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Study on Limited Filamentous Sludge Bulking Test in A/O Activated Sludge Process
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作者 万玉山 孙凌峰 +2 位作者 贾春霞 李娜 雷春生 《Agricultural Science & Technology》 CAS 2014年第9期1620-1623,共4页
[Objective] This study aimed to make use of the limited filamentous sludge bulking characteristics to purify water quality and save energy. [Method] The effects of dissolved oxygen (DO) on sludge bulking were explor... [Objective] This study aimed to make use of the limited filamentous sludge bulking characteristics to purify water quality and save energy. [Method] The effects of dissolved oxygen (DO) on sludge bulking were explored by changing the DO con- centration in the aerobiotic pool of NO system from the low load (0.25 kg COD/(kg MLSS.d)) and the medium to high load (0.55 kgCOD/(kg MLSSod)). [Result] In the NO activated sludge system, when the sludge load was 0.25 kg COD/(kg MLSS.d), DO=1.5 mg/L, the sludge index was at around 250, while when the sludge load- ing was 0.55 kg COD/(kg MLSS.d), DO=1.5 mg/L, the sludge index was close to 300, occurring the limited filamentous bulking. The bulked sludge still showed high removal rates to COD, SS, nitrogen and phosphorus. [Conclusion] It could improve the oxygen transfer rate and reduce the aeration rate at low DO conditions to achieve energy-saving. 展开更多
关键词 A/O process Limited filamentous sludge bulking Sludge load Energy saving
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Bulking factor of the strata overlying the gob and a three-dimensional numerical simulation of the air leakage flow field 被引量:17
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作者 Shao Hao Jiang Shuguang +1 位作者 Wang Lanyun Wu Zhengyan 《Mining Science and Technology》 EI CAS 2011年第2期261-266,共6页
The present study examines the results of the researches related to the gob bulking factor carried out at home and abroad.A mathematical function of a three-dimensional gob bulking factor is described based on a three... The present study examines the results of the researches related to the gob bulking factor carried out at home and abroad.A mathematical function of a three-dimensional gob bulking factor is described based on a three-dimensional gob model.The method of taking value for interstice and permeability ratios is also proposed.The law of air leakage of fully mechanized top coal is researched in this study.The results show that the speed of air flow near the upper and lower crossheadings is higher than that in the central section of the gob at the same distance from the working face.When the amount of air at the working face exceeds a critical amount,the width of the spontaneous combustion zone in the upper and lower crossheadings is also larger than that in the central section.In this situation,the key is preventing the coal left in the upper and lower crossheadings from self-igniting.Reducing the amount of air at the working face can decrease the width of the spontaneous combustion zone,especially the width near the upper and lower crossheadings.This also moves the spontaneous combustion zone in the direction of the working face.It can prevent the coal in the gob from self-igniting by making the coal left in the crossheadings to be inert and by effectively controlling the amount of air at the working face. 展开更多
关键词 Gob bulking factor Flow field Numerical simulation Spontaneous combustion of coal
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HEXAHEDRAL ELEMENT REFINEMENT FOR THE PREDICTION- CORRECTION ALE FEM SIMULATION OF 3D BULKINGFORMING PROCESS 被引量:1
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作者 J.Chen Y.X.Wang W.P.Dong X.Y.Ruan 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2004年第6期923-927,共5页
