Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ～ 7 6 2 K and 0 . 0 3 ～ 0 . 1 4 MPa . The results suggested that theEuAl_3...Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ～ 7 6 2 K and 0 . 0 3 ～ 0 . 1 4 MPa . The results suggested that theEuAl_3Cl_(12(g)) complex was the predormnant species. The equilibrium constants of the reaction were measured. The reaction enthalpy and entropy derived from the measurements were and展开更多
文摘Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ～ 7 6 2 K and 0 . 0 3 ～ 0 . 1 4 MPa . The results suggested that theEuAl_3Cl_(12(g)) complex was the predormnant species. The equilibrium constants of the reaction were measured. The reaction enthalpy and entropy derived from the measurements were and
