Tetragonal barium titanate was synthesized from barium hydroxide octahydrate and titanium tetrachloride through a simple one-step hydrothermal method.The effect of different solvents on the crystal structure and morph...Tetragonal barium titanate was synthesized from barium hydroxide octahydrate and titanium tetrachloride through a simple one-step hydrothermal method.The effect of different solvents on the crystal structure and morphology of barium titanate nanoparticles during the hy-drothermal process was investigated.Except for ethylene glycol/water solvent,impurity-free barium titanate was synthesized in pure water,methanol/water,ethanol/water,and isopropyl alcohol/water mixed solvents.Compared with other alcohols,ethanol promotes the formation of a tetragonal structure.In addition,characterization studies confirm that particles synthesized in methanol/water,ethanol/water,and isopropyl al-cohol/water mixed solvents are smaller in size than those synthesized in pure water.In the case of alcohol-containing solvents,the particle size decreases in the order of isopropanol,ethanol,and methanol.Among all the media used in this study,ethanol/water is considered the optimum reaction media for barium titanate with high tetragonality(defined as the ratio of two lattice parameters c and a,c/a=1.0088)and small aver-age particle size(82 nm),which indicates its great application potential in multilayer ceramic capacitors.展开更多
This is the first time that a novel anode material, spinel Li4Ti5O12 which is well known as a "zero-strain" anode material for lithium storage, has been introduced for sodium-ion battery. The Li4Ti5O12 shows an aver...This is the first time that a novel anode material, spinel Li4Ti5O12 which is well known as a "zero-strain" anode material for lithium storage, has been introduced for sodium-ion battery. The Li4Ti5O12 shows an average Na storage voltage of about 1.0 V and a reversible capacity of about 145 mAh/g, thereby making it a promising anode for sodiumion battery. Ex-situ X-ray diffraction (XRD) is used to investigate the structure change in the Na insertion/deinsertion process. Based on this, a possible Na storage mechanism is proposed.展开更多
Aluminum titanate was in-situ synthesized by using industrial waste-residue in the aluminum factory and TiO2 as the main raw materials and the influence of different reaction temperatures on the purity and microstruct...Aluminum titanate was in-situ synthesized by using industrial waste-residue in the aluminum factory and TiO2 as the main raw materials and the influence of different reaction temperatures on the purity and microstructures of synthesized products were mainly discussed. The obtained Al2TiO5 was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and relevant analytical software. The results show that elevating the sintering temperature can increase the content of aluminum titanate; and at 1420 ℃, it reaches the highest in the synthesized ceramic. When the sintering temperature continues to increase, the produced aluminum titanate will decompose resulting in the drop of its content. Therefore, the optimum sintering temperature of in-situ synthesis of aluminum titanate is determined as 1420 ℃, at which the grains of aluminum titanate grow completely, the purity of aluminum titanate is 89.3wt%., the highest density is 2.75 g/cm^3, and the porosity is 9%.展开更多
In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO3), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other ca...In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO3), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO3 was characterized for particle size, morphology and material/ phase identification (using XRD). By varying SrTiO3 content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO3 causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.展开更多
Pyrochlore titanate oxides, R2Ti2O7(R=Gd3+, Tb3+, Dy3+), were synthesized under mild hydrothermal conditions. The crystal growth of pyrochlore titanate oxides and taking place of chemical reaction in the hydrothe...Pyrochlore titanate oxides, R2Ti2O7(R=Gd3+, Tb3+, Dy3+), were synthesized under mild hydrothermal conditions. The crystal growth of pyrochlore titanate oxides and taking place of chemical reaction in the hydrothermal processing were sensitive to the alkalinity, temperature, reaction time, the nature of the rare earth ion and the composition of initial reaction mixture. The as-prepared samples were characterized by powder X-ray diffraction, scanning electron microscopy, Raman spectrum and variable temperature dc magnetic susceptibility(Superconductivity quantum interference device, SQUIDS). The magnetic studies gave 7.29×10-23 A·m2/Gd3+ and -8.28 K, 8.75×10-23 A·m2/ Tb3+ and -19.7 K, and 8.85×10-23 A·m2/Dy3+ and 0.84 K effective moments and Weiss constants for Gd2Ti2O7, Tb2Ti2O7 and Dy2Ti2O7, respectively.展开更多
The effect of Sm 2O 3 dopant on the sintering characteristics and dielectric properties of barium zirconium titanate ceramics (BaZr x Ti 1- x O 3) was investigated. It is shown that trace amount of Sm ...The effect of Sm 2O 3 dopant on the sintering characteristics and dielectric properties of barium zirconium titanate ceramics (BaZr x Ti 1- x O 3) was investigated. It is shown that trace amount of Sm 2O 3 can greatly affect the grain growth and densification of barium zirconium titanate ceramics during sintering. At the same time, the dielectric peak at high temperature shifts to lower temperature and that at low temperature shifts to higher temperature. The two dielectric peaks overlap with each other when the Sm 2O 3 dopant content varies from 0 25% to 1%, and the maximum relative dielectric constant is greatly enhanced. These effects may be attributed to the substitution actions of the rare earth element in perovskite lattice. At the doping content of 0 75%, the dielectric constant maximum of 23570 can be obtained. By adopting some proper additives, an excellent Y5V dielective material is obtained, and the room temperature properties are as follows: relative dielectric constant ε RT ≥23,000, dielectric loss tgδ≤0 0075 and the breakdown strength under alternating field E b≥5 kV·mm -1 .展开更多
