Evaluation of Total Hydrocarbons Levels and Traces Metals in Water and Sediment from Main Outfall Drain in Al-Nassiriya City/Southern Iraq

This study was conducted during Dec2011-Nov2012 on three stations located in the south sector of Main Outfall Drain (MOD) River. Station 1 was near Al-Holandee Bridge which was the general carriage way in the center of Al-Nassiriya city, station 2 was 20 km far from the first station, while station 3 was in the beginning of the new branch. This study reveals the Seasonal Variation of Total petroleum hydrocarbons (TPHs) in both surface waters, sediment and it is related with trace metals nickel and vanadium in water (dissolved, particulate) and sediment (residual and exchangeable) phases. Also, the study shows the relationships between the concentration of Ni and V with Total Organic Carbon (TOC%) in the sediment.

Comparison on Determination Results of Methane and Total Hydrocarbons by Glass Syringe Method and Air Bag Method

Samples at different setting time were determined by glass syringe method and air bag method, and their results were analyzed. The results showed that concentrations of methane and total hydrocarbons obviously declined with the prolonging of setting time by glass syringe method, and recovery rate of sample declined to 60% after 8 h. In air bag method, analysis results of methane and total hydrocarbons were stabler, and recovery rate of sample was 93% after 8 h.

Laboratory Design Criteria for Monitoring Biostimulated Bioremediation of a Crude Oil Contaminated Soil in Niger Delta Using Total Petroleum Hydrocarbon

The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/sediment in muddy, dry soil and wetlands. Though, there have been varied environmental conditions that have hampered the success of the bioremediation process. This study has evaluated the effectiveness of a biostimulated bioremediation of crude oil-impacted soil using some design criteria—nutrient amendment (NPK fertilizer) and moisture content. Soil sample sets—A, B, C, D, E, F, and G were impacted with crude oil at a ratio of 10 g/kg and amended with varying amounts of nutrient 30, 60, and 80 g of N.P.K fertilizer. The medium for the inoculation of the nutrient was water and the volume of water applied varied from 30% to 80% saturation. The soil sample sets were harvested at an interval of 3 months for 180 days to determine the concentration of total petroleum hydrocarbon left in the soil. The analysis of the total petroleum hydrocarbon was achieved using a GC-FID with a capillary column and autosampler. Soil samples were extracted with mixed solvent dichloromethane and acetone at a 1:1 ratio. The total petroleum hydrocarbon results show that biostimulated bioremediation achieved better results in soil sample sets with low moisture content (30% water saturation) and moderate nutrient amendment. The biodegradation of the sample sets with high water saturation and a high nutrient amendment was slow with a higher amount of total hydrocarbon content at the end of the 180 days. The variability in the hydrocarbon degradation pattern of contaminated soil shows that biostimulated bioremediation achieved better results in soils with low moisture content than in soil environments with high water content (saturation). More so, nutrient overdosing of the substrate hampered the effectiveness of the remediation process.

The Impact Of Oil Spill To The Total Petroleum Hydrocarbon(Tph)Concentration In Fishes At North Coastal Of Karawang Regency,West Java Province

The coastal area is one of the areas that is quite vulnerable to the threat of pollution caused by human activities,including pollution caused by oil spills(hydrocarbons)in the sea.The incident can be caused by several factors including the explosion,leakage of petroleum pipelines on the seabed,leakage of tanks or petroleum tankers at sea and disposal of waste petroleum products into the environment.Oil spills continuously can cause environmental contamination and pollution both aquatic and terrestrial.If the petroleum hydrocarbons enter sea waters,some of them will be absorbed by aquatic organisms because the nature of the petroleum hydrocarbons is difficult to decompose in waters.The intentional and unintentional entry of hazardous and toxic substances into marine ecosystems such as petroleum hydrocarbons and chemical solvents resulting from industrial wastes has become a serious problem for human health and the environment.The purpose of this study was to determine the concentration of Total Petroleum Hydrocarbon(TPH)contained in fish in coastal waters of Karawang Regency,West Java Province.This research was conducted in September-November 2019 by taking several fish samples at Ciparage Jaya Fish Auction Place,Betok Mati and Sungai Buntu Rive with a total sample of 24 fish,and taking seawater samples in the three study sites.TPH analysis was carried out at the Integrated Chemistry Laboratory,Bogor Agricultural University.TPH values in fish at Ciparage-1,Ciparage-2,Betok Mati and Sungai Buntu stations,in general,have different mean values but are almost uniform,each at 6.82;6.82;7.45 and 5.12 mg/kg.Based on the average TPH concentration in fish,it can be said that the average TPH in fish at Betok Mati station is relatively higher compared to other stations.TPH values in all fish samples exceed the safe threshold,which is a maximum of 0.002 mg/kg.Based on the results of the Bioaccumulation factor(BAF)analysis showed that the average TPH in fish was 6.55 mg/kg and the average TPH in the waters was 11.23 mg/l,so the BAF value was 58.35 which means that the absorption rate of TPH by fish organisms against the concentration of TPH in the waters of 58.35%.The analysis shows that the value of Ecological Hazard Assessment(EHA)is 3743.33 which means that the level of influence of the hazard on ecosystems and organisms is 3743.33.This value exceeds the recommended threshold according to the European Union,which is a maximum of 0.002 mg/l.