Based on the characteristics of 3D bulk forming process, the arbitrary Lagrangian-Eulerian (ALE) formulation-based FEM is studied, and a prediction-correction ALE-based FEM is proposed which integrates the advantages ... Based on the characteristics of 3D bulk forming process, the arbitrary Lagrangian-Eulerian (ALE) formulation-based FEM is studied, and a prediction-correction ALE-based FEM is proposed which integrates the advantages of precisely predicting the boundary configuration of the deformed material, and of efficiently avoiding hexahedron remeshing processes. The key idea of the prediction-correction ALE FEM is elaborated in detail. Accordingly, the strategy of mesh quality control, one of the key enabling techniques for the 3D bulk forming process numerical simulation by the prediction-correction ALE FEM is carefully investigated, and the algorithm for hexahedral element refinement is formulated based on the mesh distortion energy. 展开更多
关键词 prediction-correction ALE FEM 3D bulk forming numerical simulation HEXAHEDRON mesh refinement
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Static aerobic composting of municipal sewage sludge with forced ventilation:Using matured compost as bulking conditioner 被引量:4
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作者 欧阳建新 施周 +3 位作者 钟华 刘卫 柴琦 袁兴中 《Journal of Central South University》 SCIE EI CAS 2014年第1期303-309,共7页
Static aerobic composting of municipal sewage sludge with forced ventilation or air ventilation using matured compost as bulking conditioner was investigated. Physical and chemical parame ,eters, e.g., temperature, mo... Static aerobic composting of municipal sewage sludge with forced ventilation or air ventilation using matured compost as bulking conditioner was investigated. Physical and chemical parame ,eters, e.g., temperature, moisture content, VSS, CODcr, pH, and germination index (GI), were analyzed to characterize the composting process. Fermentation starts quickly in both forced and air ventilation compost heaps and reaches high-temperature stage after 2 d, owing to the bulking function of matured compost. Compared to air ventilation, however, forced ventilation enables the high-temperature stage to last longer for approximately 7 d. The moisture content of both compost bodies decreases from 62% to about 50% as a result of evaporation, and it decreases slightly faster in forced ventilation compost heap after 13 d due to the higher temperature and better ventilation condition. Although no obvious differences of VSS and pH are observed between both compost heaps, the soluble CODcr and GI show differences during the second half period of fermentation. In forced ventilation compost, the soluble CODcr has a small rebound after 13 d, and GI decreases from 46% to 35% but then increases. These results show that in general, the matured compost is a good conditioner and force ventilation with a proper air supply strategy can be more efficient than air ventilation. 展开更多
关键词 municipal sewage sludge static aerobic composting forced ventilation matured compost bulking conditioner
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Time effect and prediction of broken rock bulking coefficient on the base of particle discrete element method 被引量:4
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作者 Fanfei Meng Hai Pu +4 位作者 Takashi Sasaoka Hideki Shimada Sifei Liu Tumelo KM Dintwe Ziheng Sha 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第4期643-651,共9页
Bulking characteristics of gangue are of great significance for the stability of goafs in mining overburden in the caving zones.In this paper,a particle discrete element method with clusters to represent gangue was ad... Bulking characteristics of gangue are of great significance for the stability of goafs in mining overburden in the caving zones.In this paper,a particle discrete element method with clusters to represent gangue was adopted to explore the bulking coefficient time effect of the broken rock in the caving zone under three-dimensional triaxial compression condition.The phenomena of stress corrosion,deformation,and failure of rock blocks were simulated in the numerical model.Meanwhile,a new criterion of rock fragments damage was put forward.It was found that the broken rock has obvious viscoelastic properties.A new equation based on the Burgers creep model was proposed to predict the bulking coefficient of broken rock.A deformation characteristic parameter of the prediction equation was analyzed,which can be set as a fixed value in the mid-and long-term prediction of the bulking coefficient.There are quadratic function relationships between the deformation characteristic parameter value and Talbot gradation index,axial pressure and confining pressure. 展开更多
