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The Akp-Btk value method and the resultsfor the retrieval of the parameters of the Earth's free core nutation 被引量:1
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作者 雷湘鄂 贾民育 李辉 《Acta Seismologica Sinica(English Edition)》 CSCD 2000年第3期342-350,358,共10页
The rotation of the Earth's liquid core creates the Nearly Diurnal Free Wobble (NDFW). It is one of the problems of researching the Earth's liquid core for us to retrieve the parameters of the Earth's Free... The rotation of the Earth's liquid core creates the Nearly Diurnal Free Wobble (NDFW). It is one of the problems of researching the Earth's liquid core for us to retrieve the parameters of the Earth's Free Core Nutation (FCN),from the Earth's liquid core resonance of gravity tide waves on the diurnal frequency band. Since 1987, some scientists in many different countries have come to calculate the parameters of FCN by using the observational data of gravity tide waves on the diumal frequency band. They basically followed the Stacking method, which needed five diurnal waves for the resolution. In this paper, authors introduced the Aky-Btk value method with clearly geometrical meaning as a new method, which only requires three very high signal-noise-ratio waves o1, K1 and P1 for the resolution. Authors chose the observational data of the three superconducting gravimeter stations respectively located in Cantley of Canada, Wuhan of China and Brussels of Belgium, to compute the parameters of FCN. It was the first time that the observational results of the parameters of FCN obtained from gravitational tide were in accord with the parameters of FCN gained from VLBI since 1987. 展开更多
关键词 earth's liquid core resonance of gravity tide (LCR) parameters of earth's free core nutation triangle of LCR Akp-Btk value method
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THE IMPACTS OF ORBITAL PARAMETERS ON SUMMER PRECIPITATION OVER CHINA IN THE HOLOCENE
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作者 黄建斌 王绍武 +4 位作者 闻新宇 周天军 朱锦红 杨保 任国玉 《Journal of Tropical Meteorology》 SCIE 2011年第2期103-112,共10页
The impact of orbital parameters on the climate of China in the Holocene is simulated from 11kaBP to 0kaBP with an interval of 1ka using National Center for Atmospheric Research (NCAR) Community Atmosphere Model versi... The impact of orbital parameters on the climate of China in the Holocene is simulated from 11kaBP to 0kaBP with an interval of 1ka using National Center for Atmospheric Research (NCAR) Community Atmosphere Model version 2 (CAM2). The geographic distributions of summer precipitation around both 9kaBP and 4kaBP were realistically captured by CAM2, compared to the proxy data collected from 80 stations. Among all orbital parameters, the precession plays a major role in computing solar radiation, which dominates the variations of summer precipitation over China during the Holocene. The summers around 9kaBP were the wettest in China. Later on, the precipitation gradually reduced to the minimum around 0kaBP by about 10%. This tremendous change occurred from the Northeast China and the eastern Inner Mongolia extending southwestwards to the Qinghai-Tibet Plateau, especially over the Qinghai-Tibet Plateau. 展开更多
关键词 HOLOCENE climate simulation orbital parameters climate humidity
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Simulation of the Impacts of Single LEO Satellite Orbit Parameters on the Distribution and Number of Occultation Events
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作者 XU Xiaohua LI Zhenghang LUO Jia 《Geo-Spatial Information Science》 2006年第1期13-17,共5页