Lattice parameters of lead titanate were precisely re-determined in thetemperature range of-150-950 deg C by high precision XRPD measurements. It was clarified that therewas no any evidence for a new phase transition ...Lattice parameters of lead titanate were precisely re-determined in thetemperature range of-150-950 deg C by high precision XRPD measurements. It was clarified that therewas no any evidence for a new phase transition at low tempera-lures. Tetragonal distortion straindecreases with temperature increasing. A novel thermal expansion was observed, positive thermalexpansion from -150 deg C to room temperature (RT) and above 490 deg C, and the negative thermalexpansion in the temperature range of RT-490 deg C. A big jump of thermal expansion coefficient isattributed to the tetragonal-cubic phase transition. A rationalization for the negative thermalexpansion of PbTiO_3 is due to the decrease of anion-anion repulsion as polyhedra become moreregular at heating. The mechanisms of positive and negative thermal expansions were elucidated asthe same nature in the homogenous tetragonal phase at present case.展开更多
Barium titanate(BTO) thin films were deposited on polycrystalline Ni foils by using the polymer assisted deposition(PAD) technique.The growth conditions including ambient and annealing temperatures were carefully ...Barium titanate(BTO) thin films were deposited on polycrystalline Ni foils by using the polymer assisted deposition(PAD) technique.The growth conditions including ambient and annealing temperatures were carefully optimized based on thermal dynamic analysis to control the oxidation processing and interdiffusion.Crystal structures,surface morphologies,and dielectric performance were examined and compared for BTO thin films annealed under different temperatures.Correlations between the fabrication conditions,microstructures,and dielectric properties were discussed.BTO thin films fabricated under the optimized conditions show good crystalline structure and promising dielectric properties with εr~ 400 and tan δ 〈 0.025 at 100 kHz.The data demonstrate that BTO films grown on polycrystalline Ni substrates by PAD are promising in device applications.展开更多
SrTiO3 submicro-wires were prepared by the reaction of layered titanatc nanowircs with Sr(OH)2 powder in an autoclave. The wires were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM...SrTiO3 submicro-wires were prepared by the reaction of layered titanatc nanowircs with Sr(OH)2 powder in an autoclave. The wires were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Ultra-violet visible (UV-vis), photoluminescence (PL) and Raman spectroscopy. The XRD measurement shows that the prepared SrTiO3 submicro-wircs hardly have impurity phases. The SEM and TEM images demonstrate that the scalable wires, which need to be processed at the reaction temperature of 180℃ for about 48 hours, are not composed of single crystals. The PL shows that the wire-like SrTiO3 has emission peaks at the wavelengths of 568 and 585 nm. Further, the Raman spectroscopy reveals structural changes in the products through different reaction time.展开更多
The crystalline phase formed during aluminum titanate at 750-1300 ℃ as well as the relationship between its content change and decomposition dynamics was mainly discussed in this paper.Dynamical equation was establis...The crystalline phase formed during aluminum titanate at 750-1300 ℃ as well as the relationship between its content change and decomposition dynamics was mainly discussed in this paper.Dynamical equation was established for calculating the reaction activation energy.It aimed at providing dynamics basic data for taking up necessary measures to inhibit the decomposition of aluminum titanate.Experimental results showed that aluminum titanate would decompose into TiO2 and corundum at 750-1300 ℃.Content of aluminum titanate would reduce with the increase of decomposition time,and the order of decomposition rates at different temperature was 1100 1200 1000 900 ℃.The decomposition was a chemical reaction with control steps,and could meet the first order reaction dynamic equation-F(G) = [(1-G)-2/3-1] = Kt.According to the calculation,rate constants of different decomposition reaction dynamic equations were K900 = 2.2×10-3,K1000 = 1.2×10-2,K1100 = 4×10-1 and K1200 = 1.5×10-1,and the reaction activation energy ΔGave = 203.21 KJ/mol.展开更多
Different amounts of dysprosium oxide were incorporated into barium titanate powders synthesized by hydrothermal method. Relations of substitution behaviors and lattice parameters with solid-solubility were studied. F...Different amounts of dysprosium oxide were incorporated into barium titanate powders synthesized by hydrothermal method. Relations of substitution behaviors and lattice parameters with solid-solubility were studied. Furthermore, the influences of dysprosium oxide doping fraction on grain size and dielectric properties of barium titanate ceramic, including dielectric constant and breakdown electric field strength , were investigated via scanning electron microscope, X-ray diffraction and electric property tester. The results show that dysprosium oxide can restrain abnormal grain growth during sintering and that fine-grained and high density of barium titanate ceramic can result in excellent dielectric properties. As mass fraction of dysprosium oxide is 0.6%, the lattice parameters of grain increase to the maximum because of the lowest vacancy concentration. The electric property parameters are cited as following: dielectric constant (25 ℃ ) reaches 4100, the change in relative dielectric constant with temperature is - 10% to 10% within the range of - 15 - 100 ℃, breakdown electric field strength (alternating current) achieves 3.2 kV·mm^-1, which can be used in manufacturing high voltage ceramic capacitors展开更多
