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An Experimental and Numerical Thermal Flow Analysis in a Solar Air Collector with Different Delta Wing Height Ratios
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作者 Ghobad Shafiei Sabet Ali Sari +3 位作者 Ahmad Fakhari Nasrin Afsarimanesh Dominic Organ Seyed Mehran Hoseini 《Frontiers in Heat and Mass Transfer》 EI 2024年第2期491-509,共19页
This study conducts both numerical and empirical assessments of thermal transfer and fluid flow characteristics in a Solar Air Collector(SAC)using a Delta Wing Vortex Generator(DWVG),and the effects of different heigh... This study conducts both numerical and empirical assessments of thermal transfer and fluid flow characteristics in a Solar Air Collector(SAC)using a Delta Wing Vortex Generator(DWVG),and the effects of different height ratios(Rh=0.6,0.8,1,1.2 and 1.4)in delta wing vortex generators,which were not considered in the earlier studies,are investigated.Energy and exergy analyses are performed to gain maximum efficiency.The Reynolds number based on the outlet velocity and hydraulic diameter falls between 4400 and 22000,corresponding to the volume flow rate of 5.21–26.07 m^(3)/h.It is observed that the delta wing vortex generators with a higher height ratio yield maximum heat transfer enhancement and overall enhancement ratio.The empirical and numerical findings demonstrate that the exergy and thermal efficiencies decline in a specific range.TheNusselt number,pressure drop,energy,and exergy efficiencies enhance with rising Reynolds number,although the friction coefficient diminishes.The maximum heat transfer enhancement is 57%.According to the evaluation of exergy efficiency,the greatest efficiency of 31.2%is obtained at Rh=1.4 and Reynolds number 22000. 展开更多
关键词 Vortex generators heat transfer augmentation numerical simulation solar air collector empirical height ratio
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Carbonation of Pure Minerals in Portland Cement:Evolution in Products as a Function of Water-to-solid Ratio
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作者 XIONG Kun SHANG Xiaopeng +1 位作者 LI Hongyan WANG Dan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1214-1222,共9页
Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and prod... Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and product evolution for CO_(2)curing at various water-to-solid ratios.These pure minerals were synthesized and subject to CO_(2)curing in this study to make an in-depth understanding for the carbonation properties of cement-based materials.Results showed that the optimum water-to-solid ratios of C_(3)S,β-C_(2)S,C_(3)A and C_(4)AF were 0.25,0.15,0.30 and 0.40 for carbonation,corresponding to 2 h carbonation degree of 38.5%,38.5%,24.2%,and 21.9%,respectively.The produced calcite duringβ-C_(2)S carbonation decreased as the water-to-solid ratio increased,with an increase in content of metastable CaCO_(3)of vaterite and aragonite.The thermodynamic stability of CaCO_(3)produced during carbonation was C_(3)A>C_(4)AF>β-C_(2)S>C_(3)S.The carbonation degree of Portland cement was predicted based on the results of pure minerals and the composition of cement,and the error of predicted production of CaCO_(3)was only 1.1%,which provides a potential method to predict carbonation properties of systems with a complex mineral composition. 展开更多
关键词 accelerated carbonation portland cement calcium carbonate water-to-solid ratio
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Tunnel flexibility effect on the ground surface acceleration response 被引量:8
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作者 Mohammad Hassan Baziar asoud Rabeti Moghadam +1 位作者 Yun Wook Choo Dong-Soo Kim 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2016年第3期457-476,共20页
Flexibility of underground structures relative to the surrounding medium, referred to as the flexibility ratio, is an important factor that influences their dynamic interaction. This study investigates the flexibility... Flexibility of underground structures relative to the surrounding medium, referred to as the flexibility ratio, is an important factor that influences their dynamic interaction. This study investigates the flexibility effect of a box-shaped subway tunnel, resting directly on bedrock, on the ground surface acceleration response using a numerical model verified against dynamic centrifuge test results. A comparison of the ground surface acceleration response for tunnel models with different flexibility ratios revealed that the tunnels with different flexibility ratios influence the acceleration response at the ground surface in different ways. Tunnels with lower flexibility ratios have higher acceleration responses at short periods, whereas tunnels with higher flexibility ratios have higher acceleration responses at longer periods. The effect of the flexibility ratio on ground surface acceleration is more prominent in the high range of frequencies. Furthermore, as the flexibility ratio of the tunnel system increases, the acceleration response moves away from the free field response and shifts towards the longer periods. Therefore, the flexibility ratio of the underground tunnels influences the peak ground acceleration (PGA) at the ground surface, and may need to be considered in the seismic zonation of urban areas. 展开更多
关键词 box-shaped tunnel flexibility ratio acceleration response ground surface centrifuge modeling numericalsimulation