Focusing on carrying out GPS occultation observat io ns with a receiver set on LEO satellite, this paper develops the LEO orbit simul ation system based on which the occultation events can be simulated taking into acc... Focusing on carrying out GPS occultation observat io ns with a receiver set on LEO satellite, this paper develops the LEO orbit simul ation system based on which the occultation events can be simulated taking into account the geometric relationship of the satellites and the field of view of th e receiver antenna. In this paper, the impacts of 4 types of LEO orbit parameter s including argument of latitude (AOL), right ascension of ascending node (RAAN) , orbit height and orbit inclination on the distribution and number of occultati on events observed with a single LEO satellite are discussed through simulat ion and some conclusions are drawn. 展开更多
关键词 卫星 全球定位系统 GPS 轨道参数
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The Figure and Dynamical Parameters of Io Inferred from Internal Structure Models
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作者 HongZhang Cheng-ZhiZhang 《Chinese Journal of Astronomy and Astrophysics》 CSCD 北大核心 2001年第3期275-280,共6页
The recent Galileo spacecraft explored Jupiter and its satellite system and provided us with new geodetic data. In order to discuss the dynamical parameters and secular tidal effect of Io, the theory of synchronous s... The recent Galileo spacecraft explored Jupiter and its satellite system and provided us with new geodetic data. In order to discuss the dynamical parameters and secular tidal effect of Io, the theory of synchronous satellite is described in detail. Using the new geodetic data of Io, two sets of Io's internal structure models are constructed based on the asthenosphere assumption. The liberation parameters α,β,γ and dynamical flattening H are calculated for the models of Io. A comparison of Io with the Moon indicates that they are quite different in many characteristics in spite of the fact that they are approximately equal in mass and size and that they both orbit synchronously. 展开更多
关键词 Io-synchronous orbit-dynamical parameters
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The Orbital Error Analysis and Study of Space Vehicle Active Phase
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作者 Tian jiu Leng Tai Xiang Li Qiong Tang 《International Journal of Technology Management》 2014年第8期50-53,共4页
关键词 卫星轨道 误差分析 车主 空间 三维坐标 微分方程 方程拟合 观测条件
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航天器入轨状态与偏差传播分析
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作者 彭祺擘 刘将辉 +1 位作者 张海联 周建平 《系统工程与电子技术》 EI CSCD 北大核心 2024年第6期2117-2127,共11页
本文研究了航天器入轨状态和入轨偏差传播问题。推导了火箭熄火时的入轨速度平方比率及速度仰角与主要轨道参数之间的关系,从而分析航天器的入轨状态。建立了航天器转移轨道的偏差传播矩阵,得到入轨偏差对转移轨道的影响。将本文的偏差... 本文研究了航天器入轨状态和入轨偏差传播问题。推导了火箭熄火时的入轨速度平方比率及速度仰角与主要轨道参数之间的关系,从而分析航天器的入轨状态。建立了航天器转移轨道的偏差传播矩阵,得到入轨偏差对转移轨道的影响。将本文的偏差传播分析方法与传统轨道误差分析方法进行对比以验证本文方法的正确性。最后,通过仿真算例分析了航天器入轨状态和入轨偏差对转移轨道的影响。 展开更多
关键词 轨道参数 入轨状态 入轨偏差 偏差传播矩阵
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参量共振单摆的理论与实验研究
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作者 白在桥 王爱记 平澄 《物理实验》 2024年第2期1-9,22,共10页
为了将参量共振引入基础物理实验教学,搭建了参量驱动单摆实验系统,并从理论和实验上研究了平衡点附近的运动.理论上,利用微扰方法计算了轨道的一般形式,在此基础上确定了参量共振带的边界,并得到了轨道特征量与驱动参量(频率与幅度)的... 为了将参量共振引入基础物理实验教学,搭建了参量驱动单摆实验系统,并从理论和实验上研究了平衡点附近的运动.理论上,利用微扰方法计算了轨道的一般形式,在此基础上确定了参量共振带的边界,并得到了轨道特征量与驱动参量(频率与幅度)的依赖关系.实验上,利用2个一维激光位移传感器组装成二维位移传感器,实现了单摆轨迹的实时测量.在参量共振带内,测量了不同驱动频率下的轨道发散指数和振子-驱动相位差;在参量共振带的中心,测量了发散指数与驱动幅度之间的关系;在参量共振带的外边缘,测量了轨道包络的拍频和调制深度与驱动频率的关系.所有测量结果都与一阶微扰计算符合良好. 展开更多
关键词 参量共振 单摆轨迹 轨道特征量 驱动参量
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星基并置轨道配置对地球自转参数解算的影响
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作者 陈子超 李星星 +3 位作者 张柯柯 张伟 黄适 袁勇强 《导航定位学报》 CSCD 北大核心 2024年第2期13-22,共10页
为了进一步研究全球卫星导航系统(GNSS)和卫星激光测距(SLR)低轨卫星(LEO)星基并置对于地球自转参数(ERP)解算的贡献,综合评估星基并置轨道配置和空间连接误差对地球自转参数解算的影响:通过仿真实验,联合地面全球定位系统(GPS)、低轨... 为了进一步研究全球卫星导航系统(GNSS)和卫星激光测距(SLR)低轨卫星(LEO)星基并置对于地球自转参数(ERP)解算的贡献,综合评估星基并置轨道配置和空间连接误差对地球自转参数解算的影响:通过仿真实验,联合地面全球定位系统(GPS)、低轨卫星星载GPS,以及低轨卫星激光测距观测数据,分析低轨卫星轨道配置、空间连接误差对地球自转参数解算精度的影响。结果表明,ERP的估计精度受低轨星基并置站的轨道高度和倾角影响较为明显;相比于低轨道、低倾角卫星,高轨道、高倾角卫星对于极移参数的解算精度提升效果更为显著,这主要是得益于该轨道配置可提供更多的SLR观测数据;此外,空间连接误差分析结果表明,ERP对于低轨卫星SLR棱镜质心改正的误差更加敏感,特别是在Z向,2 cm的Z向SLR棱镜质心改正误差可使得极移X分量和Y分量的估计精度分别下降24%和14%。 展开更多
