Across two phylogeographic breaks: Quaternary evolutionary history of a mountain aspen (Populus rotundifolia) in the Hengduan Mountains

Biogeographical barriers to gene flow are central to plant phylogeography.In East Asia,plant distribution is greatly influenced by two phylogeographic breaks,the Mekong-Salween Divide and Tanaka-Kaiyong Line,however,few studies have investigated how these barriers affect the genetic diversity of species that are distributed across both.Here we used 14 microsatellite loci and four chloroplast DNA fragments to examine genetic diversity and distribution patterns of 49 populations of Populus rotundifolia,a species that spans both the Mekong-Salween Divide and the Tanaka-Kaiyong Line in southwestern China.Demographic and migration hypotheses were tested using coalescent-based approaches.Limited historical gene flow was observed between the western and eastern groups of P.rotundifolia,but substantial flow occurred across both the Mekong-Salween Divide and Tanaka-Kaiyong Line,manifesting in clear admixture and high genetic diversity in the central group.Wind-borne pollen and seeds may have facilitated the dispersal of P.rotundifolia following prevalent northwest winds in the spring.We also found that the Hengduan Mountains,where multiple genetic barriers were detected,acted on the whole as a barrier between the western and eastern groups of P.rotundifolia.Ecological niche modeling suggested that P.rotundifolia has undergone range expansion since the last glacial maximum,and demographic reconstruction indicated an earlier population expansion around 600 Ka.The phylogeographic pattern of P.rotundifolia reflects the interplay of biological traits,wind patterns,barriers,niche differentiation,and Quaternary climate history.This study emphasizes the need for multiple lines of evidence in understanding the Quaternary evolution of plants in topographically complex areas.

基于Quaternary编码的球面三角格网邻近搜索算法

分析了球面Quaternary编码的特点,给出了三角格网方向判断的规则,并对该算法与Bartholdi邻近搜索算法的时间复杂度进行了对比。结果表明,分解算法的平均时间耗时量约是Bartholdi邻近搜索算法的23.66%。

关于是否在地层系统中取消“第四纪”(Quaternary)一名词的讨论和危机

文章详细介绍了最近INUQA组织和INQUA地层与年代学委员会在“Episodes”杂志 2 0 0 4年第 2 7卷第 2期公布的新的地质时代标尺 ,并就关于“第四系”这个地层单位的重新定义问题提出了重要的见解。对于取消“第四纪”(Quaternary)一词 ,发表了意见以及不认同的观点 ,同时文章还呼吁 ,希望更多的从事第四纪研究的工作者踊跃发表意见、积极呼吁 ,使“第四纪”(Quaternary)一词正式保持不变。

Palaeoclihlatic Indicators of China's Quaternary Saline Lake Sediments and Hydrochemistry

In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.

Studies on a Cationically Modified Quaternary Ammonium Salt of Lignin

A new quaternary ammonium salt monomer was synthesized and a quaternary amination of lignin（ noted as QL）, with the monomer was carried out by grafting copolymerization. The products were characterized by Fourier Transform Infrared spectroscopy（ FTIR）. The experimental results indicate that the yield of the monomer was 99.06%, and the conversion of the monomer and the grafting yield of QL were 93.69% and 185.78%, respectively. The feasibility of QL as the flocculant to be applied in color removal of five artificial dyes, erioehrome black T（dye A）, gongo red（dye B ）, direct fast black G （dye C ）, cuprofix blue green B （dye D ）, and acid black ATT （dye E ） was examined. Results show that OL exhihits the favorable flocculation nerformance and high stability.

