One-step hydrothermal synthesis of 2,5-PDCA-containing MgAl-LDHs three-layer composite coating with high corrosion resistance on AZ31

The addition of 2,5-pyridinedicarboxylic acid(2,5-PDCA)to the Mg-Al LDH coating,which was prepared by one-step hydrothermal synthesis,had extremely enhanced the corrosion protection of AZ31 Mg alloy,although the 2,5-PDCA could not be intercalated into the interlayer spacing.The corrosion current density of 0.05 mol L^(−1)2,5-PDCA LDH containing LDH coating is 3.18 nA cm^(−2),reduced by two orders of magnitude compared to the LDH coating without inhibitor,and the corrosion inhibition efficiency of the coating is 98.05%.The coating formed on the surface of AZ31 was peeled off from the substrate by using a mechanical method and SEM observation of the cross-section showed that the coating consisted of three different layers.The innermost layer is a thick layer that consists of Mg(OH)_(2)and the intermediate layer is LDH,which is vertical to the substrate and the outmost layer is a thin but very dense deposit layer of LDH agglomerates with complexes of 2,5-PDCA and Mg.This kind of sediment/LDH/Mg(OH)_(2)three-layer composite structure was accountable for the increase in the corrosion resistance of AZ31 Mg alloy.

One-step Eco-friendly Fabrication of Antibacterial Polyester Via On-line Amination Reaction by Melt Coextrusion

The work is dedicated to develop a one-step eco-friendly method to prepare antibacterial polyethylene terephthalate(PET).We report a one-step eco-friendly method to manufacture antibacterial PET via on-line amination reaction by melt coextrusion.Beside evenly mixing of poly(hexamethylene guanidine)(PHMG)and PET in the melt coextrusion procedure,the amination reaction also occurred between PHMG and PET under high temperature(230-270℃).The antibacterial ability of composite PET showed obvious PHMG concentration dependence,and antibacterial activity reached more than 99%when PHMG content was 2.5 wt%.Moreover,LIVE/DEAD fluorescence test further confirmed that the composite PET could kill bacteria quickly and efiectively(within 30 min);while negligible cytotoxicity was observed to HSF and HUVEC cells.Onestep eco-friendly fabrication of composite antibacterial PET was accomplished by on-line melt coextrusion.The composite antibacterial PET has potential use in multiple fields to combat with pathogenic including textiles,packaging materials,decoration materials and biomedical devices,etc.

Direct-chill semi-continuous casting process of three-layer composite ingot of 4045/3004/4045 aluminum alloys

Three-layer composite ingot of 4045/3004/4045 aluminum alloys was prepared by direct-chill semi-continuous casting process,the temperature field distribution near the composite interface,macro-morphology,microstructure and composition distribution of the composite interface were investigated.The results show that semi-solid layer with a certain thickness forms near the interface due to the effect of cooling plate,which ensures successful implementation of casting the composite ingot.Two different aluminum alloys are well bonded metallurgically.The mechanical properties of composite interface were measured,the tensile and shearing strengths of composite interface are 105 and 88 MPa,respectively,which proves that the composite interface is a kind of metallurgical bonding.

Improving electrochemical performances of LiFePO_4 /C cathode material via a novel three-layer electrode

As an improvement on the conventional two-layer electrode （active material layerlcurrent collector）, a novel sandwich-like three-layer electrode （conductive layerlactive material layertcurrent collector） for cathode material LiFePO4/C was introduced in order to improve its electrochemical performance. LiFePO4/C in the three-layer electrode exhibited superior rate capability in comparison with that in the two-layer electrode in accordance with charge-discharge examination. Cyclic voltammetry and electrochemical impedance spectroscopy indicated that Fe3＋/Fe2＋ redox couple for LiFePO4 in the three-layer electrode displayed faster kinetics, better reversibility and much lower charge transfer resistance than that in the two-layer electrode in electrochemical process. For three-layer electrode, the holes in the surface of active material layer were filled by smaller acetylene black grains, which formed electrical connections and provided more pathways to electron transport to/from LiFePO4/C particles exposed to the bulk electrolyte.

