated by three directions of mass movements. Recent mass movement deposits in the canyons exhibit translucent reflections or parallel reflections which represent the brittle deformation and the plastic deformation, respectively. The area of most landslides in the canyons is less than 3 km2. The trigger mechanisms for mass movements in the study area are gravitational overloading, slope angle and weak properties of soil. Geophysical data indicate that the genesis of submarine canyons is the erosion of mass movements and consequent turbidity currents. The significant effects of mass movements on canyon are incision and sediment transportation at the erosion phases and fillings supply at the fill phases. This research will be helpful for the geological risk assessments and understanding the sediment transportation in the northern margin of the SCS.

Hydrological analysis of Kuroshio water intrusion into the South China Sea

Using CFD and ADCP data collected by four research vessels from both sides of the Taiwan Strait in the northeastern area of the forth China Sea in August - September 1994 and incorporating with CTD data collected in the same area in March 1992 and some historical hydrologic data, the water features and the intrusion of Kuroshio water into the South China Sea are discussed, which shows that the water mass distribution in the survey period was similar to that in the cruise of late winter and early spring (March 1992), that is, the water structure in the northeast of the sea and in the Northwest Pacific had their own independent features of temperature and salinity. Though the intrusion of Kuroshio water into the sea was found, it was very weak. Therefore there would be no direct Kuroshio branch into the sea in the late summer and early autumn. Even the Kuroshio water intrusion from the Bashi Channel into the Taiwan Strait, its influence was also very weak. Analysis of isopycnic surface and geretrophic current and the Observed ADCP data show that there was a rather strong northward flow in the southeast pat of the survey area which flowed northward along the west coast of Philippines, rounded the northwest corner of Luzon Island and then flowed northeastward. Some kind of mixing with Kuroshio water was shown in the Bashi Channel. The water mass was obviously of high temperature and low salinity in winter and comparatively low temperature and low salinity in summer.

Multi-scale variability of subsurface temperature in the South China Sea

Using Morlet wavelet transform and harmonic analysis the multi-scale variability of subsurface temperature in the South China Sea is studied by analyzing one-year (from April 1998 to April 1999) ATLAS mooring data. By wavelet transform, annual and semi-annual cycle as well as intrasea-sonal variations are found, with different dominance, in subsurface temperature. For annual harmonic cycle, both the downward net surface heat flux and thermocline vertical movement partially control the subsurface temperature variability. For semi-annual cycle and intraseasonal variability, the subsurface temperature variability is mainly linked to the vertical displacement of thermocline.

An Anomalous Seamount on the Southwestern Mid-Ridge of the South China Sea

Objective The development of continental rifting and seafloor spreading can be predominated by magmatic upwelling （magma-rich） or tectonic stretching （magma-poor）. Located in the terminal portion of propagating seafloor spreading of the South China Sea （SCS）, the southwestern mid-ridge of the southwest sub-basin （SWSB） of the SCS was found with much thin crust and numerous faulted blocks coupling with magma-poor continental margins along its flanks. Therefore, the southwestern part of the SWSB is most likely to be a tectonic-dominated basin. To justify the hypothesis with further evidence, we investigated the nature of seamounts on the southwestern mid-ridge of the SWSB which may inherit seafloor spreading.

