Thermoelectric devices are one of the technologies used either to generate electricity by applying a temperature difference using thermal energy or as a heating/cooling system by applying an electrical voltage.The num...Thermoelectric devices are one of the technologies used either to generate electricity by applying a temperature difference using thermal energy or as a heating/cooling system by applying an electrical voltage.The number of materials required to produce a product is an important factor in determining its price.Production costs associated with these materials,as well as their availability and quality,play a crucial role in price determination by manufacturers.In this context,a method that employs a uniform volume distribution was implemented.This approach enabled the analysis to focus on other variables,thereby promoting a more precise and relevant evaluation of overall performance.Based on the finite element method,this study investigated the influence of geometric shape,including Rect-leg,Y-leg,Pin-leg and X-leg designs,on the performance of solar thermoelectric generators and thermoelectric coolers.The study was conducted considering the same hot alumina junction surface that receives solar radiation;however,the ef-fective surface,which corresponded to the heat flow area and had a similar area near the exposed surface,varied depending on the chosen leg geometry,thus impacting the heat flux due to the variation in thermal resistance.In the case of a solar thermoelectric generator,the Rect-leg model,having the same effective surface area,presented the lowest heat loss value resulting from convection and radiation in the heat spreader and the hot alumina plate.Under the same conditions,the Y-leg showed the highest value.The Rect-leg design generated,by using thermal and optical concentration,the highest output power of 0.028 and 0.054 W,and efficiency of 3.47%and 4.7%,respectively,whereas the Y-leg generated lower values of 0.006523 and 0.018744 W for power,and 2.83%and 2.71%for efficiency,respectively.In the case of the thermoelectric coolers,the Y-leg generated the highest temperature difference between the hot and cold sides of 67.28 K at an electric current value of 1.8 A,whereas the Rect-leg,Pin-leg and X-leg generated~66.25,~67.02 and~67.19 K at 6.1,2.7 and 2.6 A.展开更多
Recently,the performance and fabrication of thin-ilm thermoeletric materials have been jargely enhanced.Based on this enhancement,the thin-film thermoelectric cooler(TEC)is becoming a research hot topic,due to its hig...Recently,the performance and fabrication of thin-ilm thermoeletric materials have been jargely enhanced.Based on this enhancement,the thin-film thermoelectric cooler(TEC)is becoming a research hot topic,due to its high cooling flux and microchip level size.To fulfill a thin-film TEC,interfacial problems are unavoidable,as they may largely reduce the properties of a thin-film TEC.Moreover,the architecture of a thin-film TEC should also be properly designed.In this review,we introduced the enhancement of thermoelectric properties of(Bi,Sb)2(Te,Se)3 solid solution materials by chemical vapor deposition,physical vapor deposition and electro-deposition.Then,the interfacial problems,including contact resistance,interfacial diffusion and thermal contact resistance,were discussed.Furthermore,the design,fabrication,as well as the performance of thin-film TECs were summarized.展开更多
An experimental study was carried out in this article to investigate the transient operating performance of a Dual Compensation Chamber Loop Heat Pipe(DCCLHP) with Thermoelectric Cooler(TEC) under acceleration conditi...An experimental study was carried out in this article to investigate the transient operating performance of a Dual Compensation Chamber Loop Heat Pipe(DCCLHP) with Thermoelectric Cooler(TEC) under acceleration conditions and ammonia was selected as the working fluid.For the purpose of comparison, experimental work was conducted under terrestrial gravity.Sensitivity analysis was performed to explore the effect of several control parameters such as the heat load, acceleration magnitude and TEC assist on the startup and operating performance of the DCCLHP.Experimental results indicate that the DCCLHP can get to a steady-state operation when the heat load changes from 25 W to 300 W under terrestrial gravity.While under acceleration conditions, the DCCLHP can work at a high operating temperature or even fail to operate, which shows the acceleration effect plays a significant impact on the loop operation.The TEC assist with power of 10 W can improve the operating performance and reduce the operating temperature for the case of small heat load and acceleration magnitude.When the acceleration exceeds 3 g at large heat load, the effect of TEC assist on the operation at large heat load can be ignored.展开更多