环境空气监测用氮中甲烷气体标准物质质量评估

为了解和掌握当前环境空气非甲烷总烃监测所使用的氮中甲烷气体标准物质的质量状况,通过对全国范围内开展环境空气非甲烷总烃监测的实验室中的99家进行使用情况调查,发现共涉及35家制造商。选择其中使用占比较高的10家,另外再随机选取6家,通过匿名采购等方式获取31瓶氮中甲烷气体标准物质。经两家测试单位分别测试后,采用归一化偏差(E_(n))法和相对偏差法两种方法评价所选标准物质的量值准确性和监测适用性,同时依照相关国家计量技术规范评估其证书完整性和规范性。结果显示,两种方法的评价结果一致。16家制造商中,14家的27瓶气体标准物质定值准确,2家的4瓶气体标准物质定值不准确;9家证书相对完整、规范,其余7家普遍存在缺少标准物质唯一标识等问题,部分制造商甚至存在涉嫌冒用证书、证书中的定值浓度超出认定范围等问题。鉴于氮中甲烷气体标准物质是保障非甲烷总烃监测结果准确性、可比性和可溯源性的重要基础,且制造商数量众多,建议使用者加强标准物质质量评估工作,并审查其所附证书的规范性。

Assessing Earthworm Influence on Remediating Potentials of Soil Micro-Organisms, and Bioavailable Hydrocarbon Pollutant in the Niger Delta, Nigeria

In the Niger Delta region of Nigeria, oil explorations and exploitations abound, causing environmental pollution with serious consequences on soil ecosystem and its biodiversity. In spite of the relationship between microbes and fauna in soil ecosystem, such that both organisms can metabolize certain range of petroleum hydrocarbon substrates with the fauna influencing the remediation potentials of bacteria, yet soil fauna is still not fully considered in bioremediation. The influence of earthworm;Lumbricus terrestris on the remediating potentials of soil bacteria in petroleum hydrocarbon contaminated soils was investigated. Eighteen pots were filled with 700 g of soil each, with nine treated with mixture of 3 levels crude oil and remediated with earthworm, while the other nine had no earthworm. The total petroleum hydrocarbon (TPH), soil physical, nutrient compositions, and TPH degrading bacteria biodiversity were determined before contamination or commencement of study and thirty days after. The results showed a decrease in TPH concentration of 55.58%, 62.57% and 67.07% in 1 ml, 2 ml and 3 ml crude oil contaminated soil, respectively. Species richness and abundance of bacteria organisms increased with high relative abundance in soils remediated with earthworms, hydrocarbon utilizing bacteria increased from less than 0.1 cfu/g to 0.4 cfu/g, and total heterotrophic bacteria 1.6 cfu/g at the end of the study. Earthworms increased rate of remediation potentials of bacteria, such that within 30 days post remediation treatment, 34.14% of reduced concentration was achieved over soil samples without earthworms at 3 ml, and 25.14% at 2 ml concentration. Reduction in pH levels in remediated soils was between 6.39 to 6.17 and 6.74 to 6.72 in unremediated soils, while moisture content was 6.73% to 6.77% unremediated and 5.85% to 6.62% in earthworm remediated soils. Total organic carbon, nitrates in soils inoculated with earthworms were lower in concentration than those without earthworms. Reverse was the case with potassium, phosphate and phosphorous concentrations which were above those without earthworms. Results indicate statistically, significant difference between reduction in TPH in earthworm remediated soils and unremediated soils, pointing out that earthworm is a good candidate for facilitation of bacteria remediation-petroleum hydrocarbon contamination.