关键词 bulking coefficient Time effect Deformation prediction Broken rock Particle discrete element model
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15 nm Bulk nFinFET器件性能研究及参数优化
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作者 侯天昊 范杰清 +3 位作者 赵强 张芳 郝建红 董志伟 《强激光与粒子束》 CAS CSCD 北大核心 2024年第3期92-99,共8页
为研究Bulk FinFET工作时基本结构参数、器件温度和栅极材料对其性能的影响,建立了一个15 nm n型Bulk FinFET器件模型,仿真分析了不同栅长、鳍宽、鳍高、沟道掺杂浓度、器件工作温度、栅极材料对器件性能的影响,发现增长栅长、降低鳍宽... 为研究Bulk FinFET工作时基本结构参数、器件温度和栅极材料对其性能的影响,建立了一个15 nm n型Bulk FinFET器件模型,仿真分析了不同栅长、鳍宽、鳍高、沟道掺杂浓度、器件工作温度、栅极材料对器件性能的影响,发现增长栅长、降低鳍宽和增加鳍高有助于抑制短沟道效应;1×10^(17)cm^(-3)以下的低沟道掺杂浓度对器件特性影响不大,但高掺杂会使器件失效;器件工作温度的升高会导致器件性能的下降;采用高K介质材料作为栅极器件性能优于传统材料SiO_(2)。 展开更多
关键词 bulk FinFET 短沟道效应 器件性能 参数优化 栅极材料
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袋型阻尼密封动力学特性双控制体Bulk Flow模型
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作者 桂佳强 李志刚 李军 《西安交通大学学报》 EI CAS CSCD 北大核心 2024年第7期26-38,共13页
为快速准确预测袋型阻尼密封泄漏特性和动力学特性,针对传统单控制体Bulk Flow模型预测精度低、无法预测交叉动力系数的问题,提出了袋型阻尼密封双控制体Bulk Flow模型和动力学特性数值预测方法,并开发了计算程序。首先,依据边界层理论... 为快速准确预测袋型阻尼密封泄漏特性和动力学特性,针对传统单控制体Bulk Flow模型预测精度低、无法预测交叉动力系数的问题,提出了袋型阻尼密封双控制体Bulk Flow模型和动力学特性数值预测方法,并开发了计算程序。首先,依据边界层理论,将袋型密封腔室划分为两个控制体,推导了控制体的连续性、周向动量和能量方程,引入Swamee-Jain和Takahashi方程,计算流体-壁面间和流体-流体间的周向黏性摩擦力;其次,采用牛顿-拉夫森算法和摄动分析法分别求解0阶和1阶控制方程,获得各刚度、阻尼动力特性系数;然后,通过与袋型阻尼密封泄漏量和动力特性系数的实验值、单控制体Bulk Flow模型和非定常计算流体动力学(CFD)数值结果进行比较,验证了模型和方法的准确性和可靠性;最后,研究了转子转速(10 000、15 000、20 000 r/min)和预旋比(0.067、0.724、0.997)对袋型阻尼密封动力学特性的影响。结果表明:所发展的模型和方法具有计算速度快、预测精度高(泄漏量预测误差小于6%,动力特性系数预测误差小于38%)的优点;转子转速和进口预旋的增大均会导致袋型阻尼密封有效阻尼显著减小,穿越频率显著增大,易诱发轴系失稳。 展开更多
关键词 袋型阻尼密封 泄漏特性 动力学特性 双控制体 bulk Flow模型
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Sludge Bulking Property of Membrane Bio-reactor in Albumen Wqastewater Treatment
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作者 ZHANG Ying~(1,2), REN Nan-qi~1, LIU Xiao-lei~1, WU Yi-ning~1, DU Chang-jie~2 (1. School of Municipal & Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China 2. School of Resource & Environment, Northeast Agriculture University, Harbin 150030, China) 《地球科学进展》 CAS CSCD 2004年第S1期511-515,共5页
Albumen wastewater was treated by Membrane Bio-reactor. Sludge bulking property of Membrane Bio-Reactor was investigated in this study through contrast research. When the sludge bulking appeared, the removal efficienc... Albumen wastewater was treated by Membrane Bio-reactor. Sludge bulking property of Membrane Bio-Reactor was investigated in this study through contrast research. When the sludge bulking appeared, the removal efficiency of COD in Membrane Bio-reactor increased slightly under the function of filamentous bacteria. However, the negative effects of the higher net water-head differential pressures,the higher block rate of membrane pore and the great quantity of filamentous bacteria at the externalsurface pres... 展开更多
关键词 Membrane Bio-reactor Sludge bulking property Membrane fouling
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Negative Effects of Sludge Bulking in Membrane Bio-Reactor
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作者 ZHANG Ying HUANG Zhi +1 位作者 REN Nanqi MENG Qingjuan 《Journal of Northeast Agricultural University(English Edition)》 CAS 2006年第2期153-156,共4页
Sludge bulking property of membrane bio-reactor was investigated in this study through contrast research. When the sludge bulking appeared, the removal efficiency of COD in membrane bio-reactor increased slightly thro... Sludge bulking property of membrane bio-reactor was investigated in this study through contrast research. When the sludge bulking appeared, the removal efficiency of COD in membrane bio-reactor increased slightly through the function of filamentous bacteria. However, the negative effects of the higher net water-head differential pressures, the high block rate of membrane pore and the great quantity of filamentous bacteria at the external surface presented at the same time. Thus, plenty of methods should be performed to control sludge bulking once it happened in membrane bio-reactor. 展开更多
