A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-Ir...A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-IrO_2-SnO_2/Ti anodes. The influences of electric current density, inlet liquid circulation flowrate, high gravity factor, sodium chloride concentration,and initial pH value on phenol degradation efficiency were investigated, with the optimal operating conditions determined. The results showed that under the optimal operating conditions covering a current density of 35 mA/cm^2, an inlet liquid circulation flowrate of 48 L/h, a high gravity factor of 20, a sodium chloride concentration of 8.5 g/L, an initial pH value of 6.5, a reaction time of 100 min, and an initial phenol concentration of 500 mg/L, the efficiency for removal of phenol reached 99.7%, which was improved by 10.4% as compared to that achieved in the normal gravity field. The tendency regarding the change in efficiency for removal of phenol, total organic carbon(TOC), and chemical oxygen demand(COD)over time was studied. The intermediates and degradation pathway of phenol were deduced by high performance liquid chromatography(HPLC).展开更多
The performance of BaC12-TiO2-SnO2 composite catalysts in oxidative coupling of methane reaction has been investigated. A series of BaC12-TiO2, BaC1E-SnO2, TiO2-SnO2, and BaC12-TiO2-SnO2 catalysts were prepared, and c...The performance of BaC12-TiO2-SnO2 composite catalysts in oxidative coupling of methane reaction has been investigated. A series of BaC12-TiO2, BaC1E-SnO2, TiO2-SnO2, and BaC12-TiO2-SnO2 catalysts were prepared, and characterized by BET, XRD, XPS, CO2-TPD and H2-TPR, respectively. The synergistic effect among BaC12, SnO2 and TiO2 compositions enhances the catalytic performance. The best C2 selectivity and ethylene yield are obtained on the catalyst with the equal molar amount of the three compositions （BaC12 ： TiO2 ： SnO2 molar ratio of 1 ： 1 ： 1）. The optimal reaction conditions are as follows： 800 ℃, 44 mL.min-1 for methane, 22 mL.min-1 for oxygen and a space velocity of 5000 mL-h-1 .g-1, and the C2H4 yield over the catalyst is 20.1% with the CH4 conversion of 43.8% and C2 selectivity of 53.3%.展开更多
基金financially supported by the Nature Science Foundation of China (Grant No.U1610106)the Nature Science Foundation of China (Grant No.21703208)
文摘A novel high gravity multi-concentric cylinder electrodes-rotating bed(MCCE-RB) was developed for the electrocatalytic degradation of phenol wastewater in order to enhance the mass transfer with the self-made RuO_2-IrO_2-SnO_2/Ti anodes. The influences of electric current density, inlet liquid circulation flowrate, high gravity factor, sodium chloride concentration,and initial pH value on phenol degradation efficiency were investigated, with the optimal operating conditions determined. The results showed that under the optimal operating conditions covering a current density of 35 mA/cm^2, an inlet liquid circulation flowrate of 48 L/h, a high gravity factor of 20, a sodium chloride concentration of 8.5 g/L, an initial pH value of 6.5, a reaction time of 100 min, and an initial phenol concentration of 500 mg/L, the efficiency for removal of phenol reached 99.7%, which was improved by 10.4% as compared to that achieved in the normal gravity field. The tendency regarding the change in efficiency for removal of phenol, total organic carbon(TOC), and chemical oxygen demand(COD)over time was studied. The intermediates and degradation pathway of phenol were deduced by high performance liquid chromatography(HPLC).
文摘The performance of BaC12-TiO2-SnO2 composite catalysts in oxidative coupling of methane reaction has been investigated. A series of BaC12-TiO2, BaC1E-SnO2, TiO2-SnO2, and BaC12-TiO2-SnO2 catalysts were prepared, and characterized by BET, XRD, XPS, CO2-TPD and H2-TPR, respectively. The synergistic effect among BaC12, SnO2 and TiO2 compositions enhances the catalytic performance. The best C2 selectivity and ethylene yield are obtained on the catalyst with the equal molar amount of the three compositions （BaC12 ： TiO2 ： SnO2 molar ratio of 1 ： 1 ： 1）. The optimal reaction conditions are as follows： 800 ℃, 44 mL.min-1 for methane, 22 mL.min-1 for oxygen and a space velocity of 5000 mL-h-1 .g-1, and the C2H4 yield over the catalyst is 20.1% with the CH4 conversion of 43.8% and C2 selectivity of 53.3%.
