Abstract: Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtit...Abstract: Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagioclase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10?6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and Ni, poor in Ba, Nb and Sr. All kinds of magmatogenic enclaves have the same REE pattern without Eu anomaly, and the total REE is 74.9×10?6 for spinel pyroxene cumulate, 179.7×10?6 for hornblende cumulate, 226.9 × 10?6 for hornblende cumulate crystal, 289.9×10?6 for micrograined dioritic mixtite and 131.2×10?6 for chilled border enclaves. Calculation with the thermometer and barometer for minerals shows that the temperature and pressure of formation are 1126 °C and 8.44 kbar (7.15–9.04 kbar) for the spinel pyroxene cumulate, 1065 °C-1029 °C and 8.23 kbar (7.13–9.50 kbar) for the hornblende pyroxene cumulate, 959 °C and 3.40 kbar (2.86–4.09 kbar) for the micrograined dioritic mixtite enclaves, and 951 °C and 0.59 kbar for the dioritic chilled border enclaves, respectively. Thus, the following conclusions can be drawn. Relic enclaves were derived from the crustal partial melting and all cumulate enclaves originated from deep magma chambers near the Moho in the lower crust, which are cumulate fragments formed by fractional crystallization of basic magma; mixtite came from shallow magma chambers in the middle-upper crust, formed by the mixture of mantle-derived magma and acid magma derived from the crustal partial melting; and the chilled border enclaves came from the border fragments of early intrusive bodies.展开更多
This paper determines the crystallization ages of the Xiaotongguanshan quartz monzodiorite and Shatanjiao quartz monzonitc porphyry from the Tongling area using the SHRIMP zircon U-Pb method. The crystallization age o...This paper determines the crystallization ages of the Xiaotongguanshan quartz monzodiorite and Shatanjiao quartz monzonitc porphyry from the Tongling area using the SHRIMP zircon U-Pb method. The crystallization age of the former is 142.8±1.8 Ma; that of the latter is 151.8±2.6 Ma. These data indicate that they were formed during the Late Jurassic (142.8 to 151.8 Ma). Zoned magma chamber was formed because of double diffusive convection. Therefore, the intrusive sequence of magma is generally from quartz monzonite through quartz monzodiorite to pyroxene monzodiorite, i.e. an inverted sequence.展开更多
The Tongling ore cluster area experienced intensive compression and associated shearing during the Indosinian-Yanshanian Epoch, which formed a trunk ore-controlling fold and fault system in the caprock. The magmatic i...The Tongling ore cluster area experienced intensive compression and associated shearing during the Indosinian-Yanshanian Epoch, which formed a trunk ore-controlling fold and fault system in the caprock. The magmatic intrusion in the Yanshanian Epoch induced a multi-stage unmixing of poly-phase fluids, resulting in mineralization characterized by multi-layer, wide-range, and multiform styles. The magmatic intrusion in the Tongling area not only supplied the essential ore-forming materials, but also reconstructed the ore-controlling structures according to a trend surface simulation of the following five strata boundaries: Silurian-Devonian, Devonian-Carboniferous, Carboniferous- Permian, Middle Permian-Upper Permian and Permian -Triassic. The result of this simulation shows that there exists a significant difference between the strata in the upper part and those in the lower. The lower trend surfaces are antiform whereas the upper trend surfaces are synform. In addition, superposing of the trend surfaces of adjacent bed boundaries (such as, Silurian-Devonian boundary superposed upon Devonian-Carboniferous boundary) shows that the lower trend surface always pierces the one above. Moreover, the position and orientation of the pierced parts of the different superposed trend surfaces are similar and show E-W-trending zonal distribution in accordance with the distribution of the regional E-W-trending magmatic-metallogenic belt. Based on comprehensive analysis of the mechanical properties of the strata, structural deformation mechanisms, and field phenomena, it seems that the special characteristics of the stratal trend surface resulted from jacking due to magmatic intrusion into the caprock previously controlled by an E-W-trending basement fault. Therefore, it is deduced that the major ore-controlling structures, which formed during regional horizontal compression, were reconstructed by the vertical jacking function of ore-forming magmas during the Yanshanian Epoch. During the ore-forming process, the local vertical jacking of magmas, coupled with the regional horizontal compression, optimized an extensive environment in the fluid- conduit network and accelerated the unmixing of poly-phase fluids following magmatic emplacement. Jacking also strengthened the vertical and lateral fluid-guiding structures, supplying more suitable physical conditions for multi-layer emplacement and wide-ranging transport of poly-phase fluids.展开更多
A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Pr...A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa (width of the multifractal spectrum) of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R (spectrum symmetry parameter) and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.展开更多
Lithological observations and mineralogical analyses on pyroxene and hornblende megacrysts and pyroxene and hornblende cumulates in xenoliths in the Mesozoic plutons of the Tongling region, Anhui Province, provide evi...Lithological observations and mineralogical analyses on pyroxene and hornblende megacrysts and pyroxene and hornblende cumulates in xenoliths in the Mesozoic plutons of the Tongling region, Anhui Province, provide evidence for the magmatic underplating of mantle-derived alkali-olivine basalt at circa 140 Ma. The pyroxene and hornblende megacrysts and cumulates were formed through the AFC process at depths ranging from 27 to 35 km.展开更多
The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (L...The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.展开更多
