The microstructural evolution and precipitation location of the secondary phase of an as-cast Ti-25 V-15 Cr-0.3 Si titanium alloy were investigated via isothermal compression experiments and heat treatment. The averag...The microstructural evolution and precipitation location of the secondary phase of an as-cast Ti-25 V-15 Cr-0.3 Si titanium alloy were investigated via isothermal compression experiments and heat treatment. The average aspect（length-to-width） ratio, average area and size of the grains at different heat treatment temperatures and holding time were analyzed and the effects of deformation and annealing time on the grain area and size were considered. It was found that the grain size was strongly influenced by the height reduction and holding time. Grain growth was significant when annealing time increased from 10 min to 2 h at 950 °C and height reduction of 30%; however, grain growth was minimal at annealing time between 2 and 4 h. Many dispersion particles were observed to form in continuous chains; the precipitation location was confirmed to be along initial grain boundaries, and the dispersion particles were identified to be Ti5 Si3 phase by TEM.展开更多
The effect of heat treatment and thermal exposure on the microstructure and mechanical properties of non burning β titanium alloy Ti 25V 15Cr 2Al 0.2C (mass fraction, %) was investigated. It is found that the amount ...The effect of heat treatment and thermal exposure on the microstructure and mechanical properties of non burning β titanium alloy Ti 25V 15Cr 2Al 0.2C (mass fraction, %) was investigated. It is found that the amount of α precipitation in samples after solution treatment followed by air cooling increases with increasing solution temperature. After solution treatment, the alloy was subjected to two different heat treatments to stabilize the material. The results show that the single ageing treatment(700 ℃, 4 h, AC) leads to a large amount of α precipitation, while the triplex treatment(850 ℃, 2 h, FC+700 ℃, 6 h, FC+540 ℃, 6 h, AC) significantly suppresses the formation of α precipitates. It is more important that after long term exposure at 540 ℃(the expected application temperature) samples heat treated by the triplex treatment have markedly higher ductility than those given the single aging treatment. The intermetallic compound TiCr 2 is observed in samples after long term exposure, which further degrades the ductility of the alloy.展开更多
The Ti-35V-15Cr-0.05C (wt% is a new nonburning titanium alloy. The test for alloy combustibility was carried out by using CO2 laser. A 430 watt and 6mm diameter laser spot impinges directly on the sample within normal...The Ti-35V-15Cr-0.05C (wt% is a new nonburning titanium alloy. The test for alloy combustibility was carried out by using CO2 laser. A 430 watt and 6mm diameter laser spot impinges directly on the sample within normal atmospheric pressure and temperature. The results show that the ignition time of the nonburning titanium alloy is the longest in the eight examined titanium alloys, and is 3.5 times that of TC4 alloy. The ignition tempeerature of the nonburning alloy is 2991° C, and is higher than that of TC4 alloy by 1976°C. On the condition of high tempeerature and rich oxygen,the surface of alloy forms a melting layer which plays roles of oxygen insulation, heat insulation and burning products insulation. This is the mechanism of combustion resistance.展开更多
A new high throughput heat-treatment method with a continuous temperature gradient between 600 and 700 ？C was utilized on the Ti-5553 alloy（Ti-5 Al-5 Mo-5 V-3 Cr, mass fraction, %）. The temperature gradient was ind...A new high throughput heat-treatment method with a continuous temperature gradient between 600 and 700 ？C was utilized on the Ti-5553 alloy（Ti-5 Al-5 Mo-5 V-3 Cr, mass fraction, %）. The temperature gradient was induced by the variation of the axial section of sample, which was heated by the direct current. The variation of continuous cooling rates on the treated sample was realized by using the end quenching method. The microstructural evolution and mechanical properties under different heat treatment conditions were evaluated. The results show that the pseudo-spinodal decomposition of the alloy occurs at（617±1） ？C, and the size of the precipitated α phase is around 300 nm. Moreover, the highest microhardness is obtained after the heat treatment at the pseudo-spinodal decomposition temperature for 4 h. These indicate that the high throughput method is efficient and fast to determine the phase transformation temperature and corresponding microstructural evolution of alloys.展开更多
The texture evaluation of α2 phase in Ti-25Al-10Nb-3V-1Mo sheet during rolling and annealing has been investigated by means of microstructure observation and ODF analysis. From the weak initial {1010} (1210) and {000...The texture evaluation of α2 phase in Ti-25Al-10Nb-3V-1Mo sheet during rolling and annealing has been investigated by means of microstructure observation and ODF analysis. From the weak initial {1010} (1210) and {0001}(1210) textures a {1210}(1010) texture and a {0001}(uvtw)fibre texture are formed after cold rolling. The {0001} (1210) texture is also strengthened simultaneously. The activation process of slip systems is discussed concerning formation of the rolling texture. Because of the disappearance of {0001} (nvtw) fibre texture the primary recrystallization process should occur and the {1210}(1010) texture forms during annealing展开更多
Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the a...Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the amorphous and crystalline filler alloys as well as the joints brazed with them were investigated in details.Results showed that the amorphous filler alloy possessed narrower melting temperature interval,lower liquidus temperature and melting active energy compared with the crystalline filler alloy,and it also exhibited better brazeability on the surface of the Ti.47Al.2Nb.2Cr.0.15B alloy.The TiAl joints brazed with crystalline and amorphous filler alloys were composed of two interfacial reaction layers and a central brazed layer.Under the same conditions,the tensile strength of the joint brazed with the amorphous filler alloy was always higher than that with the crystalline filler alloy.The maxmium tensile strength of the joint brazed at 1273 K with the amorphous filler alloy reached 254 MPa.展开更多
基金Projects(51501122,51604181) supported by the National Natural Science Foundation of ChinaProject(20172009) supported by the Postdoctoral Sustentation Fund of Taiyuan University of Science and Technology,China+3 种基金Project(20132016) supported by the Research Fund for the Doctoral Program of Higher Education of ChinaProject(201501004-8) supported by the Jincheng Science and Technology Plan Project,ChinaProject(U1510131) supported by NSFC-Shanxi Coal-based Low-carbon United Fund and"Shanxi Young Scholars"Program,ChinaProject(201603D121010) supported by Key R&D Program of Shanxi Province,China
文摘The microstructural evolution and precipitation location of the secondary phase of an as-cast Ti-25 V-15 Cr-0.3 Si titanium alloy were investigated via isothermal compression experiments and heat treatment. The average aspect（length-to-width） ratio, average area and size of the grains at different heat treatment temperatures and holding time were analyzed and the effects of deformation and annealing time on the grain area and size were considered. It was found that the grain size was strongly influenced by the height reduction and holding time. Grain growth was significant when annealing time increased from 10 min to 2 h at 950 °C and height reduction of 30%; however, grain growth was minimal at annealing time between 2 and 4 h. Many dispersion particles were observed to form in continuous chains; the precipitation location was confirmed to be along initial grain boundaries, and the dispersion particles were identified to be Ti5 Si3 phase by TEM.