关键词 membrane bio-reactor sludge bulking property membrane fouling
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Injectable Biological Bulking Agent to Treat Stress Urinary Incontinence in Women: A Feasibility Pilot Study
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作者 Salvador V. C. Lima Eugê +4 位作者 nio S. Lustosa Fernanda C. F. S. Calisto Evandilson G. C. De Barros Bruno C. A. Santos Fábio O. Vilar 《Open Journal of Urology》 2022年第2期107-116,共10页
Background: Urinary incontinence mainly affects women regardless of age and, as it affects their quality of life, influences work, sex life and independence for activities of daily living. The treatment of stress urin... Background: Urinary incontinence mainly affects women regardless of age and, as it affects their quality of life, influences work, sex life and independence for activities of daily living. The treatment of stress urinary incontinence including urethral volume injection therapy can provide an intermediate option over non-surgical and surgical therapies. One of the mechanisms for stress continence depends on the effective coaptation of the urethra during the increase in intra-abdominal pressure. The bulking agents can be injected transurethral or periurethral retrogradely, using direct vision from a cystoscope. Purpose: To evaluate the feasibility and preliminary outcome performance of the bacterial polysaccharide gel used as biological bulking agent applied in female patients with stress urinary incontinence. Methods: A prospective clinical pilot study was performed, in a single institution, including female patients who were admitted to the urologic outpatient clinic with Stress Urinary Incontinence (SUI) without previous treatments and they were selected and underwent bulking agent procedure. The evaluation was performed at the time of enrollment and 6 months after treatment. The primary outcome was Quality of Life (QOL) using the ICIQ-SF Questionnaire. The amount of urine leakage measured by the 1-HOUR PAD-TEST was the second outcome. Results: Fifteen women (with an average age of 53 years) were submitted to the application of bacterial cellulose gel and she was analyzed. Only two patients presented unchanged incontinence. The study considered as primary outcome the improvement or disappearance of symptoms after six months of intervention. Post-intervention Quality of Life (QOL) questionnaire indicated that all of these patients related a better quality of life (62.5%). Through the PAD-test it was possible to observe a decrease in urinary leak of 85% comparing the results pre and post-intervention (BCA—Bacterial Cellulose Application) with p-value equal to 0.000009. Conclusions: The results of this pilot study suggest that the use of biological bulking agent is a promising approach to treat stress urinary incontinence in female patients. Trial registration: Registration number and date of registration should be instated in this section. 展开更多
关键词 bulking Agents Urinary Incontinence STRESS Biopolymers
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Characteristics of Nutrients Removal under Viscous Sludge Bulking Treating Synthetic Wastewater
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作者 Zhaoxu Peng Zhongyuan Zhao +2 位作者 Tianyu Lou Kun Jiang Lei Li 《Journal of Harbin Institute of Technology(New Series)》 CAS 2021年第6期37-43,共7页