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Contribution of patchy reconnection to the ion-to-electron temperature ratio in the Earth’s magnetotail 被引量:3
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作者 ChuXin Chen Chih-Ping Wang 《Earth and Planetary Physics》 CSCD 2019年第6期474-480,共7页
The ion-to-electron temperature ratio is a good indicator of the processes involved in the plasma sheet.Observations have suggested that patchy reconnection and the resulting earthward bursty bulk flows(BBFs)transport... The ion-to-electron temperature ratio is a good indicator of the processes involved in the plasma sheet.Observations have suggested that patchy reconnection and the resulting earthward bursty bulk flows(BBFs)transport may be involved in causing the lower temperature ratios at smaller radial distances during southward IMF periods.In this paper,we estimate theoretically how a patchy magnetic reconnection electric field can accelerate ions and electrons differently.If both ions and electrons are non-adiabatically accelerated only once within each reconnection,the temperature ratio would be preserved.However,when reconnection occurs closer to the Earth where magnetic field lines are shorter,particles mirrored back from the ionosphere can cross the reconnection region more than once within one reconnection;and electrons,moving faster than ions,can have more crossings than do ions,leading to electrons being accelerated more than ions.Thus as particles are transported from tail to the near-Earth by BBFs through multiple reconnection,electrons should be accelerated by the reconnection electric field more times than are ions,which can explain the lower temperature ratios observed closer to the Earth. 展开更多
关键词 the ion-to-electron temperature ratio plasma sheet patchy magnetic RECONNECTION non-adiabatical acceleration
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Preservation and variation of ion-to-electron temperature ratio in the plasma sheet in geo-magnetotail 被引量:3
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作者 ChuXin Chen 《Earth and Planetary Physics》 CSCD 2021年第4期337-347,共11页
The ion-to-electron temperature ratio is a good indicator of the processes involved in solar wind plasma entering and being transported inside Earth’s plasma sheet.In this study,we have demonstrated that patchy magne... The ion-to-electron temperature ratio is a good indicator of the processes involved in solar wind plasma entering and being transported inside Earth’s plasma sheet.In this study,we have demonstrated that patchy magnetic reconnection has the potential to preserve the ion-to-electron temperature ratio under certain conditions.If the charged particles are non-adiabatically accelerated no more than once in a single reconnection,the temperature ratio would be preserved;on the other hand,this ratio would not be preserved if they are accelerated multiple times.Consequently,under a northward interplanetary magnetic field(IMF)condition,the reconnection in the nonlinear phase of the Kelvin-Helmholtz instability is the dominant process for solar-originated plasma entering the Earth’s magnetosphere,and the ion-to-electron temperature ratio is preserved inside the plasma sheet.When the direction of the IMF is southward,the reflection of electrons from the magnetic mirror point,and subsequent multiple non-adiabatic accelerations at the reconnection site,are the primary reasons for the observed low ion-to-electron temperature ratio close to the Earth at midnight.While reconnections that occur in the night-side far tail might preserve the ratio,turbulence on the boundaries of the bursty bulk flows(BBFs)could change the ratio in the far tail through the violation of the frozen-in condition of the ions.The plateau in the contour of the calculated ion-to-electron temperature ratio in the down tail distance between 40 and 60 Earth radii may explain the strong correlation between the ion and electron temperatures in the outer central plasma sheet,which has not been clearly understood till date. 展开更多
关键词 plasma sheet ion-to-electron temperature ratio patchy magnetic reconnection non-adiabatic acceleration bursty bulk flows far tail
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Effect of Structural Parameters on the Performance of NS High-efficiency Composite TraysⅠ.The Effect of Aperture and Opening Ratio on NS High-efficiency Composite Trays 被引量:2
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作者 Qiao Yingyun Tian Yuanyu +1 位作者 Xu Jingfang Xie Kechang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第3期56-61,共6页
In this paper,the structure and characteristics of the NS high-efficiency composite trays based on the doublelayer aperture jet sieve plate and compositely structured packing were investigated.The effect of aperture a... In this paper,the structure and characteristics of the NS high-efficiency composite trays based on the doublelayer aperture jet sieve plate and compositely structured packing were investigated.The effect of aperture and opening ratio of plate on the fluid dynamics of the NS high-efficiency composite trays,such as the dry tray pressure drop,the wet tray pressure drop,the entrainment,the froth height,the leakage and mass transfer characteristics,were investigated.As a result, the low pressure drop,the high efficiency and the high capacity are the main advantages of the NS high-efficiency composite trays compared to other types of trays.According to this study,small aperture is useful for reducing the pressure drop and entrainment with a high mass transfer efficiency;while large aperture can achieve high capacity and efficiency in a broader operating range at the same pressure drop and entrainment. 展开更多
