Paleoenvironmental reconstruction and organic matter accumulation of the paleogene shahejie oil shale in the Zhanhua Sag, Bohai Bay Basin, Eastern China

The controlling factors of organic-rich shale accumulation is essential for the exploration and development of shale oil and gas resources.The sedimentary environment plays a vital role in the formation of organic-rich sediments in lacustrine facies.This article unravels the mineralogy,geochemistry,and paleoenvironmental evolution during the deposition of the Paleogene Shahejie Formation(Es_(3)^(L)).It discusses the effects of paleoclimate,paleosalinity,paleoredox conditions,paleowater depth,and paleoproductivity on organic matter(OM)enrichment.Finally,the OM enrichment model was established.The results show that the mineralogical compositions are mainly composed of calcite(avg.40.13%),quartz(avg.21.64%)and clay minerals(avg.24.07%),accompanied by dolomite(avg.7.07%),feldspar(avg.6.36%)and pyrite(avg.2.95%).The Es_(3)^(L) shale has a high abundance of OM,with total organic carbon(TOC)ranging from 1.07%to 5.12%.The organic matter type is mainly composed of type I-II_(1) kerogen,which is generally considered a good-quality source rock.The source of OM is a mixture of lower bacteria,algae,and plants.During the early sedimentary period,the paleoclimate was dry and cold,with high salinity,intense reducibility,and relatively low productivity.During the late sedimentary period,the climate became warmer and more humid.As a result,the salinity decreased to a level that was suitable for biological reproduction,and productivity increased gradually due to the input of terrigenous plants.Paleosalinity and paleoclimate determined the environment of the sedimentary period,in addition,paleoproductivity and paleoredox condition indicated the formation and preservation conditions of OM.The warm and humid climate,brackish water,suitable reduction conditions and high productivity are the favorable conditions for the generation and preservation of organic matter.The research results may have implications for the genetic mechanisms of organic matter accumulation.They will provide theoretical and technical insights into the exploration and development of shale oil.

Extended finite element-based cohesive zone method for modeling simultaneous hydraulic fracture height growth in layered reservoirs

In this study,a fully coupled hydromechanical model within the extended finite element method(XFEM)-based cohesive zone method(CZM)is employed to investigate the simultaneous height growth behavior of multi-cluster hydraulic fractures in layered porous reservoirs with modulus contrast.The coupled hydromechanical model is first verified against an analytical solution and a laboratory experiment.Then,the fracture geometry(e.g.height,aperture,and area)and fluid pressure evolutions of multiple hydraulic fractures placed in a porous reservoir interbedded with alternating stiff and soft layers are investigated using the model.The stress and pore pressure distributions within the layered reservoir during fluid injection are also presented.The simulation results reveal that stress umbrellas are easily to form among multiple hydraulic fractures’tips when propagating in soft layers,which impedes the simultaneous height growth.It is also observed that the impediment effect of soft layer is much more significant in the fractures suppressed by the preferential growth of adjoining fractures.After that,the combined effect of in situ stress ratio and fracturing spacing on the multi-fracture height growth is presented,and the results elucidate the influence of in situ stress ratio on the height growth behavior depending on the fracture spacing.Finally,it is found that the inclusion of soft layers changes the aperture distribution of outmost and interior hydraulic fractures.The results obtained from this study may provide some insights on the understanding of hydraulic fracture height containment observed in filed.

Organic Matter and Elemental Composition of Mudstones in the Member 3 of Paleogene Shahejie Formation in the Dongying Depression, Eastern China

The organic matter distribution and hydrocarbon generation potential as well as element distribution in the lacustrine mudstones of lower Member 3 of Paleogene Shahejie Formation in the Dongying depression, eastern China were investigated using methods of Rock-Eval pyrolysis, inductively coupled plasma emission spectrometer. The results show that most of the samples are high-quality source rocks with high TOC and?S2, and the oil shale samples are excellent source rocks with the TOC and?S2?greater than 5.0% and 20.0 mg/g, respectively. A freshwater depositional?environment in the deep lake for the mudstones was indicated by lower values of biomarker?ratios gammacerane/C30?Hopane and C35Hopane/C34?Hopane. With the lacustrine regression, the ratios Ca/U, Ca/Ba, Ca/Mg, Ca/B, Ca/Li, Ca/Sr and Sr/Ba decrease, while Fe/(Ca + Mg) increases. In the section 3330 - 3370 m with enrichment of oil shale, the organic matter and inorganic elements present strong fluctuation. The quantitative relations among U, U/Th and TOC,?S2, %Ca are divided into two parts at boundary values of 7.0%, 32 mg/g and 11% for TOC,?S2?and %Ca, respectively.

