A series of YBa 2Cu 3O 6.5-0.5x+δ F x (x=0, 0.3, 0.6, 1.0, 1.5, 2.0) samples were synthesized using state reaction method. The superconducting properties and microstructures of the samples were studied with AC suscep...A series of YBa 2Cu 3O 6.5-0.5x+δ F x (x=0, 0.3, 0.6, 1.0, 1.5, 2.0) samples were synthesized using state reaction method. The superconducting properties and microstructures of the samples were studied with AC susceptibility, DC resistivity, fluorine and oxygen content measurements, XRD, IR and XPS techniques. The results show that F doping increases the T C and decreases the transition width, and fluorine atoms have entered into the superconducting phase and substituted for the oxygen atoms at O(4) sites. The mechanism of improving superconducting properties is that fluorine doping adjusts the hole carrier concentration in the Cu O planes.展开更多
For Fe-doped T1-1223 phase,the excess oxygen defects induced by Fe dopants are studied by means of Hall coefficient,thermogravimetric measurements,Mossbauer spectroscopy,and the model calculation of the effective bond...For Fe-doped T1-1223 phase,the excess oxygen defects induced by Fe dopants are studied by means of Hall coefficient,thermogravimetric measurements,Mossbauer spectroscopy,and the model calculation of the effective bond valence.The extra oxygen defects have effects on carrier density and microstructure of the superconductors.In the light doping level of Fe (x=0-0.05),the superconducting transition and carrier density have significant corresponding relation--the zero resistance temperature Tco and carrier densities decrease linearly with Fe dopants increasing.The thermogravimetric measurements show that the Fe3+ ions' substituting for Cu2+ ions can bring the extra oxygen into the lattice to form extra oxygen defects.The calculation of the effective bond valence shows that the decrease of carrier density originates the strongly localized binding of the extra oxygen defects.The distortion of Cu-O layer induced by the extra oxygen defects decreases the superconductive transition temperature.The microstructures of the extra oxygen defects including the oxygen occupying and the shifts of Fe and O are discussed.展开更多
文摘A series of YBa 2Cu 3O 6.5-0.5x+δ F x (x=0, 0.3, 0.6, 1.0, 1.5, 2.0) samples were synthesized using state reaction method. The superconducting properties and microstructures of the samples were studied with AC susceptibility, DC resistivity, fluorine and oxygen content measurements, XRD, IR and XPS techniques. The results show that F doping increases the T C and decreases the transition width, and fluorine atoms have entered into the superconducting phase and substituted for the oxygen atoms at O(4) sites. The mechanism of improving superconducting properties is that fluorine doping adjusts the hole carrier concentration in the Cu O planes.
基金Project supported in part by the National Center for Research and Development on Superconductivity and National Laboratory of Nuclear Technology.
文摘For Fe-doped T1-1223 phase,the excess oxygen defects induced by Fe dopants are studied by means of Hall coefficient,thermogravimetric measurements,Mossbauer spectroscopy,and the model calculation of the effective bond valence.The extra oxygen defects have effects on carrier density and microstructure of the superconductors.In the light doping level of Fe (x=0-0.05),the superconducting transition and carrier density have significant corresponding relation--the zero resistance temperature Tco and carrier densities decrease linearly with Fe dopants increasing.The thermogravimetric measurements show that the Fe3+ ions' substituting for Cu2+ ions can bring the extra oxygen into the lattice to form extra oxygen defects.The calculation of the effective bond valence shows that the decrease of carrier density originates the strongly localized binding of the extra oxygen defects.The distortion of Cu-O layer induced by the extra oxygen defects decreases the superconductive transition temperature.The microstructures of the extra oxygen defects including the oxygen occupying and the shifts of Fe and O are discussed.
