Comprehensive Summary Developing new catalysts for highly selectivity and conversion of saturated C(sp^(3))-H bonds is of great significance.In order to obtain catalysts with high catalytic performance,six Eu-based MO...Comprehensive Summary Developing new catalysts for highly selectivity and conversion of saturated C(sp^(3))-H bonds is of great significance.In order to obtain catalysts with high catalytic performance,six Eu-based MOFs with different structural characteristics were obtained by using europium ions and different organic acid ligands,namely Eu-1~Eu-6.Eu-1,Eu-2 and Eu-3 featured three-dimensional structures,while Eu-4 and Eu-5 featured two-dimensional structures.展开更多
Accurate estimation of the postmortem interval(PMI)is an important task in forensic practice.In the last half-century,the use of postmortem biochemistry has become an important ancillary method in determining the time...Accurate estimation of the postmortem interval(PMI)is an important task in forensic practice.In the last half-century,the use of postmortem biochemistry has become an important ancillary method in determining the time of death.The present study was carried out to determine the correlation between blood oxidation-reduction potential(ORP)values and PMIs,and to develop a three-dimensional surface equation to estimate the PMI under various temperature conditions.A total of 48 rabbits were placed into six groups and sacrificed by air embolism.Blood was obtained from the right ventricle of each rabbit,and specimens were stored at 10℃,15℃,20℃,25℃,30℃,and 35℃.At different PMIs(once every 4 h),the blood ORP values were measured using a PB-21 electrochemical analyzer.Statistical analysis and curve fitting of the data yielded cubic polynomial regression equations and a surface equation at different temperatures.Result:The results showed that there was a strong positive correlation between the blood ORP values at different temperatures and the PMI.This study provides another example of using a three-dimensional surface equation as a tool to estimate the PMI at various temperature conditions.展开更多
通过改变氧化剂用量制备不同氧化程度的氧化石墨(GO),经超声分散,水热还原制备出系列三维还原氧化石墨烯(3D r GOs),采用扫描电镜、X射线衍射、红外光谱、拉曼光谱和紫外可见分光光度计等分析测试手段研究了氧化程度对3D rGOs形貌结构...通过改变氧化剂用量制备不同氧化程度的氧化石墨(GO),经超声分散,水热还原制备出系列三维还原氧化石墨烯(3D r GOs),采用扫描电镜、X射线衍射、红外光谱、拉曼光谱和紫外可见分光光度计等分析测试手段研究了氧化程度对3D rGOs形貌结构、光谱特征和吸附性能的影响。结果表明:随着氧化程度的增加,水热还原产物在微观上由多层堆积的片状结构逐渐转向均匀多孔网状结构,最后转变为断裂碎片交联的网状结构。吸附容量随氧化程度的增加先增大后减小,当GO羟基含量最多而环氧基含量最少时,3D rGOs吸附性能最好,对罗丹明B、亚甲基蓝和甲基紫吸附量最高分别可达90.9、145.4和237.4 mg/g。展开更多
基金supported by Changsha Municipal Natural Science Foundation(kq2014164)the Natural Science Foundation of Hunan Province(Grant 2020JJ4684)Science and Technology Innovation Project of Hunan Academy of Agricultural Sciences(2020CX45).
文摘Comprehensive Summary Developing new catalysts for highly selectivity and conversion of saturated C(sp^(3))-H bonds is of great significance.In order to obtain catalysts with high catalytic performance,six Eu-based MOFs with different structural characteristics were obtained by using europium ions and different organic acid ligands,namely Eu-1~Eu-6.Eu-1,Eu-2 and Eu-3 featured three-dimensional structures,while Eu-4 and Eu-5 featured two-dimensional structures.
基金This study was supported by the Key Projects in the National Science and Technology Pillar Program during the Eleventh Five‑year Plan Period(2012BAK16B02)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,the State Education Ministry[(2013)1792]+2 种基金the Training Programmers Foundation for the Beijing Talents(2013D002023000002)the Beijing Planning Project of Philosophy and Social Science(13FXC032)the Project of Young Teachers’Academic Innovation Team by China University of Political Science and Law(2014CXTD04).
文摘Accurate estimation of the postmortem interval(PMI)is an important task in forensic practice.In the last half-century,the use of postmortem biochemistry has become an important ancillary method in determining the time of death.The present study was carried out to determine the correlation between blood oxidation-reduction potential(ORP)values and PMIs,and to develop a three-dimensional surface equation to estimate the PMI under various temperature conditions.A total of 48 rabbits were placed into six groups and sacrificed by air embolism.Blood was obtained from the right ventricle of each rabbit,and specimens were stored at 10℃,15℃,20℃,25℃,30℃,and 35℃.At different PMIs(once every 4 h),the blood ORP values were measured using a PB-21 electrochemical analyzer.Statistical analysis and curve fitting of the data yielded cubic polynomial regression equations and a surface equation at different temperatures.Result:The results showed that there was a strong positive correlation between the blood ORP values at different temperatures and the PMI.This study provides another example of using a three-dimensional surface equation as a tool to estimate the PMI at various temperature conditions.
