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TiO_2/polyaniline composites:An efficient photocatalyst for the degradation of methylene blue under natural light 被引量:10
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作者 Fang Wang Shi Xiong Min 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第10期1273-1277,共5页
Polyaniline (PAn) sensitized nanocrystalline TiO2 composites (TiO2/PAn) were successfully prepared and used as an efficient photocatalyst for the degradation of dye methylene blue (MB). The results showed that P... Polyaniline (PAn) sensitized nanocrystalline TiO2 composites (TiO2/PAn) were successfully prepared and used as an efficient photocatalyst for the degradation of dye methylene blue (MB). The results showed that PAn was able to sensitize TiO2 efficiently and the composite photocatalyst could be activated by absorbing both the ultraviolet and visible light (λ: 190 ~ 800 nm), whereas pure TiO2 absorbed ultraviolet light only (λ 〈 380 nm). Under the irradiation of natural light, MB could be degraded more efficiently on the TiO2/PAn composites than on the TiO2 Furthermore, it could be easily separated from the solution by simple sedimentation. 展开更多
关键词 tio2/PAn composite photocatalyst methylene blue degradation natural light
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Synthesis and photocatalytic activity of TiO_2/conjugated polymer complex nanoparticles 被引量:2
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作者 Shi Xiong Min Fang Wang Lei Feng Yong Chun Tong Zi Rong Yang 《Chinese Chemical Letters》 SCIE CAS CSCD 2008年第6期742-746,共5页
A photocatalyst of nanometer TiO2/conjugated polymer complex was successfully synthesized and characterized by spectroscopic methods and photocatalytic experiments. The complex photocatalyst could be activated by abso... A photocatalyst of nanometer TiO2/conjugated polymer complex was successfully synthesized and characterized by spectroscopic methods and photocatalytic experiments. The complex photocatalyst could be activated by absorbing both ultraviolet and visible light (λ = 190-800 nm). Methylene blue (MB) could be degraded more efficiently on the complex photocatalyst than on the TiO2 under natural light. The conjugated polymer played a promoting role in the photocatalytic degradation of MB. The calcination temperature had an important effect in degradation of dye and could be summarized as 260℃ 〉 300 ℃ 〉 340 ℃ 〉 220 ℃ 〉 180 ℃. 展开更多
关键词 tio2 conjugated polymer Complex photocatalyst methylene blue degradation natural light
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TiO_2/共轭高分子纳米复合材料在自然光下的光催化性能 被引量:3
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作者 敏世雄 王芳 +4 位作者 安红钢 吴冬青 韩玉琦 冯雷 佟永纯 《应用化学》 CAS CSCD 北大核心 2009年第4期409-412,共4页
以PVC和TiCl4为原料,利用溶胶-凝胶法制备了复合光催化剂前驱物,经260℃热处理后得到了TiO2/共轭高分子(CP)纳米复合光催化剂材料。通过亚甲基蓝的光催化降解研究了该催化剂的催化性能,并用TEM、XRD、IR和UV-Vis等测试技术对复合材料... 以PVC和TiCl4为原料,利用溶胶-凝胶法制备了复合光催化剂前驱物,经260℃热处理后得到了TiO2/共轭高分子(CP)纳米复合光催化剂材料。通过亚甲基蓝的光催化降解研究了该催化剂的催化性能,并用TEM、XRD、IR和UV-Vis等测试技术对复合材料的结构进行了表征。结果表明,在自然光作用下,当焙烧温度为260℃并且TiO2的质量分数为66.36%,复合催化剂在15 min内可使亚甲基蓝的降解率接近80%,催化活性优于纯TiO2。复合材料颗粒平均尺寸约30 nm,其中TiO2为锐钛矿型结构。CP与TiO2复合后能吸收紫外-可见区的全程光波(λ为190-800 nm),对光生电荷具有很高的分离能力,从而表现出较高的催化活性。 展开更多
关键词 tio2/共轭高分子 纳米复合微粒 自然光 亚甲基蓝 降解
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