关键词 NS high-efficiency composite trays APERTURE opening ratio fluid dynamics mass transfer characteristics
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The Effect of the Gap Ratio on the Flow and Heat Transfer over a Bluff Body in Near-Wall Conditions 被引量:1
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作者 Shaohua Zhai Guannan Xi 《Fluid Dynamics & Materials Processing》 EI 2022年第1期109-130,共22页
In order to study the effect of different gap ratios on the thermofluid-dynamic field around a bluff body located in proximity to a heated wall,a series of experiments and numerical simulations have been conducted.The... In order to study the effect of different gap ratios on the thermofluid-dynamic field around a bluff body located in proximity to a heated wall,a series of experiments and numerical simulations have been conducted.The former were carried out using an open circulating water tank experimental platform and a single cylinder and square column as geometrical models(their characteristic length being D).The latter were based on the well-known SIMPLE algorithm for incompressible flow.The results show that the gap ratio is an important factor affecting the wake characteristics of near-wall bluff bodies.When the gap ratio is small,the influence of the wall on the bluff body wake is large.With an increase in the gap extension,periodic vortex shedding is enabled and heat transfer is strengthened accordingly;in addition,the vortex shedding period is larger for the square column.The square column displays hysteresis compared with the cylinder at the same gap ratio(the critical gap ratio of cylinder is 0.2~0.4,while that of square column is 0.40.6). 展开更多
关键词 Transition flow gap ratio near-wall flow characteristic enhanced heat transfer
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Numerical Study on the Effects of Contraction Ratio in a Two-Phase Flow Injection Nozzle 被引量:1
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作者 Haider Ali Kyung Won Kim +2 位作者 Jae Sik Kim Jong Yun Choi Cheol Woo Park 《Open Journal of Fluid Dynamics》 2016年第1期1-10,共10页
The Euler-Euler numerical method was used to investigate the effects of contraction ratio on twophase flow mixing with mass transfer in the flow injection nozzle. The geometric shape of the nozzle was modified to impr... The Euler-Euler numerical method was used to investigate the effects of contraction ratio on twophase flow mixing with mass transfer in the flow injection nozzle. The geometric shape of the nozzle was modified to improve carbonation efficiency. A gas inlet hole was created to increase the flow mixing of CO2 with water. A nozzle throat was also introduced to increase the gas dissolution by increasing flow rates. Various contraction ratios of nozzle throat, inlet gas and liquid velocities, and gas bubble sizes were employed to determine their effects on gas hold-up, gas concentration, and mass transfer coefficient. Results revealed that the flow injection nozzle with high contraction ratios improved carbonation because of high gas hold-up. Gas concentration was directly related to contraction ratio and gas flow velocities. Carbonation reduced when high liquid velocities and large gas bubbles were employed because of inefficient flow mixing. This study indicated that flow injection nozzle with large contraction ratios were suitable for carbonation because of their ability to increase gas hold-up, gas concentration, and mass transfer coefficient. 展开更多
关键词 Flow Injection Nozzle Nozzle Throat Contraction ratio Gas-Liquid Flow Mass Transfer
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REACTIVITY RATIOS FOR COPOLYMERIZATION WITH THE PARTICIPATION OF A CHARGE-TRANSFER COMPLEX
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作者 Guo-rong Shan Zhi-xue Weng +1 位作者 Zhi-ming Huang Zu-ren Pan Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2000年第5期423-430,共8页
The complexation between styrene (St) and N-phenylmaleimide (PMI) was investigated by H-1-NMR spectroscopy, and the existence of a complex was proved. The equilibrium constant of St/PMI in chloroform at 50 degrees C w... The complexation between styrene (St) and N-phenylmaleimide (PMI) was investigated by H-1-NMR spectroscopy, and the existence of a complex was proved. The equilibrium constant of St/PMI in chloroform at 50 degrees C was determined to be 0.27. New elementary propagation reactions were proposed. On the basis of the propagation elementary reactions for copolymerization with the participation of a charge-transfer complex (CTC), a method for measuring the reactivity ratios is presented. Four reactivity ratios and relative reactivities of free monomer and CTC were obtained. They are r(12) = 0.034, r(21) = 0.012, r(1C) = 0.0030, r(2C) = 0.0034, and k(1C)/k(12) = 11.34, k(2C)/k(21) = 3.42. 展开更多
关键词 charge-transfer complex COPOLYMERIZATION reactivity ratio
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Characteristics of response spectra for long-periods of main-shock recordings of the Chi-Chi earthquake 被引量:3
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作者 陈勇 俞言祥 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2007年第2期111-121,共11页