Stratigraphy of late Quaternary deposits in the mid-western North Yellow Sea

The North Yellow Sea(NYS) is characterized by strong land-sea interaction and paleoenvironmental changes with sea-level fluctuations during the late Quaternary. However, large-time scale depositional stratigraphy in this area and its relationship with sea-level changes remain unresolved. Highresolution seismic profiles from NYS were subdivided into eleven seismic units(U1 to U11 in descending order). A 70.6-m-long borehole(DLC70-2) from localities on seismic profiles, analyzed for lithology, microfossil assemblages and geochronology, comprises eleven sedimentary units(D1 to D11 in descending order), which were clearly correlated with the eleven seismic units. These units constitute four distinctive sequences(SQ1 to SQ4 from top to bottom) bounded by three sequence boundaries(S3, S5 and S10) with obvious depositional hiatus, correlated with sea-level lowstands of MIS2, MIS4 and MIS6, respectively. The lowermost SQ4 below S10, has been identified only upper part of transgressive systems tract(TST)(D11, tidal flat facies in early MIS6). SQ3 overlying S10 consists of a set of lowstand systems tracts(LST)(D10, fluvial to incised-channel filling facies in late MIS6), TST and highstand systems tracts(HST)(D9 to D6, interactive deposits of neritic and littoral facies in MIS5 and early MIS4). SQ2 above S5 is composed of LST(D5, channel-filling facies in late MIS4) and TST(D4, littoral to estuary facies in early-middle MIS3), but lack of HST resulting from subaerial exposure and channel incising during the Last Glacial Maximum(LGM). The uppermost SQ1 overlying S3 comprises LST(D3, channel-filling to flooding plain or marsh facies in MIS2), Holocene TST(D2, littoral and tidal sand ridge facies) and HST(D1, neritic facies). The unusual depositional stratigraphy was largely dominated by sea-level fluctuations and the Bohai Strait topography. This study confirms that TSTs are relative continuous and widely distributed, while LSTs vary considerably in thickness and lateral extent since MIS6 in NYS.

Near surface velocity and Q_s structure of the Quaternary sediment in Bohai basin,China

Heavily populated by Beijing and Tianjin cities, Bohai basin is a seismically active Cenozoic basin suffering from huge lost by devastating earthquakes, such as Tangshan earthquake. The attenuation （Qp and Qs） of the surficial Quaternary sediment has not been studied at natural seismic frequency （1-10 Hz）, which is crucial to earthquake hazards study. Borehole seismic records of micro earthquake provide us a good way to study the velocity and attenuation of the surficial structure （0-500 m）. We found that there are two pulses well separated with simple waveforms on borehole seismic records from the 2006 Mw4.9 Wen＇an earthquake sequence. Then we performed waveform modeling with generalized ray theory （GRT） to confirm that the two pulses are direct wave and surface reflected wave, and found that the average vp and Vs of the top 300 m in this region are about 1.8 km/s and 0.42 km/s, leading to high ve/vs ratio of 4.3. We also modeled surface refleeted wave with propagating matrix method to constrain Qs and the near surface velocity structure. Our modeling indicates that Qs is at least 30, or probably up to 100, much larger than the typically assumed extremely low Q（-10）, but consistent with Qs modeling in Mississippi embayment. Also, the velocity gradient just beneath the free surface （0-50 m） is very large and velocity increases gradually at larger depth. Our modeling demonstrates the importance of borebole seismic records in resolving shallow velocity and attenuation structure, and hence may help in earthquake hazard simulation.

Quaternary Lake Deposits of Nam Co, Tibet, with a Discussion of the Connection of Nam Co with Ring Co-Jiuru Co

Shorelines are widespread and lake deposits and lake geomorphology are welldeveloped on the northern Tibetan Plateau. Through field observations of lacustrine deposits of NamCo-the highest and largest Quaternary lake in Tibet, the authors found four-step shore terracescomposed of sands and clays with well-developed horizontal bedding and 3-12 m, 15-22 m, 25-30 m and35-45 m higher than the lake surface respectively, lacustrine deposits resting on the bedrocks and60-150 m higher than the lake surface, and up to approx 50 levees composed of oblate lakeshoregravels. Moreover they found lacustrine and lakeshore deposits making up the terraces and levees onthe bottoms of wide dividing valleys connecting Nam Co with the Rencoyuema, Rencogongma and Jiuru Conorthwest of Nam Co (the valley bottoms are 20 m, 90 m and 60 m higher than the above-mentionedthree lakes) and on slopes north of it, i.e. terraces II and III of Nam Co. Thus they confirm thatNam Co and Ring Co-Jiuru Co had connected with each other several times, i.e. formed a unified largelake several times, rather than had been different lakes connected only by river channels. Fromindications such as the distribution of the highest shoreline and lake deposits and geomorphology,the authors conclude that the total area of the old large lakes on the northern Tibetan Plateau is afew times larger than that of the modern lakes and that the last-stage old large lakes formed inthe interglacial interval of the last glaciation.

Synthesis and Characterization of Quaternary Complex of Sm-CH_3C(CH_2OH)_2COOH-Phen

A new quaternary complex with 2,2-dihydroxymethyl propionic acid and 1,10-phenanthroline, Sm(CH3C(CH2OH)2COO)(NO3)2(phen), was synthesized in ethanol solution and characterized by elemental analysis, IR and solid-state 13C NMR. The result of molar electrolytic conductivity of the complex indicates that it is non-electrolyte. Solution and thermal properties of the complex further verifies that the complex and ligant are different. In addition, the analytical results also imply that the two hydroxyl groups of 2,2-dihydroxymethyl propionic acid are not involved in the coordinate reaction. This will provide a new way for producing new multifunctional polymer materials with excellent fluorescent property. The fluorescence spectra of the complex were also studied. The main fluorescence emission peak of the complex appeared at 555, 604 and 646 nm. These fluorescent emission peaks correspond to transitions from 4G5/2 to 6H5/2, 6H7/2 and 6H9/2 energy levels of samarium(Ⅲ) ion, respectively. The most intense peak is at 646 nm, which lies in the range of absorption wavelength of chlorophyll a and chlorophyll b (600～680 nm), and it is beneficial to the crops to grow up.