The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, t...The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication (S1), fracture-controlled quartz-sericite-pyrite alteration (S2-3), and upper-level sub-discordant quartz-sericite-chlorite alteration (D3), were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock (S1) and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include (1) anhydrite-barite, (2) jasper-chert, (3) Mg-rich mudstone-pyrite shale, (4) barite lens, (5) siderite-Fe-bearing dolomite, and (6) Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones (minerals) and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.展开更多
The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurre...The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.展开更多
Based on investigation of the characteristics of solid waste of two different mines, the Fenghuangshan copper mine and the Xinqiao pyrite mine in Tongling, Anhui province in central-east China, the possibility and the...Based on investigation of the characteristics of solid waste of two different mines, the Fenghuangshan copper mine and the Xinqiao pyrite mine in Tongling, Anhui province in central-east China, the possibility and the differences of acid mine drainage (AMD) of the railings and the waste rocks are discussed, and the modes of occurrence of heavy metal elements in the mine solid waste are also studied. The Fenghuangshan copper mine hardly produces AMD, whereas the Xinqiao pyrite mine does and there are also differences in the modes of occurrence of heavy metal elements in the railings. For the former, toxic heavy metals such as Cu, Pb, Zn, Cd, As and Hg exist mostly in the slag mode, as compared to the latter, where the deoxidization mode has a much higher content, indicating that large amounts minerals in the waste rocks have begun to oxidize at the earth surface. AMD is proved to promote the migration and spread of the heavy metals in mining waste rocks and lead to environmental pollution of the surroundings of the mine area.展开更多
REE geochemical characteristics of the magmatic rocks and gold deposits in Shizishan ore-field of Tongling were studied. Three types of the magmatic rocks have almost the same chondrite-normalized REE patterns, Eu and...REE geochemical characteristics of the magmatic rocks and gold deposits in Shizishan ore-field of Tongling were studied. Three types of the magmatic rocks have almost the same chondrite-normalized REE patterns, Eu and Ce anomalous values, and ∑REE, ∑LREE/∑HREE regular changes, which indicates that their magmas come from the same source and their digenetic mechanism is fractional crystallization. In three gold deposits, the mineral ores and related altered rocks have similar chondrite-normalized REE patterns and sharp Eu positive anomalous values. The REE contents reduced from the magmatic rocks to skamization or alteration magmatic rocks, skam type ores, sulphide type ores, wall-rocks limestone or marble. The REE geochemical characteristics of the ores and related rocks show that primary fluids originated from magmatic differentiation in lower pressure of shallow crust, ore-forming hydrothermal solutions gained REE and mineralization elements further from leaching the magmatic rocks, then superimposed and reformed the limestones or marbles and deposited ore-forming material.展开更多
The Fenghuangshan Pluton is located in the Tongling polymineral-cluster district in the middle-lower section of the Yangtze metallogenic belt. In tectonic terms, it is in the middle of the Guichi-Fanchang faulted fold...The Fenghuangshan Pluton is located in the Tongling polymineral-cluster district in the middle-lower section of the Yangtze metallogenic belt. In tectonic terms, it is in the middle of the Guichi-Fanchang faulted fold bundle of the lower Yangtze Platform fold belt between the Dabie Orogenic Belt and the Jiangnan Massif. Analyses of the structural deformation characteristics of both the contact zone and the interior of the pluton are used to explain its emplacement mechanism. The foliation and lineation of the pluton, consisting of the oriented distribution of dark minerals and xenoliths, mainly concentrate along the margin of the pluton. Toward the center of the pluton, the foliation structure becomes weak, showing intense compression formation at the margin, and reflecting the conformable intrusion of the pluton. The relatively gentle lineation is evidence of a rotatory emplacement mechanism. Relatively steep marginal foliation reflects compression expanding. Affected by the thermal power of the pluton, the metamorphism of the contact zone has zonation. Both the strike of the axial plane of fold at the contact zone and that of the flow cleavage of the ductile shear zone are consistent with the boundary of the pluton, which reflects the speciality of conformable intrusion. The hinges of the folds are mostly inclined and erect, reflecting both the rotation of the pluton and its upward spiraling emplacement mechanism. Boudins developed in both the contact zone and the steep strata indicate the emplacement characteristic of the ballon expanding. The surrounding rock of the contact zone shortens horizontally. The average percentage of shortening is 39.7%, which further proves the mechanism of the pluton expanding, and the space occupied by the active expanding intrusion was provided by the shortening of the surrounding rock. The left-lateral shear shown by the ductile shear zone and the rheomorphic fold reveals that the pluton emplacement and the deformation of surrounding rock are controlled by a NNE-striking left-lateral shear stress field. These characteristics of pluton structures provide a mechanism of emplacement. In the deep, the pluton apirally rose left lateral, and in the shallow, the one forcefully emplaced balloningly.展开更多