Deformation and heat treatment ability of three-layer 6009/7050/6009 Al alloy clad slab prepared by direct-chill casting

Three-layer6009/7050/6009aluminum alloy clad slab was fabricated by an innovative direct-chill casting process.To study the response of the clad slab to plastic deformation and heat treatments,homogenization annealing,hot rolling,solution and aging were successively performed on the as-cast6009/7050/6009clad samples.The results revealed that excellent metallurgical bonding between7050alloy layer and6009alloy layer was achieved under optimal parameters.The clad ratio obviously decreased when the annealed sample was rolled to55%hot reduction level,and then changed slightly with further rolling.Furthermore,the content of rodlike Zn-rich phases increased significantly in7050alloy layer in the homogenized clad samples after rolling at55%,65%and75%hot reduction levels,and the higher level of hot reduction resulted in narrower diffusion layer.Subsequent solution and aging significantly improved the hardness in7050alloy layer,interfaces and6009alloy layers of the rolled samples except for the thin side for the75%hot reduction sample.

A Short-Term Traffic Flow Forecasting Method Based on a Three-Layer K-Nearest Neighbor Non-Parametric Regression Algorithm

Short-term traffic flow is one of the core technologies to realize traffic flow guidance. In this article, in view of the characteristics that the traffic flow changes repeatedly, a short-term traffic flow forecasting method based on a three-layer K-nearest neighbor non-parametric regression algorithm is proposed. Specifically, two screening layers based on shape similarity were introduced in K-nearest neighbor non-parametric regression method, and the forecasting results were output using the weighted averaging on the reciprocal values of the shape similarity distances and the most-similar-point distance adjustment method. According to the experimental results, the proposed algorithm has improved the predictive ability of the traditional K-nearest neighbor non-parametric regression method, and greatly enhanced the accuracy and real-time performance of short-term traffic flow forecasting.

Structure Design and Properties of Three-Layer Particleboard Based on High Voltage Electrostatic Field(HVEF)

In this study,the effects of three different particle sizes of wood wastes(A=–8+12 mesh;B=–12+20 mesh;C=–20+30 mesh)and factory shavings(D)on the properties of particleboard were investigated.According to the test results,three-layer particleboard was designed.Particleboard face layers made with mixture of A,B,and C.The core layer made with D.The ratio of core layer to face layers is 50:50.Three-layer particleboard were fabricated with 12%urea-formaldehyde(UF)resins and three different high voltage electrostatic field intensities(0 kv,30 kv,60 kv).The internal bond(IB)strength,modulus of rupture(MOR),modulus of elasticity(MOE),thickness swelling(TS),and water absorption(WA)of particleboard were evaluated.The density distribution of the three-layer particleboard were examined by vertical density profiles(VDP),and the bonding mechanism and functional groups changes in the particles were analyzed by FTIR analysis.The results showed that HVEF treatment intensity play a remarkable role in properties of particleboard.The particleboard with higher electrostatic field intensities treatment has higher MOE,MOR,IB,and TS.Under HVEF treatment(60 kv),the MOR,modulus of MOE,and IB of three-layer particleboard were 23.61 N/mm^(2),2787.09 N/mm^(2),and 0.86 N/mm^(2),respectively.FTIR indicated that the surface activity of wood particles was increased electric field treatment.

Characteristics Analysis of Chemical Concentration Sensor Based on Three-layer FBG

The three-layer structure model of the fiber Bragg grating is proposed in this paper. And through experimental study and reasoning calculation to verify the three layer structure of the optical waveguide model, so the sensitivity characteristic of the Bragg wavelength to the refractive index of chemical solution is obtained. And the relationships between the concentration and the shift of Bragg wavelength of sucrose, ethanol, and Nacl solution are achieved. Finally the shifts of the Bragg wavelength with the external concentration are obtained by experiments. A kind of simple structure, small size, good stability, high sensitivity chemical concentration sensor is obtained.