This study aimed to examine the biocompatibility of calcium titanate(CaTiO3) coating prepared by a simplified technique in an attempt to assess the potential of CaTiO3coating as an alternative to current implant coati...This study aimed to examine the biocompatibility of calcium titanate(CaTiO3) coating prepared by a simplified technique in an attempt to assess the potential of CaTiO3coating as an alternative to current implant coating materials. CaTiO3-coated titanium screws were implanted with hydroxyapatite(HA)-coated or uncoated titanium screws into medial and lateral femoral condyles of 48 New Zealand white rabbits. Imaging, histomorphometric and biomechanical analyses were employed to evaluate the osseointegration and biocompatibility 12 weeks after the implantation. Histology and scanning electron microscopy revealed that bone tissues surrounding the screws coated with CaTiO3were fully regenerated and they were also well integrated with the screws. An interfacial fibrous membrane layer, which was found in the HA coating group, was not noticeable between the bone tissues and CaTiO3-coated screws. X-ray imaging analysis showed in the CaTiO3coating group, there was a dense and tight binding between implants and the bone tissues; no radiation translucent zone was found surrounding the implants as well as no detachment of the coating and femoral condyle fracture. In contrast, uncoated screws exhibited a fibrous membrane layer, as evidenced by the detection of a radiation translucent zone between the implants and the bone tissues. Additionally, biomechanical testing revealed that the binding strength of CaTiO3coating with bone tissues was significantly higher than that of uncoated titanium screws, and was comparable to that of HA coating. The study demonstrated that CaTiO3coating in situ to titanium screws possesses great biocompatibility and osseointegration comparable to HA coating.展开更多
The magnetically separable ternary polyetherimide/titanate@Fe3O4(PTF) photocatalysts of special heterostructure between magnetite(Fe3O4) microspheres and titanates nanosheets modified by polyetherimide(PEI) were succe...The magnetically separable ternary polyetherimide/titanate@Fe3O4(PTF) photocatalysts of special heterostructure between magnetite(Fe3O4) microspheres and titanates nanosheets modified by polyetherimide(PEI) were successfully fabricated via a simple facile hydrothermal deposition method. The as-prepared photocatalysts were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, Transmission electron microscopy and UV-vis diffuse reflectance spectroscopy etc. The results showed that the as-fabricated material had a structure of Fe3O4microspheres coated with titanates nanosheets modified by PEI. The special interfacial contact between 3 D microsphere and 2 D nanosheets in the nanoarchitectures was formed via electrostatic attraction. Furthermore, the resulted photocatalysts were tested by degradation reaction of methylene blue under visible light irradiation and demonstrated an enhanced performance than the pure Fe3O4microspheres, and the photocatalytic activity enhanced with the molar ratio of Fe3O4microspheres and modified titanate gradually, which was attributed to the expansion of the surface area and the different electrostatic contact between the Fe3O4microspheres and titanate nanosheets. Moreover, the obtained results revealed the high yield magnetic separation and efficient reusability of PTF-5(96.7%) over 3 times reuse.展开更多
Potassium titanate (K4Ti3O8) was synthesized by the reaction between ilmenite and concentrated KOH solution in the atmosphere of nitrogen,still air,and oxygen,respectively.The obtained samples were systematically in...Potassium titanate (K4Ti3O8) was synthesized by the reaction between ilmenite and concentrated KOH solution in the atmosphere of nitrogen,still air,and oxygen,respectively.The obtained samples were systematically investigated by X-ray diffraction (XRD),inductively coupled plasma optical emission spectrometer (ICP-OES),and scanning electron microscopy (SEM).XRD results indicate that K4Ti3O8 have been synthesized in different atmospheres.The oxidizing atmosphere could enhance the conversion rate of Ti from ilmenite to K4Ti3O8,and Fe(II) is easily oxidized to trivalent iron Fe(III) during the reaction.Furthermore,SEM images show that the different atmospheres have significant effect on K4Ti3O8 crystal morphology and particle size.Well shaped K4Ti3O8 crystals are obtained in nonoxidizing atmosphere.展开更多