Numerical simulation of fluid migration during the ore-forming process of the Carboniferous exhalation- sedimentary (Sedex) massive sulfide deposits in the Tongling district shows that fluid and thermal activities in ...Numerical simulation of fluid migration during the ore-forming process of the Carboniferous exhalation- sedimentary (Sedex) massive sulfide deposits in the Tongling district shows that fluid and thermal activities in lying-wall rocks were limited to a small area around the main draining passage, which led to weak mineralization and alteration in the lying-wall rock. Temperature and fluid fields indicate that mineralization and alteration in the lying-wall rock of the Sedex-type deposits are usually weaker than those of volcano-hosted massive sulfide deposits. Fluid migration involves the following processes: seawater penetrating and leaching the lying-wall rocks, then mixing with ascending hydrothermal fluids in the main draining passage, and finally jetting into seafloor. Although fluid activity-influenced area is rather small, the content of metals leached out from the lying-wall rocks is high enough to form large-scale ore deposits. Tensional contemporaneous faults accompanied with strong heat flows controlled the formation and distribution of Sedex deposits. The tensional tectonic regime on the northern margin of the Yangtze block during the Hercynian provided Sedex deposits with a prerequisite geodynamic condition.展开更多
A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongli...A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion展开更多
The Yaojialing deposit is the first large-scale Zn-Au-Cu polymetallic skarn deposit located in the Shatanjiao ore field of the Tongling area in the Middle-Lower Yangtze belt.It has distinct metallogenic characteristic...The Yaojialing deposit is the first large-scale Zn-Au-Cu polymetallic skarn deposit located in the Shatanjiao ore field of the Tongling area in the Middle-Lower Yangtze belt.It has distinct metallogenic characteristics and is clearly different from the known skarn Cu-Au deposits in the Tongling area and the Middle-Lower Yangtze belt.Previous studies of the Yaojialing deposit have included rock geochemistry,alteration and mineralization characteristics,as well as metallogenesis and metallogenic models.However,there are still numerous problems concerning the coexistence of multiple elements,metallogenetic specialization of the magma and the metallogenic model.In this study,using the latest production exploration work on the deposit,we investigated the Yaojialing deposit including its geological characteristics,petrography,LA-ICP MS zircon U-Pb dating and whole rock geochemistry.Two kinds of magmatic rocks have been distinguished for the first time in the deposit,amongst which the granodiorite porphyry exposed on the surface of the mining area,which is the host rock of the veined lead-zinc ore body,is the wall-rock intrusion;and the deep concealed quartz monzonite porphyry is the causative intrusion,the distribution of orebodies and wall-rock alteration characteristics showing regular zoning around the quartz monzonite porphyry.The^(206)Pb/^(238)U weighted average age of the granodiorite porphyry is 140.2±1.0 Ma(MSWD=0.85,n=13)by LA-ICP MS zircon U-Pb dating,while the quartz monzonite porphyry is 138.9±1.2 Ma(MSWD=0.60,n=16),which is consistent with petrographic evidence.The geochemical characteristics show that the quartz monzonite porphyry is a high-K calc-alkaline series peraluminous rock.The trace element characteristics show that the quartz monzonite porphyry is enriched in LILE such as K,Rb,Sr,Ba and LREE,yet depleted in HFSE such as Nb,Ta,P and Ti.The Yaojialing deposit shows the mineralization characteristics of proximal skarn and distal skarn,having the common characteristics of'multi-storey'and'Trinity'metallogenic models.展开更多
Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts,bel...Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts,belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts. Such pyrrhotite-chalcopyrite-bearing amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.展开更多
The Xinqiao deposit is one of several polymetallic deposits in the Tongling ore district. There are two types of mineralization in the Xinqiao: skarn-type and stratiform-type. The skarn-type mineralization is charact...The Xinqiao deposit is one of several polymetallic deposits in the Tongling ore district. There are two types of mineralization in the Xinqiao: skarn-type and stratiform-type. The skarn-type mineralization is characterized by iron oxides such as magnetite and hematite, whereas stratiform-type mineralization is characterized by massive sulfides with small amounts of magnetite and hematite. We defined three types of ores within the strati- form-type mineralization by the mineral assemblages and ore structures. Type Ⅰ ore is represented by magnetite crosscut by minor calcite veins. Type Ⅱ is a network ore composed of magnetite and crosscutting pyrite. Type Ⅲ is a massive ore containing calcite and hematite. Type Ⅰ magnetite is characterized by highly variable trace element content, whereas Type Ⅱ magnetite has consistently higher Si, Ti, V, and Nb. Type Ⅲ magnetite contains more In, Sn, and As than the other two types. Fluid-rock interaction, oxygen fugacity (fO2), and temperature (T) are the main factors controlling element variation between the different magnetite types. Type I magnetite was formed by more extensive fluid-rock interaction than the other two types at moderate fO2 and T conditions. Type Ⅱ magnetite is thought to have formed in relatively low fO2 and high-Tenvironments, and Type Ⅲ in relatively high fOe and moderate-T environments. Ca + Al + Mn and Ti + V discrimination diagrams show that magnetite in the Xin qiao deposit is hydrothermal in origin and is possibly linked with skarn.展开更多
Pb isotope ratios and their variation have been measured and explained on ores of massive S-Fe-Au depos-its hosted in the Middle-Upper Carboniferous, on feldspars from diorite bodies closely related tomineralization a...Pb isotope ratios and their variation have been measured and explained on ores of massive S-Fe-Au depos-its hosted in the Middle-Upper Carboniferous, on feldspars from diorite bodies closely related tomineralization and on whole rocks from ore-hosting strata (carbonate rocks) in the Tongling area, Anhui Prov-ince. Through a comparison of Pb isotope features of these geological bodies, it has been suggested that oresubstances of the deposits were derived from ore-hosting strata. In the meanwhile, the measurement of ore Pbisotopes of different mineralization types of the same deposit indicates that different mineralization types havedistinct Pb isotope characteristics, showing the potentiality of the Pb isotopic method used in mineral explora-tion.展开更多