In this paper,a one-dimensional thermodynamic model was developed to evaluate the device-level performance of thermoelectric cooler(TEC)with the Thomson effect,contact resistance,gap heat leakage,heat sink,and heat lo...In this paper,a one-dimensional thermodynamic model was developed to evaluate the device-level performance of thermoelectric cooler(TEC)with the Thomson effect,contact resistance,gap heat leakage,heat sink,and heat load taken into account.The model was generalized and simplified by introducing dimensionless parameters.Experimental measurements showed good agreement with analytical results.The parametric analysis indicated that the influence of the Thomson effect on cooling capacity continued to expand with increasing current,while the effect on COP hardly changed with current.Low thermal contact resistance was beneficial to obtain lower hot-junction temperature,which can even reduce 2 K compared with the electrical contact resistance in the case study.The gap heat leakage was a negative factor affecting the cooling performance.When the thermal resistance of the heat sink was small,the negative effect of heat leakage on performance would be further enlarged.The enhancement of heat load temperature would increase the cooling power of the TEC.For example,an increase of 5 K in heat load can increase the cooling capacity by about 4%.However,once the current exceeded the optimum value,the raising effect on the cooling power would be weakened.The research can provide an analytical approach for the designer to perform trade studies to optimize the TEC system.展开更多
The thin-film thermoelectric cooler(TEC)is a promising solid-state heat pump that can remove the high local heat flux of chips utilizing the Peltier effect.When an electric current pulse is applied to the thin-film TE...The thin-film thermoelectric cooler(TEC)is a promising solid-state heat pump that can remove the high local heat flux of chips utilizing the Peltier effect.When an electric current pulse is applied to the thin-film TEC,the TEC can achieve an instantaneous lower temperature compared to that created by a steady current.In this paper,we developed a novel strategy to reduce the peak temperature of the chip working under dynamic power,thus making the semiconductor chip operate reliably and efficiently.A three-dimensional numerical model was built to study the transient cooling performance of the thin-film TEC on chips.The effects of parameters,such as the current pulse,the heat flux,the thermoelement length,the number of thermoelements,and the contact resistance on the performance of the thin-film TEC,were investigated.The results showed that when a current pulse of 0.6 A was applied to the thin-film TEC before the peak power of the chip,the peak temperature of the chip was reduced by more than 10℃,making the thin-film thermoelectric cooler a promising technology for the temperature control of modern chips with high peak powers.展开更多
With the development of 5G technology and increasing chip integration,traditional active cooling methods struggle to meet the growing thermal demands of chips.Thermoelectric coolers(TECs)have garnered great attention ...With the development of 5G technology and increasing chip integration,traditional active cooling methods struggle to meet the growing thermal demands of chips.Thermoelectric coolers(TECs)have garnered great attention due to their rapid response,significant cooling differentials,strong compatibility,high stability and controllable device dimensions.In this review,starting from the fundamental principles of thermoelectric cooling and device design,high-performance thermoelectric cooling materials are summarized,and the progress of advanced on-chip TECs is comprehensively reviewed.Finally,the paper outlines the challenges and opportunities in TEC design,performance and applications,laying great emphasis on the critical role of thermoelectric cooling in addressing the evolving thermal management requirements in the era of emerging chip technologies.展开更多