Seasonal variation and formation mechanism of the South China Sea warm water

The South China Sea warm water (SCSWW) is identified as the warm water body withtemperature no less than 28*. There are three stages in the seasonal variation of the SCSWW. The SCSWW expands rapidly and deepens quickly in the developing stage. The warm water thickness decreases near the coast of Vietnam and increases near Palawan Island in the steady stage. The SCSWW flinches southward while its thickness off Palawan Island remains no less than 50 m in the flinching stage. The maximum thickness of the SCSWW is always located near the southeastern SCS. The seasonal variation of the SCSWW has a close relationship with seasonal variation of the thermocline. According to the analysis of the numerical experiment results from the Princeton Ocean Model (POM), the mechanism of the seasonal variation of the SCSWW can be interpreted as: (1) in the developing stage, the rapidly expanding and thickening feature of the SCSWW is mainly due to buoyancy flux effect (67% contribution). The weak wind and anticyclonic wind stress curl (22% contribution) present an environment which facilitates the accumulation of warm water; (2) in the steady stage, the decrease feature near the Vietnam coast and increase eature in southeast of the SCSWW thickness are mainly caused by wind stress (70% contribution); (3) in the flinching stage, the thickness reduction of the SCSWW is mainly due to upwelling and enhanced turbulent mixing caused by wind stress (accounts for 60%).

A new type of internal solitary waves with a re-appearance period of 23 h observed in the South China Sea

The South China Sea （SCS）, in particular the northern SCS, is one of ocean areas where energetic internal solitary waves （ISWs）occur most frequently （Cai et al., 2012; Zheng, 2017）. Based on the re-appearance period （RP） at an observation station, Ramp et al.（2004） divided the ISWs into two types：Type-a and Type-b. Type-a ISWs arrive regularly at the same time every day, i.e., the RP is about 24 h, and Type-b ISWs arrive about one hour late every day, i.e., the RP is about 25 h.

A possible role of the South China Sea in ENSO cycle

A data-based hypothesis on the role of the South China Sea (SCS) in ENSO cycle is proposed: during El Nino, there are westerly wind anomaly over the western equatorial Pacific and positive SST anomaly in the eastern equatorial Pacific. Meanwhile anomalous convection moves to the central Pacific with anomalous sinking over Indonesian Archipelago. The latter can cause southerly wind anomaly over the north of South China Sea (NSCS) and makes the NSCS warmer. The warm NSCS can attract the anomalous convection to it in some degree. This attraction is in favor for producing easterly wind anomaly over the western equatorial Pacific, so it helps to form a cycle.

ISOLATION AND STRUCTURE ELUCIDATION OF A NOVEL STEROL FROM THE SOUTH CHINA SEA SPONGE DYSIDEA SP.

A novel and unusual sterol with unsaturation in the△^(5(14)) position,5α-cholesta-8(14),24(25)-diene-3β,6α-diol 1,was isolated from the South China Ses sponge Dysidea sp.The structure and relative stereochemistry of 1 was established by spectral analysis and comparison to the spectral data of known sterols.

Sea surface height anomaly and geostrophic circulation variations in the South China Sea from TOPEX/POSEIDON altimetry

The sea surface height anomaly (SSHA) and geostrophic circulation in the South ChinaSea (SCS) are studied using TOPEX/POSEIDON (T/P) altimetry data. The SSHA, which is obtained after tidal correction based on the tidal results from T/P data, is predominated by seasonal alternating monsoons. The results reveal that the SSHA in the central part of the SCS is positive in spring and summer, but negative in autumn and winter. It is also found that the SSHA in the SCS can be approached with the sum of tidal constituents SA and SSA. The geostrophic circulations in the SCS are calculated according to sea surface dynamic topography, which is the sum of SSHA and mean sea surface height. It is suggested that the circulation in the upper layer of the SCS is generally cyclonic and notably western intensified during autumn and winter, while the western intensification is weak during spring and summer. It is also indicated that the Kuroshio intrudes into the northeastern SCS throuth the Luzon Strait in winter. But there is no indication of Kuroshio intruding into the SCS in summer.