The formation of calcium titanate in the carbothermic reduction of vanadium titanomagnetite concentrate(VTC)by adding CaCO3 was investigated.Thermodynamic analysis was employed to show the feasibility of calcium titan...The formation of calcium titanate in the carbothermic reduction of vanadium titanomagnetite concentrate(VTC)by adding CaCO3 was investigated.Thermodynamic analysis was employed to show the feasibility of calcium titanate formation by the reaction of ilmenite and Ca CO3 in a reductive atmosphere,where ilmenite is more easily reduced by CO or carbon in the presence of CaCO3.The effects of CaCO3 dosage and reduction temperature on the phase transformation and metallization degree were also investigated in an actual roasting test.Appropriate increase of CaCO3 dosages and reduction temperatures were found to be conducive to the formation of calcium titanate,and the optimum conditions were a CaCO3 dosage of 18 wt%and a reduction temperature of 1400°C.Additionally,scanning electron microscopy–energy dispersive spectrometry(SEM–EDS)analysis shows that calcium titanate produced via the carbothermic reduction of VTC by CaCO3 addition was of higher purity with particle size approximately 50μm.Hence,the separation of calcium titanate and metallic iron will be the focus in the future study.展开更多
A group of poly (phthalazinone ether sulfone ketone)/potassium-titanate-whisker (PPSEK/whisker) composites was prepared by coprecipitation from solution. The whisker surface was modified using titanate coupling agent ...A group of poly (phthalazinone ether sulfone ketone)/potassium-titanate-whisker (PPSEK/whisker) composites was prepared by coprecipitation from solution. The whisker surface was modified using titanate coupling agent prior to blending. The tensile, impact, morphology and thermal properties of the moulded composites were investigated. The measurements showed that the tensile strength and impact strength of the composites increased with increasing whiskers content up to 10 to 20 phr, thereafter they showed a decrease in the whiskers content reached 40 phr. At the same time, the modulus of the composites increased with increasing whiskers content. Scanning electron microscopy studies revealed that the whiskers within the composites were dispersed uniformly by treated with coupling agent. Finally, thermogravimetric analysis showed that the heat resistance of the composites tended to increase with increasing whisker content. The results were analysed and discussed in terms of established models of the behaviour of short-fiber reinforced composites.展开更多
High-purity aluminum titanate was synthesized via a water quenching method with waste-residue in the aluminum factory and industrial TiO2 as the main raw materials, which belongs to the comprehensive utilization of so...High-purity aluminum titanate was synthesized via a water quenching method with waste-residue in the aluminum factory and industrial TiO2 as the main raw materials, which belongs to the comprehensive utilization of solid wastes. Compared with the conventional method, it can reduce synthesis temperature, effectively inhibit decomposition and raise the content of AT; the addition of tiny silicon powder can improve the sintering and optimize the properties of AT. The crystalline phase structure and microstructure of each sample were characterized with XRD and SEM methods; the content of each crystalline phase in each sample was confirmed with Rietveld Quantification method; the properties of each sample were also tested. The experimental results showed that No. 4 is the optimum specimen, with the corresponding mass ratio of Al2O3/TiO2 to be 1.27 and the content of AT of 97.2 wt%. The addition of optimum tiny silicon powder is confirmed to be 8wt%; its corresponding bulk density is 2.63 g/cm^3, bending strength is 46.34 MPa, and the retention of one thermal vibration bending strength is 71.5%.展开更多
Lithium titanate has unique "zero-strain" characteristics, which makes it promising for rapid energy storage lithium-ion capacitors. However, extremely low electronic conductivity and lithium ion diffusion c...Lithium titanate has unique "zero-strain" characteristics, which makes it promising for rapid energy storage lithium-ion capacitors. However, extremely low electronic conductivity and lithium ion diffusion coefficient severely limit its performance at high rate. Herein, we have constructed in situ clusters of porous lithium titanate nanoparticles on self-supporting carbon nanotube film by combining iron oxide hard template method and F127 soft template method. Due to the nano-structured particle size and the penetrating lithium ion transmission channel, a greatly improved lithium ion diffusion coefficient has been achieved, which brings significantly better electrochemical performance than dense lithium titanate. By assembling with a durable graphene foam cathode, a lithium-ion capacitor with an energy density of up to 101.8 Wh kg-1 was realized(at a power density of 436.1 W kg-1). And its capacitance retention reaches 84.8% after 5000 cycles. With such an alluring result, our work presents a novel lithium-ion capacitor system with practical application prospects.展开更多
To study the extraction difficulty of lithium ions from various crystal planes of Li2 TiO3, according to the first principle, four representative crystal surfaces of Li2TiO3(precursor),(-133),(-206),(002) and...To study the extraction difficulty of lithium ions from various crystal planes of Li2 TiO3, according to the first principle, four representative crystal surfaces of Li2TiO3(precursor),(-133),(-206),(002) and(-131), were selected to establish a model and to calculate the surface energy, bond length and population using Materials Studio 5.5(MS 5.5). The results demonstrate that there is no direct relationship between the surface energy and the order of disappearance of the four diffraction peaks when lithium titanate is treated with hydrochloric acid, instead, the difficulty of Li~+ extraction from various crystal faces corresponds to the Li-O bond strength. Lithium ion is easy to remove from(-133) and(-206) due to the relatively weak Li-O bond strength. In contrast, Li+ extraction requires a longer time for(002) and(-131).展开更多
基金supported by Chongqing Newcent New Materials Co.,Ltd.,China (No.2021GKF-0708).