This paper discusses the strategy for successfully predicting the location of potential hidden ore bodies in aged ore field, and presents the result of location prediction of hidden ore bodies in Fenghuangshan ore fie...This paper discusses the strategy for successfully predicting the location of potential hidden ore bodies in aged ore field, and presents the result of location prediction of hidden ore bodies in Fenghuangshan ore field, Tongling. Innovative conceptual targeting procedures based on a genetic understanding of mineralization systems, carefully geological investigation and correct deduction, together with new geochemical and geophysical technology and integrating of comprehensive information are all very important for the successful prediction. In the aged Fenghuangshan ore field, through researching by application of the metallogenic theory of polygenetic compound ore deposits and triple frequency induced polarization method and exploration tectono geochemical method, we predicted location and quality of hidden ore bodies. According to the prediction, hidden high quality Cu Au ore bodies of skarn type and porphyry type have been discovered.展开更多
Based on the geological conditions and characteristics of mineralization present,three-dimensional geological modelling is used in conjunction with previous deep research results,in order to discuss the process of dee...Based on the geological conditions and characteristics of mineralization present,three-dimensional geological modelling is used in conjunction with previous deep research results,in order to discuss the process of deep mineralization in the Tongling ore district.The structural analysis shows that surface deformation is strong,deep deformation is weak,the surface has mainly experienced brittle deformation,with the possibility of a large number of deep ductile deformations.There is a thrust nappe between the Tongling uplift and the Nanling basin,that is the boundary of the Tongling block,which has resulted in the southwest uplift of the Tongling block.Combined with the deep exploration data,the threedimensional shape of the main rock masses is interpreted,with three-layer structures in the deep magma chamber.The spatial distribution of magmatic rocks is mainly controlled by the structure.The movement of magmatic hydrothermal fluid is dominated by mesoscale seepage in the deep part and'dike'type upwelling in the shallow part.There is a certain coupling relationship between the ore-forming rock mass and the surrounding rock.The ore-forming age is dominated by the Yanshanian period.Based on the distribution,types and metallogenic characteristics of the deposits,the metallogenic model of'layer coupling'in the Tongling ore district is summarized,with the'one body,two belts and a multilayer metallogenic system'is established,which is significant for the future direction of deep prospecting in the Tongling area.展开更多
According to Anhui Statistical Yearbook( 2003-2012) and the second national land survey data,this article analyzes the current situation of land use and the dynamic change in the total arable land in Tongling City. On...According to Anhui Statistical Yearbook( 2003-2012) and the second national land survey data,this article analyzes the current situation of land use and the dynamic change in the total arable land in Tongling City. On the basis of this,using grey relational analysis,this article analyzes the driving forces for arable land changes in Tongling City. Studies show that population growth,the improvement of level of urbanization and the rapid development of the economy are the main driving forces for arable land changes. Based on the findings,the strategies are put forth in order to ensure the dynamic balance of total arable land.展开更多
文摘Abstract: Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagioclase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10?6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and Ni, poor in Ba, Nb and Sr. All kinds of magmatogenic enclaves have the same REE pattern without Eu anomaly, and the total REE is 74.9×10?6 for spinel pyroxene cumulate, 179.7×10?6 for hornblende cumulate, 226.9 × 10?6 for hornblende cumulate crystal, 289.9×10?6 for micrograined dioritic mixtite and 131.2×10?6 for chilled border enclaves. Calculation with the thermometer and barometer for minerals shows that the temperature and pressure of formation are 1126 °C and 8.44 kbar (7.15–9.04 kbar) for the spinel pyroxene cumulate, 1065 °C-1029 °C and 8.23 kbar (7.13–9.50 kbar) for the hornblende pyroxene cumulate, 959 °C and 3.40 kbar (2.86–4.09 kbar) for the micrograined dioritic mixtite enclaves, and 951 °C and 0.59 kbar for the dioritic chilled border enclaves, respectively. Thus, the following conclusions can be drawn. Relic enclaves were derived from the crustal partial melting and all cumulate enclaves originated from deep magma chambers near the Moho in the lower crust, which are cumulate fragments formed by fractional crystallization of basic magma; mixtite came from shallow magma chambers in the middle-upper crust, formed by the mixture of mantle-derived magma and acid magma derived from the crustal partial melting; and the chilled border enclaves came from the border fragments of early intrusive bodies.
文摘This paper determines the crystallization ages of the Xiaotongguanshan quartz monzodiorite and Shatanjiao quartz monzonitc porphyry from the Tongling area using the SHRIMP zircon U-Pb method. The crystallization age of the former is 142.8±1.8 Ma; that of the latter is 151.8±2.6 Ma. These data indicate that they were formed during the Late Jurassic (142.8 to 151.8 Ma). Zoned magma chamber was formed because of double diffusive convection. Therefore, the intrusive sequence of magma is generally from quartz monzonite through quartz monzodiorite to pyroxene monzodiorite, i.e. an inverted sequence.
基金the Fostering Plan Fund for Beyond-Century Excellent Talent of the Ministry of Education the Science and Technology Key Item of the Ministry of Education (No. 03178)+4 种基金 the National Natural Science Foundation of China (No. 40234051) the 0pen Foundation of the State Key Laboratory of Geological Processes and Mineral Resources (GPMR0528) the China Postdoctoral Science Foundation (2005038361) the Special Plans of Science and Technology of the Land Resources Department (No. 20010103) the 111 Project (No. B07011).