Geochemical insights into contribution of petroleum hydrocarbons to the formation of hydrates in the Taixinan Basin, the South China Sea

Methane hydrate in the South China Sea (SCS) has extensively been considered to be biogenic on the basis of its δ13C andδD values.Although previous efforts have greatly been made,the contribution of thermogenic oil/gas has still been underestimated.In this study,biomarkers and porewater geochemical parameters in hydrate-free and hydrate-bearing sediments in the Taixinan Basin,the SCS have been measured for evaluating the contribution of petroleum hydrocarbons to the formation of hydrate deposits via a comparative study of their source inputs of organic matters,environmental conditions,and microbial activities.The results reveal the occurrence of C_(14)–C_(16) branched saturated fatty acids (bSFAs) with relatively high concentrations from sulfate-reducing bacteria(SRBs) in hydrate-bearing sediments in comparison with hydrate-free sediments,which is in accord with the positive δ^(13)C values of dissolved inorganic carbon (DIC),increasing methane concentrations,decreasing alkalinity,and concentration fluctuation of ions (Cl^(-),Br^(-),SO_(4)^(2-),Ca^(2+),and Mg^(2+)).These data indicate the relatively active microbial activities in hydrate-bearing sediments and coincident variations of environmental conditions.Carbon isotope compositions of b SFAs (-34.0‰to -21.2‰),n-alkanes (-34.5‰to-29.3‰),and methane(-70.7‰to -69.9‰) jointly demonstrate that SRBs might thrive on a different type of organic carbon rather than methane.Combining with numerous gas/oil reservoirs and hydrocarbon migration channels in the SCS,the occurrence of unresolved complex mixtures (UCMs),odd-even predominance (OEP) values (about 1.0),and biomarker patterns suggest that petroleum hydrocarbons from deep oil/gas reservoirs are the most probable carbon source.Our new results provide significant evidence that the deep oil/gas reservoirs may make a contribution to the formation of methane hydrate deposits in the SCS.

Evaluation of natural gas hydrate resources in the South China Sea by combining volumetric and trend-analysis methods

Natural gas hydrate(NGH),considered as a type of premium energy alternative to conventional hydrocarbons,has been broadly studied.The estimate of the total NGH resources in the world has decreased by more than 90%since the first evaluation in 1973.Geographic and geophysical conditions of the South China Sea(SCS)are favorable for the formation of NGH,which has been proved by drilling results up to date.The recoverability of the NGH in the SCS has been confirmed by the production tests using both vertical and horizontal wells.Since 2001,35 estimates of NGH resources in the SCS have been made,with relatively stable results varying between 600 and 900×109 ton oil equivalent.In these estimations,the volumetric method was commonly adopted,but the geological conditions,the migration-accumulation mechanisms of NGH,and the practical recoverability were not considered.These estimates cannot be regarded as evaluated resources according to the international resource evaluation standards,but are at most about prospective gas content of NGH,thus inefficient for guiding explorations and developments.To solve these problems,this study divides the past NGH surveys in the SCS into seven stages,acquires key geological parameters of every stage based on previous studies and analogy with other areas,evaluates the NGH resources of these seven stages by using the volumetric method,then adopts a new trend-analysis method to simulate the downward trend of these estimates,and finally predicts the NGH resources in the SCS at 2025 and 2030.The downward trend is because of the continuous improvement of NGH understanding over time,which is consistent with the trend of global NGH estimates.At the present stage(from 2019 to 2021),the average technically recoverable resource(ATRR)is 7.0×10^(12)m^(3),and the estimates of 2025 and 2030 ATRR are 6.46×10^(12)m^(3) and 4.01×10^(12)m^(3)respectively,with a difference of less than 40%.Therefore,it can be inferred that the ATRR of NGH in the SCS is between 4.0 and 6.5×10^(12)m^(3),with an average of 5.25×10^(12)m^(3).

Reserves of Natural Gas Hydrates Equivalent to 100–150 Billion m^3 Natural Gas Has Been Discovered in the Pearl Mouth Basin of the South China Sea

Scientists have suggested that combustible ice in global marginal seas,deep trough areas and ocean basins covers an area of 400million km2,and its total reserve is twice the amount of the global proven oil,coal and gas reserves,equivalent to 50 times the amount of conventional natural gas reserves.