关键词 低轨卫星(LEO) 星基并置站 地球自转参数(ERP) 轨道配置 空间连接误差
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LEO星载GPS实时精密定轨伪模糊度随机过程参数优化
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作者 张万威 刘宇槺 王甫红 《大地测量与地球动力学》 CSCD 北大核心 2024年第7期680-683,736,共5页
提出在定轨策略及其他变量不变的情况下,使用一种数值步进的搜索比较方法,以确定伪模糊度随机过程参数的最优设置。使用GRACE-C、SWARM-A两颗LEO卫星2021年doy92~101共10 d的GPS数据及同时段的CNT、MADOCA两种实时精密星历产品,以模拟... 提出在定轨策略及其他变量不变的情况下,使用一种数值步进的搜索比较方法,以确定伪模糊度随机过程参数的最优设置。使用GRACE-C、SWARM-A两颗LEO卫星2021年doy92~101共10 d的GPS数据及同时段的CNT、MADOCA两种实时精密星历产品,以模拟在轨实时精密定轨的方式,对伪模糊度随机过程参数开展优化实验。结果表明,在伪模糊度参数最优值方案下,两颗LEO卫星的实时精密定轨三维位置误差(RMS)约为4.62~7.56 cm,相比于传统模糊度浮点解方案,使用CNT和MADOCA产品的实时定轨精度分别平均提升约39.15%和29.61%。 展开更多
关键词 低轨卫星 实时精密定轨 伪模糊度 随机过程噪声 参数优化
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Ion-acoustic waves with non-planar wavefronts
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作者 Shujaht BUKHARI Muhammad SHAHID Ata-ur RAHMAN 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第1期1-7,共7页
The ion-acoustic(IA) mode exhibiting various orbital angular momentum(OAM) states is examined in a plasma with drifting electrons.The constituent plasma species are modeled with a non-gyrotropic Maxwellian distributio... The ion-acoustic(IA) mode exhibiting various orbital angular momentum(OAM) states is examined in a plasma with drifting electrons.The constituent plasma species are modeled with a non-gyrotropic Maxwellian distribution and discussion of dispersion relation and growth rate of twisted IA waves under various conditions is presented.In the domain of kinetic model,the twisted IA waves are characterized by Laguerre-Gaussian(LG) solutions,where plasma distribution function and electric field are decomposed into axial and azimuthal components.The plasma response function is obtained under paraxial approximations and investigated for threshold condition of instability growth rate with helical electric field structures.The impact of an extra electron specie on the instability is demonstrated through a comparison of twisted waves for single and double electron species. 展开更多
关键词 INSTABILITY twist parameter wave excitation orbital angular momentum threshold limit
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沁水盆地左权地区山西组米氏旋回识别及其天文年代标尺
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作者 苟苏恒 吕佳阳 +2 位作者 李柯良 刘亮亮 邵龙义 《中国煤炭地质》 2024年第4期1-7,12,共8页
依据地层序列的旋回信号进行地球轨道参数周期的识别,是确定深时时间尺度的有效方法之一。以沁水盆地左权地区山西组为例,使用时间序列分析法与相关系数法对钻孔剖面自然伽马测井曲线进行旋回性分析,并据此建立山西组年代地层标尺。使... 依据地层序列的旋回信号进行地球轨道参数周期的识别,是确定深时时间尺度的有效方法之一。以沁水盆地左权地区山西组为例,使用时间序列分析法与相关系数法对钻孔剖面自然伽马测井曲线进行旋回性分析,并据此建立山西组年代地层标尺。使用频谱分析,在区内山西组识别出7.13 m、1.62~2.23 m的优势沉积旋回,分别对应405 kyr的长偏心率周期和91.9~126.4 kyr的短偏心率周期,经过天文检验,证实沁水盆地山西组受到天文周期驱动。通过高斯带通滤波,建立沁水盆地山西组“浮动”天文年代标尺,确定出9个405 kyr长偏心率旋回,据此获得山西组沉积时限为3.82 Myr。建立的天文年代标尺可为沁水盆地山西组古环境、古气候和各种地质事件的演化提供年代学依据。 展开更多
关键词 山西组 旋回地层学 天文年代标尺 轨道参数周期 沁水盆地
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Ka波段大回旋电子注介质加载回旋行波管输入耦合器研究
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作者 杨锦涛 王峨锋 +3 位作者 雷子涵 曾旭 高东硕 冯进军 《真空电子技术》 2024年第3期53-56,75,共5页
针对Ka波段大回旋电子注回旋行波管设计了一个TE 21模式输入耦合器。该输入耦合器结构为Y形功分器,将输入的矩形波导TE 10模式转换为圆波导的TE 21模式进行输出。本文对其转换原理进行了简要介绍,通过仿真确定了输入耦合器模型的参数,... 针对Ka波段大回旋电子注回旋行波管设计了一个TE 21模式输入耦合器。该输入耦合器结构为Y形功分器,将输入的矩形波导TE 10模式转换为圆波导的TE 21模式进行输出。本文对其转换原理进行了简要介绍,通过仿真确定了输入耦合器模型的参数,并加工出部件,并进行了实际测试,测试的结果满足Ka波段大回旋行波管的信号输入要求。 展开更多
关键词 Ka波段大回旋行波管 输入耦合器 模式转换器 S 21参数
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定量研究地球轨道参数和温室气体浓度变化对中全新世气候的影响
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作者 亢一博 杨海军 《北京大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第4期607-614,共8页
依据最新的古气候耦合模式比较计划(PMIP4)协议,利用完全耦合的气候模式CESM1.0,研究中全新世与工业革命前气候的差异,量化地球轨道参数(ORB)和温室气体(GHG)对中全新世气候变化的影响。3个模拟试验结果表明,与工业革命前相比,中全新世... 依据最新的古气候耦合模式比较计划(PMIP4)协议,利用完全耦合的气候模式CESM1.0,研究中全新世与工业革命前气候的差异,量化地球轨道参数(ORB)和温室气体(GHG)对中全新世气候变化的影响。3个模拟试验结果表明,与工业革命前相比,中全新世北半球高纬度地区气候偏温,全球其他地区气候偏冷,北半球大部分地区更湿润,南半球则较为干燥;ORB导致全球中高纬度地区升温,GHG在降低全球气温和减少中高纬度地区降水方面发挥作用;这种差异引起大气和海洋环流的变化,导致地球经向热量输送的差异;就总经向热量输送的变化范围而言,ORB对气候的影响大约是GHG的5倍。研究结果对深入了解中全新世气候及其对不同外部强迫的响应有积极意义。 展开更多