文摘The Tongling ore cluster area experienced intensive compression and associated shearing during the Indosinian-Yanshanian Epoch, which formed a trunk ore-controlling fold and fault system in the caprock. The magmatic intrusion in the Yanshanian Epoch induced a multi-stage unmixing of poly-phase fluids, resulting in mineralization characterized by multi-layer, wide-range, and multiform styles. The magmatic intrusion in the Tongling area not only supplied the essential ore-forming materials, but also reconstructed the ore-controlling structures according to a trend surface simulation of the following five strata boundaries: Silurian-Devonian, Devonian-Carboniferous, Carboniferous- Permian, Middle Permian-Upper Permian and Permian -Triassic. The result of this simulation shows that there exists a significant difference between the strata in the upper part and those in the lower. The lower trend surfaces are antiform whereas the upper trend surfaces are synform. In addition, superposing of the trend surfaces of adjacent bed boundaries (such as, Silurian-Devonian boundary superposed upon Devonian-Carboniferous boundary) shows that the lower trend surface always pierces the one above. Moreover, the position and orientation of the pierced parts of the different superposed trend surfaces are similar and show E-W-trending zonal distribution in accordance with the distribution of the regional E-W-trending magmatic-metallogenic belt. Based on comprehensive analysis of the mechanical properties of the strata, structural deformation mechanisms, and field phenomena, it seems that the special characteristics of the stratal trend surface resulted from jacking due to magmatic intrusion into the caprock previously controlled by an E-W-trending basement fault. Therefore, it is deduced that the major ore-controlling structures, which formed during regional horizontal compression, were reconstructed by the vertical jacking function of ore-forming magmas during the Yanshanian Epoch. During the ore-forming process, the local vertical jacking of magmas, coupled with the regional horizontal compression, optimized an extensive environment in the fluid- conduit network and accelerated the unmixing of poly-phase fluids following magmatic emplacement. Jacking also strengthened the vertical and lateral fluid-guiding structures, supplying more suitable physical conditions for multi-layer emplacement and wide-ranging transport of poly-phase fluids.
文摘A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa (width of the multifractal spectrum) of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R (spectrum symmetry parameter) and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.
基金the NationalNatural Science Foundation of China(Grants 40272034, 40133020)the Ministry of Science and Technology of China(Grant 1999043206) the Korea Science and Engineering Foundation(Grant KOSEF-20005-131-03-02).
文摘Lithological observations and mineralogical analyses on pyroxene and hornblende megacrysts and pyroxene and hornblende cumulates in xenoliths in the Mesozoic plutons of the Tongling region, Anhui Province, provide evidence for the magmatic underplating of mantle-derived alkali-olivine basalt at circa 140 Ma. The pyroxene and hornblende megacrysts and cumulates were formed through the AFC process at depths ranging from 27 to 35 km.
基金supported by the DREAM project of MOST China (No.2016YFC0600404)the Natural Science Foundation of China (Grant Nos.41372087, 41673040)the Project of Geological Science and Technology of Anhui Province (2015-K-01)
文摘The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.
文摘The Tongling area is one of the 7 ore-cluster areas in the Middle-Lower Yangtze metallogenic belt, East China, and has tectonically undergone a long-term geologic history from the late Paleozoic continental rifting, through the Middle Triassic continent-continent collision to the Jurassic-Cretaceous intracontinental tectono-magmatic activation. The Carboniferous sedimentary-exhalative processes in the area produced widespread massive sulfides with ages of 303-321 Ma, which partly formed massive pyrite-Cu deposits, but mostly provided significant sulfur and metals to the skarn Cu mineralization associated with the Yanshanian felsic intrusions.To understand the Carboniferous submarine hydrothermal system, an area of about 1046 km^2 was chosen to carry out the geological fluid mapping. Associated with massive sulfide formation, footwall sequences 948 m to 1146 m thick, composed of the Lower Silurian-Upper Devonian sandstone, siltstone and thin-layered shale, were widely altered. This hydrothermal alteration is interpreted to reflect largescale hydrothermal fluid flow associated with the late Paleozoic crustal rifting and subsidence. Three hydrothermal alteration types, i.e., deep-level semiconformable siliclfication (S1), fracture-controlled quartz-sericite-pyrite alteration (S2-3), and upper-level sub-discordant quartz-sericite-chlorite alteration (D3), were developed to form distinct zones in the mapped area. About 50-m thick semiconformable silicification zones are located at -1-km depth below massive sulfides and developed between an impermeable shale caprock (S1) and the underlying Ordovician unaltered limestone. Comparisons with modern geothermal systems suggest that the alteration zones record a sub-seafioor aquifer with the most productive hydrothermal fluid flow. Fracture-controlled quartz-sericite-pyrite alteration formed transgressive zones, which downward crosscut the semiconformable alteration zones, and upwards grade into sub-discordant alteration zones that enveloped no economic stringer- stockwork zones beneath massive sulfides. This transgressive zone likely marks an upfiow path of high- flux fluids from the hydrothermal aquifer. Lateral zonation of the sub-discordant alteration zones and their relationship to overlying massive sulfide lenses suggest lateral flows and diffusive discharging of the hydrothermal fluids in a permeable sandstone sequence. Three large-sized, 14 middle-small massive sulfide deposits, and 40 massive sulfide sites have been mapped in detail. They show regional strata- bound characters and two major styles, i.e., the layered sheet plus strata-bound stringer-style and the mound-style. Associated exhalite and chemical sedimentary rock suites include (1) anhydrite-barite, (2) jasper-chert, (3) Mg-rich mudstone-pyrite shale, (4) barite lens, (5) siderite-Fe-bearing dolomite, and (6) Mn-rich shale-mudstone, which usually comprise three sulfide-exhalite cyclic units in the area.The spatial distribution of these alteration zones (minerals) and associated massive sulfdes and exhalites, and regional variation in δ^34S of hydrothermal pyrite and in δ^18O-δ^34C of hanging wall carbonates, suggest three WNW-extending domains of fluid flow, controlled by the basement faults and syn-depositional faults. Each fluid domain appears to have at least two upflow zones, with estimated even spacing of about 5-8 km in the mapped area. The repeated appearance of sulfide-sulfate or sulfide-carbonate rhythmic units in the area suggests episodically venting of fluids through the upfiow conduits by breaking the overlying seals of the hydrothermal aquifer.