Comprehensive Evaluation on the Irrigation Water Quality in Turpan City Based on Matter Element Analysis Method

Matter-element analysis method was used to construct the comprehensive matter-element model for the evaluation of the quality of various kinds of irrigation water in Turpan City to evaluate the quality of irrigation water（such as river water,spring water, Karez well water, pumped well water） in Turpan City, Xinjiang. The results showed that the quality of the irrigation water was the best in October,which was in Grade I or Grade 2; in May, the quality of some of the irrigation water became poorer to Grade II, which was easy to soil salinization; in March, the detected qualities of the water samples water from the Meiyaogou basin were all in Grade IV, which was not suitable for farmland irrigation. The comparison on the evaluation results of matter-element analysis and fuzzy evaluation method showed that the results of the 2 methods were almost consistent with each other, and showed good uniformity.

Numerical analysis of rock fracturing by gas pressure using the extended finite element method

High energy gas fracturing is a simple approach of applying high pressure gas to stimulate wells by gen- erating several radial cracks without creating any other damages to the wells. In this paper, a numerical algorithm is proposed to quantitatively simulate propagation of these fractures around a pressurized hole as a quasi-static phenomenon. The gas flow through the cracks is assumed as a one-dimensional transient flow, governed by equations of conservation of mass and momentum. The fractured medium is modeled with the extended finite element method, and the stress intensity factor is calculated by the simple, though sufficiently accurate, displacement ex- trapolation method. To evaluate the proposed algorithm, two field tests are simulated and the unknown parameters are determined through calibration. Sensitivity analyses are performed on the main effective parameters. Considering that the level of uncertainty is very high in these types of engineering problems, the results show a good agreement with the experimental data. They are also consistent with the theory that the final crack length is mainly determined by the gas pressure rather than the initial crack length produced by the stress waves.

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary

This paper reports the relationship between the biogeochemical characteristics of C. N. P and flocculation and settling of suspended materials in the Changjiang Estuary. Regional activities of bacteria and the plankton and biogeochemical processes at the water-particle interface under some environmental conditions are quite variable. This leads to the transition of material phase with speciation variation of elements C. N. P. in the transfer processes. Therefore, the composition and reactivity of particle surface and dissolved constituent are modified, affecting the stability of the particulate dispersion system. In summer, the concentration of NO3 and PO4 are positively correlated with turbidity, while the weight percentage of PON, POC and PP are negatively correlated with turbidity. When particles in the river move seaward, two zones can be distinguished: i) zone with maximum flocculation speed, in salinity 0. 1～2. 0 ;ii) zone with huge coagulating particles netting and high turbidity at the bottom, in salinity 2～11.The highest values of C/N in particles (or the low valley of C. E. C.of particle surface) appear in the two zones. These results demonstrate that the biogeochemical action is one of the major factors and mechanisms to dominate the flocculation of particles in the Changjiang Estuary.

Thermoelastic analysis of multiple defects with the extended finite element method

In this paper, the extended finite element method (XFEM) is adopted to analyze the interaction between a single macroscopic inclusion and a single macroscopic crack as well as that between multiple macroscopic or microscopic defects under thermal/mechanical load. The effects of different shapes of multiple inclusions on the material thermomechanical response are investigated, and the level set method is coupled with XFEM to analyze the interaction of multiple defects. Further, the discretized extended finite element approximations in relation to thermoelastic problems of multiple defects under displacement or temperature field are given. Also, the interfaces of cracks or materials are represented by level set functions, which allow the mesh assignment not to conform to crack or material interfaces. Moreover, stress intensity factors of cracks are obtained by the interaction integral method or the M-integral method, and the stress/strain/stiffness fields are simulated in the case of multiple cracks or multiple inclusions. Finally, some numerical examples are provided to demonstrate the accuracy of our proposed method.

Organic/ Inorganic Occurrence of Metallic Elements of the Black Shale-Hosted Baiguoyuan Silver-Vanadium Deposit in Xingshan, Hubei

: By means of kerogen purification, the proton induced X-ray emission (PIXE) and instrumental neutron activation analysis (INAA), the authors have studied the organic/inorganic occurrence modes of the metallic elements of the Baiguoyuan silver-vanadium deposit hosted in black shale in Hubei Province, China. The result shows that Au, Hg and Ta have a strong tendency to occur organically, with more than 70% of these elements being associated organically. Se, Ga, Ag and Hf are partly associated with organic matter, with more than 20% of them occurring organically. Compared with the above elements, Zn, Cu, As and Sb are weakly associated organically, and tend to be enriched in kerogen. However, Mn, Th, U, V, Co, Cr, AI, Fe and Sc usually occur inorganically. Of the rare earth elements (REE), La, Ce, Tb, Dy, Yb and Lu have stronger ability to be associated with organic matter than Sm and Eu.