燃煤机组烟气挥发性有机物排放特征

为了解不同容量燃煤机组烟气挥发性有机物(VOCs)的排放特性和不同尾部空气污染物控制设备(APCDs)对VOCs的控制作用,在福建省国投云顶湄洲湾电力公司400 MW亚临界对冲燃烧机组和1 000 MW超超临界切圆燃烧机组进行在线法和离线法采样测试,获取烟气中甲烷、非甲烷总烃和其他VOCs的全流程浓度。结果表明,1 000 MW机组SCR前的非甲烷总烃质量浓度(24.66 mg/m^(3))低于400 MW机组(33.36 mg/m^(3))。由于1 000 MW机组负荷和炉膛温度高,且煤在切圆燃烧炉内比对冲燃烧停留时间长,故煤燃烧更彻底。两机组SCR系统均能脱除超过70%的非甲烷总烃,400 MW和1 000 MW机组的SCR脱除效果分别为88.43%和74.32%。而在静电除尘过程(ESP)中,高压静电场可能会导致飞灰释放部分VOCs,增加烟气VOCs浓度。经所有APCDs后,400 MW机组和1 000 MW机组的VOCs排放质量浓度分别为8.40和8.47 mg/m^(3),整体脱除率为73.98%和63.02%,几乎未检出甲烷。离线测试结果:印尼煤燃烧后VOCs主要为正己烷、苯系物和苯甲醛。各固体样品(如煤、灰、石膏)有机物浓度分析显示,VOCs种类与机组大小无明显关联。这些发现有助于深入理解燃煤电厂对空气质量影响及优化污染控制设备设计。燃煤电厂实际运营中需依具体情况优化污染控制设备,以达到最大脱除效果,也需考虑机组大小和运行效率,有效控制VOCs排放。

沧东凹陷孔二段页岩生排烃效率及对含油性的影响

渤海湾盆地沧东凹陷孔二段页岩油资源潜力巨大,且通过水平井钻控获得了稳产工业油流。应用常规热解和分步热解技术,优化生排烃物质平衡法,提出了基于原始生烃潜力和现今残余生烃潜力的页岩生烃和排烃效率氢指数平衡计算方法,并探索成熟度以外孔二段页岩排烃效率的主控因素及其与含油性的关系。选取深度和成熟度较为接近的样品,以排除成熟度这一公认的生排烃效率指标的影响。结果表明,页岩有机质丰度和类型、微观孔隙结构和岩石类型等是控制其生排烃效率的重要因素。Ⅲ型干酪根产物以轻烃为主,排烃效率变化大且普遍高于Ⅰ型和Ⅱ型干酪根。Ⅰ型和Ⅱ型干酪根在TOC超过3%以后,排烃效率随TOC的增加而增大。墨水瓶型孔对液态烃的滞留能力强于狭缝型孔;对气态烃而言墨水瓶型孔反而是利于排烃的优势通道。纹层状页岩比薄层状页岩具有更低的排烃效率。生排烃共同控制着页岩的含油量,页岩中含油量与排烃效率整体呈负相关,但与生烃潜力、生烃效率和滞留烃率的乘积呈明显的正相关性,展示了生排烃效率计算方法的可靠性和实用性。

微型气体监测仪比对用非甲烷总烃采样装置

设计出一种微型气体监测仪比对用非甲烷总烃采样装置,并描述其具体结构和使用方法。该采样装置包括承接组件、导向组件和过滤组件。承接组件包括装配筒、承接辊,主要是对装置结构起到承接作用,外接进风管的装配筒内部设有电加热网和随动叶轮,可以对抽取的环境废气进行加热,规避温湿度的影响。导向组件包括导向环、弧形导向边、链轮传动组、传动杆和辅助辊,不仅起到定向导向作用,而且凸部的传感器能够触发驱动装置和链轮传动组,通过齿轮带动放卷辊和收卷辊的定向运动。过滤组件包括保护壳、清洁辊、控制器、齿轮组、放卷辊、收卷辊和滤网布,滤网布对从弧形采样口进入的气体进行过滤,当对应弧形采样口处的滤网布堵塞满杂质时,进而触发启动驱动装置使得放卷辊放卷滤网布,收卷辊收卷滤网布,从而更换滤网布的使用位置,避免对应弧形采样口处的滤网布产生堵塞,影响采样样品气体的质量。该采样装置整体结构简单、易操作,能够显著提高样品气体的采样质量。

