Thermal modification of brittle CoFeNi_(2)(Ti_(3)Si_(5))_(0.16) eutectic high-entropy alloy by annealing treatment

Adopting the idea of thermal modification of conventional Si-containing eutectic alloys,this study performed heating of the brittle CoFeNi_(2)(Ti_(3)Si_(5))_(0.16) eutectic high-entropy alloy under various annealing conditions to attempt the fragmentation and spheroidization of eutectic microstructure and improve fracture plasticity.Results reveal that the as-cast alloy exhibited fine eutectic microstructures with lamellar+network morphologies,consisting of face-centered cubic(FCC)and M_(16)Ti_(6)Si_(7)-type silicide.After annealing at 1100℃×120 h,the lamellar+network eutectic morphologies were effectively fragmented and spheroidized into granular+irregular morphologies.The resulting alloy featured excellent mechanical properties with an ultimate compressive strength(UCS)of 1980±50 MPa,fracture plasticity of~16.6%±1%,and hardness of~448±15 HV.Compared with the as-cast specimen,the fracture plasticity of the specimen annealed for 120 h increased by 12.7 times,with no UCS reduction.With a further increase in the annealing time,the hard M_(16)Ti_(6)Si_(7)-type silicide was seriously coarsened,deteriorating the alloy’s room-temperature mechanical properties but improving its high-temperature ones.

Chromium adsorption on surface activated biochar made from tannery liming sludge:A waste-to-wealth approach

In a beamhouse,liming plays a key role in the removal of hair/wool and epidermis,but problems are created when waste liming sludge is discharged to the environment.The treatment of tannery wastewater is another major challenge to the industry.In this study,thermally-activated biochars derived from liming sludge were studied for their effective adsorption of chromium(Cr)from the tannery wastewater.The thermally activated biochars(B500,B550,B600,and B650)were prepared at different temperatures from the liming sludge.Their characteristics before and after the treatment were investigated using Fourier transform infrared spectroscopy,energy dispersive X-ray spectroscopy,Bru-nauer-Emmett-Teller,and scanning electron microscopy analyses.The related functional groups(C-H,O-H,C-N,and=C-O)and chromium adsorption capacity were determined according to the surface morphology,element contents(C,O,Ca,Na,Al,Mg,and Si),surface area(5.8-9.2 m^(2)/g),pore size(5.22-5.53 nm),and particle size(652-1034 nm)of the experimental biochars.The biochar originated at 600°C from the tannery liming sludge(B600)had a greater surface area with a chromium adsorption capacity of 99.8%in comparison to B500,B550,and B650 biochars.This study developed an innovative way of utilizing liming sludge waste to minimize the pollution load and wastewater treatment cost in the tannery industry.

Solutions of the modification heating conduction equations of a kind of laser thermal effect

This paper has solved the Chester modified heat conduction equation of the different relaxation time r value under different temperature conditions, different boundary conditions and the different initial conditions by different means of methods. These solutions can help to obtain temperature field of laser thermal effects.

Phosphate removal from domestic wastewater using thermally modified steel slag

This study was performed to investigate the removal of phosphate from domestic wastewater using a modified steel slag as the adsorbent. The adsorption effects of alkalinity, salt, water,and thermal modification were investigated. The results showed that thermal activation at 800℃ for 1 hr was the optimum operation to improve the adsorption capacity. The adsorption process of the thermally modified slag was well described by the Elovich kinetic model and the Langmuir isotherm model. The maximum adsorption capacity calculated from the Langmuir model reached 13.62 mg/g. Scanning electron microscopy indicated that the surface of the modified slag was cracked and that the texture became loose after heating. The surface area and pore volume did not change after thermal modification. In the treatment of domestic wastewater, the modified slag bed（35.5 kg） removed phosphate effectively and operated for 158 days until the effluent P rose above the limit concentration of 0.5 mg/L. The phosphate fractionation method, which is often applied in soil research, was used to analyze the phosphate adsorption behavior in the slag bed. The analysis revealed that the total contents of various Ca-P forms accounted for 81.4%-91.1%, i.e., Ca10-P 50.6%-65.1%, Ca8-P 17.8%-25.0%,and Ca2-P 4.66%-9.20%. The forms of Al-P, Fe-P, and O-P accounted for only 8.9%-18.6%. The formation of Ca10-P precipitates was considered to be the main mechanism of phosphate removal in the thermally modified slag bed.