Discovery and Significance of Quaternary Glacial Vestiges in the Hexigten Area of the Southern Da Hinggan Mountains, Inner Mongolia

The question whether there have been Quaternary glaciations in the Da Hinggan area has puzzled glacial geologists for many years because no sufficient glacial evidence has been found in this area. The study of Quaternary glaciers in the Da Hinggan area is also a key issue of the glaciology in China because of the special location of this area. In the past two years, a large number of complete and typical glacial vestiges have been found in Hexigten in the southern Da Hinggan Mountains, such as fossil cirque groups, horns, knife-edge crests, terminal moraines, glacial stepped stones. These landforms are located at a watershed, which are thus impossible to be formed due to tectonic processes, water or weathering, but can only be formed by glaciation. The calculated flat indexes of the fossil cirques in the Hexigten are 1.7-4.5, 4-5 and 1.3-5, which are within the range of 1.7-5 that is the flat index of real cirques. The typical and complete moraines have also been found in this area. All these glacial vestiges prove that the Quaternary glaciers did exist in the Da Hinggan Mountains of eastern China. Thus, it is of important scientific significance for the research on Chinese, even the global climatic and environmental evolution since the Quaternary.

Paleoenvironmental changes during the late Quaternary as inferred from foraminifera assemblages in the Laizhou Bay

Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C（AMS14C） and optically stimulated luminescence（OSL） ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of marine isotopic stage 7（MIS7）, the last interglacial period（MIS5） and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the foraminifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.

Effects of quaternary ammonium chain length on the antibacterial and remineralizing effects of a calcium phosphate nanocomposite

Composites containing nanoparticles of amorphous calcium phosphate （NACP） remineralize tooth lesions and inhibit caries. A recent study synthesized quaternary ammonium methacrylates （QAMs） with chain lengths （CLs） of 3-18 and determined their effects on a bonding agent. This study aimed to incorporate these QAMs into NACP nanocomposites for the first time to simultaneously endow the material with antibacterial and remineralizing capabilities and to investigate the effects of the CL on the mechanical and biofilm properties. Five QAMs were synthesized： DMAPM （CL3）, DMAHM （CL6）, DMADDM （CL12）, DMAHDM （CL16）, and DMAODM （CL18）. Each QAM was incorporated into a composite containing 20% NACP and 50% glass fillers. A dental plaque microcosm biofilm model was used to evaluate the antibacterial activity. The flexural strength and elastic modulus of nanocomposites with QAMs matched those of a commercial control composite （n = 6; P 〉 0.1）. Increasing the CL from 3 to 16 greatly enhanced the antibacterial activity of the NACP nanocomposite （P 〈 0.05）; further increasing the CL to 18 decreased the antibacterial potency. The NACP nanocomposite with a CL of 16 exhibited biofilm metabolic activity and acid production that were 10-fold lesser than those of the control composite. The NACP nanocomposite with a CL of 16 produced 2-log decreases in the colony-forming units （CFU） of total microorganisms, total streptococci, and mutans streptococci. In conclusion, QAMs with CLs of 3-18 were synthesized and incorporated into an NACP nanocomposite for the first time to simultaneously endow the material with antibacterial and remineralization capabilities. Increasing the C/reduced the metabolic activity and acid production of biofilms and caused a 2-log decrease in CFU without compromising the mechanical properties. Nanocomposites exhibiting strong anti-biofilm activity, remineralization effects, and mechanical properties are promising materials for tooth restorations that inhibit caries.