Current practice uses predictive models to extrapolate long-period response spectra based on far-field recordings in moderate and weak earthquakes. However, the spectra are not long enough and the data are often not r... Current practice uses predictive models to extrapolate long-period response spectra based on far-field recordings in moderate and weak earthquakes. However, the spectra are not long enough and the data are often not reliable, which means that the seismic design code cannot accurately define seismic design requirements for long-period structures. The near-field recordings in the main-shock of the Chi-Chi earthquake have a large signal-to-noise ratio (SNR), which makes them suitable for studying the long-period acceleration response spectrum up to 20 sec. The acceleration response spectra from 246 stations within 120 km of the causative fault are statistically analyzed in this paper. The influence of distance and site conditions on long-period response spectrum is discussed, and the shapes of the amplification spectra are compared with the standard spectra specified in the seismic design code of China. Finally, suggestions for future revisions to the code are proposed. 展开更多
关键词 long-period main-shock recordings Chi-Chi earthquake signal-to-noise ratio acceleration response spectrum amplification spectrum
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Effect of Radial Porosity Oscillation on the Thermal Performance of Packed Bed Latent Heat Storage 被引量:5
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作者 H.B.Liu C.Y.Zhao 《Engineering》 SCIE EI 2021年第4期515-525,共11页
Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing... Owing to its high heat storage capacity and fast heat transfer rate,packed bed latent heat storage(LHS)is considered as a promising method to store thermal energy.In a packed bed,the wall effect can impact the packing arrangement of phase change material(PCM)capsules,inducing radial porosity oscillation.In this study,an actual-arrangement-based three-dimensional packed bed LHS model was built to consider the radial porosity oscillation.Its fluid flow and heat transfer were analyzed.With different cylindrical sub-surfaces intercepted along the radial direction in the packed bed,the corresponding relationships between the arrangement of capsules and porosity oscillation were identified.The oscillating distribution of radial porosity led to a non-uniform distribution of heat transfer fluid(HTF)velocity.As a result,radial temperature distributions and liquid fraction distributions of PCMs were further affected.The effects of different dimensionless parameters(e.g.,tube-to-capsule diameter ratio,Reynolds number,and Stefan number)on the radial characteristics of HTF and PCMs were discussed.The results showed that different diameter ratios correspond to different radial porosity distributions.Further,with an increase in diameter ratio,HTF velocity varies significantly in the near wall region while the non-uniformity of HTF velocity in the center region will decrease.The Reynolds and Stefan numbers slightly impact the relative velocity distribution of the HTF-while higher Reynolds numbers can lead to a proportional improvement of velocity,an increase in Stefan number can promote heat storage of the packed bed LHS system. 展开更多
关键词 Packed bed latent heat storage Radial porosity oscillation Fluid flow Heat transfer Diameter ratio
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Proton acceleration from picosecond-laser interaction with a hydrocarbon target
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作者 杨宇晨 黄太武 +2 位作者 蒋轲 郁明阳 周沧涛 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第2期77-85,共9页
As an intense picosecond laser pulse irradiates a hydrocarbon target,the protons therein can be accelerated by the radiation pressure as well as the sheath field behind the target.We investigate the effect of the lase... As an intense picosecond laser pulse irradiates a hydrocarbon target,the protons therein can be accelerated by the radiation pressure as well as the sheath field behind the target.We investigate the effect of the laser and hydrocarbon target parameters on proton acceleration with two/threedimensional particle-in-cell simulations.It is found that the resulting two-ion species plasma can generate a multiple peaked charge-separation field that accelerates the protons.In particular,a smaller carbon-to-hydrogen ratio,as well as the thinner and/or lower density of the target,leads to a larger sheath field and thus proton beams with a larger cutoff energy and smoother energy spectrum.These results may be useful in achieving high-flux quasi-monoenergetic proton beams by properly designing the hydrocarbon target. 展开更多
关键词 picosecond laser pulse proton acceleration multiple peaked charge-separation field carbon-to-hydrogen ratio
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Design space exploration of neural network accelerator based on transfer learning
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作者 吴豫章 ZHI Tian +1 位作者 SONG Xinkai LI Xi 《High Technology Letters》 EI CAS 2023年第4期416-426,共11页
With the increasing demand of computational power in artificial intelligence(AI)algorithms,dedicated accelerators have become a necessity.However,the complexity of hardware architectures,vast design search space,and c... With the increasing demand of computational power in artificial intelligence(AI)algorithms,dedicated accelerators have become a necessity.However,the complexity of hardware architectures,vast design search space,and complex tasks of accelerators have posed significant challenges.Tra-ditional search methods can become prohibitively slow if the search space continues to be expanded.A design space exploration(DSE)method is proposed based on transfer learning,which reduces the time for repeated training and uses multi-task models for different tasks on the same processor.The proposed method accurately predicts the latency and energy consumption associated with neural net-work accelerator design parameters,enabling faster identification of optimal outcomes compared with traditional methods.And compared with other DSE methods by using multilayer perceptron(MLP),the required training time is shorter.Comparative experiments with other methods demonstrate that the proposed method improves the efficiency of DSE without compromising the accuracy of the re-sults. 展开更多