Latice Deformation and Meso-Phase Structure in Poly(Ethylene Terephthalate)From Solid State Coextrusion

The development of crystalline and Meso-phase structure by solid state extrusion from50℃ to 90℃ is studied for PET. The unit cell parameters of stress-induced crystallites inextrudates are determined as a function of extrusion draw ratio (EDR), and

Trapped Modes in a Three-Layer Fluid

In this work,trapped mode frequencies are computed for a submerged horizontal circular cylinder with the hydrodynamic set-up involving an infinite depth three-layer incompressible fluid with layer-wise different densities.The impermeable cylinder is fully immersed in either the bottom layer or the upper layer.The effect of surface tension at the surface of separation is neglected.In this set-up,there exist three wave numbers:the lowest one on the free surface and the other two on the internal interfaces.For each wave number,there exist two modes for which trapped waves exist.The existence of these trapped modes is shown by numerical evidence.We investigate the variation of these trapped modes subject to change in the depth of the middle layer as well as the submergence depth.We show numerically that two-layer and single-layer results cannot be recovered in the double and single limiting cases of the density ratios tending to unity.The existence of trapped modes shows that in general,a radiation condition for the waves at infinity is insufficient for the uniqueness of the solution of the scattering problem.

Effects of anisotropy on quantum fluctuation of a three-layer system with mutisublattice

The quantum fluctuations of a three-layer Heisenberg model with six sublattices are studied by the retarded Green＇s function method and the spin-wave theory. The effects of anisotropy on the quantum fluctuations at zero temperature are discussed. The results show that the interlayer anisotropy plays an important role in balancing the quantum competitions.

The three-layer model of the thermohaline structure in the shallow seas

A three-layer model of the thermohaline structure is developed on the basis of the two -layer model of thermocline. The model is able to simulate the depth,thickness and intensity of both thermocline and halocline, and the temperature and salinity of both upper layer and lower layer in the shallow seas.Camparison of simulation with data is favorable.Detailed analysis is made on a variety of factors affecting the intensity of the thermocline.

Wave Scattering by a Submerged Sphere in Three-Layer Fluid

Using linear water wave theory,three-dimensional problems concerning the interaction of waves with spherical structures in a fluid which contains a three-layer fluid consisting of a layer of finite depth bounded above by freshwater of finite depth with free surface and below by an infinite layer of water of greater density are considered.In such a situation timeharmonic waves with a given frequency can propagate with three wavenumbers.The sphere is submerged in either of the three layers.Each problem is reduced to an infinite system of linear equations by employing the method of multipoles and the system of equations is solved numerically by standard technique.The hydrodynamic forces(vertical and horizontal forces)are obtained and depicted graphically against the wavenumber.When the density ratio of the upper and middle layer is made to approximately one,curves for vertical and horizontal forces almost coincide with the corresponding curves for the case of a two-layer fluid with a free surface.This means that in the limit,the density ratio of the upper and middle layer goes to approximately one,the solution agrees with the solution for the case of a two-layer fluid with a free surface.

A Three-layered Contrasting Analysis of the Theme in Once more to the lake

Once more to the lake is a representative work of the American Writer, Elwyn Brooks White, and has been acclaimed by people in the world. The paper offers a three-layered contrasting analysis of the essay. By detailed analysis of the contrasts running through the whole essay, the author finds that those contrasts are symbol of White's internal struggle and reflection for life.On the foundation of the three-layered contrasts, the paper presents the theme analysis and clarifies the content of the essay.

Study on Three-layered Grid Conceptual Prototype Using Ecological Network Computing Environment

Next generation grid systems where the emphasis shifts to distributed global collaboration, a service-oriented approach and information layer issues exhibit a strong sense of automation. Requirements for these systems resemble the self-organizing and the healing properties of natural ecosystems. Some key ecological concepts and mechanisms are introduced into the design for the third generation grid computing architectures by inspiration of this resemblance. Also, an Ecological Network-based Computing Environment (ENCE) platform is designed in this paper. Based on the ENCE platform, a grid-computing model of three-layered grid conceptual prototype that embeds the ENCE layers is presented from the viewpoint of implementation. The implementation model should be useful to the design of the third generation grid systems.