非甲烷总烃分析仪专用Co_(3)O_(4)/Al_(2)O_(3)催化剂的制备及性能研究

挥发性有机化合物(volatile organic compounds,VOCs)是引发霾和光化学烟雾等环境问题的重要原因,达到一定浓度会对人类健康造成威胁。非甲烷总烃(non-methane hydrocarbon,NMHC)作为VOCs总量统计的重要指标,在一定程度上可以简单、直观地反映VOCs污染状况,因此,监控NMHC对保护环境与人类健康具有重要意义。本文中制备了层状结构、球形结构和立方体结构3种不同形貌的Co_(3)O_(4)纳米材料,将纳米材料均匀负载于活性Al_(2)O_(3)颗粒表面作为NMHC分析专用催化剂。通过XRD、FESEM、BET和XPS技术对制备的Co_(3)O_(4)催化剂进行表征;并将催化剂用于NMHC的检测,对不同形貌催化剂的催化性能进行评价。结果表明,当煅烧温度为400℃、煅烧时间为3 h,催化剂具有较高的催化活性,其中立方体结构催化剂具有最高的催化活性,能在236℃将NMHC完全降解,层状结构与球形结构催化剂分别在261℃与257℃将NMHC完全降解。升高煅烧温度有助于催化活性的提高,因为煅烧温度的升高增大了催化剂中Co_(3)O_(4)的相对结晶度与O_(ads)/O_(latt)摩尔比,使得气体转移速度加快,因而使催化剂具有更高的催化活性。催化剂经过耐水性、热失重测试与催化循环测试后仍能保持较高的催化活性。

活化过硫酸盐氧化处理某深基坑土壤高浓度石油烃污染

石油烃是土壤修复场地中重点关注的有机污染物,存在高毒性和持久性。本文以上海普陀区实际土壤修复项目中的深层、高浓度石油烃污染土的氧化修复为案例,讨论了深基坑开挖的风险、应对技术,并通过小试探究了以过硫酸钠、生石灰为代表的高级氧化体系对石油烃的修复效果,小试及中试试验证明,在1%过硫酸钠及1%生石灰的投加量条件下,石油烃污染物的去除率可达到76%。本研究明确了实际大体量石油烃土壤修复过程中的氧化剂及激活剂的有效投加量,补充现有的工程应用数据,为后续相关修复项目提供参考。

总烃、甲烷和非甲烷总烃分析仪校准方法

建立总烃、甲烷和非甲烷总烃分析仪的校准方法,评定校准结果的不确定度。根据分析仪原理和使用情况,选取仪器的示值误差、重复性、转化效率作为校准项目,通过试验和参考其他技术规范给出了参考技术指标,示值误差为±10%,重复性不大于3%,转化效率不小于95%。利用校准实例对校准方法进行验证,该校准方法切实可行,参考技术指标合理。

便携式非甲烷总烃检测仪校准方法

建立了一种便携式非甲烷总烃检测仪的校准方法。根据便携式非甲烷总烃检测仪的工作原理,提出了示值误差、重复性、漂移等校准项目,示值误差不大于±5%,定量重复性不大于2%,零点漂移不大于±2%,量程漂移不大于±3%。使用标准气体稀释装置将摩尔分数为3.0%的甲烷标准气体稀释至仪器满量程浓度的10%、40%、60%通入仪器,经过数据验证,该校准方法较为可行,可以用于便携式非甲烷总烃检测仪的校准。

挥发性有机物催化氧化催化剂的性能及工业应用

评价了中国石油石油化工研究院研发的挥发性有机物催化氧化催化剂的性能,并在某石化公司污水处理厂考察了其工业应用情况。结果表明:自研催化剂活性组分涂层脱落率仅为0.19%;在反应温度低于200℃时,自研催化剂的C_(6)H_(6)转化率为50%和90%时的反应温度分别为155,176℃,高于进口催化剂的;在反应温度为252~451℃,体积空速为9000~13000 h^(-1),催化氧化装置进口废气中非甲烷总烃(NMHC)质量浓度为27~1300 mg/m^(3),C_(6)H_(6)质量浓度为10~1000 mg/m3的条件下,在100 d长周期工业运行过程中,NMHC去除率稳定在97%以上,C_(6)H_(6)去除率稳定在99%以上。