Viscous sludge bulking is a rare phenomenon in activated sludge process.The performances of nutrients removal were investigated with normal sludge and viscous bulking sludge.The results showed that when COD loading an... Viscous sludge bulking is a rare phenomenon in activated sludge process.The performances of nutrients removal were investigated with normal sludge and viscous bulking sludge.The results showed that when COD loading and C/N ratio were around 0.13 mg COD/(mg MLSS·d)and 7.67,the effect of viscous sludge bulking on the maximum specific oxidation rates of NH_(4)^(+)⁃N was very little,while the maximum specific oxidation rates of NO_(2)^(-)⁃N decreased from 24.69 mg/(g·h)to 1.20 mg/(g·h).Compared with normal sludge,viscous bulking sludge had bigger particle size and more extracellular polymeric substances(EPS).The mass transfer resistance in sludge flocs might be the main cause of the difference in NO-2⁃N oxidation rates.Therefore,this study demonstrates that viscous sludge bulking is beneficial to enhance simultaneous nitrification and denitrification(SND),and excessive EPS will exhibit storage function during phosphorus removal process. 展开更多
关键词 activated sludge nitrogen removal viscous sludge bulking nitrification kinetics phosphorus uptake
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Endoscopicandimagingappearanceafterinjectionofanano-rectalbulking agent
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作者 Papafragkakis H Changela K +5 位作者 Bhatia T Ona MA Malieckal A Paleti V Fuksbrumer MS Anand S 《World Journal of Gastrointestinal Endoscopy》 2014年第7期324-327,共4页
The use of hyaluronic acid and dextranomer (Solesta, Salix) injection in the anal canal is an emerging modal-ity in the treatment of fecal incontinence. However, little is known regarding the endoscopic and radiologic... The use of hyaluronic acid and dextranomer (Solesta, Salix) injection in the anal canal is an emerging modal-ity in the treatment of fecal incontinence. However, little is known regarding the endoscopic and radiological appearance following injection of this ano-rectal bulking agent. We report computed tomography and endoscopic findings after hyaluronic acid/dextranomer injection in the ano-rectal area. 展开更多
关键词 Fecal incontinence Ano-rectal bulking agent Hyaluronic acid Dextranomer
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Anisotropic Band Evolution of Bulk Black Phosphorus Induced by Uniaxial Tensile Strain
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作者 邓亚丰 张艺琳 +7 位作者 赵亚飞 徐永康 代兴泽 王双海 陆显扬 黎遥 徐永兵 何亮 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第3期83-96,共14页
We investigate the anisotropic band structure and its evolution under tensile strains along different crystallographic directions in bulk black phosphorus(BP)using angle-resolved photoemission spectroscopy and density... We investigate the anisotropic band structure and its evolution under tensile strains along different crystallographic directions in bulk black phosphorus(BP)using angle-resolved photoemission spectroscopy and density functional theory.The results show that there are band crossings in the Z-L(armchair)direction. 展开更多
关键词 DIRECTIONS bulk PHOSPHORUS
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Influences of polymorphism of packed particles on bulk characterizations in fluidization realm
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作者 Quanhong Zhu Yalong Cao +4 位作者 Qiang Zhang Wankun Liu Hao Guan Donghui Liu Hengjun Gai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期238-248,共11页
The characterization of a particle ensemble(rather than a single particle) is of paramount significance to various particle technologies and has long been a fundamental subject in the fluidization realm. However, many... The characterization of a particle ensemble(rather than a single particle) is of paramount significance to various particle technologies and has long been a fundamental subject in the fluidization realm. However, many of such bulk characterizations as loosely-packed density(ρbl), minimum fluidization velocity(Umf), sphericity(φ), discharge rate through orifice(q), angle of repose(β), and segregation index(S),were found to be poorly reproducible, making the reported results seldom comparable. Since these bulk characterizations started from the packed state of particles, such poor reproducibility was ascribed to the polymorphism of packed particles in this work. We observed that in the fluidized bed, the settled/packed state of particles varied monotonously with the settling rate(a) from complete fluidization to zero. This phenomenon confirmed the polymorphic