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非晶态TiO_2-W薄膜的光催化性能研究 被引量:6
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作者 黄佳木 赵国栋 +1 位作者 蔡小平 董晓霞 《环境科学学报》 CAS CSCD 北大核心 2006年第4期620-625,共6页
采用磁控溅射技术在玻璃基片上制备了W掺杂的非晶态TiO2薄膜,用XRD、XPS和椭圆偏光测厚仪等对薄膜进行了微观分析.结果表明,TiO2-W薄膜为非晶态结构.Ti以+4价存在;W以0价和+6价形式存在,并且6价和0价W的原子浓度比为6.4∶1;薄膜中Ti和W... 采用磁控溅射技术在玻璃基片上制备了W掺杂的非晶态TiO2薄膜,用XRD、XPS和椭圆偏光测厚仪等对薄膜进行了微观分析.结果表明,TiO2-W薄膜为非晶态结构.Ti以+4价存在;W以0价和+6价形式存在,并且6价和0价W的原子浓度比为6.4∶1;薄膜中Ti和W的原子浓度比为2.6∶1.对5mg·L-1的亚甲基蓝溶液光催化脱色试验表明,随着膜厚的增加,光催化降解率递增,当膜厚达到141nm时,所制备的TiO2-W薄膜对亚甲基蓝的脱色率在2h达到90%;当膜厚大于141nm时,光催化降解率不再增加. 展开更多
关键词 磁控溅射 tio2-w薄膜 光催化 薄膜厚度
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Photocatalytic degradation characteristic of amorphous TiO_2-W thin films deposited by magnetron sputtering
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作者 黄佳木 李月霞 +1 位作者 赵国栋 蔡小平 《中国有色金属学会会刊:英文版》 CSCD 2006年第B01期280-284,共5页
TiO2-W films were deposited on the slides by reactive magnetron sputtering. Properties of the films were analyzed via AFM, XRD, XPS, STS, UV-Vis and ellipse polarization apparatus. The results show that TiO2-W films a... TiO2-W films were deposited on the slides by reactive magnetron sputtering. Properties of the films were analyzed via AFM, XRD, XPS, STS, UV-Vis and ellipse polarization apparatus. The results show that TiO2-W films are amorphous. The AFM map reveals that the surface of the film is tough and porous. The experiments of decomposing methylene blue indicate that the thickness threshold on these films is 141 nm, at which the rate of photodegradation is 90% in 2 h. And when the thickness is over 141 nm, the rate of photodegradation does not increase any more. This result is completely different from that of crystalloid TiO2 thin film. 展开更多
关键词 非晶态tio2-w薄膜 磁控管溅射法 沉积 光催化剂 光催化降解特性
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