关键词 design space exploration(DSE) transfer learning neural network accelerator multi-task learning
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Road identification method based on angular acceleration of vehicle driving wheel
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作者 李福庆 刘昭度 《Journal of Beijing Institute of Technology》 EI CAS 2012年第4期466-471,共6页
The fundamental principle of road identification by using angular acceleration of driving wheels was demonstrated in this paper. Based on the analysis of energy conversion and parameters variation during the vehicle d... The fundamental principle of road identification by using angular acceleration of driving wheels was demonstrated in this paper. Based on the analysis of energy conversion and parameters variation during the vehicle drive slip process, the change of adhesion coefficient relative to the an- gular acceleration were theoretically studied experimentally validated. The variation shows that the change of adhesion coefficient relative to the angular acceleration and the change of slip ratio in the drive slip process have same trend-both of them exist an only optimal angular acceleration corre- sponding to the peak value of adhesion coefficient. The peak adhesion coefficient of the prototype vehicle is about 0. 14 on the ice-covered road surfaces, with the corresponding optimal angular accel- eration of about 23.5 rad/s2 and optimal slip ratio of about 9. 4%. 展开更多
关键词 road surface identification adhesion coefficient angular acceleration slip ratio
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Optimal allocation method of electric/air braking force of high-speed train considering axle load transfer
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作者 Feng Guo Jing He 《High-Speed Railway》 2024年第2期77-84,共8页
Reasonable distribution of braking force is a factor for a smooth,safe,and comfortable braking of trains.A dynamic optimal allocation strategy of electric-air braking force is proposed in this paper to solve the probl... Reasonable distribution of braking force is a factor for a smooth,safe,and comfortable braking of trains.A dynamic optimal allocation strategy of electric-air braking force is proposed in this paper to solve the problem of the lack of consideration of adhesion difference of train wheelsets in the existing high-speed train electric-air braking force optimal allocation strategies.In this method,the braking strategy gives priority to the use of electric braking force.The force model of a single train in the braking process is analyzed to calculate the change of adhesion between the wheel and rail of each wheelset after axle load transfer,and then the adhesion of the train is estimated in real time.Next,with the goal of maximizing the total adhesion utilization ratio of trailer/motor vehicles,a linear programming distribution function is constructed.The proportional coefficient of adhesion utilization ratio of each train and the application upper limit of braking force in the function is updated according to the change time point of wheelset adhesion.Finally,the braking force is dynamically allocated.The simulation results of Matlab/Simulink show that the proposed algorithm not only uses the different adhesion limits of each trailer to reduce the total amount of braking force undertaken by the motor vehicle,but also considers the adhesion difference of each wheelset.The strategy can effectively reduce the risk and time of motor vehicles during the braking process and improve the stability of the train braking. 展开更多
关键词 Braking force allocation WHEELSET Dynamicity Axle load transfer total Adhesion utilization ratio
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STUDY OF THE HEAT AND HUMIDITY TRANSFER PROCESSES BETWEEN AIR AND WATER IN THE AIR WASHER
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作者 刘刚 《Journal of China Textile University(English Edition)》 EI CAS 1997年第1期49-53,共5页
The processes of heat and humidity transfer between air and water are what to be studied mainly in the paper, we put forward some main factors which influence the processes of heat and humidity transfer in the air was... The processes of heat and humidity transfer between air and water are what to be studied mainly in the paper, we put forward some main factors which influence the processes of heat and humidity transfer in the air washer. We come to the conclusion that we can change these main factors to achieve different heat and humidity transfer processes and decide processes of heat and humidity transfer of air and water with the initial temperature of spraying water in the air washer. All these results can make things convenient for the air conditioning management. 展开更多
关键词 AIR WASHER the processes of HEAT and humidity transfer water-air ratio the initialstate of the AIR the initial temperature of SPRAYING WATER AIR CONDITIONING WATER droplet.