基金funded by the National Natural Science Foundation of China(NSFC)(grant numbers 41472066,40972063 and 41672038)the Program of the Deep Exploration in China(SinoProb-03-05)+1 种基金the National KeyR&S Program of China(2016 YFC0600209)the Land and Resources Science and Techonolgy Foundation of Anhui Province(2016-K-03 and No.2014-K-03)
文摘The Tongling ore district is one of the most economically important ore areas in the Middle–Lower Yangtze River Metallogenic Belt, eastern China. It contains hundreds of polymetallic copper–gold deposits and occurrences. Those deposits are mainly clustered(from west to east) within the Tongguanshan, Shizishan, Xinqiao, Fenghuangshan, and Shatanjiao orefields. Until recently, the majority of these deposits were thought to be skarn-or porphyry–skarn-type deposits; however there have been recent discoveries of numerous vein-type Au, Ag, and Pb-Zn deposits that do not fall into either of these categories. This indicates that there is some uncertainty over this classification. Here, we present the results of several systematic geological studies of representative deposits in the Tongling ore district. From investigation of the ore-controlling structures, lithology of the host rock, mineral assemblages, and the characteristics of the mineralization and alteration within these deposits, three genetic types of deposits(skarn-, porphyry-, and vein-type deposits) have been identified. The spatial and temporal relationships between the orebodies and Yanshanian intrusions combined with the sources of the ore-forming fluids and metals, as well as the geodynamic setting of this ore district, indicate that all three deposit types are genetically related each other and constitute a magmatic–hydrothermal system. This study outlines a model that relates the polymetallic copper–gold porphyry-, skarn-, and vein-type deposits within the Tongling ore district. This model provides a theoretical basis to guide exploration for deep-seated and concealed porphyry-type Cu(–Mo, –Au) deposits as well as shallow vein-type Au, Ag, and Pb–Zn deposits in this area and elsewhere.
基金supported by the National Natural Science Foundation of China(Nos 40452072 and 40472026)the National Natural Science Foundation of Anhui province.
文摘Based on investigation of the characteristics of solid waste of two different mines, the Fenghuangshan copper mine and the Xinqiao pyrite mine in Tongling, Anhui province in central-east China, the possibility and the differences of acid mine drainage (AMD) of the railings and the waste rocks are discussed, and the modes of occurrence of heavy metal elements in the mine solid waste are also studied. The Fenghuangshan copper mine hardly produces AMD, whereas the Xinqiao pyrite mine does and there are also differences in the modes of occurrence of heavy metal elements in the railings. For the former, toxic heavy metals such as Cu, Pb, Zn, Cd, As and Hg exist mostly in the slag mode, as compared to the latter, where the deoxidization mode has a much higher content, indicating that large amounts minerals in the waste rocks have begun to oxidize at the earth surface. AMD is proved to promote the migration and spread of the heavy metals in mining waste rocks and lead to environmental pollution of the surroundings of the mine area.
基金Project supported bythe National Natural Science Foundation of China (40472052)
文摘REE geochemical characteristics of the magmatic rocks and gold deposits in Shizishan ore-field of Tongling were studied. Three types of the magmatic rocks have almost the same chondrite-normalized REE patterns, Eu and Ce anomalous values, and ∑REE, ∑LREE/∑HREE regular changes, which indicates that their magmas come from the same source and their digenetic mechanism is fractional crystallization. In three gold deposits, the mineral ores and related altered rocks have similar chondrite-normalized REE patterns and sharp Eu positive anomalous values. The REE contents reduced from the magmatic rocks to skamization or alteration magmatic rocks, skam type ores, sulphide type ores, wall-rocks limestone or marble. The REE geochemical characteristics of the ores and related rocks show that primary fluids originated from magmatic differentiation in lower pressure of shallow crust, ore-forming hydrothermal solutions gained REE and mineralization elements further from leaching the magmatic rocks, then superimposed and reformed the limestones or marbles and deposited ore-forming material.
基金the Major State Basic Research Program(No.G1999043206)the Project of National Natrual Science Foundation of China(No.40372050) the Project of Resources Assessment of the China Geological Survey(No.200310200064).