文摘Tetragonal barium titanate was synthesized from barium hydroxide octahydrate and titanium tetrachloride through a simple one-step hydrothermal method.The effect of different solvents on the crystal structure and morphology of barium titanate nanoparticles during the hy-drothermal process was investigated.Except for ethylene glycol/water solvent,impurity-free barium titanate was synthesized in pure water,methanol/water,ethanol/water,and isopropyl alcohol/water mixed solvents.Compared with other alcohols,ethanol promotes the formation of a tetragonal structure.In addition,characterization studies confirm that particles synthesized in methanol/water,ethanol/water,and isopropyl al-cohol/water mixed solvents are smaller in size than those synthesized in pure water.In the case of alcohol-containing solvents,the particle size decreases in the order of isopropanol,ethanol,and methanol.Among all the media used in this study,ethanol/water is considered the optimum reaction media for barium titanate with high tetragonality(defined as the ratio of two lattice parameters c and a,c/a=1.0088)and small aver-age particle size(82 nm),which indicates its great application potential in multilayer ceramic capacitors.
基金supported by the National High Technology Research and Development Program of China (Grant No.2009AA033101)the National Basic Research Program of China (Grant No.2010CB833102)+2 种基金the National Natural Science Foundation of China (Grant No.50972164)the Chinese Academy of Sciences Project (Grant No.KJCX2-YW-W26)the Hundred-Talent Project of the Chinese Academy of Sciences
文摘This is the first time that a novel anode material, spinel Li4Ti5O12 which is well known as a "zero-strain" anode material for lithium storage, has been introduced for sodium-ion battery. The Li4Ti5O12 shows an average Na storage voltage of about 1.0 V and a reversible capacity of about 145 mAh/g, thereby making it a promising anode for sodiumion battery. Ex-situ X-ray diffraction (XRD) is used to investigate the structure change in the Na insertion/deinsertion process. Based on this, a possible Na storage mechanism is proposed.
基金The project was supported by the Natural Science Foundation of Fujian Province (No T08J0129)the Science and Technology Developing Foundation of Fuzhou University (No 2008-XQ-001)2007-year New Century Talents Supporting Program of Fujian Province (No XSJRC2007-17)
文摘Aluminum titanate was in-situ synthesized by using industrial waste-residue in the aluminum factory and TiO2 as the main raw materials and the influence of different reaction temperatures on the purity and microstructures of synthesized products were mainly discussed. The obtained Al2TiO5 was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and relevant analytical software. The results show that elevating the sintering temperature can increase the content of aluminum titanate; and at 1420 ℃, it reaches the highest in the synthesized ceramic. When the sintering temperature continues to increase, the produced aluminum titanate will decompose resulting in the drop of its content. Therefore, the optimum sintering temperature of in-situ synthesis of aluminum titanate is determined as 1420 ℃, at which the grains of aluminum titanate grow completely, the purity of aluminum titanate is 89.3wt%., the highest density is 2.75 g/cm^3, and the porosity is 9%.
文摘In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO3), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO3 was characterized for particle size, morphology and material/ phase identification (using XRD). By varying SrTiO3 content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO3 causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.
基金Supported by the National Natural Science Foundation of China(Nos.90922034 20771042)
文摘Pyrochlore titanate oxides, R2Ti2O7(R=Gd3+, Tb3+, Dy3+), were synthesized under mild hydrothermal conditions. The crystal growth of pyrochlore titanate oxides and taking place of chemical reaction in the hydrothermal processing were sensitive to the alkalinity, temperature, reaction time, the nature of the rare earth ion and the composition of initial reaction mixture. The as-prepared samples were characterized by powder X-ray diffraction, scanning electron microscopy, Raman spectrum and variable temperature dc magnetic susceptibility(Superconductivity quantum interference device, SQUIDS). The magnetic studies gave 7.29×10-23 A·m2/Gd3+ and -8.28 K, 8.75×10-23 A·m2/ Tb3+ and -19.7 K, and 8.85×10-23 A·m2/Dy3+ and 0.84 K effective moments and Weiss constants for Gd2Ti2O7, Tb2Ti2O7 and Dy2Ti2O7, respectively.