characteristic of packed particles and further enabled us to systematically disclose/clarify its influences on the aforementioned bulk characterizations. Such influences could be comprehensively and intuitively reflected by the impacts induced by a. With the decrease of a, ρbl, φ and q first increased, then decreased, and finally leveled off while Umfand β showed an opposite trend. On the other hand, S first increased and then remained invariant. As per these findings and definitions of these bulk characterizations, benchmarks were indicated to unify the selection of settled state among future scholars and further make their outcomes become fairly comparable. Additionally, most packed states of the particle ensemble were proved to be metastable with their formation and behavior being identical to those of the amorphous state. 展开更多
关键词 FLUIDIZATION FLUIDIZED-BED Particle POLYMORPHISM bulk characterization Comparability
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“Glass-quake”in elastically loaded bulk metallic glasses
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作者 Qi Huang Kaiguo Chen +7 位作者 Chen Liu Guisen Liu Yang Shao Chenlong Zhao Ran Chen Hengtong Bu Lingti Kong Yao Shen 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第11期367-371,共5页
Amorphous solids exhibit scale-free avalanches,even under small external loading,and thus can work as suitable systems to study critical behavior and universality classes.The abundance of scale-free avalanches in the ... Amorphous solids exhibit scale-free avalanches,even under small external loading,and thus can work as suitable systems to study critical behavior and universality classes.The abundance of scale-free avalanches in the entire elastic tension regime of bulk metallic glass(BMG)samples has been experimentally observed using acoustic emission(AE)measurements.In this work,we compare the statistics of avalanches with those of earthquakes,and find that they both follow the Gutenberg–Richter law in the statistics of energies and Omori’s law of aftershock rates,and share the same characteristics in the distribution of recurrence times.These resemblances encourage us to propose the term“glass-quake”to describe avalanches in elastically loaded BMGs.Furthermore,our work echoes the potential universality of critical behavior in disordered physical systems from atomic to planetary scales,and motivates the use of elastic loaded BMGs as valuable laboratory simulators of seismic dynamics. 展开更多
关键词 bulk metallic glass AVALANCHE EARTHQUAKE disorder system time series
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Bulk geochemistry,Rb-Sr,Sm-Nd,and stable O-H isotope systematics of the Metzimevin high-grade iron ore deposit,Mbalam iron ore district,southern Cameroon
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作者 Samndong Cyril Tufoin Cheo Emmanuel Suh +1 位作者 Tabod Charles Tabod George Lemewihbwen Ngiamte 《Acta Geochimica》 EI CAS CSCD 2024年第4期677-706,共30页
Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore d... Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore district,Southern Cameroon,Metzimevin iron ore deposit is a hematite-magnetite BIF system,dominated by SiO_(2)+Fe_(2)O_(3)(97.1 to 99.84 wt%),with low concentrations of clastic elements e.g.,Al_(2)O_(3),TiO_(2),and HFSE,depicting a nearly pure chemical precipitate.The REE+Y signature of the iron deposit displays strong positive Eu anomaly,strong negative Ce anomaly,and chondritic to superchondritic Y/Ho ratios,suggestive of formation by mixed seawater-high temperature hydrothermal fluids in oxidising environment.The^(87)Sr/^(86)Sr ratios of the BIF are higher than the maximum^(87)Sr/^(86)Sr evolution curves for all Archean reservoirs(bulk silicate earth,Archean crust and Archean seawater),indicating involvement of continentally-derived components during BIF formation and alteration.TheƐ_(Nd)(t)(+2.26 to+3.77)and Nd model age indicate that chemical constituents for the BIF were derived from undifferentiated crustal source,between 3.002 and 2.88 Ga.The variable and diverse O and H isotope data(−1.9‰to 17.3‰and−57‰to 136‰respectively)indicate that the Metzimevin iron ore formed initially from magmatic plumes and later enriched by magmatic-metamorphic-modified meteoric fluids.Mass balance calculations indicate mineralisation by combined leaching and precipitation,with an average iron enrichment factor of>2.67 and SiO_(2)depletion factor of>0.99.This is associated with an overall volume reduction of 28.27%,reflecting net leaching and volume collapse of the BIF protholith. 展开更多