关键词 中全新世 全球气候 地球轨道参数 温室气体 经向热量输送
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CAS-FGOALS Datasets for the Two Interglacial Epochs of the Holocene and the Last Interglacial in PMIP4 被引量:2
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作者 Weipeng ZHENG Yongqiang YU +6 位作者 Yihua LUAN Shuwen ZHAO Bian HE Li DONG Mirong SONG Pengfei LIN and Hailong LIU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2020年第10期1034-1044,共11页
Two versions of the Chinese Academy of Sciences Flexible Global Ocean-Atmosphere-Land System model(CASFGOALS),version f3-L and g3,are used to simulate the two interglacial epochs of the mid-Holocene and the Last Inter... Two versions of the Chinese Academy of Sciences Flexible Global Ocean-Atmosphere-Land System model(CASFGOALS),version f3-L and g3,are used to simulate the two interglacial epochs of the mid-Holocene and the Last Interglacial in phase 4 of the Paleoclimate Modelling Intercomparison Project(PMIP4),which aims to study the impact of changes in orbital parameters on the Earth’s climate.Following the PMIP4 experimental protocols,four simulations for the mid-Holocene and two simulations for the Last Interglacial have been completed,and all the data,including monthly and daily outputs for the atmospheric,oceanic,land and sea-ice components,have been released on the Earth System Grid Federation(ESGF)node.These datasets contribute to PMIP4 and CMIP6(phase 6 of the Coupled Model Intercomparison Project)by providing the variables necessary for the two interglacial periods.In this paper,the basic information of the CAS-FGOALS models and the protocols for the two interglacials are briefly described,and the datasets are validated using proxy records.Results suggest that the CAS-FGOALS models capture the large-scale changes in the climate system in response to changes in solar insolation during the interglacial epochs,including warming in mid-to-high latitudes,changes in the hydrological cycle,the seasonal variation in the extent of sea ice,and the damping of interannual variabilities in the tropical Pacific.Meanwhile,disagreements within and between the models and the proxy data are also presented.These datasets will help the modeling and the proxy data communities with a better understanding of model performance and biases in paleoclimate simulations. 展开更多
关键词 PMIP4 CMIP6 CAS-FGOALS interglacials orbital parameters
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Predictive Modeling and Parameter Optimization of Cutting Forces During Orbital Drilling 被引量:1
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作者 单以才 李亮 +2 位作者 何宁 秦晓杰 章婷 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2014年第5期521-529,共9页
To optimize cutting control parameters and provide scientific evidence for controlling cutting forces,cutting force modeling and cutting control parameter optimization are researched with one tool adopted to orbital d... To optimize cutting control parameters and provide scientific evidence for controlling cutting forces,cutting force modeling and cutting control parameter optimization are researched with one tool adopted to orbital drill holes in aluminum alloy 6061.Firstly,four cutting control parameters(tool rotation speed,tool revolution speed,axial feeding pitch and tool revolution radius)and affecting cutting forces are identified after orbital drilling kinematics analysis.Secondly,hybrid level orthogonal experiment method is utilized in modeling experiment.By nonlinear regression analysis,two quadratic prediction models for axial and radial forces are established,where the above four control parameters are used as input variables.Then,model accuracy and cutting control parameters are analyzed.Upon axial and radial forces models,two optimal combinations of cutting control parameters are obtained for processing a13mm hole,corresponding to the minimum axial force and the radial force respectively.Finally,each optimal combination is applied in verification experiment.The verification experiment results of cutting force are in good agreement with prediction model,which confirms accracy of the research method in practical production. 展开更多