文摘The effect of Sm 2O 3 dopant on the sintering characteristics and dielectric properties of barium zirconium titanate ceramics (BaZr x Ti 1- x O 3) was investigated. It is shown that trace amount of Sm 2O 3 can greatly affect the grain growth and densification of barium zirconium titanate ceramics during sintering. At the same time, the dielectric peak at high temperature shifts to lower temperature and that at low temperature shifts to higher temperature. The two dielectric peaks overlap with each other when the Sm 2O 3 dopant content varies from 0 25% to 1%, and the maximum relative dielectric constant is greatly enhanced. These effects may be attributed to the substitution actions of the rare earth element in perovskite lattice. At the doping content of 0 75%, the dielectric constant maximum of 23570 can be obtained. By adopting some proper additives, an excellent Y5V dielective material is obtained, and the room temperature properties are as follows: relative dielectric constant ε RT ≥23,000, dielectric loss tgδ≤0 0075 and the breakdown strength under alternating field E b≥5 kV·mm -1 .
基金This work is financially supported by Natural Science Foundation of Beijing(No.2032010)National Natural Science Foundation of China(No.20171006)Funds of Ministry of Education of China for Training Ph.D.Candidates (No.2001008005)
文摘Lattice parameters of lead titanate were precisely re-determined in thetemperature range of-150-950 deg C by high precision XRPD measurements. It was clarified that therewas no any evidence for a new phase transition at low tempera-lures. Tetragonal distortion straindecreases with temperature increasing. A novel thermal expansion was observed, positive thermalexpansion from -150 deg C to room temperature (RT) and above 490 deg C, and the negative thermalexpansion in the temperature range of RT-490 deg C. A big jump of thermal expansion coefficient isattributed to the tetragonal-cubic phase transition. A rationalization for the negative thermalexpansion of PbTiO_3 is due to the decrease of anion-anion repulsion as polyhedra become moreregular at heating. The mechanisms of positive and negative thermal expansions were elucidated asthe same nature in the homogenous tetragonal phase at present case.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11028409 and 60976061)the Fundamental Research Funds for the Central Universities of China (Grant No. ZYGX2009Z0001)
文摘Barium titanate(BTO) thin films were deposited on polycrystalline Ni foils by using the polymer assisted deposition(PAD) technique.The growth conditions including ambient and annealing temperatures were carefully optimized based on thermal dynamic analysis to control the oxidation processing and interdiffusion.Crystal structures,surface morphologies,and dielectric performance were examined and compared for BTO thin films annealed under different temperatures.Correlations between the fabrication conditions,microstructures,and dielectric properties were discussed.BTO thin films fabricated under the optimized conditions show good crystalline structure and promising dielectric properties with εr~ 400 and tan δ 〈 0.025 at 100 kHz.The data demonstrate that BTO films grown on polycrystalline Ni substrates by PAD are promising in device applications.
基金Scientific Research Foundation for the Returned Over-seas Scholar from the State Education Ministry, China
文摘SrTiO3 submicro-wires were prepared by the reaction of layered titanatc nanowircs with Sr(OH)2 powder in an autoclave. The wires were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Ultra-violet visible (UV-vis), photoluminescence (PL) and Raman spectroscopy. The XRD measurement shows that the prepared SrTiO3 submicro-wircs hardly have impurity phases. The SEM and TEM images demonstrate that the scalable wires, which need to be processed at the reaction temperature of 180℃ for about 48 hours, are not composed of single crystals. The PL shows that the wire-like SrTiO3 has emission peaks at the wavelengths of 568 and 585 nm. Further, the Raman spectroscopy reveals structural changes in the products through different reaction time.
基金Sponsored by the Fujian Provincial Reform and Development Commission
文摘The crystalline phase formed during aluminum titanate at 750-1300 ℃ as well as the relationship between its content change and decomposition dynamics was mainly discussed in this paper.Dynamical equation was established for calculating the reaction activation energy.It aimed at providing dynamics basic data for taking up necessary measures to inhibit the decomposition of aluminum titanate.Experimental results showed that aluminum titanate would decompose into TiO2 and corundum at 750-1300 ℃.Content of aluminum titanate would reduce with the increase of decomposition time,and the order of decomposition rates at different temperature was 1100 1200 1000 900 ℃.The decomposition was a chemical reaction with control steps,and could meet the first order reaction dynamic equation-F(G) = [(1-G)-2/3-1] = Kt.According to the calculation,rate constants of different decomposition reaction dynamic equations were K900 = 2.2×10-3,K1000 = 1.2×10-2,K1100 = 4×10-1 and K1200 = 1.5×10-1,and the reaction activation energy ΔGave = 203.21 KJ/mol.