Revisiting Late Quaternary Slip-rate along the Maqu Segment of the Eastern Kunlun Fault, Northeast Tibet

The Late Quaternary slip rate along the Maqu segment of the eastern Kunlun Fault was estimated using a combination of high-resolution remote sensing imagery interpretation, field observations and differential Global Positioning System（GPS） measurements of offset river terraces, and 14 C dating of snail shells collected from offset risers. The results show that the left-slip rate along the segment is 3–5 mm/a, and that the vertical slip rate is 0.3–0.5 mm/a. Both the horizontal and vertical slips on the segment remain consistent over a distance of ~100 km. It means that no slip gradient as previously suggested occurred along the Maqu segment, and which thus might behave as an independent seismogenic fault. Judging from multiple relationships among young terrace offsets, we infer that co-seismic surface rupture produced by a characteristic earthquake with a magnitude of Ms7.0–7.5 on the Maqu fault could generate a horizontal slip of 4.5–5 m and a vertical slip of 0.45–0.5 m, with a corresponding ratio（Dh/Dv） of about 9. Two surface rupture events must have occurred over the past 3300 years, the latest one possibly between 1485 cal BP and 1730 cal BP.

A Late Quaternary Climate Record Based on Multi-Proxies Analysis from the Jiaochang Loess Section in the Eastern Tibetan Plateau,China

We compared the stable carbon isotopic records from a loess transect of the Jiaochang in the eastern Tibetan Plateau, spanning the last -21,000 years, with multiproxy data for pedogenesis, including magnetic susceptibility, clay fraction, Fed/Fet ratio, carbonate and total organic carbon content, in order to probe the mechanisms of δ^13C values of organic matter and Late Quaternary climate variations in the eastern Tibetan Plateau. Our results indicate that there is no simple relationship between δ^13C of organic matter and summer monsoon variations. The change in δ^13C values of organic matter （in accordance with the ratios of C3 to C4 plants） results from the interaction among temperature, aridity and atmospheric pCO2 level. Drier climate and lower atmospheric pCO2 level contribute to positive carbon isotopic excursion, while negative carbon isotopic excursion is the result of lower temperature and increased atmospheric pCO2 level. Additionally, our results imply that the Tibetan monsoon may play an important role in climate system in the eastern Tibet Plateau, which specifically reflects frequently changing climate in that area. The results provide new insights into the forcing mechanisms on both the δ^13C values of organic matter and the local climate system.

Phase Equilibrium of Quaternary System Cd^(2+)//Cl^-,SO_4^(2-),NO_3^--H_2O at 298 K

Solid-liquid equilibrium of quaternary system Cd2＋//Cl–, SO42–, NO3–-H2O at 298 K was studied by means of an isothermal solution saturation method. Experimental results indicate that there are three univariant curves BE, AE and CE, one invariant point E and three crystallization fields in the quaternary system. The quaternary system belongs to a simple type, and there are no double salts or solid solution existing. The crystallization zones of equilibrium solid phases are CdCl2·5/2H2O（AEB field）, 3CdSO4·8H2O（AEC field） and Cd（NO3）2·4H2O（BEC field）, respectively. The composition of the invariant point is CdCl2, Cd（NO3）2, CdSO4 and H2O and the contents of which are 17.02%, 45.50%, 4.52% and 32.96%, respectively. The physico-chemical properties of solution in the quaternary system show regular changes along with the increased cadmium concentration. The results indicate that Cd（NO3）2 possessed the highest solubility among those three salts, which means a strong transfer of Cd ion and a high pollution risk of soil environment. And the solubility of CdSO4 would be restrained as the salts existing together.

New Quaternary Mammalian Faunas and Cave Deposits in the Zhoukoudian Area,Beijing

From 1985 to 1987, four new localities with abundant fossil mammals were dis-covered by Cao, Tian and others in the Zhoukoudian (Choukoutien) area, Beijing. They are theEast, West, Shangdian and Donglingzi caves. The East Cave fauna consists of 28 speices ofmammals and its age is middle Early Pleistocene. The East Cave assemblage shows that a tem-perature-falling event took place at around 1.20 Ma B.P. at Zhoukoudian. Sixteen species ofmammals were collected from the West Cave, which are mainly forms of late Early Pleistoceneage. The West Cave fauna represents a transitional fauna from the East Cave fauna (dry-cold)to the fauna (warm) at locality 9. The Shangdian Cave fauna is composed of four forms, beingMiddle Pleistocene in age. The Donglingzi Cave fauna contains 21 Late Pleistocene forms. Inthe cave two fossil horizons may be distinguished. The age of the lower horizon is early LatePleistocene, which is equivalent to that of the New Cave fauna; while the fauna of the upper ho-rizon may be correlated with the Upper Cave fauna.

Synthesis of cyclic carbonates from epoxides or olefins and CO_2 catalyzed by metal-organic frameworks and quaternary ammonium salts

Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions （8 bar CO2, 25 ~C）. Styrene and propylene carbonates were formed with high yields （95% and 82%, respectively）. Catalytic performance of Cr-MIL-101 was compared with other MOFs： Fe-MIL-101, Zn-MOF-5 and HKUST-1, The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H202 as oxidants at 8-100bar CO2 and 25-80 ~C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.