关键词 bulk geochemistry RB-SR SM-ND Mitzimevin High-grade iron ore
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A bulk extraction method to determine the stable isotope ratios of iron,nickel,copper,zinc,and cadmium in seawater using multi-collector inductively coupled plasma mass spectrometry
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作者 Zhan Shen Yuncong Ge +3 位作者 Jiahui Liu Wenkai Guan Wenfeng Hu Ruifeng Zhang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2024年第7期125-137,共13页
The oceanic trace metals iron(Fe),nickel(Ni),copper(Cu),zinc(Zn),and cadmium(Cd)are crucial to marine phytoplankton growth and global carbon cycle,and the analysis of their stable isotopes can provide valuable insight... The oceanic trace metals iron(Fe),nickel(Ni),copper(Cu),zinc(Zn),and cadmium(Cd)are crucial to marine phytoplankton growth and global carbon cycle,and the analysis of their stable isotopes can provide valuable insights into their biogeochemical cycles within the ocean.However,the simultaneous isotopic analysis of multiple elements present in seawater is challenging because of their low concentrations,limited volumes of the test samples,and high salt matrix.In this study,we present the novel method developed for the simultaneous analysis of five isotope systems by 1 L seawater sample.In the developed method,the NOBIAS Chelate-PA1 resin was used to extract metals from seawater,the AG MP-1M anion-exchange resin to purify Cu,Fe,Zn,Cd,and the NOBIAS Chelate-PA1 resin to further extract Ni from the matrix elements.Finally,a multi-collector inductively coupled plasma mass spectroscope(MC-ICPMS)was employed for the isotopic measurements using a doublespike technique or sample-standard bracketing combined with internal normalization.This method exhibited low total procedural blanks(0.04 pg,0.04 pg,0.21 pg,0.15 pg,and 3 pg for Ni,Cu,Fe,Zn,and Cd,respectively)and high extraction efficiencies(100.5%±0.3%,100.2%±0.5%,97.8%±1.4%,99.9%±0.8%,and 100.1%±0.2%for Ni,Cu,Fe,Zn,and Cd,respectively).The external errors and external precisions of this method could be considered negligible.The proposed method was further tested on the seawater samples obtained from the whole vertical profile of a water column during the Chinese GEOTRACES GP09 cruise in the Northwest Pacific,and the results showed good agreement with previous related data.This innovative method will contribute to the advancement of isotope research and enhance our understanding of the marine biogeochemical cycling of Fe,Ni,Cu,Zn,and Cd. 展开更多
关键词 trace metal stable isotopes seawater bulk extraction
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单细胞测序与Bulk RNA测序联合分析构建膀胱癌风险预后模型
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作者 李自智 李俊义 +1 位作者 曹庆飞 佟明 《锦州医科大学学报》 CAS 2024年第2期30-39,共10页
目的本研究致力于开发一种基于膀胱癌核心细胞差异性表达基因的预后风险评估模型。通过在多个数据集中验证其效力,旨在为膀胱癌患者提供一个新的临床应用工具,用于预后风险评估。方法本研究综合利用了单细胞和Bulk RNA测序数据。我们首... 目的本研究致力于开发一种基于膀胱癌核心细胞差异性表达基因的预后风险评估模型。通过在多个数据集中验证其效力,旨在为膀胱癌患者提供一个新的临床应用工具,用于预后风险评估。方法本研究综合利用了单细胞和Bulk RNA测序数据。我们首先从GEO数据库下载并分析了相关的膀胱癌单细胞和芯片RNA数据集。通过生物信息学方法,我们鉴定了核心细胞的差异性表达基因,并对其进行了功能及通路富集分析。基于这些分析,我们使用单变量和多变量Cox回归方法筛选出与膀胱癌预后显著相关的关键基因,并据此构建了一个预后风险评估模型。该模型在TCGA-BLCA数据集中进一步进行了效力验证。结果经过全面的生物信息学分析,我们鉴定出了223个核心细胞的差异性表达基因。这些基因在细胞外基质的结构和功能方面发挥着重要作用。构建的预后风险评估模型包括5个独立的预后相关基因(MFAP5、PDE4D、ISG15、ADAMTS1和FGL2)。在GEO和TCGA-BLCA数据集中的验证结果表明,该模型具有良好的预测效力,为膀胱癌患者的预后评估提供新型生物学标志工具。结论本研究成功开发了一个基于5个关键基因标志物的膀胱癌预后风险评估模型并具有良好的预测效力。此模型的开发为膀胱癌的生物学研究和临床预后评估提供了一个新的工具,有助于更好地理解膀胱癌的生物学特性并指导患者的个性化治疗。 展开更多
关键词 膀胱癌 单细胞RNA测序 bulk RNA测序 预后风险评估模型 生物信息学分析
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Thermodynamics-directed bulk/grain-boundary engineering for superior electrochemical durability of Ni-rich cathode