文摘The effect of heat treatment and thermal exposure on the microstructure and mechanical properties of non burning β titanium alloy Ti 25V 15Cr 2Al 0.2C (mass fraction, %) was investigated. It is found that the amount of α precipitation in samples after solution treatment followed by air cooling increases with increasing solution temperature. After solution treatment, the alloy was subjected to two different heat treatments to stabilize the material. The results show that the single ageing treatment(700 ℃, 4 h, AC) leads to a large amount of α precipitation, while the triplex treatment(850 ℃, 2 h, FC+700 ℃, 6 h, FC+540 ℃, 6 h, AC) significantly suppresses the formation of α precipitates. It is more important that after long term exposure at 540 ℃(the expected application temperature) samples heat treated by the triplex treatment have markedly higher ductility than those given the single aging treatment. The intermetallic compound TiCr 2 is observed in samples after long term exposure, which further degrades the ductility of the alloy.
文摘The Ti-35V-15Cr-0.05C (wt% is a new nonburning titanium alloy. The test for alloy combustibility was carried out by using CO2 laser. A 430 watt and 6mm diameter laser spot impinges directly on the sample within normal atmospheric pressure and temperature. The results show that the ignition time of the nonburning titanium alloy is the longest in the eight examined titanium alloys, and is 3.5 times that of TC4 alloy. The ignition tempeerature of the nonburning alloy is 2991° C, and is higher than that of TC4 alloy by 1976°C. On the condition of high tempeerature and rich oxygen,the surface of alloy forms a melting layer which plays roles of oxygen insulation, heat insulation and burning products insulation. This is the mechanism of combustion resistance.
基金Project(2014CB644002)supported by the National Basic Research and Development Project of ChinaProject(2015CX004)supported by the Innovation-driven Plan in Central South University,China
文摘A new high throughput heat-treatment method with a continuous temperature gradient between 600 and 700 ？C was utilized on the Ti-5553 alloy（Ti-5 Al-5 Mo-5 V-3 Cr, mass fraction, %）. The temperature gradient was induced by the variation of the axial section of sample, which was heated by the direct current. The variation of continuous cooling rates on the treated sample was realized by using the end quenching method. The microstructural evolution and mechanical properties under different heat treatment conditions were evaluated. The results show that the pseudo-spinodal decomposition of the alloy occurs at（617±1） ？C, and the size of the precipitated α phase is around 300 nm. Moreover, the highest microhardness is obtained after the heat treatment at the pseudo-spinodal decomposition temperature for 4 h. These indicate that the high throughput method is efficient and fast to determine the phase transformation temperature and corresponding microstructural evolution of alloys.
文摘The texture evaluation of α2 phase in Ti-25Al-10Nb-3V-1Mo sheet during rolling and annealing has been investigated by means of microstructure observation and ODF analysis. From the weak initial {1010} (1210) and {0001}(1210) textures a {1210}(1010) texture and a {0001}(uvtw)fibre texture are formed after cold rolling. The {0001} (1210) texture is also strengthened simultaneously. The activation process of slip systems is discussed concerning formation of the rolling texture. Because of the disappearance of {0001} (nvtw) fibre texture the primary recrystallization process should occur and the {1210}(1010) texture forms during annealing
基金Foundation item:Project(51865012)supported by the National Natural Science Foundation of ChinaProject(2016005)supported by the Open Foundation of National Engineering Research Center of Near-net-shape Forming for Metallic Materials,China+2 种基金Project(GJJ170372)supported by the Science Foundation of Educational Department of Jiangxi Province,ChinaProject(JCKY2016603C003)supported by the GF Basic Research Project,ChinaProject(JPPT125GH038)supported by the Research Project of Special Furnishment and Part,China
文摘Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the amorphous and crystalline filler alloys as well as the joints brazed with them were investigated in details.Results showed that the amorphous filler alloy possessed narrower melting temperature interval,lower liquidus temperature and melting active energy compared with the crystalline filler alloy,and it also exhibited better brazeability on the surface of the Ti.47Al.2Nb.2Cr.0.15B alloy.The TiAl joints brazed with crystalline and amorphous filler alloys were composed of two interfacial reaction layers and a central brazed layer.Under the same conditions,the tensile strength of the joint brazed with the amorphous filler alloy was always higher than that with the crystalline filler alloy.The maxmium tensile strength of the joint brazed at 1273 K with the amorphous filler alloy reached 254 MPa.
