Diffusion couples,WC/Co-1at.%C,V8C7/Co,and WC/Co-0.3wt.%V8C7 were constructed and annealed at temperatures ranging from 1100 to 1300℃. The concentration profile of V and W atoms in these couples were measured by EPMA...Diffusion couples,WC/Co-1at.%C,V8C7/Co,and WC/Co-0.3wt.%V8C7 were constructed and annealed at temperatures ranging from 1100 to 1300℃. The concentration profile of V and W atoms in these couples were measured by EPMA. Aided by Thermo-calc & DICTRA software package,the concentration profiles of W and V in established diffusion couples were calculated by the moving boundary model according to revised dynamic parameters and MOB database,respectively. Then the concentration profile of W in Co binder during sintering WC-Co cemented carbide was simulated by the Cell model. It can provide reference for composition and sintering process design of cemented carbides with high performance. Meanwhile,the validity of revised dynamic parameters of the W-C-Co-V system is verified by the comparison of experimental and simulated results.展开更多
AISI H13 hot work tool steel is widely used for hot forging, hot-extrusion and die-casting because of its high temperature strength, impact toughness, heat checking resistance and wear resistance, etc. The thermally i...AISI H13 hot work tool steel is widely used for hot forging, hot-extrusion and die-casting because of its high temperature strength, impact toughness, heat checking resistance and wear resistance, etc. The thermally induced surface damage, i. e., thermal fatigne,is believed to be controlled by the magnitude of the imposed cyclic strain. The thermal fatigue on the surface of hot working die, which is responsible to the initiation of the cracks, is reported to result in more than 80 % of the failure of dies.展开更多
Thermo-Calc software package (TCP+DICTRA) was used to simulate the carbide transformation process in die steel for plastic. Combined with TEM analysis, the calculated result confirms that the carbide in equilibrium st...Thermo-Calc software package (TCP+DICTRA) was used to simulate the carbide transformation process in die steel for plastic. Combined with TEM analysis, the calculated result confirms that the carbide in equilibrium state is M_7C_3 carbide. The dissolution of M_7C_3 carbide in steel is predicted by DICTRA program. It was shown that the temperature remarkably affects the dissolution process of M_7C_3 carbide, but the influence of alloy elements such as manganese and molybdenum can be neglected in this steel.展开更多
基金the National Natural Science Foundation of China (No. 50471101)the Flan-ders-China Bilateral Project BIL 02/04.
文摘Diffusion couples,WC/Co-1at.%C,V8C7/Co,and WC/Co-0.3wt.%V8C7 were constructed and annealed at temperatures ranging from 1100 to 1300℃. The concentration profile of V and W atoms in these couples were measured by EPMA. Aided by Thermo-calc & DICTRA software package,the concentration profiles of W and V in established diffusion couples were calculated by the moving boundary model according to revised dynamic parameters and MOB database,respectively. Then the concentration profile of W in Co binder during sintering WC-Co cemented carbide was simulated by the Cell model. It can provide reference for composition and sintering process design of cemented carbides with high performance. Meanwhile,the validity of revised dynamic parameters of the W-C-Co-V system is verified by the comparison of experimental and simulated results.
文摘AISI H13 hot work tool steel is widely used for hot forging, hot-extrusion and die-casting because of its high temperature strength, impact toughness, heat checking resistance and wear resistance, etc. The thermally induced surface damage, i. e., thermal fatigne,is believed to be controlled by the magnitude of the imposed cyclic strain. The thermal fatigue on the surface of hot working die, which is responsible to the initiation of the cracks, is reported to result in more than 80 % of the failure of dies.
文摘Thermo-Calc software package (TCP+DICTRA) was used to simulate the carbide transformation process in die steel for plastic. Combined with TEM analysis, the calculated result confirms that the carbide in equilibrium state is M_7C_3 carbide. The dissolution of M_7C_3 carbide in steel is predicted by DICTRA program. It was shown that the temperature remarkably affects the dissolution process of M_7C_3 carbide, but the influence of alloy elements such as manganese and molybdenum can be neglected in this steel.