Cracking Propagation of Hardening Concrete Based on the Extended Finite Element Method

Self-deformation cracking is the cracking caused by thermal deformation, autogenous volume deformation or shrinkage deformation. In this paper, an extended finite element calculation method was deduced for concrete crack propagation under a constant hydration and hardening condition during the construction period, and a corresponding programming code was developed. The experimental investigation shows that initial crack propagation caused by self-deformation loads can be analyzed by this program. This improved algorithm was a preliminary application of the XFEM to the problem of the concrete self-deformation cracking during the hydration and hardening period. However, room for improvement exists for this algorithm in terms of matching calculation programs with mass concrete temperature fields containing cooling pipes and the influence of creep or damage on crack propagation.

The evaluation of ecosystem health in mining areas on the matter element method

According to the characteristics of ecosystem and concept of the ecosystem in mining area, the index system of the ecosystem health in mining area was set up, and the evaluation standard was established. Aiming at the complexion in which the information lost in index ration, the matter element method was put forward to evaluate the ecosystem health in mining area. Making use of the model set up, the weight was built up by the method of index number heavy, the matter element, clas- sical field, and limit field were set up. The rating hierarchy was calculated by relating function. As a case study in the mining area of Pingyangsi Town, the results show that the ecosystem is good and sustainable from 2003 to 2006, but the healthy degree is not high, and some indexes have depravation.

On the Existence of a Minimum Universal Speed of Physical Transmissions Associated with Matter Wave in Special Relativity

In this work, we show that it is possible to establish coordinate transformations between inertial reference frames in the theory of special relativity with a minimum universal speed of physical transmissions. The established coordinate transformations, referred to as modified Lorentz transformations because they have almost identical form to the Lorentz transformations, also comply with the requirement of invariance of the Minkowski line element. Particularly, the minimum universal speed can be associated with the phase speed of de Broglie matter wave. As application, we also discuss the possibility to formulate relativistic classical and quantum mechanics for the special relativity associated with the modified Lorentz transformations, which describes physical processes that represent an expansion or a collapsing of massive quantum particles.

Evaluation on Urban Land Ecological Security Based on the PSR Model and Matter-Element Analysis: A Case Study of Zhuhai, Guangdong, China

As one of the Special Economic Zones since the reform and opening up, Zhuhai has developed during the past 30 years. Its economic development, industrial structure and ecological environment have undergone great changes. Research on changes in Zhuhai’s land ecological security is of great significance. Using relevant data from 2007-2012, this study established a land ecological security assessment system based on the PSR conceptual framework model. The system contained 18 indicators from 3 aspects according to the concrete features of Zhuhai. Then we used the matterelement analysis and the improved entropy weight to analyze and evaluate the land ecological security of Zhuhai. The results showed that: from 2007 to 2012, the levels of the land ecological security of Zhuhai were “secure”, and the value increased year by year;as the land ecological security response value increased, Zhuhai was capable of solving land ecosystem problems. However, it should be noted that the structure of land ecosystem in Zhuhai has not formed and that rapid expansion of construction land has caused the shortage of cultivated land and other issues. Measures should be taken to control the construction area, improve land intensive utilization and improve the land ecological security.

Application of matter-element analysis based on entropy right to evaluate the pavement condition in permafrost region

Evaluation of pavement performance is one of the most important issues in a pavement-management system.By employing the concept of entropy,the matter-element model for evaluating pavement is established,and the weights of the evaluation indices are obtained from sur-veying data.By calculating the degree of dependence of the matter-element model,the pavement performance evaluation can be obtained by this method.The results show that the matter-element model based on entropy right has good performance for evaluating the pavement condition in permafrost region.

Application of Matter Element Analysis Theory for Blasting Classification of Rock

The grading criterion of blasting classification, evaluating indexand the characteristic value are taken as matter elements. first, therelational function is constructed according to the gradingcriterion, and then, the grade of rock blasting is evaluated by thecomprehensive relational degree. The author has presented a systemmethod of blasting classification of rock. The practical exampleproves that it is simple in calculation and reasonable in evaluation.

Mesoscopic characterization and modeling of microcracking in cementitious materials by the extended finite element method

This study develops a mesoscopic framework and methodology for the modeling of microcracks in concrete. A new algorithm is first proposed for the generation of random concrete meso-structure including microcracks and then coupled with the extended finite element method to simulate the heterogeneities and discontinuities present in the meso-structure of concrete. The proposed procedure is verified and exemplified by a series of numerical simulations. The simulation results show that microcracks can exert considerable impact on the fracture performance of concrete. More broadly, this work provides valuable insight into the initiation and propagation mechanism of microcracks in concrete and helps to foster a better understanding of the micro-mechanical behavior of cementitious materials.