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Electro Dynamo Theory of Gravity (g)
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作者 Greg Poole 《Journal of High Energy Physics, Gravitation and Cosmology》 2019年第3期773-789,共17页
In this paper, flux transfer events from the Sun to the Earth are represented as an electrical frequency. The Earth’s inner core is modeled as a motor armature and the mechanical speed is calculated from the frequenc... In this paper, flux transfer events from the Sun to the Earth are represented as an electrical frequency. The Earth’s inner core is modeled as a motor armature and the mechanical speed is calculated from the frequency of flux transfer events. The speed of the inner core creates a centripetal acceleration at the center of the Earth that is much higher than ever thought possible. The synchronous speed is the speed of the electromagnetic field that orbits or rotates around the Earth. All electrical machines have a rotating electromagnetic field that establishes the synchronous speed. Gravity is a centripetal acceleration derived from the synchronous speed of the electromagnetic field. The mechanical speed is somewhat less based on slip, which ranges from 1% to 10% for the electrical machine we call Earth. Flux transfer event from the Sun to the Earth is what powers the machine. By adjusting for the altitude distance, from the inner core to the surface of the Earth, a value of 9.806 m/s2 is calculated. The very nature of gravity has been discovered and explained using electrical equations and classical physics. There are only three forces of nature: electromagnetic, strong nuclear and weak nuclear. 展开更多
关键词 CENTRIPETAL acceleration DYNAMO Flux Transfer Event GRAVITY (g) GYROSCOPE SYNCHRONOUS Speed
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Elucidation of Acceleration Mechanisms by a Photosensitive Onium Salt for Nitroxide-Mediated Photocontrolled/Living Radical Polymerization
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作者 Eri Yoshida 《Open Journal of Polymer Chemistry》 2014年第3期47-55,共9页
The acceleration mechanisms by a photosensitive onium salt for the nitroxide-mediated photocontrolled/living radical polymerization (photo-NMP) were determined. The photo-NMP of methyl methacrylate was performed by ir... The acceleration mechanisms by a photosensitive onium salt for the nitroxide-mediated photocontrolled/living radical polymerization (photo-NMP) were determined. The photo-NMP of methyl methacrylate was performed by irradiation at room temperature using 4-methoxy-2,2,6,6-tetramethylpiperidine-1-oxyl (MTEMPO) as the mediator and (2RS, 2’RS)-azobis(4-methoxy-2,4-dimethylvaleronitrile) as the initiator. The polymerization was accelerated in the presence of (4-tertbutylphenyl)diphenylsulfonium triflate (tBuS) to produce a polymer with a molecular weight distribution as narrow as the polymerization in its absence. (±)-Camphor-10-sulfonic acid or 2-fluoro-1-methylpyridinium p-toluenesulfonate had no effect on the polymerization speed, suggesting that tBuS did not serve as the photo-acid generator for the photo-NMP. It was found that the acceleration of the polymerization was based on the electron transfer from MTEMPO into tBuS in the excited state to temporarily generate a free radical propagating chain end and an oxoaminium salt (OAS), the one-electron oxidant of MTEMPO. This electron transfer mechanism was verified on the basis of the fact that the photo-NMP in the presence of tBuS was still accelerated by triphenylamine, the electron transfer inhibitor, to partly produce a polymer with an uncontrolled molecular weight. The formation of an uncontrolled molecular weight polymer indicated the generation of a free radical propagating chain end due to the deactivation of the OAS by the triphenylamine. It was deduced that tBuS served as the electron acceptor from MTEMPO in the excited state to temporarily produce a free radical propagating chain end along with OAS, resulting in the acceleration of the polymerization. 展开更多
关键词 Photocontrolled/Living Radical Polymerization acceleration MECHANISMS Electron Transfer (4-tert-Butylphenyl)Diphenylsulfonium TRIFLATE 4-Methoxy-2 2 6 6-Tetramethylpiperidine-1-Oxyl Oxoaminium Salt
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Theory of Electromagnetism and Gravity —Modeling Earth as a Rotating Solenoid Coil
