The transmetallation reaction of 4 Schiff base type arylmercury compounds with metallic tin has been carried out in refluxing xylene.It was found that the reaction proceeds in the same manner as that of chloro[2-(phen...The transmetallation reaction of 4 Schiff base type arylmercury compounds with metallic tin has been carried out in refluxing xylene.It was found that the reaction proceeds in the same manner as that of chloro[2-(phenylazo)phenyl]mercury(Ⅱ) to give dichlorobisaryltin(Ⅳ).The ~1H NMR spectra of the products provide evidence for the presence of N→Sn intramolecular coordination.The formation of dichlorobisaryltin(Ⅳ)as a unique product probably arises from the N→Sn intramolecular coordination which results in the increasing of the stability of the molecule.展开更多
China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.F...China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.From the aspect of exploitation and utilization,the most important types are cassiterite-sulfide type and quartz vein type.The cassiterite-sulfide type tin deposits are mainly located in Northern Guangxi and Eastern Yunnan,skarn type deposits are mainly distributed in the ore-concentration areas of South Hunan in Middle Nanling,and the quartz vein type tin deposits are mainly distributed in South China,such as Western Fujian,Middle Jiangxi,Northern Guangzhou and Southern Hunan.The most important metallogenic epoch for tin deposits is the Mesozoic era.The metallogenic geotectonic background is mainly continental environments after orogeny process,with strong tectonic changes,interlaced deep fracture and frequent magmatism.And the most distinctive feature is the well developed Mesozoic granites,which have a close relationship with tin mineralization.Based on the detailed study of the data from 873 tin deposits in China,this paper summarized the metallogenic regularity of tin deposits,classified 20 important metallogenic series of tin or tin-associated deposits,and inferred that the cassiterite-sulfide type,skarn type,quartz vein type and greisen type are the main prediction types of tin resources.Forty-four tin-mineralization belts were divided,among which,19 belts are the most important.In addition,a series of maps about tin metallogenic belts and tin metallogenic regularity were compiled,aiming to provide theoretical basis for potential estimation and prediction of tin mineral resources.展开更多
文摘The transmetallation reaction of 4 Schiff base type arylmercury compounds with metallic tin has been carried out in refluxing xylene.It was found that the reaction proceeds in the same manner as that of chloro[2-(phenylazo)phenyl]mercury(Ⅱ) to give dichlorobisaryltin(Ⅳ).The ~1H NMR spectra of the products provide evidence for the presence of N→Sn intramolecular coordination.The formation of dichlorobisaryltin(Ⅳ)as a unique product probably arises from the N→Sn intramolecular coordination which results in the increasing of the stability of the molecule.
基金supported by the National Natural Science Foundation(grant No.41202025,41302058)Funds on basic researches for central public welfare academic institutes(grant No.K1325 and YK1401)the China Geological Survey Project(Nos.1212011220369, 1212010633903,12120114039601 and 12120114019401)
文摘China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.From the aspect of exploitation and utilization,the most important types are cassiterite-sulfide type and quartz vein type.The cassiterite-sulfide type tin deposits are mainly located in Northern Guangxi and Eastern Yunnan,skarn type deposits are mainly distributed in the ore-concentration areas of South Hunan in Middle Nanling,and the quartz vein type tin deposits are mainly distributed in South China,such as Western Fujian,Middle Jiangxi,Northern Guangzhou and Southern Hunan.The most important metallogenic epoch for tin deposits is the Mesozoic era.The metallogenic geotectonic background is mainly continental environments after orogeny process,with strong tectonic changes,interlaced deep fracture and frequent magmatism.And the most distinctive feature is the well developed Mesozoic granites,which have a close relationship with tin mineralization.Based on the detailed study of the data from 873 tin deposits in China,this paper summarized the metallogenic regularity of tin deposits,classified 20 important metallogenic series of tin or tin-associated deposits,and inferred that the cassiterite-sulfide type,skarn type,quartz vein type and greisen type are the main prediction types of tin resources.Forty-four tin-mineralization belts were divided,among which,19 belts are the most important.In addition,a series of maps about tin metallogenic belts and tin metallogenic regularity were compiled,aiming to provide theoretical basis for potential estimation and prediction of tin mineral resources.
基金supported by the National Natural Science Foundation of China(No.92162103)the Natural Science Foundation of Hunan Province,China(No.2022JJ30699)+1 种基金the Science and Technology Innovation Program of Hunan Province,China(No.2021RC4055)the Open Research Project from the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(No.GPMR202112)。