催化氧化技术在橡胶干燥尾气治理中的应用

当前,我国的环境污染问题已经引起了全球的广泛关注。环境承载力已经达到或接近其极限,整体环境状况表现为环境质量较差、污染物排放量巨大。在石化行业中,挥发性有机物是主要的污染物,而在橡胶生产过程中,尾气的主要组分包括己烷和环己烷。本文着重介绍了贵金属催化氧化技术在橡胶尾气治理中的应用与实践,旨在为相关行业的尾气治理工作提供有价值的参考和借鉴。通过这项技术,我们期望能够有效改善环境状况,促进可持续发展。

石化污水处理场有机废气分类治理技术应用

根据不同废气源排放的废气流量与浓度的差异,将污水处理场有机废气分为5类,并采用低温柴油吸收-碱液吸收脱硫→脱硫及总烃浓度均化-催化氧化→洗涤-吸附→再生气催化氧化技术进行废气治理。废气1为中浓度VOCs(挥发性有机物)废气,密闭收集后输送至脱硫及总烃浓度均化-催化氧化段处理;废气2和废气3为高浓度VOCs废气,需经过柴油吸收-碱液吸收脱硫预处理后再与废气1一同输送至催化氧化段处理;废气4和废气5为低浓度VOCs废气,送入洗涤-吸附处理,吸附尾气达标后排放,吸附剂饱和后使用催化氧化的高温净化气进行热再生,再生产生的高浓度尾气进入脱硫及总烃浓度均化-催化氧化单元进行处理。治理后净化气中非甲烷总烃质量浓度小于15 mg/m^(3),苯、甲苯与二甲苯浓度均满足排放限值要求,H_(2)S质量浓度低于10 mg/m^(3),净化气污染物排放浓度满足环保排放标准要求。

一起特高压换流变压器油中总烃超标问题的分析和处理

某特高压换流变压器运行时油中总烃超标,最后被迫退出运行,返厂检修。利用油色谱分析、长时空载试验、局部放电试验、超声波定位、解体检查等手段,对故障原因进行分析,最终确定换流变压器总烃超标与三角形硅钢片、纠结线虚焊导致的两处过热点有关,并进行了相应处理,处理后换流变压器顺利通过了出厂试验,为类似故障的分析和处理提供了参考。

采样容器对环境空气中非甲烷总烃检测结果的影响

随着工业化和城市化的发展,环境空气污染问题日益严重。非甲烷总烃是一类重要的大气污染物,其浓度反映了空气污染的程度。因此,准确地测定非甲烷总烃的浓度对于环境保护具有重要意义。然而,采样容器的选择对非甲烷总烃的检测结果有着重要影响。本研究选取了玻璃瓶、不锈钢容器、聚合物袋、积雪采集器和活性碳管作为采样容器,对比了它们对非甲烷总烃检测结果的影响,旨在为实际工作提供参考。

全烃峰形面积计算方法在霸县凹陷岔河集油田解释评价中的应用

全烃数据是解释评价中的重要参数,由于全烃峰形形态的评价主要依靠肉眼识别,主观因素占比较大,其应用效果受到一定限制。为了实现全烃峰形形态的定量化评价,从全烃曲线基本原理出发,先通过梯形分割计算出全烃峰形的绝对面积,再通过其绝对面积与矩形面积的比值建立全烃峰形相对面积计算方法。基于全烃峰形绝对面积、相对面积与全烃最高值、甲烷相对百分含量建立解释评价图板,区分流体性质的效果良好。该方法在霸县凹陷岔河集油田进行应用验证,符合率达77.3%,可以满足生产需求,为全烃峰形形态的定量化评价提供了一种新方法。

氢火焰离子化检测器法测定非甲烷总烃的方法验证及结果分析

依据《实验室和检验机构管理评审指南》以及《环境监测分析方法标准制定技术导则》(HJ 168—2020)[1]中方法验证的相关要求,通过对方法的检出限、精密度、正确度、样品加标回率、量程漂移、零点漂移等分量开展方法验证。实验结果显示,该方法的检出限为0.15 mg/m3;回收率为100.3%~105.8%;标准偏差0.10%~1.1%;正确度0.85%~2.6%;量程漂移0.50%~0.70%;零点漂移0.021%~0.027%;各项验证参数均达到《固定污染源废气总烃、甲烷和非甲烷总烃的测定便携式气相色谱—氢火焰离子化检测器法》(HJ 1332—2013)[2]质量控制要求。