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Laser processing effects on Ti−45Nb alloy surface,corrosive and biocompatible properties
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作者 I.CVIJOVIĆ-ALAGIĆ S.LAKETIĆ +5 位作者 M.MOMČILOVIĆ J.CIGANOVIĆ Đ.VELJOVIĆ J.BAJAT V.KOJIĆ M.RAKIN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2533-2551,共19页
The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatme... The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatment,(Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface.The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment.Nevertheless,the improved corrosion resistance after laser treatment was evident(the corrosion current density of the alloy before laser irradiation was 2.84×10^(−8)A/cm2,while that after laser treatment with 5 mJ was 0.65×10^(−8)A/cm2)and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer.Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability,morphology,and proliferation were also investigated.The Ti−45Nb alloy showed no cytotoxic effect.Moreover,cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment.The highest average cell viability of 115.37%was attained for the alloy laser-irradiated with 15 mJ.Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment. 展开更多
关键词 ti−45Nb alloy laser surface scanning electrochemical properties BIOCOMPAtiBILITY cell morphology
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递归法研究Pt对Ti合金腐蚀影响 被引量:1
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作者 刘贵立 《物理学报》 SCIE EI CAS CSCD 北大核心 2009年第5期3359-3363,共5页
采用递归法计算了Ti及Ti合金的电子态密度、环境敏感镶嵌能、费米能级和格位能等电子结构参量.计算发现Pt在晶体中环境敏感镶嵌能和格位能高于表面,从电子层面证实Pt易在Ti合金表面偏聚.偏聚在表面的Pt有序能为正值,故Pt以有序相(Pt与T... 采用递归法计算了Ti及Ti合金的电子态密度、环境敏感镶嵌能、费米能级和格位能等电子结构参量.计算发现Pt在晶体中环境敏感镶嵌能和格位能高于表面,从电子层面证实Pt易在Ti合金表面偏聚.偏聚在表面的Pt有序能为正值,故Pt以有序相(Pt与Ti的化合物)形式分布在合金表面.晶体表面Pt与Ti的化合物电极电位较低,它与Ti形成微电池.在腐蚀介质的作用下,Pt与Ti的化合物分解,Pt沉淀到晶体表面造成Pt在合金表面形成凹凸不平的Pt电催化层.Pt电催化层加强Ti钝化作用,从而提高了Ti合金的抗腐蚀能力. 展开更多
关键词 电子结构 ti合金表面 钝化
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