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作者 Greg Poole 《Journal of High Energy Physics, Gravitation and Cosmology》 2017年第4期663-692,共30页
Presented in this manuscript are conventional electrical engineering tools to model the earth as a rotating electrical machine. Calculations using known parameters of the earth and measured field data has resulted in ... Presented in this manuscript are conventional electrical engineering tools to model the earth as a rotating electrical machine. Calculations using known parameters of the earth and measured field data has resulted in new understanding of the earth’s electrical system and gyroscopic rotation. The material makeup of the inner earth is better understood based on derived permeability and permittivity constants. The planet has been modeled as simple coils and then as a parallel impedance circuit which has led to fundamental insight into planetary speed control and RLC combination for Schumann Resonance of 7.83 Hz. Torque and Voltage Constants and the inverse Speed Constant are calculated using three methods and all compare favorably with Newton’s Gravitational Constant. A helical resonator is referenced and Schumann’s Resonant ideal frequency is calculated and compared with others idealism. A new theory of gravity based on particle velocity selector at the poles is postulated. Two equations are presented as the needed links between Faraday’s electromagnetism and Newtonian physics. Acceleration and Deceleration of earth is explained as a centripetal governor. A new equation for planetary attraction and the attraction of atomic matter is theorized. Rotation of the earth’s electrical coil is explained in terms of the Richardson effect. Electric power transfer from the sun to the planets is proposed via Flux Transfer Events. The impact of this evolving science of electromagnetic modeling of planets will be magnified as the theory is proven, and found to be useful for future generations of engineers and scientists who seek to discover our world and other planets. 展开更多
关键词 Ampere Biot-Savart CENTRIPETAL acceleration CENTRIPETAL GOVERNOR Dynamo EARTH Einstein-de Haas Effect Electric Field Electromagnetism Flux Transfer Events GOVERNOR Control GRAVITY Gravitational CONSTANT Helical Resonator Lenz Law Lorentz Lightning Magnetic Field Motor CONSTANT Parallel Impedance Planet SPEED Control Schumann Resonance Richardson Effect Solenoid SPEED CONSTANT Solar Power System Torque CONSTANT Velocity Selector Voltage CONSTANT
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Site response in the Qionghai Basin in the Wenchuan earthquake 被引量:3
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作者 Wang Haiyun Xie Lili +1 位作者 Wang Suyang Ye Peng 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2013年第2期195-199,共5页
Amplification effects of soil site response can significantly impact ground motions, and must be considered in the seismic fortification of buildings/structures to prevent or mitigate this potential seismic hazard. Ut... Amplification effects of soil site response can significantly impact ground motions, and must be considered in the seismic fortification of buildings/structures to prevent or mitigate this potential seismic hazard. Utilizing acceleration time histories from the main shock of the Wenchuan earthquake recorded at four stations (i.e., one on bedrock and three on soil) in the Qionghai Basin, the site responses from three soil sites are studied by using the traditional spectral ratio method. The bedrock site is selected as a reference site. This study found that peak ground accelerations (PGAs) on the soil sites are much larger than on bedrock, with EW, NS and UD components of 3.96-6.58, 6.27-10.98, and 3.17-6.66 times those of the bedrock site, respectively. The amplification effects of the soil sites on ground motions in the frequency range of 0.1 Hz to 10 Hz are significant, depending on the thickness of the soil layer and the frequency content of the site. A significant amplification occurs with high frequency components of ground motion at shallow soil sites, and low and high frequency components of ground motion at intermediate soil sites. 展开更多
关键词 site response traditional spectral ratio method acceleration time history Qionghai Basin Wenchuan earthquake
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