A thermodynamic model of a thermoelectric generator(TEG)-driven thermoelectric cooler(TEC) device considering Thomson effect and external heat transfer(HT) is established based on the combination of non-equilibrium an...A thermodynamic model of a thermoelectric generator(TEG)-driven thermoelectric cooler(TEC) device considering Thomson effect and external heat transfer(HT) is established based on the combination of non-equilibrium and finite time thermodynamic theories. The expressions of cooling capacity and coefficient of performance(COP) are obtained. Performances are compared with and without considering Thomson effect using numerical optimization method. The influences of Thomson effect on the optimal performances, optimum allocations of thermoelectric(TE) element number and HT surface area are discussed. The results indicate that Thomson effect decreases the maximum cooling capacity and COP. More TE elements should be allocated to TEG, and more HT area should be allocated to the heat exchanger(HEX) of TEG, the hot-side HEX of TEG and the cold-side HEX of TEC in the design of the device considering Thomson effect. The results obtained can be used to help design TEG-TEC devices.展开更多
As a promising energy conversion technology,transient thermoelectric device has potential applications in temperature control and refrigeration.The performance is sensitive to the applied current pulse.However,the con...As a promising energy conversion technology,transient thermoelectric device has potential applications in temperature control and refrigeration.The performance is sensitive to the applied current pulse.However,the conventional current pulse is limited to regular current shapes,which cannot achieve the best super-cooling performance.There exist strong coupling effects between the parameters of pulse shape,pulse amplitude,and pulse width.Simultaneous optimization of all the variables involved in a current pulse is a prerequisite to further improve the super-cooling.To bridge this gap,a constraint-free current pulse design concept was proposed in this study,which was successfully validated by a multi-objective optimization method.The results show that,the effective cooling regime and temperature overshoot both exhibit excellent features after optimization.Compared with the current t~0(mostly employed in previous studies),the betterments are improved by 88.33%and 92.13%for the effective cooling regime and the temperature overshoot,respectively.The underlying physics reveals that,the appropriate mediation between Peltier cooling,Joule heating,and Fourier conduction effects by a wave-like irregular current pulse is responsible for the improvement.The Pareto-optimal front found in the optimized current shape is beneficial for scientists and engineers to make an appropriate decision towards specific practical application.展开更多
A diode-pumped single frequcncy Tm,Ho:YLF laser operating at an eye-safe wavelength of 2 μm has been developed. Temperature of the laser crystal was controlled at room temperature with a thermoelectric cooler. The l...A diode-pumped single frequcncy Tm,Ho:YLF laser operating at an eye-safe wavelength of 2 μm has been developed. Temperature of the laser crystal was controlled at room temperature with a thermoelectric cooler. The line-width narrowing elements were two solid uncoated fused silica etalons whose thicknesses were 1 and 0.1 mm, respectively. Continuous wave single frequency power of 113 mW was obtained.展开更多
Entropy engineering has emerged as an effective strategy for improving the figure-of-merit zT by decelerating the phonon transport while maintaining good electrical transport properties of thermoelectric materials.Her...Entropy engineering has emerged as an effective strategy for improving the figure-of-merit zT by decelerating the phonon transport while maintaining good electrical transport properties of thermoelectric materials.Herein,a high average zT of 1.54 and a maximum zT of 2.1 are achieved in the mid-entropy GeTe constructed by Ag,Sb,and Pb alloying.At room temperature,the mid-entropy GeTe tends to be a cubic structure.And the power factor is improved from 7.7μW·cm^(-1)·K^(-2) to 16.2μW·cm·cm^(-1)·K^(-2) due to the large increase in effective mass and the optimized carrier concentration.The increasing disorder created by heavy and off-centering Ag,Sb,and Pb atoms induces strong mass/strain fluctuations and phonon scattering to decelerate the phonon transport in GeTe.A low lattice thermal conductivity is obtained in the medium-entropy GeTe-based material.Moreover,a GeTe-based thermoelectric cooler is fabricated with the cooling temperature difference of 66.6 K with the hot end fixed at 363 K.This work reveals the effectiveness of entropy engineering in improving the average zT in GeTe and shows potential application of GeTe as a thermoelectric cooler.展开更多