关键词 orbital drilling cutting force hybrid level orthogonal experiment method prediction model parameter optimization
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Modeling the Asian Aridity during the Early Cenozoic
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作者 ZHANG Ran JIANG Dabang 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第S01期80-82,共3页
Asian aridity can be traced back to the early Cenozoic(e.g.,Guo et al.,2008;Licht et al.,2016;Li et al.,2018a).Previous modelling studies focus mainly on the monsoon climate during the early Cenozoic,and studies for t... Asian aridity can be traced back to the early Cenozoic(e.g.,Guo et al.,2008;Licht et al.,2016;Li et al.,2018a).Previous modelling studies focus mainly on the monsoon climate during the early Cenozoic,and studies for the Asian aridity are still limited(e.g.,Huber and Goldner,2012;Zhang et al.,2012;Li et al.,2018b).Here Asian aridity during the early Cenozoic is investigated through climate modelling by changing atmospheric CO2 concentration,orbital parameters,and topography. 展开更多
关键词 Modelling EARLY CENOZOIC ASIAN ARIDITY orbital parameters
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Causes of Mid-Pliocene Strengthened Summer and Weakened Winter Monsoons over East Asia
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作者 ZHANG Ran JIANG Dabang ZHANG Zhongshi 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2015年第7期1016-1026,共11页
The mid-Pliocene warm period was the most recent geological period in Earth's history that featured long-term warming. Both geological evidence and model results indicate that East Asian summer winds (EASWs) streng... The mid-Pliocene warm period was the most recent geological period in Earth's history that featured long-term warming. Both geological evidence and model results indicate that East Asian summer winds (EASWs) strengthened in monsoonal China, and that East Asian winter winds (EAWWs) weakened in northern monsoonal China during this period, as compared to the pre-industrial period. However, the corresponding mechanisms are still unclear. In this paper, the results of a set of numerical simulations are reported to analyze the effects of changed boundary conditions on the mid-Pliocene East Asian monsoon climate, based on PRISM3 (Pliocene Research Interpretation and Synoptic Mapping) palaeoenvironmental recon- struction. The model results showed that the combined changes of sea surface temperatures, atmospheric CO2 concentration, and ice sheet extent were necessary to generate an overall warm climate on a large scale, and that these factors exerted the greatest effects on the strengthening of EASWs in monsoonal China. The orographic change produced significant local warming and had the greatest effect on the weakening of EAWWs in northern monsoonal China in the mid-Pliocene. Thus, these two factors both had important but different effects on the monsoon change. In comparison, the effects of vegetational change on the strengthened EASWs and weakened EAWWs were relatively weak. The changed monsoon winds can be ex- plained by a reorganization of the meridional temperature gradient and zonal thermal contrast. Moreover, the effect of orbital parameters cannot be ignored. Results showed that changes in orbital parameters could have marked!y affected the EASWs and EAWWs, and caused significant short-term oscillations in the mid-Pliocene monsoon climate in East Asia. 展开更多
关键词 mid-Pliocene East Asian monsoon orographic change orbital parameters
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Limit cycles and homoclinic orbits and their bifurcation of Bogdanov-Takens system
