Improvement on the Oxidation Resistance of a Ti_3Al Based Alloy by Cr1-xAl_xN (0≤x≤0.47) Coatings

Cr1-xAlxN coatings have been deposited on a Ti3Al based alloy by reactive sputtering method. The results of the isothermal oxidation test at 800-900℃ showed that Cr1-xAlxN coatings could remarkably reduce the oxidation rate of the alloy owing to the formation of Al2O3＋Cr2O3 mixture oxide scale on the surface of the coatings. No spallation of the coatings or oxide scales took place during the cyclic oxidation at 800℃. Ti was observed to diffuse into the coatings, the diffusion distance of which was very short, and the diffusion ability of it was proportional to the AI content in the coatings. Compared to Ti, Nb can diffuse much more easily through the whole coatings and oxide scales.

Diffusion Bonding of Ti_3Al Base Alloy

: The effects of diffusion bonding temperature and holding time on the joint strength of Ti3Al base alloy has been investigated in this paper. The shear strength of Ti-14Al-21Nb-3Mo-V alloy diffusion bonding joint under pressure of 12 MPa at 990℃ for 70 min was obtained to 797.6 MPa which approaches the base material strength. In addition, a short-time diffosion bonding process was studied in order to decrease the bonding cost. With the deformation of the specimens of 2.5% and the bonding temperature of 990℃ for 15 min, the bonding strength could reach 801 MPa.

Effect of Cooling Rate on Microstructure of Alloy Ti_3Al-10Nb-3V-1Mo

The microstructure of alloy Ti 3Al 10Nb 3V 1Mo after heated at 1170℃ for 1 h and cooled to room temperature at different rates was investigated by TEM. The result showed that W.Q. microstructure consisted of single B2 phase, A.C. microstructure consisted of B2 phase matrix and second phase in some regions of the B2 phase crystal grains, and C.C. and F.C. microstructure appeared as a Widmannstatten structure consisting of coarse α 2 phase plates and β phase stripes between the plates. With the decreasing of colling rate, the tension strength was obviously decreased and the plasticity was slightly increased at room temperature.

Microstructure and Strength of Brazed Joints of Ti_(3)Al Base Alloy with Cu-P Filler Metal

Brazing of Ti3Al alloys with the filler metal Cu-P was carried out at 1173-1273 K for 60-1800 s. When products are brazed, the optimum brazing parameters are as follows： brazing temperature is 1215-1225 K; brazing time is 250-300 s. Four kinds of reaction products were observed during the brazing of Ti3Al alloys with the filler metal Cu-P, i.e., Ti3Al phase with a small quantity of Cu （Ti3Al（Cu）） formed close to the Ti3Al alloy; the TiCu intermetallic compounds layer and the Cu3P intermetallic compounds layer formed between Ti3Al（Cu） and the filler metal, and a Cu-base solid solution formed with the dispersed Cu3P in the middle of the joint. The interracial structure of brazed Ti3Al alloys joints with the filler metal Cu-P is Ti3Al/Ti3Al（Cu）/TiCu/Cu3P/Cu solid solution （Cu3P）/Cu3P/TiCu/Ti3Al（Cu）/Ti3Al, and this structure will not change with brazing time once it forms. The thickness of TiCu＋Cu3P intermetallic compounds increases with brazing time according to a parabolic law. The activation energy Q and the growth velocity/to of reaction layer TiCu＋Cu3P in the brazed joints of Ti3Al alloys with the filler metal Cu-P are 286 kJ/mol and 0.0821 m2/s, respectively, and growth formula was y2=O.O821exp（-34421.59/T）t.Careful control of the growth for the reaction layer TiCu＋Cu3P can influence the final joint strength. The formation of the intermetallic compounds TiCu＋Cu3P results in embrittlement of the joint and poor joint properties. The Cu-P filler metal is not fit for obtaining a high-quality joint of Ti3Al brazed.

Oxidation behavior of a novel multi-element alloyed Ti2AlNbbased alloy in temperature range of 650-850℃

The oxidation behavior of a novel multi-element alloyed Ti2A1Nb-based alloy （Ti-22Al-25Nb-1Mo-1V-1Zr-0.2Si） was studied in the temperature range of 650-850℃. X-ray diffraction （XRD） and scanning electron microscopy （SEM） equipped with an energy-dispersive spectroscopy （EDS） were used to identify the phase constituents and microstructure of the scales formed on the specimens after oxidation at different temperatures. Isothermal oxidation tests show that the oxidation rate of the alloyed TiEAlNb-based alloy is obviously reduced at all temperatures, and the mass gains are very low for this alloy in comparison with those of Ti-22Al-25Nb alloy. The alloying elements Mo, V, Zr and Si have an obvious affect on the oxidation products of the alloys. The improved oxidation resistance for the alloy is ascribed to the introduction of Mo, V, Zr and Si elements, which are beneficial to the selective oxidation of Al to form protective oxides while are disadvantage of the formation of poor oxidation resistance oxides such as AlNbO4.

Improvements in tribological and anticorrosion performance of porous Ti–6Al–4V via PEO coating

Medical implants manufactured using biomaterial Ti–6Al–4V exhibit some disadvantages.Its higher elastic modulus than that of natural bone can cause stress shielding problems.This can be avoided using Ti–6Al–4V with pores in the implant structure.However,poor corrosion and tribocorrosion behaviors are yielded because of the large area exposed to the medium.To mitigate both issues,coating technologies can be applied.The plasma electrolytic oxidation(PEO)process is a cost‐effective process that has been used successfully in nonporous Ti alloys.In this study,two PEO coatings with different amounts of Ca/P are used.However,reports regarding their application in porous materials are scarce.The effects of PEO treatments on corrosion and tribocorrosion in Ti–6Al–4V powder metallurgy are analyzed herein.The porous materials provide an efficient surface for PEO coatings,as demonstrated via scanning electron microscopy(SEM)and atomic force microscopy(AFM),and the porosity of the substrates improved the adherence of the coatings.The corrosion resistance measured via electrochemical impedance spectroscopy confirmed the beneficial effect of the coatings,particularly for long exposure time.The lower roughness,small pore size,and more compact film observed in the PEO–Ca/P sample resulted in favorable tribological and corrosion properties.