文摘Thermoelectric devices are one of the technologies used either to generate electricity by applying a temperature difference using thermal energy or as a heating/cooling system by applying an electrical voltage.The number of materials required to produce a product is an important factor in determining its price.Production costs associated with these materials,as well as their availability and quality,play a crucial role in price determination by manufacturers.In this context,a method that employs a uniform volume distribution was implemented.This approach enabled the analysis to focus on other variables,thereby promoting a more precise and relevant evaluation of overall performance.Based on the finite element method,this study investigated the influence of geometric shape,including Rect-leg,Y-leg,Pin-leg and X-leg designs,on the performance of solar thermoelectric generators and thermoelectric coolers.The study was conducted considering the same hot alumina junction surface that receives solar radiation;however,the ef-fective surface,which corresponded to the heat flow area and had a similar area near the exposed surface,varied depending on the chosen leg geometry,thus impacting the heat flux due to the variation in thermal resistance.In the case of a solar thermoelectric generator,the Rect-leg model,having the same effective surface area,presented the lowest heat loss value resulting from convection and radiation in the heat spreader and the hot alumina plate.Under the same conditions,the Y-leg showed the highest value.The Rect-leg design generated,by using thermal and optical concentration,the highest output power of 0.028 and 0.054 W,and efficiency of 3.47%and 4.7%,respectively,whereas the Y-leg generated lower values of 0.006523 and 0.018744 W for power,and 2.83%and 2.71%for efficiency,respectively.In the case of the thermoelectric coolers,the Y-leg generated the highest temperature difference between the hot and cold sides of 67.28 K at an electric current value of 1.8 A,whereas the Rect-leg,Pin-leg and X-leg generated~66.25,~67.02 and~67.19 K at 6.1,2.7 and 2.6 A.
基金supported by the State Key Program of National Natural Science Foundation of China(Grant No.61534001)the Joint Funds of the National Natural Science Foundation of China(Grant No.U1601213)+2 种基金the National Natural Science Foundation of China(Grant Nos.51601005 and 61704006)the Beijing Natural Science Foundation(Grant No.2182032)the Fundamental Research Funds for the Central Universities.
文摘Recently,the performance and fabrication of thin-ilm thermoeletric materials have been jargely enhanced.Based on this enhancement,the thin-film thermoelectric cooler(TEC)is becoming a research hot topic,due to its high cooling flux and microchip level size.To fulfill a thin-film TEC,interfacial problems are unavoidable,as they may largely reduce the properties of a thin-film TEC.Moreover,the architecture of a thin-film TEC should also be properly designed.In this review,we introduced the enhancement of thermoelectric properties of(Bi,Sb)2(Te,Se)3 solid solution materials by chemical vapor deposition,physical vapor deposition and electro-deposition.Then,the interfacial problems,including contact resistance,interfacial diffusion and thermal contact resistance,were discussed.Furthermore,the design,fabrication,as well as the performance of thin-film TECs were summarized.
基金the financial supports from the Fundamental Research Funds for the Central Universities of China(YWF-14-HKXY-019)。
文摘An experimental study was carried out in this article to investigate the transient operating performance of a Dual Compensation Chamber Loop Heat Pipe(DCCLHP) with Thermoelectric Cooler(TEC) under acceleration conditions and ammonia was selected as the working fluid.For the purpose of comparison, experimental work was conducted under terrestrial gravity.Sensitivity analysis was performed to explore the effect of several control parameters such as the heat load, acceleration magnitude and TEC assist on the startup and operating performance of the DCCLHP.Experimental results indicate that the DCCLHP can get to a steady-state operation when the heat load changes from 25 W to 300 W under terrestrial gravity.While under acceleration conditions, the DCCLHP can work at a high operating temperature or even fail to operate, which shows the acceleration effect plays a significant impact on the loop operation.The TEC assist with power of 10 W can improve the operating performance and reduce the operating temperature for the case of small heat load and acceleration magnitude.When the acceleration exceeds 3 g at large heat load, the effect of TEC assist on the operation at large heat load can be ignored.