文摘Different amounts of dysprosium oxide were incorporated into barium titanate powders synthesized by hydrothermal method. Relations of substitution behaviors and lattice parameters with solid-solubility were studied. Furthermore, the influences of dysprosium oxide doping fraction on grain size and dielectric properties of barium titanate ceramic, including dielectric constant and breakdown electric field strength , were investigated via scanning electron microscope, X-ray diffraction and electric property tester. The results show that dysprosium oxide can restrain abnormal grain growth during sintering and that fine-grained and high density of barium titanate ceramic can result in excellent dielectric properties. As mass fraction of dysprosium oxide is 0.6%, the lattice parameters of grain increase to the maximum because of the lowest vacancy concentration. The electric property parameters are cited as following: dielectric constant (25 ℃ ) reaches 4100, the change in relative dielectric constant with temperature is - 10% to 10% within the range of - 15 - 100 ℃, breakdown electric field strength (alternating current) achieves 3.2 kV·mm^-1, which can be used in manufacturing high voltage ceramic capacitors
基金supported by the National Natural Science Foundation of China(Nos.81572150,81571939)the Natural Science Foundation of Hunan Province(No.2015JJ2187)the Wu Jie-Ping Medical Foundation of the Minister of Health of China(No.320675014118)
文摘This study aimed to examine the biocompatibility of calcium titanate(CaTiO3) coating prepared by a simplified technique in an attempt to assess the potential of CaTiO3coating as an alternative to current implant coating materials. CaTiO3-coated titanium screws were implanted with hydroxyapatite(HA)-coated or uncoated titanium screws into medial and lateral femoral condyles of 48 New Zealand white rabbits. Imaging, histomorphometric and biomechanical analyses were employed to evaluate the osseointegration and biocompatibility 12 weeks after the implantation. Histology and scanning electron microscopy revealed that bone tissues surrounding the screws coated with CaTiO3were fully regenerated and they were also well integrated with the screws. An interfacial fibrous membrane layer, which was found in the HA coating group, was not noticeable between the bone tissues and CaTiO3-coated screws. X-ray imaging analysis showed in the CaTiO3coating group, there was a dense and tight binding between implants and the bone tissues; no radiation translucent zone was found surrounding the implants as well as no detachment of the coating and femoral condyle fracture. In contrast, uncoated screws exhibited a fibrous membrane layer, as evidenced by the detection of a radiation translucent zone between the implants and the bone tissues. Additionally, biomechanical testing revealed that the binding strength of CaTiO3coating with bone tissues was significantly higher than that of uncoated titanium screws, and was comparable to that of HA coating. The study demonstrated that CaTiO3coating in situ to titanium screws possesses great biocompatibility and osseointegration comparable to HA coating.
基金Funded by the National Natural Science Foundation of China(Nos.21103054,21003055,and 50872037)the Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications(Xiamen University of Technology)(No.608160030215)the Program for Innovative Research Team in Science and Technology in Fujian Province University(IRTSTFJ)
文摘The magnetically separable ternary polyetherimide/titanate@Fe3O4(PTF) photocatalysts of special heterostructure between magnetite(Fe3O4) microspheres and titanates nanosheets modified by polyetherimide(PEI) were successfully fabricated via a simple facile hydrothermal deposition method. The as-prepared photocatalysts were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, Transmission electron microscopy and UV-vis diffuse reflectance spectroscopy etc. The results showed that the as-fabricated material had a structure of Fe3O4microspheres coated with titanates nanosheets modified by PEI. The special interfacial contact between 3 D microsphere and 2 D nanosheets in the nanoarchitectures was formed via electrostatic attraction. Furthermore, the resulted photocatalysts were tested by degradation reaction of methylene blue under visible light irradiation and demonstrated an enhanced performance than the pure Fe3O4microspheres, and the photocatalytic activity enhanced with the molar ratio of Fe3O4microspheres and modified titanate gradually, which was attributed to the expansion of the surface area and the different electrostatic contact between the Fe3O4microspheres and titanate nanosheets. Moreover, the obtained results revealed the high yield magnetic separation and efficient reusability of PTF-5(96.7%) over 3 times reuse.
基金supported by the National Key Technologies R&D Program (No. 2006BAC02A05)the National Basic Research Program of China (No.2007CB613501)+1 种基金the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KGCX2-YW-214)the Special Funds of "Mountain Tai Scholar" Construction Project and BHP Billiton LTD
文摘Potassium titanate (K4Ti3O8) was synthesized by the reaction between ilmenite and concentrated KOH solution in the atmosphere of nitrogen,still air,and oxygen,respectively.The obtained samples were systematically investigated by X-ray diffraction (XRD),inductively coupled plasma optical emission spectrometer (ICP-OES),and scanning electron microscopy (SEM).XRD results indicate that K4Ti3O8 have been synthesized in different atmospheres.The oxidizing atmosphere could enhance the conversion rate of Ti from ilmenite to K4Ti3O8,and Fe(II) is easily oxidized to trivalent iron Fe(III) during the reaction.Furthermore,SEM images show that the different atmospheres have significant effect on K4Ti3O8 crystal morphology and particle size.Well shaped K4Ti3O8 crystals are obtained in nonoxidizing atmosphere.
