Spinodal phase separation behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends was investigated by the time-resolved small angle light scattering (SALS) technique. It was found that t...Spinodal phase separation behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends was investigated by the time-resolved small angle light scattering (SALS) technique. It was found that the influence of temperature on the scattering intensity evolution followed the time-temperature superposition principle. The relationship between temperature and the relaxation ti me of scattering intensity I(t) can be well described by the Williams-Landel-Ferry (WLF) function.展开更多
Using the time-temperature superposition principle, the dynamic properties of viscoelastic materials can be shifted to obtain a master curve. A shifting method based on the Generalized Maxwell Model （ GMMBS ） , is p...Using the time-temperature superposition principle, the dynamic properties of viscoelastic materials can be shifted to obtain a master curve. A shifting method based on the Generalized Maxwell Model （ GMMBS ） , is proposed for the time-temperature superposition process of thermo-rheological simple, linear viscoelastic materials. Experimental data points under different temperatures are all considered as a whole and expressed with one unified representation by the GMMBS, which utilizes the feature that the Generalized Maxwell Model can describe a large class of viscoelastic materials with needed accuracy. Compared with traditional overlapping window based shifting methods, the proposed constitutive model based method needn＇t judge the size or existence of the overlapping window first, and computes shift factors with useful information contained in all experimental data points. The effectiveness of the proposed method is verified by simulated data, generated from published test results, with various experimental noise levels, densities of data points and sizes of overlapping windows. It has been shown that the GMMBS is robust and accurate.展开更多
基金This work was supported by the Special Funds for Major State Basic Research Projects (Grand G1999064800)
文摘Spinodal phase separation behavior of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) (PMMA/SAN) blends was investigated by the time-resolved small angle light scattering (SALS) technique. It was found that the influence of temperature on the scattering intensity evolution followed the time-temperature superposition principle. The relationship between temperature and the relaxation ti me of scattering intensity I(t) can be well described by the Williams-Landel-Ferry (WLF) function.
基金supported by the National Science and Technology Major Project through the contract 2010zx04008-041
文摘Using the time-temperature superposition principle, the dynamic properties of viscoelastic materials can be shifted to obtain a master curve. A shifting method based on the Generalized Maxwell Model （ GMMBS ） , is proposed for the time-temperature superposition process of thermo-rheological simple, linear viscoelastic materials. Experimental data points under different temperatures are all considered as a whole and expressed with one unified representation by the GMMBS, which utilizes the feature that the Generalized Maxwell Model can describe a large class of viscoelastic materials with needed accuracy. Compared with traditional overlapping window based shifting methods, the proposed constitutive model based method needn＇t judge the size or existence of the overlapping window first, and computes shift factors with useful information contained in all experimental data points. The effectiveness of the proposed method is verified by simulated data, generated from published test results, with various experimental noise levels, densities of data points and sizes of overlapping windows. It has been shown that the GMMBS is robust and accurate.
