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Ti-Si-Fe合金添加量对Si_(3)N_(4)结合SiC材料结构与性能的影响
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作者 姚路炎 韩兵强 +1 位作者 张锦化 柯昌明 《耐火材料》 CAS 北大核心 2024年第4期277-283,共7页
为促进Si_(3)N_(4)结合SiC耐火材料的致密化,降低Si粉氮化温度,以SiC颗粒和细粉、Si粉为主要原料,利用从高钛型高炉渣提取的Ti-Si-Fe合金部分取代Si粉,在埋碳气氛下于1350℃反应烧结5 h,制备了Si_(3)N_(4)结合SiC耐火材料。研究了Ti-Si... 为促进Si_(3)N_(4)结合SiC耐火材料的致密化,降低Si粉氮化温度,以SiC颗粒和细粉、Si粉为主要原料,利用从高钛型高炉渣提取的Ti-Si-Fe合金部分取代Si粉,在埋碳气氛下于1350℃反应烧结5 h,制备了Si_(3)N_(4)结合SiC耐火材料。研究了Ti-Si-Fe合金添加量(加入质量分数分别为0、1.8%、3.6%、5.4%、7.2%)对Si粉的氮化行为、材料力学性能和显微结构的影响,并探讨了氮化反应烧结机制。结果表明:1)随着Ti-Si-Fe合金添加量的增加,材料的常温力学性能和高温抗折强度明显改善,荷重软化温度均超过1700℃,Ti-Si-Fe合金添加量超过3.6%(w)后材料性能的增幅变缓;2)Ti-Si-Fe合金促进了Si粉在较低温度下的完全氮化和材料的反应烧结,Ti-Si-Fe合金中各物相及Si粉氮化反应的体积增加能够充填气孔,氮化产物改善骨料与基质、基质内部的结合状态,从而提高材料的致密化程度,改善力学性能;3)引入Ti-Si-Fe合金后,反应体系中形成了富含Ti、Si、N、Fe成分的液相,氮化物的形成除传统的VS、VLS机制外,溶解-沉淀机制在短柱状β-Si_(3)N_(4)、粒状TiN的形成中起到主导作用,交错连结的α-Si_(3)N_(4)晶须、短柱状β-Si_(3)N_(4)、粒状TiN对材料的力学性能起到增强作用。 展开更多
关键词 ti-Si-fe合金 反应烧结 Si_(3)N_(4)结合SiC耐火材料 致密化 溶解-沉淀
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Ti/Fe EUTECTIC REACTION PROCESS
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作者 WU Mingfang MA Cheng YANG Min 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2006年第4期614-617,共4页
To obtain satisfactory joining between titanium alloys end stainless steel, it is of great significance to study the process of Ti-Fe eutectic reaction. The preliminary studies about the liquid forming, spreading end ... To obtain satisfactory joining between titanium alloys end stainless steel, it is of great significance to study the process of Ti-Fe eutectic reaction. The preliminary studies about the liquid forming, spreading end the structure of the contact reaction between pure Ti and pure Fe are carried out at 1 120℃ for different holding times in high-frequency induction heated vacuum furnace. The results show that for Fe(particle-like)/Ti(plate-like) contact reaction couples, owing to Fe's higher density then titanium's, the Fe/Ti eutectic reaction develops in the thickness direction of plate-like Ti, named "deposition effect". Then the eutectic reaction can be realized without the inter-diffusion between Ti end Fe atoms, so the formation rate of the liquid phase is very quick. For Ti (particle-like)/ Fe (plate-like) contact reaction couples, the eutectic reaction has a strong direction, i.e. the eutectic liquid is formed mostly at the Ti side, which leads to much dissolution of Ti particle end very little dissolution of the Fe base metal. It can be seen that the diffusion rate of Fe in Ti determines the whole process of the eutectic reaction, behaved as that the dissolution rate of Ti (particle-like)/ Fe (plate-like) is much lower then that of Fe(particle-like)/Ti(plate-like), end the dissolution rate of Ti obeys the square root law. Whatever means the Ti, Fe are assembled by, only dissolution process can be founded, the spread phenomena is unobvious, which is concerned with the formation of the inter- metallic compounds end the "deposition effect" of Fe. 展开更多
关键词 ti fe eutectic reaction dissolution spread
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