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作者 Kangyu Zou Mingzhu jiang +5 位作者 Tianxiang Ning Lei Tan Junchao Zheng Jiexi Wang Xiaobo Ji Lingjun Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期321-331,I0006,共12页
Introducing high-valence Ta element is an essential strategy for addressing the structu ral deterioration of the Ni-rich LiNi_(1-x-y)Co_(x)Mn_(y)O_(2)(NCM)cathode,but the enlarged Li/Ni cation mixing leads to the infe... Introducing high-valence Ta element is an essential strategy for addressing the structu ral deterioration of the Ni-rich LiNi_(1-x-y)Co_(x)Mn_(y)O_(2)(NCM)cathode,but the enlarged Li/Ni cation mixing leads to the inferior rate capability originating from the hindered Li~+migration.Note that the non-magnetic Ti~(4+)ion can suppress Li/Ni disorder by removing the magnetic frustration in the transition metal layer.However,it is still challenging to directionally design expected Ta/Ti dual-modification,resulting from the complexity of the elemental distribution and the uncertainty of in-situ formed coating compounds by introducing foreign elements.Herein,a LiTaO_3 grain boundary(GB)coating and bulk Ti-doping have been successfully achieved in LiNi_(0.834)Co_(0.11)Mn_(0.056)O_(2) cathode by thermodynamic guidance,in which the structural formation energy and interfacial binding energy are employed to predict the elemental diffusion discrepancy and thermodynamically stable coating compounds.Thanks to the coupling effect of strengthened structural/interfacial stability and improved Li~+diffusion kinetics by simultaneous bulk/GB engineering,the Ta/Ti-NCM cathode exhibits outstanding capacity retention,reaching 91.1%after 400 cycles at 1 C.This elaborate work contributes valuable insights into rational dual-modification engineering from a thermodynamic perspective for maximizing the electrochemical performances of NCM cathodes. 展开更多
关键词 Ni-rich layered cathode Dual-modification Grain boundary coating bulk doping Thermodynamic perspective
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Understanding the correlation between energy-state mismatching and open-circuit voltage loss in bulk heterojunction solar cells
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作者 Hyun-Seock Yang Danbi Kim +7 位作者 Chang-Mok Oh Vellaiappillai Tamilavan Pesi MHangoma Hojun Yi Bo RLee Insoo Shin In-Wook Hwang Sung Heum Park 《Carbon Energy》 SCIE EI CAS CSCD 2024年第5期164-174,共11页
Photoinduced intermolecular charge transfer(PICT)determines the voltage loss in bulk heterojunction(BHJ)organic photovoltaics(OPVs),and this voltage loss can be minimized by inducing efficient PICT,which requires ener... Photoinduced intermolecular charge transfer(PICT)determines the voltage loss in bulk heterojunction(BHJ)organic photovoltaics(OPVs),and this voltage loss can be minimized by inducing efficient PICT,which requires energy-state matching between the donor and acceptor at the BHJ interfaces.Thus,both geometrically and energetically accessible delocalized state matching at the hot energy level is crucial for achieving efficient PICT.In this study,an effective method for quantifying the hot state matching of OPVs was developed.The degree of energy-state matching between the electron donor and acceptor at BHJ interfaces was quantified using a mismatching factor(MF)calculated from the modified optical density of the BHJ.Furthermore,the correlation between the open-circuit voltage(Voc)of the OPV device and energy-state matching at the BHJ interface was investigated using the calculated MF.The OPVs with small absolute MF values exhibited high Voc values.This result clearly indicates that the energy-state matching between the donor and acceptor is crucial for achieving a high Voc in OPVs.Because the MF indicates the degree of energy-state matching,which is a critical factor for suppressing energy loss,it can be used to estimate the Voc loss in OPVs. 展开更多
关键词 bulk heterojunction open circuit voltage organic photovoltaics photoinduced charge transfer voltage loss
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