The effect of V on the high temperature deformation behavior has been investigated by using double-notch shear test.The experiment results revealed that the V additive can improve the ambient temperature ductility and...The effect of V on the high temperature deformation behavior has been investigated by using double-notch shear test.The experiment results revealed that the V additive can improve the ambient temperature ductility and decrease the ductile-brittle transition temperature.The strength of TiAl compound with the additive of V increases with the increase of temperature up to the peak value at 700℃ approximately.展开更多
Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic c...Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic compound was investigated. The kinetic equation for the cyclic oxidation of porous TiAl alloy at 600 ℃ is determined to be △m2=1.08×10-5t. After total oxidation of 140 h, porous TiAl intermetallic compound shows more stability of pore structure and the mass gain of TiAl alloy is 0.042 g/m2, which is only 10.6% that of porous 316L stainless steel. The kinetic equation for the cyclic corrosion behavior of porous TiAl alloy in hydrochloric acid with pH=2 at 90 ℃ is determined to be △m2=5.41×10-5t-2.08×10-4. After 50 h exposure, the mass loss of TiAl alloy is 0.049 g/m2, which is only 14.8% and 5.57% that of porous Ti and stainless steel, respectively. The kinetic equation in hydrochloric acid with pH=3 is determined to be △m2=2.63×10-6t-3.72×10-6.展开更多
Plastic deformation of TiAI and TiAI-V intermetallic compounds has been studied by com- pression experiment at various temperatures and strain rates.Results show that the plastic deformation in distinct temperature ra...Plastic deformation of TiAI and TiAI-V intermetallic compounds has been studied by com- pression experiment at various temperatures and strain rates.Results show that the plastic deformation in distinct temperature range is principally controlled by the mechanisms of Peierls-Nabarro,cross slip and creep of dislocations.For TiAI-V alloy deformed at a range of 600—700 K,the negative strain rate dependence of flow stress was observed,i.e.,the more the plastic strain is.the more the negative dependence will be.A possible mechanism of the anomaly could be interpreted by thermal activation of dislocation cross slipping.The effects of temperature and strain rate on work-hardening exponent were also studied and discussed.展开更多
A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using ...A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using the DV-Xα cluster method The bond orders between alloying elements and surrounding atoms, Bo_Ti,Bo_Al, are used as parameters. Two lines on the Bo_Ti-Bo_Al diagram separate the elements into three groups. The elements located outside of the two lines substitute either Ti or Al atom regardless of the composition of TiAl. The substitution behavior of elements between the two lines will be affected by the Ti/Al ratio and the amount of alloying elements added Substituting sequence in multi-element alloy is discussed The prediction based on this method agrees well with the experimental results.展开更多
文摘The effect of V on the high temperature deformation behavior has been investigated by using double-notch shear test.The experiment results revealed that the V additive can improve the ambient temperature ductility and decrease the ductile-brittle transition temperature.The strength of TiAl compound with the additive of V increases with the increase of temperature up to the peak value at 700℃ approximately.
基金Projects(20636020, 20476106 and 50825102) supported by the National Natural Science Foundation of ChinaProject(2003CB615707) supported by the National Basic Research Program of China+1 种基金Project(2006AA03Z511) supported by the Hi-tech Research and Development Program of ChinaProject(50721003) supported by the Creative Research Group of National Natural Science Foundation of China
文摘Porous TiAl intermetallic compound, as a novel substitute for current inorganic porous material, offsets the shortages of both ceramics and metals. The environmental corrosion resistance of porous TiAl intermetallic compound was investigated. The kinetic equation for the cyclic oxidation of porous TiAl alloy at 600 ℃ is determined to be △m2=1.08×10-5t. After total oxidation of 140 h, porous TiAl intermetallic compound shows more stability of pore structure and the mass gain of TiAl alloy is 0.042 g/m2, which is only 10.6% that of porous 316L stainless steel. The kinetic equation for the cyclic corrosion behavior of porous TiAl alloy in hydrochloric acid with pH=2 at 90 ℃ is determined to be △m2=5.41×10-5t-2.08×10-4. After 50 h exposure, the mass loss of TiAl alloy is 0.049 g/m2, which is only 14.8% and 5.57% that of porous Ti and stainless steel, respectively. The kinetic equation in hydrochloric acid with pH=3 is determined to be △m2=2.63×10-6t-3.72×10-6.
文摘Plastic deformation of TiAI and TiAI-V intermetallic compounds has been studied by com- pression experiment at various temperatures and strain rates.Results show that the plastic deformation in distinct temperature range is principally controlled by the mechanisms of Peierls-Nabarro,cross slip and creep of dislocations.For TiAI-V alloy deformed at a range of 600—700 K,the negative strain rate dependence of flow stress was observed,i.e.,the more the plastic strain is.the more the negative dependence will be.A possible mechanism of the anomaly could be interpreted by thermal activation of dislocation cross slipping.The effects of temperature and strain rate on work-hardening exponent were also studied and discussed.
文摘A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using the DV-Xα cluster method The bond orders between alloying elements and surrounding atoms, Bo_Ti,Bo_Al, are used as parameters. Two lines on the Bo_Ti-Bo_Al diagram separate the elements into three groups. The elements located outside of the two lines substitute either Ti or Al atom regardless of the composition of TiAl. The substitution behavior of elements between the two lines will be affected by the Ti/Al ratio and the amount of alloying elements added Substituting sequence in multi-element alloy is discussed The prediction based on this method agrees well with the experimental results.
