Thermal maturation and petroleum generation modeling of shales is essential for suc- cessful exploration and exploitation of conventional and unconventional oil and gas plays. For basin- wide unconventional resource p...Thermal maturation and petroleum generation modeling of shales is essential for suc- cessful exploration and exploitation of conventional and unconventional oil and gas plays. For basin- wide unconventional resource plays such modeling, when well calibrated with direct maturity meas- urements from wells, can characterize and locate production sweet spots for oil, wet gas and dry gas. The transformation of kerogen to petroleum is associated with many chemical reactions, but models typically focus on first-order reactions with rates determined by the Arrhenius Equation. A miscon- ception has been perpetuated for many years that accurate thermal maturity modeling of vitrinite re- flectance using the Arrhenius Equation and a single activation energy, to derive a time-temperature index （~TTIARa）, as proposed by Wood （1988）, is flawed. This claim was initially made by Sweeney and Burnham （1990） in promoting their ＂EasyRo＂ method, and repeated by others. This paper dem- onstrates through detailed multi-dimensional burial and thermal modeling and direct comparison of the ~TTIARR and ＂EasyRo＂ methods that this is not the case. The ~TTIA^R method not only provides a very useful and sensitive maturity index, it can reproduce the calculated vitrinite reflectance values derived from models based on multiple activation energies （e.g., ＂EasyRo＂）. Through simple expres- sions the ~TTIAaa method can also provide oil and gas transformation factors that can be flexibly scaled and calibrated to match the oil, wet gas and dry gas generation windows. This is achieved in a more-computationally-efficient, flexible and transparent way by the ~TTIARR method than the ＂EasyRo＂ method. Analysis indicates that the ＂EasyRo＂ method, using twenty activation energies and a constant frequency factor, generates reaction rates and transformation factors that do not realisti- cally model observed kerogen behaviour and transformation factors over geologic time scales.展开更多
Network Security Situation Awareness System YHSAS acquires,understands and displays the security factors which cause changes of network situation,and predicts the future development trend of these security factors.YHS...Network Security Situation Awareness System YHSAS acquires,understands and displays the security factors which cause changes of network situation,and predicts the future development trend of these security factors.YHSAS is developed for national backbone network,large network operators,large enterprises and other large-scale network.This paper describes its architecture and key technologies:Network Security Oriented Total Factor Information Collection and High-Dimensional Vector Space Analysis,Knowledge Representation and Management of Super Large-Scale Network Security,Multi-Level,Multi-Granularity and Multi-Dimensional Network Security Index Construction Method,Multi-Mode and Multi-Granularity Network Security Situation Prediction Technology,and so on.The performance tests show that YHSAS has high real-time performance and accuracy in security situation analysis and trend prediction.The system meets the demands of analysis and prediction for large-scale network security situation.展开更多
文摘Thermal maturation and petroleum generation modeling of shales is essential for suc- cessful exploration and exploitation of conventional and unconventional oil and gas plays. For basin- wide unconventional resource plays such modeling, when well calibrated with direct maturity meas- urements from wells, can characterize and locate production sweet spots for oil, wet gas and dry gas. The transformation of kerogen to petroleum is associated with many chemical reactions, but models typically focus on first-order reactions with rates determined by the Arrhenius Equation. A miscon- ception has been perpetuated for many years that accurate thermal maturity modeling of vitrinite re- flectance using the Arrhenius Equation and a single activation energy, to derive a time-temperature index （~TTIARa）, as proposed by Wood （1988）, is flawed. This claim was initially made by Sweeney and Burnham （1990） in promoting their ＂EasyRo＂ method, and repeated by others. This paper dem- onstrates through detailed multi-dimensional burial and thermal modeling and direct comparison of the ~TTIARR and ＂EasyRo＂ methods that this is not the case. The ~TTIA^R method not only provides a very useful and sensitive maturity index, it can reproduce the calculated vitrinite reflectance values derived from models based on multiple activation energies （e.g., ＂EasyRo＂）. Through simple expres- sions the ~TTIAaa method can also provide oil and gas transformation factors that can be flexibly scaled and calibrated to match the oil, wet gas and dry gas generation windows. This is achieved in a more-computationally-efficient, flexible and transparent way by the ~TTIARR method than the ＂EasyRo＂ method. Analysis indicates that the ＂EasyRo＂ method, using twenty activation energies and a constant frequency factor, generates reaction rates and transformation factors that do not realisti- cally model observed kerogen behaviour and transformation factors over geologic time scales.
基金This work is funded by the National Natural Science Foundation of China under Grant U1636215the National key research and development plan under Grant Nos.2018YFB0803504,2016YFB0800303.
文摘Network Security Situation Awareness System YHSAS acquires,understands and displays the security factors which cause changes of network situation,and predicts the future development trend of these security factors.YHSAS is developed for national backbone network,large network operators,large enterprises and other large-scale network.This paper describes its architecture and key technologies:Network Security Oriented Total Factor Information Collection and High-Dimensional Vector Space Analysis,Knowledge Representation and Management of Super Large-Scale Network Security,Multi-Level,Multi-Granularity and Multi-Dimensional Network Security Index Construction Method,Multi-Mode and Multi-Granularity Network Security Situation Prediction Technology,and so on.The performance tests show that YHSAS has high real-time performance and accuracy in security situation analysis and trend prediction.The system meets the demands of analysis and prediction for large-scale network security situation.