The Periodic Table of Elementary Particles for Baryonic Matter and Dark Matter: Upward-Going ANITA Events

This paper posits that the upward-going ANITA events are derived from the cosmic ray of the baryonic-dark matter (BDM) Higgs boson. In the extended standard model (ESM) for baryonic matter and dark matter, the spontaneous symmetry breaking through the Higgs mechanism for the symmetrical massless baryonic matter left-handed neutrinos and massless dark matter right-handed neutrinos produced massless baryonic matter left-handed neutrinos, sterile massive dark matter neutrinos, and the BDM Higgs boson. The BDM Higgs boson is the composite of the high-mass tau neutrino and the high-mass dark matter neutrino. During the passage through the high-density part of the Earth, the BDM Higgs boson is transformed into the oscillating BDM Higgs boson between the composite of the high-mass tau neutrino and the high-mass dark matter neutrino and the composite of the high-mass tau neutrino and the low-mass dark matter neutrino. The oscillating BDM Higgs boson decays into the high-mass tau neutrino with the extra energy and the low-mass dark matter neutrino (27 eV) in the low-density water-ice layer of the Earth. The high-mass tau neutrino is converted into ultra-high-energy tau neutrino which decays into tau lepton through the charged-current interactions, and tau lepton emerges from the surface of ice. Based on the periodic table of elementary particles, the calculated value for the high-mass tau neutrino with the extra energy is 0.47 EeV in good agreement with the observed 0.56 and 0.6 EeV. The periodic table of elementary particles for baryonic matter, dark matter, and gravity is based on the seven principal mass dimensional orbitals for stable baryonic matter leptons (electron and left-handed neutrinos), gauge bosons, gravity, and dark matter and the seven auxiliary mass dimensional orbitals for unstable leptons (muon and tau) and quarks, and calculates accurately the masses of all elementary particles and the cosmic rays by using only five known constants.

Using Extended Finite Element Method for Computation of the Stress Intensity Factor, Crack Growth Simulation and Predicting Fatigue Crack Growth in a Slant-Cracked Plate of 6061-T651 Aluminum

The 6061-T651 aluminium alloy is one of the most common aluminium alloys for marine components and general structures. The stress intensity factor (SIF) is an important parameter for estimating the life of the cracked structure. In this paper, the stress intensity factors of a slant-cracked plate, which is made of 6061-T651 aluminum, have been calculated using extended finite element method (XFEM) and finite element method (FEM) in ABAQUS software and the results were compared with theoretical values. Numerical values obtained from these two methods were close to the theoretical values. In simulations of crack growth at different crack angles, the crack propagation angle values were closer to the theoretical values in XFEM method. Also, the accuracy and validity of fatigue crack growth curve were much closer to the theoretical graph in XFEM than the FEM. Therefore, in this paper the capabilities of XFEM were realized in analyzing issues such as cracks.

Available Contents of Trace Nutrient Element and Factors Affecting Their Availability in Western Jilin

Based on the assay of the total content and available content of the trace nutrient elements and the soil pH and organic matter of the soil samples,the characteristic of the available content of the trace nutrient elements and their affecting factors are studied. The results show that the available B in western Jilin is in a middle level,the content in Nong'an is higher than that in the others; the available Mn is extremely abundant; the available Cu in Nong'an is obviously higher than other areas,and the content in Da'an differs greatly; the available Zn is in a middle level; the severe shortage of available Mo differs between different areas; and the available Fe is extremely abundant. The available Mn,Cu and Fe have significantly positive correlation with their total content; the available B has significantly positive correlation with pH,and Zn has obviously negative correlation with pH; the available Mn and Fe had significantly positive correlation with soil organic matter.

Hydro-mechanical modeling of impermeable discontinuity in rock by extended finite element method

The extended finite element method(XFEM) is a numerical method for modeling discontinuities within the classical finite element framework. The computation mesh in XFEM is independent of the discontinuities, such that remeshing for moving discontinuities can be overcome. The extended finite element method is presented for hydro-mechanical modeling of impermeable discontinuities in rock. The governing equation of XFEM for hydraulic fracture modeling is derived by the virtual work principle of the fracture problem considering the water pressure on crack surface. The coupling relationship between water pressure gradient on crack surface and fracture opening width is obtained by semi-analytical and semi-numerical method. This method simplifies coupling analysis iteration and improves computational precision. Finally, the efficiency of the proposed method for modeling hydraulic fracture problems is verified by two examples and the advantages of the XFEM for hydraulic fracturing analysis are displayed.