基金financially supported by the National Natural Science Foundation of China(NSFC)(Grant No.52106032)the Science Challenge Program(Grant No.TZ2018003)+2 种基金the National Natural Science Foundation of China(Grant No.51778511)the Hubei Provincial Natural Science Foundation of China(Grant No.2018CFA029)the Key Project of ESI Discipline Development of Wuhan University of Technology(WUT Grant No.2017001)。
文摘In this paper,a one-dimensional thermodynamic model was developed to evaluate the device-level performance of thermoelectric cooler(TEC)with the Thomson effect,contact resistance,gap heat leakage,heat sink,and heat load taken into account.The model was generalized and simplified by introducing dimensionless parameters.Experimental measurements showed good agreement with analytical results.The parametric analysis indicated that the influence of the Thomson effect on cooling capacity continued to expand with increasing current,while the effect on COP hardly changed with current.Low thermal contact resistance was beneficial to obtain lower hot-junction temperature,which can even reduce 2 K compared with the electrical contact resistance in the case study.The gap heat leakage was a negative factor affecting the cooling performance.When the thermal resistance of the heat sink was small,the negative effect of heat leakage on performance would be further enlarged.The enhancement of heat load temperature would increase the cooling power of the TEC.For example,an increase of 5 K in heat load can increase the cooling capacity by about 4%.However,once the current exceeded the optimum value,the raising effect on the cooling power would be weakened.The research can provide an analytical approach for the designer to perform trade studies to optimize the TEC system.
基金the National Natural Science Foundation of China(Grant No.51778511)Natural Science Foundation of Hubei Province(Grant No.2018CFA029)+3 种基金Key Research and Design Projects of Hubei Province(Grant No.2020BAB129)Key Project of ESI Discipline Development of Wuhan University of Technology(Grant No.2017001)Scientific Research Foundation of Wuhan University of Technology(Nos.40120237 and 40120551)the Fundamental Research Funds for the Central Universities(WUT:2021IVA037)。
文摘The thin-film thermoelectric cooler(TEC)is a promising solid-state heat pump that can remove the high local heat flux of chips utilizing the Peltier effect.When an electric current pulse is applied to the thin-film TEC,the TEC can achieve an instantaneous lower temperature compared to that created by a steady current.In this paper,we developed a novel strategy to reduce the peak temperature of the chip working under dynamic power,thus making the semiconductor chip operate reliably and efficiently.A three-dimensional numerical model was built to study the transient cooling performance of the thin-film TEC on chips.The effects of parameters,such as the current pulse,the heat flux,the thermoelement length,the number of thermoelements,and the contact resistance on the performance of the thin-film TEC,were investigated.The results showed that when a current pulse of 0.6 A was applied to the thin-film TEC before the peak power of the chip,the peak temperature of the chip was reduced by more than 10℃,making the thin-film thermoelectric cooler a promising technology for the temperature control of modern chips with high peak powers.
基金supported by the National Natural Science Foundation of China(Grant No.92163211 and 52002137)the Fundamental Research Funds for the Central Universities(Grant No.2021XXJS008).
文摘With the development of 5G technology and increasing chip integration,traditional active cooling methods struggle to meet the growing thermal demands of chips.Thermoelectric coolers(TECs)have garnered great attention due to their rapid response,significant cooling differentials,strong compatibility,high stability and controllable device dimensions.In this review,starting from the fundamental principles of thermoelectric cooling and device design,high-performance thermoelectric cooling materials are summarized,and the progress of advanced on-chip TECs is comprehensively reviewed.Finally,the paper outlines the challenges and opportunities in TEC design,performance and applications,laying great emphasis on the critical role of thermoelectric cooling in addressing the evolving thermal management requirements in the era of emerging chip technologies.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51576207, and 11305266)the Natural Science Foundation of Naval University of Engineering (Greant No. 20161505)
文摘A thermodynamic model of a thermoelectric generator(TEG)-driven thermoelectric cooler(TEC) device considering Thomson effect and external heat transfer(HT) is established based on the combination of non-equilibrium and finite time thermodynamic theories. The expressions of cooling capacity and coefficient of performance(COP) are obtained. Performances are compared with and without considering Thomson effect using numerical optimization method. The influences of Thomson effect on the optimal performances, optimum allocations of thermoelectric(TE) element number and HT surface area are discussed. The results indicate that Thomson effect decreases the maximum cooling capacity and COP. More TE elements should be allocated to TEG, and more HT area should be allocated to the heat exchanger(HEX) of TEG, the hot-side HEX of TEG and the cold-side HEX of TEC in the design of the device considering Thomson effect. The results obtained can be used to help design TEG-TEC devices.