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作者 黄赪彪 刘佳 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2008年第9期1195-1201,共7页
A quantitative analysis of limit cycles and homoclinic orbits, and the bifurcation curve for the Bogdanov-Takens system are discussed. The parameter incremental method for approximate analytical-expressions of these p... A quantitative analysis of limit cycles and homoclinic orbits, and the bifurcation curve for the Bogdanov-Takens system are discussed. The parameter incremental method for approximate analytical-expressions of these problems is given. These analytical-expressions of the limit cycle and homoclinic orbit are shown as the generalized harmonic functions by employing a time transformation. Curves of the parameters and the stability characteristic exponent of the limit cycle versus amplitude are drawn. Some of the limit cycles and homoclinic orbits phase portraits are plotted. The relationship curves of parameters μ and A with amplitude a and the bifurcation diagrams about the parameter are also given. The numerical accuracy of the calculation results is good. 展开更多
关键词 Bogdanov-Takens system limit cycle homoclinic orbit bifurcation dia-grams analytical-expressions parameter incremental method
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CONTROLLING HYPERCHAOS IN PLANAR SYSTEMS BY ADJUSTING PARAMETERS
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作者 杨凌 刘曾荣 茅坚民 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2003年第4期396-401,共6页
For the two_parameter family of planar mapping, a method to stabilize an unstable fixed point without stable manifold embedding in hyperchaos is introduced. It works by adjusting the two parameters in each iteration o... For the two_parameter family of planar mapping, a method to stabilize an unstable fixed point without stable manifold embedding in hyperchaos is introduced. It works by adjusting the two parameters in each iteration of the map. The explicit expressions for the parameter adjustments are derived, and strict proof of convergence for method is given. 展开更多
关键词 control of chaos hyperchaotic orbits parameter adjustment
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Theoretical investigations of the local distortion and electron paramagnetic resonance parameter for CdCl_2:V^(2+) and CsMgX_3:V_^(2+)(X=Cl,Br) systems
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作者 李成刚 邝小渝 +2 位作者 段美玲 张彩霞 柴瑞鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第6期459-466,共8页
This paper systematically investigates the local distortion and electron paramagnetic resonance (EPR) parameter for CdCl2:V^2+ and CsMgX3:V^2+ (X=Cl, Br) systems on the basis of the complete energy matrix, in ... This paper systematically investigates the local distortion and electron paramagnetic resonance (EPR) parameter for CdCl2:V^2+ and CsMgX3:V^2+ (X=Cl, Br) systems on the basis of the complete energy matrix, in which not only the contributions due to the spin-orbit coupling of the central ions but also that of the ligands are considered. To describe the difference of overlapping between d-orbits and p orbit, two spin-orbit coupling coefficients are introduced. By simulating the crystal field parameter and EPR parameter, the local distortion parameters are studied and the relationships between the EPR parameter and the spin-orbit coupling coefficients as well as divergent parameter are discussed. These results show that the local structures exhibit compression distortion for CdCl2:V^2+ and elongation distortions for CsMgX3:V^2+ (X:Cl, Br), respectively. It notes that the empirical formula R≈RH T (ri - rh)/2 is not suitable for CdCl2:V^2+ and CsMgX3:V^2+ (X=Cl, Br) systems. The contributions of ligand to spin-orbit coupling interaction cannot be neglected for strong covalent systems, especially for V^2+ doped in CsMgBr3:V^2+. 展开更多
关键词 complete energy matrix two spin-orbit coupling parameter model
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