文摘The Fenghuangshan Pluton is located in the Tongling polymineral-cluster district in the middle-lower section of the Yangtze metallogenic belt. In tectonic terms, it is in the middle of the Guichi-Fanchang faulted fold bundle of the lower Yangtze Platform fold belt between the Dabie Orogenic Belt and the Jiangnan Massif. Analyses of the structural deformation characteristics of both the contact zone and the interior of the pluton are used to explain its emplacement mechanism. The foliation and lineation of the pluton, consisting of the oriented distribution of dark minerals and xenoliths, mainly concentrate along the margin of the pluton. Toward the center of the pluton, the foliation structure becomes weak, showing intense compression formation at the margin, and reflecting the conformable intrusion of the pluton. The relatively gentle lineation is evidence of a rotatory emplacement mechanism. Relatively steep marginal foliation reflects compression expanding. Affected by the thermal power of the pluton, the metamorphism of the contact zone has zonation. Both the strike of the axial plane of fold at the contact zone and that of the flow cleavage of the ductile shear zone are consistent with the boundary of the pluton, which reflects the speciality of conformable intrusion. The hinges of the folds are mostly inclined and erect, reflecting both the rotation of the pluton and its upward spiraling emplacement mechanism. Boudins developed in both the contact zone and the steep strata indicate the emplacement characteristic of the ballon expanding. The surrounding rock of the contact zone shortens horizontally. The average percentage of shortening is 39.7%, which further proves the mechanism of the pluton expanding, and the space occupied by the active expanding intrusion was provided by the shortening of the surrounding rock. The left-lateral shear shown by the ductile shear zone and the rheomorphic fold reveals that the pluton emplacement and the deformation of surrounding rock are controlled by a NNE-striking left-lateral shear stress field. These characteristics of pluton structures provide a mechanism of emplacement. In the deep, the pluton apirally rose left lateral, and in the shallow, the one forcefully emplaced balloningly.
基金the National NaturalScience Foundation of China(Project No.40303008 , Key Project No.40234051)the Special Research Project of the Ministry of Land and Resources of China(No.200101030) the 973 Research Project ofthe Ministry of Science and Technology of China(No.2002CB412605).
文摘Numerical simulation of fluid migration during the ore-forming process of the Carboniferous exhalation- sedimentary (Sedex) massive sulfide deposits in the Tongling district shows that fluid and thermal activities in lying-wall rocks were limited to a small area around the main draining passage, which led to weak mineralization and alteration in the lying-wall rock. Temperature and fluid fields indicate that mineralization and alteration in the lying-wall rock of the Sedex-type deposits are usually weaker than those of volcano-hosted massive sulfide deposits. Fluid migration involves the following processes: seawater penetrating and leaching the lying-wall rocks, then mixing with ascending hydrothermal fluids in the main draining passage, and finally jetting into seafloor. Although fluid activity-influenced area is rather small, the content of metals leached out from the lying-wall rocks is high enough to form large-scale ore deposits. Tensional contemporaneous faults accompanied with strong heat flows controlled the formation and distribution of Sedex deposits. The tensional tectonic regime on the northern margin of the Yangtze block during the Hercynian provided Sedex deposits with a prerequisite geodynamic condition.
基金financially supported by the Ministry of Science and Technology of China(Grant No.1999043206)the National Natural Science Foundation of China(Grant Nos.40272034 and 40133020).
文摘A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion
基金supported by the 812 Geological Teamthe Tongling Nonferrous Metals Group Holdings Co.,Ltd+1 种基金financially supported by the National Key Research and Development Program of China(2016YFC0600206)the Major Research Program of the National Natural Science Foundation of China(91962218)。
文摘The Yaojialing deposit is the first large-scale Zn-Au-Cu polymetallic skarn deposit located in the Shatanjiao ore field of the Tongling area in the Middle-Lower Yangtze belt.It has distinct metallogenic characteristics and is clearly different from the known skarn Cu-Au deposits in the Tongling area and the Middle-Lower Yangtze belt.Previous studies of the Yaojialing deposit have included rock geochemistry,alteration and mineralization characteristics,as well as metallogenesis and metallogenic models.However,there are still numerous problems concerning the coexistence of multiple elements,metallogenetic specialization of the magma and the metallogenic model.In this study,using the latest production exploration work on the deposit,we investigated the Yaojialing deposit including its geological characteristics,petrography,LA-ICP MS zircon U-Pb dating and whole rock geochemistry.Two kinds of magmatic rocks have been distinguished for the first time in the deposit,amongst which the granodiorite porphyry exposed on the surface of the mining area,which is the host rock of the veined lead-zinc ore body,is the wall-rock intrusion;and the deep concealed quartz monzonite porphyry is the causative intrusion,the distribution of orebodies and wall-rock alteration characteristics showing regular zoning around the quartz monzonite porphyry.The^(206)Pb/^(238)U weighted average age of the granodiorite porphyry is 140.2±1.0 Ma(MSWD=0.85,n=13)by LA-ICP MS zircon U-Pb dating,while the quartz monzonite porphyry is 138.9±1.2 Ma(MSWD=0.60,n=16),which is consistent with petrographic evidence.The geochemical characteristics show that the quartz monzonite porphyry is a high-K calc-alkaline series peraluminous rock.The trace element characteristics show that the quartz monzonite porphyry is enriched in LILE such as K,Rb,Sr,Ba and LREE,yet depleted in HFSE such as Nb,Ta,P and Ti.The Yaojialing deposit shows the mineralization characteristics of proximal skarn and distal skarn,having the common characteristics of'multi-storey'and'Trinity'metallogenic models.
