Effect of Black Plate on Corrosion Resistance of T5 Tinplate

The effect of black plate on corrosion resistance of T5 tinplate was studied by glow discharge spectrograph, X-ray diffractometer （XRD）, stress tester, roughness tester and metallographic microscope. The result shows that black plate influences corrosion resistance of T5 tinplate intensely. It also indicates that the increase of content of manganese, phosphorus, silicon and aluminum in black plate would reduce the corrosion resistance of T5 tinplate and the increase of degree of crystal orientation on （200） crystal face, ｜X-Y｜ value （internal stress difference within two orientation）, roughness and exposure degree of iron grain after the same acid wash of black plate would enhance the corrosion resistance of T5 tinplate and the grain number of black plate has small effect on corrosion resistance of T5 tinplate.

Crystallographic texture and earing behavior analysis for different second cold reductions of double-reduction tinplate

Since the production of tinplate with non-earing properties is difficult, especially when it is produced via the double-reduction process, the optimal degree of second cold reduction is particularly important for achieving desirable drawing properties. The evolution of texture and the earing propensity of double-reduction tinplate with different extents of second reduction were investigated in this study. Optical microscopy and scanning electron microscopy were used to observe the changes in the microstructure at various extents of reduction. Two common testing methods, X-ray diffraction（XRD） and electron backscatter diffraction, were used to investigate the texture of the specimens, which revealed the effects of deformation percentage on the final texture development and the change in the grain boundary. The earing rate was determined via earing tests involving measurement of the height of any ear. The results obtained from both XRD analyses and earing tests revealed the same ideal value for the second cold reduction on the basis of the relationship between crystallographic texture and the degree of earing.

Degradation Mechanism of Lacquered Tinplate in Energy Drink by in-situ EIS and EN

The corrosion process of phenolic epoxy coated tinplate in energy drink was investigated by in-situ electrochemical impedance spectroscopy（EIS） and electrochemical noise（EN） techniques. The experimental results indicate that the degradation process of novolac epoxy coated tinplate in energy drink can be divided into three main stages： organic coating wetted by the beverage; corrosion initiation beneath the organic coating; and corrosion extension process. It was proposed that the tin coating and carbon steel were mainly corroded by organic acids in energy drink through the pores of the organic coating. After the tin coating was corroded, the carbon steel started to corrode due to its higher electrochemical activity and became to be the dominated corrosion reaction.

Influence of reflow processing conditions on the uniformity of the chromium passivation film on tinplate

This study aims to systematically analyze the key parameters of the reflow process that influence the uniformity of the chromium passivation film coated on tinplate. The distribution characteristics of the chromium passivation film coated on the tinplate surface under different treatment conditions were systematically characterized using the scanning Kelvin probe technique, X-ray photoelectron spectroscopy, and X-ray diffraction. Results indicate that the use of flux reduces the porosity of tin coating, thereby favoring the uniform growth of the passivation film. Furthermore, an increase in the reflow power and quenching temperature facilitates the homogeneous distribution of the passivation film on the tinplate surface,particularly when treated with electrolytic cathodic sodium dichromate.

Smudge on tinplate steel sheets and the effects of cathodic dichromate treatment

Smudge is black granules that scatter on tinplate sheet; it was formed during the process of plating and storing, and seriously affected the function and appearance of tinplate sheet. Reflowing and cathodic dichromate treatment (CDC) are two major phases in which smudge is produced. In this paper, the appearance and component of smudge was analyzed by means of whiteness meter, SEM and EDS quantitatively. Factors of CDC conditions was studied. Results of tests showed that whiteness measurement is convenient to evaluation of the degree of smudge and the effects of CDC on it , quantitatively.

Evaluation on the contribution of steel products to environmental improvement from LCA perspectives

High functionality given to steel products results in an increase of environmental loads in the steelmaking stage. However, at the stage of their utilization, the high-functional steel products prove to be more environmentally friendly than their conventional counterparts in many cases. In view of this contradiction, the evaluation on the contribution of steel products to environmental improvement requires a more integrated approach--Life Cycle Assessment （ LCA ）, which incorporates the effects over the products＇ entire life cycles. This paper discusses the relationship between the improvement of steel products＇ performance and the according environmental impact from the entire life cycle perspectives. How to evaluate and assess the contribution of high-functional steel products to environmental improvement using LCA method is explained in detail. Two case studies of Baosteel are given to substantiate the effectiveness of LCA as a scientific and systematic method for eco-material evaluation or eco-design： @ For a power transformer, by replacing silicon steel B30G130 with B30Pll0,the carbon dioxide emissions were reduced by 15.1% over the life cycle of the transformer. @ Tinplate steel of Baosteel used for two-piece steel cans experienced six reductions in thickness from 0.28 mm to 0.225 mm,which results in a 14.5% emission reduction over the life cycle of two-piece steel cans.