B_(4)C-SiC-TiB_(2)ceramics were prepared by in situ reactive hot-pressing sintering with TiSi_(2)as an additive.The reaction pathways of TiSi_(2)and B_(4)C were investigated.The sintering was found to be a multistep p...B_(4)C-SiC-TiB_(2)ceramics were prepared by in situ reactive hot-pressing sintering with TiSi_(2)as an additive.The reaction pathways of TiSi_(2)and B_(4)C were investigated.The sintering was found to be a multistep process.The reaction started at approximately 1000℃,and TiB_(2)was formed first.Part of Si and C started to react at 1300℃,and the unreacted Si melted at 1400℃to form a liquid phase.TiSi_(2)predominantly affected the intermediate sintering process of B_(4)C and increased the sintering rate.Due to the unique reaction process of TiSi_(2)and B_(4)C,a large number of aggregates composed of SiC and TiB_(2)were generated.The results showed that composite ceramics with the optimal flexural strength of 807 MPa,fracture toughness of 3.2 MPa·m1/2,and hardness of 32 GPa,were obtained when the TiSi_(2)content was 10 wt%.展开更多
本文报道了在SIMOX(Separation by IMPlanted Oxygen)薄膜材料上制备钛硅化物的研究结果。研究表明,不同厚度的SIMOX薄膜材料上都形成了均匀的TiSi_2,其薄层电阻为4.0—4.5Ω/□,上层Si中的载流子峰值浓度达2×10^(20)/cm^3,获得了...本文报道了在SIMOX(Separation by IMPlanted Oxygen)薄膜材料上制备钛硅化物的研究结果。研究表明,不同厚度的SIMOX薄膜材料上都形成了均匀的TiSi_2,其薄层电阻为4.0—4.5Ω/□,上层Si中的载流子峰值浓度达2×10^(20)/cm^3,获得了一种TiSi_2/n^+-Si/SiO_2/Si的多层结构。形成TiSi_2后,As原子在上层Si中的分布与SIMOX薄膜厚度有关,当上层Si很薄时,As原子在上层Si与SiO_2埋层的界面上的堆积是明显的。展开更多
TiSi_(2) reinforced boron phenolic composites(TP)and Vitreous silica fabric reinforced TiSi_(2)/boron phenolic composites(VTP)were prepared by compression molding,and their thermal,mechanical,ablation properties were ...TiSi_(2) reinforced boron phenolic composites(TP)and Vitreous silica fabric reinforced TiSi_(2)/boron phenolic composites(VTP)were prepared by compression molding,and their thermal,mechanical,ablation properties were studied.TG results show that thermal stabilities and residual carbon rate of boron phenolic are improved after introducing TiSi_(2) particles.Compared with VTP-0(containing 0 phr TiSi_(2)),flexural strength of VTP-60(containing 60 phr TiSi_(2))pyrolysis product increases by 29.5%at 1200℃.Raman spectrum shows that TiSi_(2) particles promote the ordering of the glass carbon structure of VTP pyrolysis product.Compared to VTP-0,the linear and mass ablation rates of VTP-60 reduce by 32.1%and 77.5%,respectively.XRD and SEM indicate the formation of an oxide coating layer,TiO_(2)-SiO_(2),integrates the bulk and protects the underlying materials from damage under high temperature oxygen-containing airstream.All these results prove that mechanical properties of pyrolysis product,thermal,and ablation resistance are improved by addition of TiSi_(2) particles.展开更多
X-ray diffraction studies of synthesized Ba_(2)TiSi_(2)O_(8) have shown that this compound has a fresnoite structure and is characterized by a polar phase P4bm at room temperature.The synthesis of Pb_(2)TiSi_(2)O_(8) ...X-ray diffraction studies of synthesized Ba_(2)TiSi_(2)O_(8) have shown that this compound has a fresnoite structure and is characterized by a polar phase P4bm at room temperature.The synthesis of Pb_(2)TiSi_(2)O_(8) in the fresnoite phase under the selected synthesis conditions has led to the formation of a perovskite tetragonal phase P4mm corresponding to PbTiO_(3).展开更多
基金Funded by the National Natural Science Foundation of China(No.52002299)。
文摘B_(4)C-SiC-TiB_(2)ceramics were prepared by in situ reactive hot-pressing sintering with TiSi_(2)as an additive.The reaction pathways of TiSi_(2)and B_(4)C were investigated.The sintering was found to be a multistep process.The reaction started at approximately 1000℃,and TiB_(2)was formed first.Part of Si and C started to react at 1300℃,and the unreacted Si melted at 1400℃to form a liquid phase.TiSi_(2)predominantly affected the intermediate sintering process of B_(4)C and increased the sintering rate.Due to the unique reaction process of TiSi_(2)and B_(4)C,a large number of aggregates composed of SiC and TiB_(2)were generated.The results showed that composite ceramics with the optimal flexural strength of 807 MPa,fracture toughness of 3.2 MPa·m1/2,and hardness of 32 GPa,were obtained when the TiSi_(2)content was 10 wt%.
文摘本文报道了在SIMOX(Separation by IMPlanted Oxygen)薄膜材料上制备钛硅化物的研究结果。研究表明,不同厚度的SIMOX薄膜材料上都形成了均匀的TiSi_2,其薄层电阻为4.0—4.5Ω/□,上层Si中的载流子峰值浓度达2×10^(20)/cm^3,获得了一种TiSi_2/n^+-Si/SiO_2/Si的多层结构。形成TiSi_2后,As原子在上层Si中的分布与SIMOX薄膜厚度有关,当上层Si很薄时,As原子在上层Si与SiO_2埋层的界面上的堆积是明显的。
基金Funded by the Joint Foundation for Pre-research Equipment of the Ministry of Education,China(Nos.6141A02022208 and 6141A02022250)the Fundamental Research Funds for the Central Universities(WUT,2021III005GX)。
文摘TiSi_(2) reinforced boron phenolic composites(TP)and Vitreous silica fabric reinforced TiSi_(2)/boron phenolic composites(VTP)were prepared by compression molding,and their thermal,mechanical,ablation properties were studied.TG results show that thermal stabilities and residual carbon rate of boron phenolic are improved after introducing TiSi_(2) particles.Compared with VTP-0(containing 0 phr TiSi_(2)),flexural strength of VTP-60(containing 60 phr TiSi_(2))pyrolysis product increases by 29.5%at 1200℃.Raman spectrum shows that TiSi_(2) particles promote the ordering of the glass carbon structure of VTP pyrolysis product.Compared to VTP-0,the linear and mass ablation rates of VTP-60 reduce by 32.1%and 77.5%,respectively.XRD and SEM indicate the formation of an oxide coating layer,TiO_(2)-SiO_(2),integrates the bulk and protects the underlying materials from damage under high temperature oxygen-containing airstream.All these results prove that mechanical properties of pyrolysis product,thermal,and ablation resistance are improved by addition of TiSi_(2) particles.
基金supported by the Ministry of Science and Higher Education of the Russian Federation(State assignment in the field of scientific activity,Southern Federal University,2020).
文摘X-ray diffraction studies of synthesized Ba_(2)TiSi_(2)O_(8) have shown that this compound has a fresnoite structure and is characterized by a polar phase P4bm at room temperature.The synthesis of Pb_(2)TiSi_(2)O_(8) in the fresnoite phase under the selected synthesis conditions has led to the formation of a perovskite tetragonal phase P4mm corresponding to PbTiO_(3).