Third-order Stokes wave solutions for interfacial internal waves in a three-layer density-stratified fluid

Interracial internal waves in a three-layer density-stratified fluid are investigated using a singular perturbation method, and third-order asymptotic solutions of the velocity potentials and third-order Stokes wave solutions of the associated elevations of the interfacial waves are presented based on the small amplitude wave theory. As expected, the third-order solutions describe the third-order nonlinear modification and the third-order nonlinear interactions between the interracial waves. The wave velocity depends on not only the wave number and the depth of each layer but also on the wave amplitude.

Two-and Three-Layered Dissolving Microneedles for Transcutaneous Delivery of Model Vaccine Antigen in Rats

Purpose: Comparison of transcutaneous immunization of ovalbumin (OA) between two-and three-layered dissolving microneedles (MN) in rats. Methods: We prepared 500 μm long two-layered and three-layered dissolving microneedle (2-MN and 3-MN, respectively) arrays from chondroitin sulfate as the base, and OA as the model antigen. The 2-MN containing OA at the acral portion and 3-MN with OA at the second portion were administered to rat skin transcutaneously. As a positive control, OA solution was injected subcutaneously (sc). The OA delivery and diffusion in the rat skin were studied using confocal microscopy with fluorescein-conjugated OA (FL-OA). Results: The formulated positions of OA were 0-155 ± 5 μm for 2-MN and 175 ± 4 – 225 ± 5 μm for 3-MN. The administered doses of OA were 2.2 ± 0.1 μg, 12.0 ± 0.2 μg and 22.0 ± 0.2 μg for 2-MN, 1.8 ± 0.2 μg, 12.6 ± 0.7 μg, and 20.4 ± 0.3 μg for 3-MN, 10 μg, 100 μg and 1000 μg for sc injection. At 4 weeks after the first administration, 3-MN showed about 2.5-7.0 fold and 5.4 fold higher total Ig (G + A + M) antibody than 2-MN and sc injection of the OA solution. Conclusions: The 3-MN, which delivered OA to the epidermis, is a useful drug delivery system for transcutaneous antigen delivery.

A three-layer model for the thermal structure in the Huanghai Sea

A one-dimentional three-layer model for the thermal structure in the Huanghai Sea is presented in this study, me model consists of the upper mixed layer caused by heating and wind mixing, the lower mixed layer driven by tidal mixing, and the thermocline with certain thickness. The entrainment velocities of the upper and lower layers are obtained respectively. The results show that the model is capable of describing the development and decline processes of the seasonal thermocline in the Huanghai Sea, simulating successfully the Huanghai Sea Cold Water Mass, the nearshore front and surface cold water off North Jiangsu and explaining reasonably their formation mechanisms as well as the strong thermocline off Qingdao. It is suggested that the tidal mixing plays key role in the formation of the nearshore front off North Jiangsu and the strong thermocline off Qingdao. The wind mixing and the tidal mixing make the lower layer water with high nutrients go up to the upper layer. This physical process may be significant for biological plant production.

On the three-layer passage reading method in English extensive reading

This paper raises, for the first time, with a model reading passage, a three-layer passage reading method （3LPRM in brief ） in English reading： reading beyond paragraphs; reading within paragraphs and sentences, and reading with coherences of words and expressions. The paper illustrates the definition, contents, characteristics and application of the method which is easy to master and apply. The paper aims at supplying readers especially beginners of E/S/FL （English as second/foreign language） with a practical passage reading method so as to improve their reading efficiency. The paper has some practical significance and directing value.

Vibration of Three-Layered FGM Cylindrical Shells with Middle Layer of Isotropic Material for Various Boundary Conditions

In the present study, vibration analysis of a three-layered cylindrical shell is performed whose inner and outer layers are composed of functionally graded materials whereas the middle one is assumed to be of isotropic material. This formation of a cylindrical shell influences stiffness modulii and the resultant material properties. The shell problem is formulated from the constitutive relations of stresses and strains with the displacement deformations and they are taken from Love’s thin shell theory. This problem is transformed into the integral form by evaluating the expressions for the strain and kinetic energies of the shell. Rayleigh-Ritz method is employed to solve the shell dynamic equations. Vibration characteristics of these cylindrical shells are investigated for a number of physical parameters and configurations of the fabrication of shells. The axial modal dependence is approximated by the characteristic beam functions that satisfy the boundary conditions. Results evaluated, show good agreement with the open literature.