Characteristics and accumulation model of the late Quaternary shallow biogenic gas in the modern Changjiang delta area, eastern China

The Changjiang（Yangtze）is one of the largest rivers in the world.It formed a huge incised valley at its mouth during the Last Glacial Maximum;the incised-valley fill,approximately 80–110 m thick,supplies an important foundation for the generation of shallow biogenic-gas reservoirs.Two cores and 13 cone penetration tests were used to elaborate the characteristics,formation mechanism,and distribution of the shallow biogenic-gas reservoirs in the study area.The natural gas is mainly composed of CH4（generally[95%）with a δ^13CCH4 and δ^13CCO2 of-75.8 to-67.7% and -34.5 to-6.6%,respectively,and a δDCH4 of-215 to-185%,indicating a biogenic origin by the carbon dioxide reduction pathway.Commercial biogenic gas occurs primarily in the sand bodies of fluvial-channel,floodplain,and paleo-estuary facies with a burial depth of 50–80 m.Gas sources as well as cap beds are gray to yellowish-gray mud of floodplain,paleoestuary,and offshore shallow marine facies.The organic matter in gas sources is dominated by immature type Ⅲ kerogen（gas prone）.The difference in permeability（about4–6 orders of magnitude）between cap beds and reservoirs makes the cap beds effectively prevent the upward escape of gas in the reservoirs.This formation mechanism is consistent with that for the shallow biogenic gas in the late Quaternary Qiantang River incised valley to the south.Therefore,this study should provide further insight into understanding the formation and distribution of shallow biogenic gas in other similar postglacial incised-valley systems.

Preparation of Hierarchically Trimodal-Porous ZSM-5 Composites through Steam-assisted Conversion of Macroporous Aluminosilica Gel with Two Different Quaternary Ammonium Hydroxides

This article presents a detailed structural study of a new spherical Mg Cl2-supported Ti Cl4 Ziegler-Natta catalyst for isotactic propylene polymerization, and researches on the relationship between catalyst structure and polymer properties. The spherical support with the chemical composition of CH3CH2 OMg OCH(CH2Cl)2 has been synthesized from a new dispersion system and is used as the supporting material to prepare Ziegler-Natta catalyst. The XRD analysis indicates that the catalyst is fully activated with δ-Mg Cl2 in the active catalyst. The far-IR spectrometric results confirm again the presence of δ-Mg Cl2 in the active catalyst. Textural property of the active catalyst exhibits high surface area coupled with high porosity. The high activity in propylene polymerization is mainly ascribed to the full activation and the porous structure of the catalyst. Scanning electron microscopy/energy dispersive spectrometer mapping results indicate a uniform titanium distribution throughout the catalyst particles. Particle size analysis shows that the catalyst has a narrow particle size distribution. The perfect spherical shape, uniform titanium distribution and narrow particle size distribution of the catalyst confirm the advantage of polymer particles production with less fines. The solid state 13 C NMR and mid-IR spectroscopic analyses indicate that there exists strong complexation between diisobutyl phthalate and Mg Cl2, which leads to the high isotacticity of polypropylene.

Adsorption of methyl orange from aqueous solution by composite magnetic microspheres of chitosan and quaternary ammonium chitosan derivative

Novel composite magnetic microspheres containing chitosan and quaternary ammonium chitosan derivative(CHMMs) were prepared by inverse suspension method,and used for the methyl orange(MO) removal from aqueous solutions.The CHMMs were characterized by a scanning electron microscope,a transmission electron microscope,and Fourier transform infrared spectroscopy,respectively.Compared with the chitosan beads,the incorporation of quaternary ammonium chitosan derivative significantly reduced the particle size.The MO adsorption by CHMMs was investigated by batch adsorption experiments.The adsorption kinetics was conformed to the pseudo second-order kinetics equation.The adsorption isotherm followed the Langmuir model better than the Freundlich model and the calculated maximum MO adsorption capacity was 266.6 mg·g^-1 at 293 K.Thermodynamic studies indicated that the MO adsorption was endothermic in nature with the enthalpy change(△H°) of 99.44 kJ·mol^-1.The CHMMs had a stable performance for MO adsorption in the pH range of 4-10,but high ionic strength deteriorated the MO removal due to the shielding of the ion exchange interaction.A 1 mol·L^-1 NaCl solution could be used to regenerate the exhausted CHMMs.The proposed CHMMs can be used as an effective adsorbent for dye removal or recovery from the dye wastewater.