Multifunctional fillers are greatly required for dental resin composites(DRCs).In this work,a spray dryer with a three-fluid nozzle was applied for the first time to construct high-performance complex nanoparticle clu...Multifunctional fillers are greatly required for dental resin composites(DRCs).In this work,a spray dryer with a three-fluid nozzle was applied for the first time to construct high-performance complex nanoparticle clusters(CNCs)consisting of different functional nanofillers for dental restoration.The application of a three-fluid nozzle can effectively avoid the aggregation of different nanoparticles with opposite zeta potentials before the spray drying process in order to construct regularly shaped CNCs.For a SiO_(2)–ZrO_(2) binary system,the SiO_(2)–ZrO_(2) CNCs constructed using a three-fluid nozzle maintained their excellent mechanical properties((133.3±4.7)MPa,(8.8±0.5)GPa,(371.1±13.3)MPa,and(64.5±0.7)HV for flexural strength,flexural modulus,compressive strength,and hardness of DRCs,respectively),despite the introduction of ZrO_(2) nanoparticles,whereas their counterparts constructed using a two-fluid nozzle showed significantly decreased mechanical properties.Furthermore,heat treatment of the SiO_(2)-ZrO_(2) CNCs significantly improved the mechanical properties and radiopacity of the DRCs.The DRCs containing over 10%mass fraction ZrO_(2) nanoparticles can meet the requirement for radiopaque fillers.More importantly,this method can be expanded to ternary or quaternary systems.DRCs filled with SiO_(2)-ZrO_(2)-ZnO CNCs with a ratio of 56:10:4 displayed high antibacterial activity(antibacterial ratio>99%)in addition to excellent mechanical properties and radiopacity.Thus,the three-fluid nozzle spray drying technique holds great potential for the efficient construction of multifunctional cluster fillers for DRCs.展开更多
The sand-driven flow is studied from the continuum viewpoint in this paper. The crux of this work is how to model the stresses of the particle phase properly. By analysing the two-fluid model which usually, works in s...The sand-driven flow is studied from the continuum viewpoint in this paper. The crux of this work is how to model the stresses of the particle phase properly. By analysing the two-fluid model which usually, works in solving gas-particle two-phase .flow,. we find that this model has many. deficiencies for studying the sand-driven flow,even for the simplest case- the steady, two-dimensional fully-developed flow.Considering this, we have proposed the three-fluid model in which the upward particles and the downward-particles ore regarded as two kinds of fluids respectively.It is shown that the three-fluid model is better than the two-fluid model in reflecting the internal structure of the flow, region and the influence of the boundary situations on the flow. and it is advantageous to find an approximate solution in that the main components of the particle-phase stresses can be explicitly expressed by those variables in the three-fluid model.In the end, the governing equations as well as the boundary. conditions for the three-fluid model are provided with a discussion.展开更多
A heat transfer model for three-fluid separated heat pipe exchanger was analyzed,and the temperature transfer matrix for general three-fluid separated heat exchanger working in parallel-flow or counter-flow mode was o...A heat transfer model for three-fluid separated heat pipe exchanger was analyzed,and the temperature transfer matrix for general three-fluid separated heat exchanger working in parallel-flow or counter-flow mode was obtained.It was found that the forms of temperature transfer matrix are similar for heat pipe rows with equal or different heat transfer surface area.Furthermore,by using the temperature transfer matrix of the heat pipe exchanger,the relationship between heat transfer effectiveness θ 1,θ 2 and M,NTU,U,Δt i were derived for the exchanger operating in parallel-flow or counter-flow mode,and a simple special example was adopted to demonstrate the correctness of these relationships.展开更多
基金the National Key Research and Development Program of China(2016YFA0201701)the National Natural Science Foundation of China(21878015).
文摘Multifunctional fillers are greatly required for dental resin composites(DRCs).In this work,a spray dryer with a three-fluid nozzle was applied for the first time to construct high-performance complex nanoparticle clusters(CNCs)consisting of different functional nanofillers for dental restoration.The application of a three-fluid nozzle can effectively avoid the aggregation of different nanoparticles with opposite zeta potentials before the spray drying process in order to construct regularly shaped CNCs.For a SiO_(2)–ZrO_(2) binary system,the SiO_(2)–ZrO_(2) CNCs constructed using a three-fluid nozzle maintained their excellent mechanical properties((133.3±4.7)MPa,(8.8±0.5)GPa,(371.1±13.3)MPa,and(64.5±0.7)HV for flexural strength,flexural modulus,compressive strength,and hardness of DRCs,respectively),despite the introduction of ZrO_(2) nanoparticles,whereas their counterparts constructed using a two-fluid nozzle showed significantly decreased mechanical properties.Furthermore,heat treatment of the SiO_(2)-ZrO_(2) CNCs significantly improved the mechanical properties and radiopacity of the DRCs.The DRCs containing over 10%mass fraction ZrO_(2) nanoparticles can meet the requirement for radiopaque fillers.More importantly,this method can be expanded to ternary or quaternary systems.DRCs filled with SiO_(2)-ZrO_(2)-ZnO CNCs with a ratio of 56:10:4 displayed high antibacterial activity(antibacterial ratio>99%)in addition to excellent mechanical properties and radiopacity.Thus,the three-fluid nozzle spray drying technique holds great potential for the efficient construction of multifunctional cluster fillers for DRCs.
文摘The sand-driven flow is studied from the continuum viewpoint in this paper. The crux of this work is how to model the stresses of the particle phase properly. By analysing the two-fluid model which usually, works in solving gas-particle two-phase .flow,. we find that this model has many. deficiencies for studying the sand-driven flow,even for the simplest case- the steady, two-dimensional fully-developed flow.Considering this, we have proposed the three-fluid model in which the upward particles and the downward-particles ore regarded as two kinds of fluids respectively.It is shown that the three-fluid model is better than the two-fluid model in reflecting the internal structure of the flow, region and the influence of the boundary situations on the flow. and it is advantageous to find an approximate solution in that the main components of the particle-phase stresses can be explicitly expressed by those variables in the three-fluid model.In the end, the governing equations as well as the boundary. conditions for the three-fluid model are provided with a discussion.
文摘A heat transfer model for three-fluid separated heat pipe exchanger was analyzed,and the temperature transfer matrix for general three-fluid separated heat exchanger working in parallel-flow or counter-flow mode was obtained.It was found that the forms of temperature transfer matrix are similar for heat pipe rows with equal or different heat transfer surface area.Furthermore,by using the temperature transfer matrix of the heat pipe exchanger,the relationship between heat transfer effectiveness θ 1,θ 2 and M,NTU,U,Δt i were derived for the exchanger operating in parallel-flow or counter-flow mode,and a simple special example was adopted to demonstrate the correctness of these relationships.