基金the National Natural Science Foundation of China(No.51674018)。
文摘The formation of calcium titanate in the carbothermic reduction of vanadium titanomagnetite concentrate(VTC)by adding CaCO3 was investigated.Thermodynamic analysis was employed to show the feasibility of calcium titanate formation by the reaction of ilmenite and Ca CO3 in a reductive atmosphere,where ilmenite is more easily reduced by CO or carbon in the presence of CaCO3.The effects of CaCO3 dosage and reduction temperature on the phase transformation and metallization degree were also investigated in an actual roasting test.Appropriate increase of CaCO3 dosages and reduction temperatures were found to be conducive to the formation of calcium titanate,and the optimum conditions were a CaCO3 dosage of 18 wt%and a reduction temperature of 1400°C.Additionally,scanning electron microscopy–energy dispersive spectrometry(SEM–EDS)analysis shows that calcium titanate produced via the carbothermic reduction of VTC by CaCO3 addition was of higher purity with particle size approximately 50μm.Hence,the separation of calcium titanate and metallic iron will be the focus in the future study.
基金the National Natural Science Foundation of China under grant No.59473901 Educational Office Fesearch Project of Liaoning Provice under grant No.2020701095.
文摘A group of poly (phthalazinone ether sulfone ketone)/potassium-titanate-whisker (PPSEK/whisker) composites was prepared by coprecipitation from solution. The whisker surface was modified using titanate coupling agent prior to blending. The tensile, impact, morphology and thermal properties of the moulded composites were investigated. The measurements showed that the tensile strength and impact strength of the composites increased with increasing whiskers content up to 10 to 20 phr, thereafter they showed a decrease in the whiskers content reached 40 phr. At the same time, the modulus of the composites increased with increasing whiskers content. Scanning electron microscopy studies revealed that the whiskers within the composites were dispersed uniformly by treated with coupling agent. Finally, thermogravimetric analysis showed that the heat resistance of the composites tended to increase with increasing whisker content. The results were analysed and discussed in terms of established models of the behaviour of short-fiber reinforced composites.
基金Supported by the Natural Science Foundation of Fujian Province (No. T0750005)the Science and Technology Developing Foundation of Fuzhou University (No. 2007-XQ-02)
文摘High-purity aluminum titanate was synthesized via a water quenching method with waste-residue in the aluminum factory and industrial TiO2 as the main raw materials, which belongs to the comprehensive utilization of solid wastes. Compared with the conventional method, it can reduce synthesis temperature, effectively inhibit decomposition and raise the content of AT; the addition of tiny silicon powder can improve the sintering and optimize the properties of AT. The crystalline phase structure and microstructure of each sample were characterized with XRD and SEM methods; the content of each crystalline phase in each sample was confirmed with Rietveld Quantification method; the properties of each sample were also tested. The experimental results showed that No. 4 is the optimum specimen, with the corresponding mass ratio of Al2O3/TiO2 to be 1.27 and the content of AT of 97.2 wt%. The addition of optimum tiny silicon powder is confirmed to be 8wt%; its corresponding bulk density is 2.63 g/cm^3, bending strength is 46.34 MPa, and the retention of one thermal vibration bending strength is 71.5%.
基金the National Natural Science Foundation of China(51673064,21875065)International Science&Technology Cooperation Program of China(2016YFE0131200)Shanghai Municipality Research Project(15520720500)。
文摘Lithium titanate has unique "zero-strain" characteristics, which makes it promising for rapid energy storage lithium-ion capacitors. However, extremely low electronic conductivity and lithium ion diffusion coefficient severely limit its performance at high rate. Herein, we have constructed in situ clusters of porous lithium titanate nanoparticles on self-supporting carbon nanotube film by combining iron oxide hard template method and F127 soft template method. Due to the nano-structured particle size and the penetrating lithium ion transmission channel, a greatly improved lithium ion diffusion coefficient has been achieved, which brings significantly better electrochemical performance than dense lithium titanate. By assembling with a durable graphene foam cathode, a lithium-ion capacitor with an energy density of up to 101.8 Wh kg-1 was realized(at a power density of 436.1 W kg-1). And its capacitance retention reaches 84.8% after 5000 cycles. With such an alluring result, our work presents a novel lithium-ion capacitor system with practical application prospects.
基金Funded partly by the Key Project of Natural Science of Sichuan Provincial Education Department(No.16ZA0309)the Doctoral Research Start-up Funding(No.15B16)
文摘To study the extraction difficulty of lithium ions from various crystal planes of Li2 TiO3, according to the first principle, four representative crystal surfaces of Li2TiO3(precursor),(-133),(-206),(002) and(-131), were selected to establish a model and to calculate the surface energy, bond length and population using Materials Studio 5.5(MS 5.5). The results demonstrate that there is no direct relationship between the surface energy and the order of disappearance of the four diffraction peaks when lithium titanate is treated with hydrochloric acid, instead, the difficulty of Li~+ extraction from various crystal faces corresponds to the Li-O bond strength. Lithium ion is easy to remove from(-133) and(-206) due to the relatively weak Li-O bond strength. In contrast, Li+ extraction requires a longer time for(002) and(-131).