A d-f heteronuclear metal-organic framework（MOF）,{[Tm3Zn6（bipy2）2（mimda）7（H2O）3]·（H2O）5}n（1,H3 mimda = 2-methyl-1-H-imidazole-4,5-dicarboxylic acid,and bipy = 4,4？-bipyridine）,has been synthesized un...A d-f heteronuclear metal-organic framework（MOF）,{[Tm3Zn6（bipy2）2（mimda）7（H2O）3]·（H2O）5}n（1,H3 mimda = 2-methyl-1-H-imidazole-4,5-dicarboxylic acid,and bipy = 4,4？-bipyridine）,has been synthesized under solvothermal conditions,and structurally characterized by elemental analysis,IR spectra and X-ray single-crystal diffraction.It crystallizes in orthorhombic system,space group Pnma with a = 16.1102（9）,b = 33.5805（19）,c = 16.8593（10） ？,β = 97.344（11）°,V = 9120.7（9） ？-3,Z = 4,F（000） = 5184,the final R = 0.0530 and w R = 0.1306.In complex 1,the Tm（Ⅲ） ions adopt two types of coordination fashions.Complex 1 shows onedimensional（1-D） Tm-Zn heteronuclear zigzag chains,and these chains are further linked by H3 mimda ligands into Tm-Zn heteronuclear 2-D lattice-like arrays.The 2-D heteronuclear units were connected through [Zn6（mimda）6] rings to give rise to the Tm-Zn heteronuclear cages.Finally,H3 mimda ligands connected the cages into a 3-D heterometallic framework by the combination of [TmO7]n and Tm-Zn heteronuclear cages.In addition,the thermal stability and luminescent property have been investigated.展开更多
The study of the spatial patterns and temporal changes of cropland is important to understand the underlying factors and the functional effects of the agricultural landscape. On the other hand, crop dynamics mapping i...The study of the spatial patterns and temporal changes of cropland is important to understand the underlying factors and the functional effects of the agricultural landscape. On the other hand, crop dynamics mapping is essential to know the overall agro-spatial diversity of the area. Therefore, this paper addressed a spatio-temporal analysis of cropland and cropping pattern change in the Bogra district of Bangladesh over the last 16 years (between 1988/89 and 2004/05). In this paper, crop mapping from multi-temporal and multi-sensor satellite images was described. Landsat TM and IRS P6 LISS III satellite images were used with GIS for spatial dynamics of cropland and cropping pattern change analysis. First, seasonal cropland maps were derived from object-based classification of satellite images, then two-date classified image differencing with GIS overlay technique and decision rules were applied. Cropping pattern change was analyzed in a spatial and quantitative way for the 16 years and for this, Integrated Land and Water Information System (ILWIS) and Land Change Modular (LCM) of IDRISI Andes were used. The results showed that in the area, mono crop cultivation was found in summer, but in winter, areas under different crop cultivation had changed dramatically. Change analysis showed that the changes mainly occurred in the north northwest and southwest of the areas, and during the time the highest change area was found under the rice-potato pattern.展开更多
基金Supported by the Foundation for Science&Technology Innovation Talents in Henan Province(Nos.14HASTIT014,and 16410010012)Natural Science Foundation of China(Nos.21671114)the Foundation of Education Committee of Henan province,China(No.14B150033)
文摘A d-f heteronuclear metal-organic framework（MOF）,{[Tm3Zn6（bipy2）2（mimda）7（H2O）3]·（H2O）5}n（1,H3 mimda = 2-methyl-1-H-imidazole-4,5-dicarboxylic acid,and bipy = 4,4？-bipyridine）,has been synthesized under solvothermal conditions,and structurally characterized by elemental analysis,IR spectra and X-ray single-crystal diffraction.It crystallizes in orthorhombic system,space group Pnma with a = 16.1102（9）,b = 33.5805（19）,c = 16.8593（10） ？,β = 97.344（11）°,V = 9120.7（9） ？-3,Z = 4,F（000） = 5184,the final R = 0.0530 and w R = 0.1306.In complex 1,the Tm（Ⅲ） ions adopt two types of coordination fashions.Complex 1 shows onedimensional（1-D） Tm-Zn heteronuclear zigzag chains,and these chains are further linked by H3 mimda ligands into Tm-Zn heteronuclear 2-D lattice-like arrays.The 2-D heteronuclear units were connected through [Zn6（mimda）6] rings to give rise to the Tm-Zn heteronuclear cages.Finally,H3 mimda ligands connected the cages into a 3-D heterometallic framework by the combination of [TmO7]n and Tm-Zn heteronuclear cages.In addition,the thermal stability and luminescent property have been investigated.
文摘The study of the spatial patterns and temporal changes of cropland is important to understand the underlying factors and the functional effects of the agricultural landscape. On the other hand, crop dynamics mapping is essential to know the overall agro-spatial diversity of the area. Therefore, this paper addressed a spatio-temporal analysis of cropland and cropping pattern change in the Bogra district of Bangladesh over the last 16 years (between 1988/89 and 2004/05). In this paper, crop mapping from multi-temporal and multi-sensor satellite images was described. Landsat TM and IRS P6 LISS III satellite images were used with GIS for spatial dynamics of cropland and cropping pattern change analysis. First, seasonal cropland maps were derived from object-based classification of satellite images, then two-date classified image differencing with GIS overlay technique and decision rules were applied. Cropping pattern change was analyzed in a spatial and quantitative way for the 16 years and for this, Integrated Land and Water Information System (ILWIS) and Land Change Modular (LCM) of IDRISI Andes were used. The results showed that in the area, mono crop cultivation was found in summer, but in winter, areas under different crop cultivation had changed dramatically. Change analysis showed that the changes mainly occurred in the north northwest and southwest of the areas, and during the time the highest change area was found under the rice-potato pattern.