基金funded by the National Natural Science Foundation of China(No.51706067 and No.51876059)the Fundamental Research Funds for the Central Universities(No.2019MS053)。
文摘As a promising energy conversion technology,transient thermoelectric device has potential applications in temperature control and refrigeration.The performance is sensitive to the applied current pulse.However,the conventional current pulse is limited to regular current shapes,which cannot achieve the best super-cooling performance.There exist strong coupling effects between the parameters of pulse shape,pulse amplitude,and pulse width.Simultaneous optimization of all the variables involved in a current pulse is a prerequisite to further improve the super-cooling.To bridge this gap,a constraint-free current pulse design concept was proposed in this study,which was successfully validated by a multi-objective optimization method.The results show that,the effective cooling regime and temperature overshoot both exhibit excellent features after optimization.Compared with the current t~0(mostly employed in previous studies),the betterments are improved by 88.33%and 92.13%for the effective cooling regime and the temperature overshoot,respectively.The underlying physics reveals that,the appropriate mediation between Peltier cooling,Joule heating,and Fourier conduction effects by a wave-like irregular current pulse is responsible for the improvement.The Pareto-optimal front found in the optimized current shape is beneficial for scientists and engineers to make an appropriate decision towards specific practical application.
基金This work was supported by the Scientic Re-search Foundation of Harbin Engineering Univer-sity (HEUF04014)
文摘A diode-pumped single frequcncy Tm,Ho:YLF laser operating at an eye-safe wavelength of 2 μm has been developed. Temperature of the laser crystal was controlled at room temperature with a thermoelectric cooler. The line-width narrowing elements were two solid uncoated fused silica etalons whose thicknesses were 1 and 0.1 mm, respectively. Continuous wave single frequency power of 113 mW was obtained.
基金This work is supported by the National Natural Science Foundation of China(Grant No.52222209,11934007,and 52302262)the Science and Technology Innovation Committee Foundation of Shenzhen(Grant No.JCYJ20220530165000001)+2 种基金the Young Elite Scientists Sponsorship Program by CAST(Grant No.2021QNRC001)the Outstanding Talents Training Fund in Shenzhen(202108)the Natural Science Foundation of Sichuan(Grant No.2023NSFSC0953).
文摘Entropy engineering has emerged as an effective strategy for improving the figure-of-merit zT by decelerating the phonon transport while maintaining good electrical transport properties of thermoelectric materials.Herein,a high average zT of 1.54 and a maximum zT of 2.1 are achieved in the mid-entropy GeTe constructed by Ag,Sb,and Pb alloying.At room temperature,the mid-entropy GeTe tends to be a cubic structure.And the power factor is improved from 7.7μW·cm^(-1)·K^(-2) to 16.2μW·cm·cm^(-1)·K^(-2) due to the large increase in effective mass and the optimized carrier concentration.The increasing disorder created by heavy and off-centering Ag,Sb,and Pb atoms induces strong mass/strain fluctuations and phonon scattering to decelerate the phonon transport in GeTe.A low lattice thermal conductivity is obtained in the medium-entropy GeTe-based material.Moreover,a GeTe-based thermoelectric cooler is fabricated with the cooling temperature difference of 66.6 K with the hot end fixed at 363 K.This work reveals the effectiveness of entropy engineering in improving the average zT in GeTe and shows potential application of GeTe as a thermoelectric cooler.