文摘Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts,belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts. Such pyrrhotite-chalcopyrite-bearing amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.
基金supported by grants from the National Key R&D Program of China(2016YFC0600207)the Chinese 973 project(2012CB416804)+1 种基金the National Natural Science Foundation of China(41503039)the ‘‘CAS Hundred Talents’’Project to J.F.Gao(Y5CJ038000)
文摘The Xinqiao deposit is one of several polymetallic deposits in the Tongling ore district. There are two types of mineralization in the Xinqiao: skarn-type and stratiform-type. The skarn-type mineralization is characterized by iron oxides such as magnetite and hematite, whereas stratiform-type mineralization is characterized by massive sulfides with small amounts of magnetite and hematite. We defined three types of ores within the strati- form-type mineralization by the mineral assemblages and ore structures. Type Ⅰ ore is represented by magnetite crosscut by minor calcite veins. Type Ⅱ is a network ore composed of magnetite and crosscutting pyrite. Type Ⅲ is a massive ore containing calcite and hematite. Type Ⅰ magnetite is characterized by highly variable trace element content, whereas Type Ⅱ magnetite has consistently higher Si, Ti, V, and Nb. Type Ⅲ magnetite contains more In, Sn, and As than the other two types. Fluid-rock interaction, oxygen fugacity (fO2), and temperature (T) are the main factors controlling element variation between the different magnetite types. Type I magnetite was formed by more extensive fluid-rock interaction than the other two types at moderate fO2 and T conditions. Type Ⅱ magnetite is thought to have formed in relatively low fO2 and high-Tenvironments, and Type Ⅲ in relatively high fOe and moderate-T environments. Ca + Al + Mn and Ti + V discrimination diagrams show that magnetite in the Xin qiao deposit is hydrothermal in origin and is possibly linked with skarn.
文摘Pb isotope ratios and their variation have been measured and explained on ores of massive S-Fe-Au depos-its hosted in the Middle-Upper Carboniferous, on feldspars from diorite bodies closely related tomineralization and on whole rocks from ore-hosting strata (carbonate rocks) in the Tongling area, Anhui Prov-ince. Through a comparison of Pb isotope features of these geological bodies, it has been suggested that oresubstances of the deposits were derived from ore-hosting strata. In the meanwhile, the measurement of ore Pbisotopes of different mineralization types of the same deposit indicates that different mineralization types havedistinct Pb isotope characteristics, showing the potentiality of the Pb isotopic method used in mineral explora-tion.
基金Doctoral Foundation and University Key Teacher Foundation of Ministry of Education andby Tongling Group Corporation of Nonferrous Metals
文摘This paper discusses the strategy for successfully predicting the location of potential hidden ore bodies in aged ore field, and presents the result of location prediction of hidden ore bodies in Fenghuangshan ore field, Tongling. Innovative conceptual targeting procedures based on a genetic understanding of mineralization systems, carefully geological investigation and correct deduction, together with new geochemical and geophysical technology and integrating of comprehensive information are all very important for the successful prediction. In the aged Fenghuangshan ore field, through researching by application of the metallogenic theory of polygenetic compound ore deposits and triple frequency induced polarization method and exploration tectono geochemical method, we predicted location and quality of hidden ore bodies. According to the prediction, hidden high quality Cu Au ore bodies of skarn type and porphyry type have been discovered.
基金funded by the Key R&D Program of the Anhui Province(201904a07020077)the Project of Geological Science and Technology of Anhui Province(2020-K-13)。
文摘Based on the geological conditions and characteristics of mineralization present,three-dimensional geological modelling is used in conjunction with previous deep research results,in order to discuss the process of deep mineralization in the Tongling ore district.The structural analysis shows that surface deformation is strong,deep deformation is weak,the surface has mainly experienced brittle deformation,with the possibility of a large number of deep ductile deformations.There is a thrust nappe between the Tongling uplift and the Nanling basin,that is the boundary of the Tongling block,which has resulted in the southwest uplift of the Tongling block.Combined with the deep exploration data,the threedimensional shape of the main rock masses is interpreted,with three-layer structures in the deep magma chamber.The spatial distribution of magmatic rocks is mainly controlled by the structure.The movement of magmatic hydrothermal fluid is dominated by mesoscale seepage in the deep part and'dike'type upwelling in the shallow part.There is a certain coupling relationship between the ore-forming rock mass and the surrounding rock.The ore-forming age is dominated by the Yanshanian period.Based on the distribution,types and metallogenic characteristics of the deposits,the metallogenic model of'layer coupling'in the Tongling ore district is summarized,with the'one body,two belts and a multilayer metallogenic system'is established,which is significant for the future direction of deep prospecting in the Tongling area.
文摘According to Anhui Statistical Yearbook( 2003-2012) and the second national land survey data,this article analyzes the current situation of land use and the dynamic change in the total arable land in Tongling City. On the basis of this,using grey relational analysis,this article analyzes the driving forces for arable land changes in Tongling City. Studies show that population growth,the improvement of level of urbanization and the rapid development of the economy are the main driving forces for arable land changes. Based on the findings,the strategies are put forth in order to ensure the dynamic balance of total arable land.